This application is based upon and claims the benefit of priority from prior Japanese Patent Application No. 2003-388076, filed Nov. 18, 2003, the entire contents of which are incorporated herein by reference.
1. Field of the Invention
The present invention relates to a semiconductor device and a method of manufacturing the same.
2. Description of the Related Art
Trench isolation has widely been used in the field of semiconductor devices. Trench isolation is utilized for isolation of a MOS (Metal Oxide Semiconductor) transistor, bipolar transistor, and the like.
One of trench isolation techniques is to cover the opening of a trench with a cap layer made of an insulator and form an airtight space in the trench. This technique is disclosed in Jpn. Pat. Appln. KOKAI Publication No. 2-119238. According to this technique, the trench is filled with gas whose relative dielectric constant is low. This technique is effective particularly in a high voltage device.
However, the present inventors have found that a cap layer formed by the prior art is readily destructed in a heat treatment such as activation annealing.
According to a first aspect of the present invention, there is provided a semiconductor device, comprising a semiconductor substrate comprising a first semiconductor layer of a first conductivity and a pair of second semiconductor layers disposed on the first semiconductor layer and spaced apart from each other, the second semiconductor layers forming a trench therebetween, wherein each of the second semiconductor layers includes a first impurity-diffused region of the first conductivity which extends from a lower surface toward an upper surface of the second semiconductor layer, and a second impurity-diffused region of a second conductivity which extends from the lower surface toward the upper surface and is adjacent to the first impurity-diffused region, an insulating layer covering a sidewall of the trench, and a cap layer which is in contact with the semiconductor substrate and covers an opening of the trench to form an enclosed space in the trench, a material of the cap layer being substantially the same as a material of the semiconductor substrate.
According to a second aspect of the present invention, there is provided a method of manufacturing a semiconductor device, comprising forming a structure which comprises a semiconductor substrate with a trench and an insulating layer covering a sidewall of the trench, wherein a surface of the semiconductor substrate comprises an uncovered portion on which the insulating layer is absent at and/or near an opening of the trench, forming a cap layer which covers the opening of the trench to form an enclosed space in the trench, forming the cap layer including epitaxially growing a material which is substantially the same as a material of the semiconductor substrate on the uncovered portion to form a single crystal layer which covers the opening of the trench, and after forming the cap layer, subjecting the structure to at least one heat treatment, the heat treatment being carried out while keeping a composition of an exposed portion of the cap layer which is exposed to the enclosed space substantially the same as a composition of the semiconductor substrate.
Embodiments of the present invention will be described below with reference to the several views of the accompanying drawing. In the following views, the same reference numerals denote components having the same or similar functions, and a repetitive description thereof will be omitted.
The semiconductor device 1 includes a semiconductor substrate 2. Trenches 2a are formed in one major surface of the semiconductor substrate 2. The trenches 2a form isolation regions, and define device regions 2b between the trenches 2a. The trenches 2a are typically very deep and have an aspect ratio of e.g., 20 or more.
A source electrode 3 is formed as a common electrode on the upper surface of the semiconductor substrate 2. A drain electrode 4 is formed as a common electrode on the lower surface of the semiconductor substrate 2. The semiconductor device 1 in
The semiconductor substrate 2 includes a first semiconductor layer 21 of the first conductivity, N+-type in this case, which is utilized as a heavily doped drain region, and a plurality of second semiconductor layers 22 spaced apart from each other on the first semiconductor layer 21. The first semiconductor layer 21 is, e.g., a silicon substrate, and the second semiconductor layer 22 is, e.g., a silicon layer formed on the first semiconductor layer 21 by epitaxial growth or the like.
The trench 2a is a recess formed between adjacent second semiconductor layers 22. The bottom surface of the trench 2a is flush with the upper surface of the first semiconductor layer 21, but may be positioned lower than the upper surface of the first semiconductor layer 21. That is, a recess communicating with the gap between the second semiconductor layers 22 may be formed in the upper surface of the first semiconductor layer 21.
Each second semiconductor layer 22 includes a first impurity-diffused region 221 of the first conductivity, N-type in this case, which extends from the lower surface toward the upper surface of the second semiconductor layer 22, and a second impurity-diffused region 222 of the second conductivity, P-type in this case, which extends from the lower surface toward the upper surface of the second semiconductor layer 22 and is adjacent to the first impurity-diffused region 221. In this example, the first impurity-diffused region 221 is positioned between the trench 2a and the second impurity-diffused region 222. The impurity-diffused regions 221 and 222 are formed by, for example, introducing impurities from the sidewall of the trench 2a into the semiconductor substrate 2, and diffusing and activating the impurities in the semiconductor substrate 2.
The second semiconductor layer 22 further includes a third impurity-diffused region 223 of the second conductivity, P+-type in this case, a source region 225 of the first conductivity, N+-type in this case, a base region 224 of the second conductivity, P-type in this case, and a channel stopper region 226. The third impurity-diffused region 223 is positioned in the surface region of the second semiconductor layer 22 above the center of the second impurity-diffused region 222, and extends in a direction perpendicular to the sheet surface. The source regions 225 are positioned in the surface region of the second semiconductor layer 22, and sandwich the third impurity-diffused region 223. The base region 224 is interposed between a layer including the third impurity-diffused region 223 and source region 225 and a layer including the first impurity-diffused region 221 and second impurity-diffused region 222, and extends in a direction perpendicular to the sheet surface. The channel stopper region 226 is positioned near the trench 2a in the surface region of the second semiconductor layer 22, and extends in a direction perpendicular to the sheet surface. The conductivity of the channel stopper region 226 is an N+-type or P+-type.
An insulating layer 5 is formed on the sidewall of the trench 2a, i.e., the side surface of the second semiconductor layer 22. The insulating layer 5 covers a portion of the side surface of the second semiconductor layer 22 which is positioned below the channel stopper region 226. The channel stopper region 226 may extend to the side portion of the insulating layer 5 owing to a thermal diffusion of impurities. In this case, the insulating layer 5 partially covers a region of the side surface of the second semiconductor layer 22 which corresponds to the channel stopper region 226.
The opening of the trench 2a is covered with a cap layer 6 to form an enclosed space in the trench 2a. The cap layer 6 is formed in contact with the semiconductor substrate 2. The material of the cap layer 6 is substantially the same as that of the semiconductor substrate 2. In this example, the cap layer 6 is a single crystal layer. When a given material is the same as another material, this means that their components are the same except impurities.
Gate insulators 7 and gate electrodes 8 are sequentially formed on a surface of the semiconductor substrate 2 in which the source regions 225 are formed. Each gate electrode 8 faces at least portions of the surface of the substrate 2 which are positioned between a pair of source regions 225 sandwiching the cap layer 6. In each device region 2b, the source electrode 3 is connected to the source regions 225. In this case, the gate electrode 8 is also formed above the cap layer 6, but may not exist above the cap layer 6.
In the first embodiment, a single crystal layer made of almost the same material as that of the semiconductor substrate 2 is formed as the cap layer 6. In the first embodiment, at least one heat treatment after forming the cap layer 6, typically all heat treatments after forming the cap layer 6 are carried out while the composition of a portion of the single crystal layer which is exposed in the space within the trench 2a is maintained at almost the same composition of the semiconductor substrate 2. This can suppress destruction of the cap layer 6 even upon heating up to about 1,100° C. in a heat treatment such as activation annealing, which will be described later. When the composition of a given component is almost the same as that of another component, this means that their compositions are the same except impurities.
The present inventors investigated why the cap layer was readily destructed in a heat treatment according to the prior art. The present inventors have found that the cause is the use of an insulator for the cap layer.
More specifically, a cap layer made of an insulator is different in thermal expansion coefficient from the semiconductor substrate 2. In a heat treatment, a high stress is applied to the cap layer of the insulator. In addition, the cap layer of the insulator must be formed in an oxidizing atmosphere such as an oxygen atmosphere. Thus, oxidizing gas such as oxygen gas is trapped in a trench sealed by the cap layer. If heating is performed in this state, gas trapped in the trench tends to expand, and a very high stress is applied to the cap layer. Such stress destructs the cap layer.
To the contrary, when the material of the cap layer 6 is almost the same as that of the semiconductor substrate 2, their thermal expansion coefficients can be set almost equal to each other. In addition, when the material of the cap layer 6 is almost the same as that of the semiconductor substrate 2, the cap layer 6 can be formed by a vacuum process such as epitaxial growth. This can prevent entrapment of gas in a trench sealed by the cap layer 6. In other words, the interior of the trench sealed by the cap layer 6 becomes a vacuum. Hence, no stress is applied to the cap layer 6 owing to the difference in thermal expansion coefficient or expansion of gas by heating, suppressing destruction of the cap layer 6 in a heat treatment.
When the material of the cap layer 6 is almost the same as that of the semiconductor substrate 2, the cap layer 6 hardly generates gas in a heat treatment, unlike a case in which an insulator is used as the material of the cap layer. From this viewpoint, it is effective for suppressing destruction of the cap layer 6 in a heat treatment to set the material of the cap layer 6 to almost the same as that of the semiconductor substrate 2.
The semiconductor device 1 can be manufactured by, e.g., the following method. The manufacturing method will be explained with reference to
According to this method, as shown in
As shown in
B is ion-implanted into the sidewall of the trench 2a and thermally diffused. Subsequently, As is ion-implanted into the sidewall of the trench 2a and thermally diffused. Accordingly, as shown in
As shown in
As shown in
As shown in
As shown in
As shown in
After that, a gate insulator 7 such as a silicon oxide layer, a gate electrode 8 such as a polysilicon layer, an insulating layer 9 such as a silicon oxide layer, and a source electrode 3 and drain electrode 4 such as Al/TiW layers are formed. A semiconductor device 1 having almost the same structure as that shown in
In this method, as described with reference to
According to this method, a structure shown in
As shown in
As shown in
As shown in
As shown in
According to this method, a structure shown in
As shown in
The resist layer 11 is etched by using, e.g., an ozone asher. As shown in
Subsequently, a hydrofluoric acid treatment or ammonium fluoride treatment is performed to etch portions of the oxide layers 5 and 51 which are exposed to the outside of the resist layer 11. For example, etching is done for 4 min with an aqueous ammonium fluoride solution. Since this etching is isotropic etching, etching of the upper and side surfaces of the oxide layer 51 and etching of a portion of the oxide layer 5 which is exposed to the outside of the resist layer 11 progress simultaneously. By stopping etching at a proper timing, a structure shown in
As shown in
According to this method, a structure shown in
The silicon oxide layers 51 and 52 are etched with a hydrofluoric acid solution. Since this etching is isotropic etching, etching of the upper and side surfaces of the oxide layer 51 and etching of the major surface of the oxide layer 52 progress simultaneously. By stopping etching at a proper timing, a structure shown in
For example, thermal oxidization is performed to form a silicon oxide layer 5 on the exposed surface of the substrate 2 and grow the oxide layer 51. Thermal oxidization is done such that the silicon oxide layer 5 has a thickness of 1,000 Å to 2,000 Å on the sidewall of the trench 2a. As a result, a structure shown in
Thereafter, the silicon oxide layers 5 and 51 are anisotropically etched. As shown in
The second embodiment of the present invention will be described.
In the first embodiment, epitaxial growth of Si occurs only near the opening of the trench 2a. In the second embodiment, epitaxial growth of Si also occurs on the upper surface of a substrate 2. A semiconductor device according to the second embodiment has almost the same structure as that of the semiconductor device according to the first embodiment except that a P+-type base region 224 and N+-type source region 225 are formed in a cap layer 6.
In this method, a structure shown in
As shown in
As shown in
As shown in
In the second embodiment, the cap layer 6 is formed not only at the opening of the trench 2a but also on the entire upper surface of the semiconductor substrate 2. For this reason, as shown in
As shown in
As described above, also in the second embodiment, similar to the first embodiment, the material of the cap layer 6 is almost the same as that of the semiconductor substrate 2, and the cap layer 6 is formed by a vacuum process. The second embodiment can suppress destruction of the cap layer 6 in a heat treatment.
The third embodiment of the present invention will be described.
In the first embodiment, portions of the oxide layer 5 and/or oxide layer 51 which are positioned at the boundary between the silicon oxide layer 51 and the sidewall of the trench 2a are removed, and Si is epitaxially grown on the exposed portions. In the third embodiment, a portion of an oxide layer 5 which is positioned on the sidewall of a trench 2a is partially removed, and Si is epitaxially grown at the exposed portion. A semiconductor device according to the third embodiment has almost the same structure as that of the semiconductor device according to the first embodiment except that an opening is formed in an insulating layer formed on the sidewall of the trench 2a.
In this method, a structure shown in
As shown in
Subsequently, the silicon oxide layer 5 and a silicon oxide layer 51 are anisotropically etched. As shown in
A silicon oxide is deposited on a surface of the substrate 2 in which the trench 2a is formed. Deposition of the silicon oxide is done under conditions in which the silicon oxide is hardly deposited at a position at which the depth from the opening of the trench 2a exceeds 2.2 μm. As shown in
The silicon oxide layers 5 and 5′ are processed with an aqueous ammonium fluoride solution. This process is performed such that, of a portion of the silicon oxide layer 5′ which is positioned on the sidewall of the trench 2a, a portion at the opening of the trench 2a remains and a portion on the silicon oxide layer 5 is removed. In this process, for example, the silicon oxide layer 5′ is removed at a position at which the depth from the opening of the trench 2a exceeds 2.2 μm, and the silicon oxide layer 5′ remains at a position at which the depth from the opening of the trench 2a is equal to or smaller than 2.2 μm. As shown in
As shown in
As shown in
As described above, in the third embodiment, similar to the first embodiment, the material of the cap layer 6 is almost the same as that of the semiconductor substrate 2, and the cap layer 6 is formed by a vacuum process. The third embodiment can suppress destruction of the cap layer 6 in a heat treatment.
In the third embodiment, various sizes may be defined as follows.
Assuming that the Si growth progresses at the same speed in the vertical and horizontal directions, the distance L3 and width W must satisfy an inequality: 2×L3>W in order to obtain the cap layer 6 covering the opening of the trench 2a.
To position the upper end of the cap layer 6 below the upper surface of the insulating layer 5′, the distances L1 to L3 satisfy an inequality: L3<L1+L2.
From this, the distances L1 and L2 and the width W may be so defined as to satisfy an inequality: W/2<L1+L2.
To position the upper end of the cap layer 6 above the upper surface of the substrate 2, the distance L1 and width W must-satisfy an inequality: L1<W/2.
To position the upper end of the cap layer 6 between the upper surfaces of the substrate 2 and insulating layer 5′, the distances L1 and L2 and the width W may be so defined as to satisfy an inequality: W/2<L1+L2<W/2+L2.
The fourth embodiment of the present invention will be described.
More specifically, the source region 225 is positioned in the surface region of a second semiconductor layer 22 above the second impurity-diffused region 222, and extends in a direction perpendicular to the sheet surface. The base region 224 is interposed between the source region 225 and the first impurity-diffused region 221 and between the source region 225 and the second impurity-diffused region 222, and extends in a direction perpendicular to the sheet surface. A channel stopper region 226 is interposed between the source region 225 and a cap layer 6 and between the base region 224 and the cap layer 6 in the surface region of the second semiconductor layer 22, and extends in a direction perpendicular to the sheet surface.
The semiconductor device 1 can be manufactured by, e.g., the following method. The manufacturing method will be explained with reference to
According to this method, a structure shown in
P is ion-implanted into the sidewall of the trench 2a and thermally diffused. Subsequently, B is ion-implanted into the sidewall of the trench 2a and thermally diffused. Accordingly, as shown in
A structure shown in
As shown in
As shown in
The silicon oxide layer 51 is removed, and a P+-type base region 224, N+-type source region 225, and channel stopper region 226 serving as a P+-type impurity-diffused region are formed in the surface region of the substrate 2. Thereafter, a gate insulator 7, gate electrode 8, insulating layer 9, source electrode 3, and drain electrode 4 are formed. A semiconductor device having almost the same structure as that shown in
As described above, in the fourth embodiment, similar to the first embodiment, the material of the cap layer 6 is almost the same as that of the semiconductor substrate 2, and the cap layer 6 is formed by a vacuum process. The fourth embodiment can suppress destruction of the cap layer 6 in a heat treatment.
In the fourth embodiment, the semiconductor device 1 may employ the following structure.
In the structure shown in
Since the upper surface of the base region 224 is partially covered with the gate insulator 7 and insulating layer 9, the contact area between the base region 224 and the source electrode 3 is not so large. When no extension region 227 is formed, it may be difficult to achieve a reliable connection between the base region 224 and the source electrode 3.
To the contrary, if the extension region 227 is formed, the base region 224 and source electrode 3 can be connected through the extension region 227. Since most of the upper surface of the extension region 227 is exposed to the outside of the gate insulator 7 and insulating layer 9, the contact area between the extension region 227 and the source electrode 3 can be enlarged. Hence, formation of the extension region 227 can easily achieve a reliable connection between the base region 224 and the source electrode 3.
The fifth embodiment of the present invention will be described.
A semiconductor device according to the fifth embodiment has almost the same structure as that of the semiconductor device 1 according to the fourth embodiment except that a cap layer 6 and base region 224 form one impurity-diffused region.
The semiconductor device according to the fifth embodiment can be manufactured by, e.g., the following method.
In this method, a structure shown in
As described above, in the fifth embodiment, similar to the first embodiment, the material of the cap layer 6 is almost the same as that of the semiconductor substrate 2, and the cap layer 6 is formed by a vacuum process. The fifth embodiment can suppress destruction of the cap layer 6 in a heat treatment.
The sixth embodiment of the present invention will be described.
In the fourth embodiment, epitaxial growth of Si occurs only near the opening of the trench 2a. In the sixth embodiment, epitaxial growth of Si also occurs on the upper surface of a substrate 2. A semiconductor device according to the sixth embodiment has almost the same structure as that of the semiconductor device according to the fourth embodiment except that a P+-type base region 224, N+-type source region 225, and the like are formed in a cap layer 6.
In this method, a structure shown in
The exposed surface of a substrate 2 is oxidized to form a silicon oxide layer 5. A silicon oxide layer 51 is then removed to obtain a structure shown in
As shown in
As shown in
As shown in
As described above, in the sixth embodiment, similar to the first embodiment, the material of the cap layer 6 is almost the same as that of the semiconductor substrate 2, and the cap layer 6 is formed by a vacuum process. The sixth embodiment can suppress destruction of the cap layer 6 in a heat treatment.
The seventh embodiment of the present invention will be described.
In the first to sixth embodiments, the cap layer 6 has a single-layered structure. In contrast, the seventh embodiment forms a cap layer 6 of a multilayered structure. A semiconductor device according to the seventh embodiment has almost the same structure as that of the semiconductor device 1 according to the first embodiment except that the multilayered structure is employed for the cap layer 6.
In this method, a structure shown in
Si is epitaxially grown on a surface of a substrate 2 which is exposed to the outside of insulating layers 5 and 51. As shown in
As shown in
As shown in
As shown in
As shown in
In the case where the single crystal layer 6a is formed thin as shown in
To the contrary, in the seventh embodiment, the polycrystalline layer 6b is formed by LP-CVD on the single crystal layer 6a, which is formed by selective epitaxial growth, and the single crystal layer 6a and polycrystalline layer 6b form the cap layer 6. LP-CVD cannot be carried out with a very high film formation rate, but can simultaneously process many, e.g., 100 substrates. The seventh embodiment can therefore achieve higher productivity in addition to the same effects as those described in the first embodiment.
In the seventh embodiment, CMP described with reference to
In the seventh embodiment, a part of the insulating layer 51 utilized for selective growth of Si is used as a gate insulator. A portion of the insulating layer 51 which is used as a gate insulator is not exposed to the outside after formation of the cap layer 6. In other words, a portion of the silicon oxide layer 51 which is used as a gate insulator is not damaged by CMP or the like. Hence, a reliable MOSFET can be obtained.
In the seventh embodiment, the polycrystalline layer 6b is formed by LP-CVD on the single crystal layer 6a which is formed by selective epitaxial growth. Alternatively, Si may be grown by nonselective epitaxial growth on the single crystal layer 6a which is formed by selective epitaxial growth. Nonselective epitaxial growth can achieve a very high deposition rate, compared to selective epitaxial growth. For example, the deposition rate is about 0.1 μm/min to 0.2 μm/min in selective epitaxial growth and 1.0 μm/min to 2.0 μm/min in nonselective epitaxial growth. Also in this case, the seventh embodiment can achieve higher productivity than that in the first embodiment, in addition to the same effects as those described in the first embodiment.
When Si is grown by nonselective epitaxial growth in the process described with reference to
The eighth embodiment of the present invention will be described.
In the eighth embodiment, the positions of a first impurity-diffused region 221 and second impurity-diffused region 222 are counterchanged from those in the semiconductor device 1 according to the seventh embodiment. In accordance with the difference in layout, the eighth embodiment changes the layout of a base region 224, source region 225, gate insulator 7, gate electrode 8, and the like from that in the semiconductor device 1 according to the seventh embodiment. The eighth embodiment is almost the same as the seventh embodiment except the layout.
According to this method, the process described in the fourth embodiment with reference to
As shown in
As shown in
As shown in
Also in the eighth embodiment, similar to the seventh embodiment, the polycrystalline layer 6b is formed by LP-CVD or nonselective epitaxial growth on the single crystal layer 6a, which is formed by selective epitaxial growth, and the single crystal layer 6a and polycrystalline layer 6b form the cap layer 6. Hence, the eighth embodiment can achieve the same effects as those described in the seventh embodiment.
The ninth embodiment of the present invention will be described.
In the first to eighth embodiments, the cap layer 6 is formed after carrying out ion implantation and a thermal diffusion for forming the first impurity-diffused region 221 and second impurity-diffused region 222. In the ninth embodiment, a thermal diffusion for forming a first impurity-diffused region 221 and/or a thermal diffusion for forming a second impurity-diffused region 222 are performed after forming a cap layer 6. The ninth embodiment is the same as the first to eighth embodiments except this process.
As described above with reference to
This method can form the first impurity-diffused region 221 with a thin film-like shape almost parallel to the sidewall of the trench 2a. In this method, however, the impurity introduction amount into a region of the second semiconductor layer 22 which is positioned near the opening of the trench 2a may become larger than that into a lower region. As a result, the first impurity-diffused region 221 may exhibit a corresponding impurity concentration distribution in which the impurity concentration is higher on an upper portion of the first impurity-diffused region 221 than on a lower portion. The impurity concentration distribution in the first impurity-diffused region 221 may distort the equipotential surface, decreasing the withstand voltage.
According to this method, a structure shown in
B is ion-implanted into the sidewall of the trench 2a, and As is ion-implanted into it. Alternatively, As is ion-implanted into the sidewall of the trench 2a, and B is ion-implanted into it. Alternatively, B is ion-implanted into the sidewall of the trench 2a and thermally diffused, and As is ion-implanted into the sidewall of the trench 2a. In any case, As is not thermally diffused on this stage. In addition, B is implanted deeper, and As is implanted shallower. For example, B ion implantation and As ion implantation are sequentially performed without thermally diffusing B and As.
The silicon oxide layer 53 is used as a mask in ion implantation. For this reason, the silicon oxide layer 53 contains impurities at a high concentration upon the completion of ion implantation. As shown in
As shown in
A cap layer 6 shown in
After that, the impurities doped into the N-type semiconductor layer 22 are thermally diffused on any stage. For example, a heat treatment for thermally diffusing the impurities is performed before a surface of the substrate 2 on which the cap layer 6 is formed is planarized.
For example, As and B are thermally diffused in the N-type semiconductor layer 22 by a heat treatment at 1,150° C. for 45 min. As shown in
The same process as that described with reference to
According to this method, the impurity concentration in the first impurity-diffused region 221 can be made more uniform, as described above. Distortion of the equipotential surface can be reduced to implement a higher breakdown voltage.
This effect can be attained even when the cap layer 6 does not completely cover the opening of the trench 2a. In other words, this effect can be achieved even when impurities are thermally diffused while the cap layer 6 does not completely cover the opening of the trench 2a, as shown in
The techniques according to the first to ninth embodiments can be combined with each other. The techniques applied to a semiconductor device having a specific structure in the first to ninth embodiments can also be applied to a semiconductor device having another structure. For example, the above techniques may be applied to a semiconductor device including a MOSFET whose structure is different from that described above. The above techniques can also be applied to a semiconductor device including, e.g., a bipolar transistor.
Additional advantages and modifications will readily occur to those skilled in the art. Therefore, the invention in its broader aspects is not limited to the specific details and representative embodiments shown and described herein. Accordingly, various modifications may be made without departing from the spirit or scope of the general inventive concept as defined by the appended claims and their equivalents.
Number | Date | Country | Kind |
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2003-388076 | Nov 2003 | JP | national |
Number | Name | Date | Kind |
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4356211 | Riseman | Oct 1982 | A |
5926721 | Hong et al. | Jul 1999 | A |
6268637 | Gardner et al. | Jul 2001 | B1 |
6362072 | Zambrano | Mar 2002 | B1 |
6740931 | Kouzuki et al. | May 2004 | B2 |
Number | Date | Country |
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2-119238 | May 1990 | JP |
11-243142 | Sep 1999 | JP |
2001-522146 | Nov 2001 | JP |
2003-309261 | Oct 2003 | JP |
Number | Date | Country | |
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20050121704 A1 | Jun 2005 | US |