The present invention relates to the field of integrated circuit, and more particularly to multiple-time-programmable memory (MTP, also known as re-programmable memory).
Three-dimensional (3-D) multiple-time-programmable memory (3D-MTP, also known as 3-D re-programmable memory) is a monolithic semiconductor memory. It comprises a plurality of vertically stacked MTP cells. In a conventional MTP, the MTP cells are formed on a two-dimensional (2-D) plane (i.e. on a semiconductor substrate). In contrast, the MTP cells of the 3D-MTP are formed in a three-dimensional (3-D) space. The 3D-OPT has a large storage density and a low storage cost.
U.S. patent application Ser. No. 15/360,895 (Pub. No. 2017/0148851 A1) filed by Hsu on Nov. 23, 2016 discloses a 3-D vertical MTP. It comprises a plurality of horizontal address lines vertically stacked above each other, a plurality of memory holes penetrating the horizontal address lines, a re-programmable layer and a selector layer covering the sidewall of each memory hole, and a plurality of vertical address lines formed in the memory holes. The 3-D vertical MTP of Hsu uses a cross-point array. The memory cells are two-terminal devices formed at the intersections of the horizontal and vertical address lines. In order to minimize cross-talk between memory cells, each memory cell of Hsu comprises a separate selector (as will be disclosed below, selector is also referred to as diode) layer. A good-quality diode layer is generally thick. For example, a P—N thin-film diode with a good rectifying ratio is at least 100 nm thick. To form a diode layer with such a thickness in the memory hole, the diameter of the memory hole has to be large (e.g. >200 nm). This leads to a lower storage density.
In the previous patent and technical publications, selector (or, selector layer) is also referred to as diode (or, diode layer), steering element, quasi-conduction layer, or similar names. All of them belong to a broad class of diode-like devices whose resistance at the read voltage (i.e. the read resistance) is substantially lower than that when the applied voltage has a magnitude smaller than or a polarity opposite to that of the read voltage. Throughout this specification, the term “diode” is used to represent this class of devices and it is equivalent to selector, steering element, quasi-conduction layer, or similar names used in the previous patent and technical publications.
It is a principle object of the present invention to improve the storage density of the 3-D vertical MTP.
It is a further object of the present invention to minimize the size of the memory holes.
It is a further object of the present invention to simplify the manufacturing process inside the memory holes.
It is a further object of the present invention to provide a properly working 3-D vertical MTP even with a leaky memory layer.
In accordance with these and other objects of the present invention, the present invention discloses a three-dimensional vertical multiple-time-programmable memory (3D-MTPV) comprising no separate diode layer.
The present invention discloses a three-dimensional vertical multiple-time-programmable memory (3D-MTPV) comprising no separate diode layer. It comprises a plurality of vertical MTP strings disposed side-by-side on the substrate circuit. Each MTP string is vertical to the substrate and comprises a plurality of vertically stacked MTP cells. During manufacturing, multiple layers of first conductive material (i.e. first conductive layers) are formed on the substrate circuit and they are vertically stacked above one another. These first conductive layers are etched together to form horizontal address lines. After etching a plurality of memory holes through the horizontal address lines, a memory layer is deposited to cover the sidewalls of the memory holes. Then a second conductive material is deposited into the remaining space of the memory holes. The second conductive material in each memory hole forms a vertical address line. The MTP cells are two-terminal devices formed at the intersections of the horizontal and vertical address lines. Depending on the MTP array configuration, the horizontal address lines could be word lines while the vertical address lines are bit lines; alternatively, the horizontal address lines could be bit lines while the vertical address lines are word lines.
The memory layer comprises at least a non-conductive material (which could be an insulating material or a lightly-doped semiconductor material) disposed between first and second conductive materials. Different from prior art, the preferred memory layer of the present invention comprises a re-programmable layer but no separate diode layer. The re-programmable layer generally comprises an insulating material (or, a lightly-doped semiconductor material). Its resistance can be switched from low to high and vice versa. Exemplary re-programmable layers include resistive RAM (RRAM) and phase-change memory (PCM) layers.
Without a separate diode layer, the memory layer could have a large reverse leakage current. Leaky memory layer has a detrimental effect on the read operation of a cross-point array. For a conventional read configuration, the word line associated with a selected MTP cell is biased at the read voltage Vr, with other word lines biased at 0; whereas, the bit line associated with the selected MTP cell is biased at 0, with other bit lines biased at the read voltage Vr. Because many MTP cells in the cross-point array are reversely biased with a large reverse bias VR=−Vr, the conventional read configuration is a large-VR configuration. For the large-VR configuration, because the reverse leakage current is too large, the read operation is error-prone and therefore, not robust.
For the MTP array to work properly, the I-V characteristic of the memory layer needs to satisfy the following current requirement: the forward current IF through the selected MTP cell should be substantially larger than the collective reverse current IR through all unselected MTP cells on the same bit line. This can be expressed as IF>>(n−1)*IR, or, IR<<IF/(n−1), where n is the number of MTP cells on the bit line. As n typically has a large value (˜1000), IR should be significantly smaller than IF, i.e. IR<<IF/1000. When the above current requirement is met, the reverse (leakage) current IR would not interfere with the read operation.
To satisfy the above current requirement, a small-VR configuration is preferred. For the small-VR configuration, the largest value of the reverse bias VR on the MTP cells during read is substantially smaller than the smallest value of the forward bias VF on the MTP cells during read, i.e. |VR|<<VF. Because the forward voltage VF is comparable to the read voltage Vr, the value of the reverse voltage VR should be substantially smaller than the read voltage Vr, i.e. |VR|<<Vr. This is substantially smaller than the conventional large-VR configuration, where |VR|˜Vr.
To realize the small-VR configuration, the MTP array preferably comprises at least a sense amplifier, which can limit the voltage swing on the bit lines. Each sense amplifier is coupled to at least a bit line. It toggles when the voltage change on the associated bit line reaches its threshold voltage Vt. Because the sense amplifier typically has a large amplifying ratio, Vt is generally small (˜0.1V or smaller). This value is much smaller than Vr (several volts), i.e. Vt<<Vr. As a result, the bit lines have a small voltage swing during read.
In addition to sense amplifiers, a full-read mode also helps to realize the small-VR configuration. For the full-read mode, the data stored in all MTP cells on a selected word line are read out during a single read cycle. The read cycle includes two read phases: a pre-charge phase and a read-out phase. During the pre-charge phase, all address lines (including all word and all bit lines) in an MTP array are pre-charged to an initial voltage Vi. During the read-out phase, all bit lines are floating; a selected word line is charged to Vr, while all unselected word lines remain at Vi. Then the selected word line starts to charge all bit lines through the MTP cells. The sense amplifiers monitor the voltage change on the bit lines. Once the voltage change reaches Vt, the sense amplifier toggles and data is read out. After the data from all MTP cells are read, the read-out phase ends.
The small-VR configuration can satisfy the above current requirement because the I-V characteristics of the memory layer, which comprises at least a non-conductive material, have a logarithmic curve or a nearly logarithmic curve. In a worst scenario, the memory layer has no rectifying effect, i.e. it has symmetric forward I-V curve and reverse I-V curve. Since VF (several volts)>>VR (˜0.1 V or smaller), the forward current IF would be several orders of magnitude larger than the reverse current IR because of the logarithmic I-V characteristics. Apparently, if the memory layer has certain rectifying effect, i.e. the forward I-V curve is higher than the reverse I-V curve, the forward current IF would be even larger than the reverse current IR and therefore, it would be even easier to meet the above current requirement.
Accordingly, the present invention discloses a three-dimensional vertical multiple-time-programmable memory (3D-MTPV), comprising: a semiconductor substrate comprising a substrate circuit; a plurality of vertically stacked horizontal address lines above said semiconductor circuit; a plurality of memory holes through said horizontal address lines; a memory layer on the sidewalls of said memory holes and in contact with said horizontal address lines; a plurality of vertical address lines in said memory holes and in contact with said memory layer; a plurality of MTP cells at the intersections of said horizontal and vertical address lines; wherein said memory layer comprises a re-programmable layer but no separate diode layer.
It should be noted that all the drawings are schematic and not drawn to scale. Relative dimensions and proportions of parts of the device structures in the figures have been shown exaggerated or reduced in size for the sake of clarity and convenience in the drawings. The same reference symbols are generally used to refer to corresponding or similar features in the different embodiments. The symbol “/” means a relationship of “and” or “or”.
Throughout the present invention, the phrase “on the substrate” means the active elements of a circuit are formed on the surface of the substrate, although the interconnects between these active elements are formed above the substrate and do not touch the substrate; the phrase “above the substrate” means the active elements are formed above the substrate and do not touch the substrate.
Those of ordinary skills in the art will realize that the following description of the present invention is illustrative only and is not intended to be in any way limiting. Other embodiments of the invention will readily suggest themselves to such skilled persons from an examination of the within disclosure.
Referring now to
The preferred embodiment shown in this figure is an MTP array 10, which is a collection of all MTP cells sharing at least an address line. It comprises a plurality of vertically stacked horizontal address lines 8a-8h. After the memory holes 2a-2d penetrating these horizontal address lines 8a-8h are formed, the sidewalls of the memory holes 2a-2d are covered with memory layers 6a-6d. The remaining space in the memory holes 2a-2d is filled to form a plurality of vertical address lines 4a-4d.
To minimize the size of the memory holes, the memory layers 6a-6d comprises a re-programmable layer but no separate diode layer. As shown in
The memory layer 6a comprises a re-programmable layer 16a but no separate diode layer. The re-programmable layer 16a generally comprises an insulating material, or a lightly-doped semiconductor material. Its resistance can be switched from low to high and vice versa. Exemplary re-programmable layers 16a include resistive RAM (RRAM) and phase-change memory (PCM) layers. RRAM and PCM are well known to those skilled in the art. RRAM has been actively researched lately. Its examples include NiO, TiO2, SrTiO3 and others. On the other hand, PCM has been used as the re-programmable layer in the 3D-XPoint product from Intel and Micron. Its examples include Ge2Sb2Te5 (GST), AgInSbTe, GeTe—Sb2Te3 and others.
With no separate diode layer, the memory layer 6a could have a large reverse leakage current (i.e. its reverse current could be comparable to its forward current). To improve the rectifying ratio of the MTP cell 1aa, different address-line materials may be used. The following paragraphs disclose several preferred embodiments.
In a first preferred embodiment, the horizontal address lines 8a comprise a heavily-doped (e.g. P+ doped) semiconductor material, while the vertical address lines 4a comprise an oppositely-doped (e.g. N+ doped) semiconductor material. They form a built-in semiconductor diode, which can improve the rectifying ratio of the MTP cell 1aa. In a second preferred embodiment, the horizontal address lines 8a comprise a metallic material, while the vertical address lines 4a comprise a doped semiconductor material. They form a built-in Schottky diode, which can improve the rectifying ratio of the MTP cell 1aa. In a third preferred embodiment, the horizontal address lines 8a comprise a doped semiconductor material, while the vertical address lines 4a comprise a metallic material. They also form a built-in Schottky diode, which can improve the rectifying ratio of the MTP cell 1aa.
In a fourth preferred embodiment, the horizontal address line 8a comprises a first metallic material, whereas the vertical address line 4a comprises a second metallic material. To ensure a proper rectifying effect, different first and second metallic materials are used. For example, the rectifying ratio of the MTP cell is improved when the first and second metallic materials have different work functions. Alternatively, the rectifying ratio is improved when a first interface 7 between the first metallic material 8a and the memory layer 6a is different from a second interface 5 between the second metallic material 4a and the memory layer 6a.
Referring now to
A first etching step is performed through all first conductive layers 12a-12h to form a stack of horizontal address lines 8a-8h (
To satisfy the above current requirement, a small-VR configuration is preferred. For the small-VR configuration, the largest value of the reverse bias VR on the MTP cells (e.g. 1bc-1hc) during read is substantially smaller than the smallest value of the forward bias VF on the MTP cells (e.g. 1aa-1ah) during read, i.e. |VR|<<VF. Because the forward voltage VF is comparable to the read voltage Vr, the value of the reverse voltage VR should be substantially smaller than the read voltage Vr, i.e. |VR|<<Vr. This is substantially smaller than the conventional large-VR configuration, where |VR|˜Vr.
To realize the small-VR configuration, the MTP array 10 preferably comprises at least a sense amplifier 30. The sense amplifier 30 is coupled to bit lines 4a-4h through a multiplexor (mux) 40. The sense amplifier 30 toggles when the voltage change on the associated bit line 4a-4h reaches its threshold voltage Vt. Because the sense amplifier 30 has a large amplifying ratio, Vt is generally small (˜0.1V or smaller). This value is much smaller than Vr (several volts), i.e. Vt<<Vr. As a result, the bit lines 4a-4h have a small voltage swing during read.
In addition to the sense amplifier 30, a full-read mode also helps to realize the small-VR configuration. For the preferred full-read mode, the data stored in all MTP cells on a selected word line are read out during a single read cycle.
To facilitate address decoding, vertical transistors are formed in the memory holes.
While illustrative embodiments have been shown and described, it would be apparent to those skilled in the art that many more modifications than that have been mentioned above are possible without departing from the inventive concepts set forth therein. The invention, therefore, is not to be limited except in the spirit of the appended claims.
Number | Date | Country | Kind |
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201610234999.5 | Apr 2016 | CN | national |
201810046412.7 | Jan 2018 | CN | national |
201810072214.8 | Jan 2018 | CN | national |
This application is a continuation-in-part of “Three-Dimensional Vertical One-Time-Programmable Memory”, application Ser. No. 15/488,489, filed on Apr. 16, 2017, which claims priority from Chinese Patent Application 201610234999.5, filed on Apr. 16, 2016, in the State Intellectual Property Office of the People's Republic of China (CN), the disclosure of which is incorporated herein by reference in its entirety. This application also claims priority from Chinese Patent Application 201810046412.7, filed on Jan. 17, 2018; Chinese Patent Application 201810072214.8, filed on Jan. 25, 2018; in the State Intellectual Property Office of the People's Republic of China (CN), the disclosure of which are incorporated herein by references in their entireties.
Number | Date | Country | |
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Parent | 15488489 | Apr 2017 | US |
Child | 15911112 | US |