1. Field of the Invention
The present invention relates to integrated circuit processing equipment and, more particularly to atomic layer deposition (ALD) equipment.
2. Description of the Background Art
Semiconductor wafer processing systems that perform atomic layer deposition (ALD) are used to form material layers on high aspect ratio structures. Referring to
In ALD processes, a material layer is formed on a substrate by sequentially chemisorbing alternating monolayers of two or more compounds thereon. Each of the alternating monolayers is chemisorbed onto the substrate by providing a different deposition gas to the chamber that comprises one of the two or more compounds used to form the material layer. After each monolayer is chemisorbed on the substrate, a purge gas is introduced into the deposition chamber to flush the deposition gas therefrom.
Since each of the alternating monolayers of the two or more compounds used to form the material layer is chemisorbed onto the substrate by providing a different deposition gas to the chamber followed by a purge gas, atomic layer deposition (ALD) processes are time consuming. As such, integrated circuit fabrication using ALD processes are costly due to decreased wafer throughput.
Therefore, a need exists in the art for atomic layer deposition (ALD) systems for integrated circuit fabrication.
A method and apparatus for atomic layer deposition (ALD) is described. The apparatus comprises a deposition chamber and a wafer support. The deposition chamber is divided into two or more deposition regions that are integrally connected one to another. The wafer support is movable between the two or more interconnected deposition regions within the deposition chamber.
The atomic layer deposition (ALD) apparatus is compatible with integrated circuit fabrication processes. In one integrated circuit fabrication process, a substrate is positioned on a wafer support in an ALD apparatus comprising two or more integrally connected deposition regions. The wafer support with the substrate thereon is then moved into a first one of the integrally connected deposition regions wherein a first monolayer of a first compound is formed on the surface thereof. After the first monolayer of the first compound of formed on the surface of the substrate the wafer support is moved to a second one of the integrally connected deposition regions wherein a second monolayer of a second compound is formed on the first monolayer of the first compound. Thereafter, alternate monolayers of the first and second compounds are deposited one over the other by moving the wafer support with the substrate thereon between the two or more integrally connected deposition regions until a material layer having a desired thickness is formed on the substrate.
The teachings of the present invention can be readily understood by considering the following detailed description in conjunction with the accompanying drawings, in which:
The deposition chamber 105 comprises two or more deposition regions 200, 300 that are integrally connected to each other. In
The two or more deposition regions 200, 300 are integrally connected one to another with an aperture 250. The aperture 250 is of a sufficient size to permit the passage therethrough of a wafer support 150 having a substrate thereon.
The aperture 250 is optionally sealed. The aperture is sealed to minimize the intermixing of deposition gases within the two or more deposition regions 200, 300. Physical and/or pressure differences may be used.
Alternatively, an inert gas flow may be used to minimize the intermixing of deposition gases at the aperture 250 between the two or more deposition regions 200, 300. The inert gas flow provides a laminar flow around the area of the aperture 250. The inert gas flow is provided around the area of the aperture 250 through orifices (not shown).
The process chamber 105 houses a wafer support 150, which is used to support a substrate such as a semiconductor wafer 190. The wafer support 150 is moveable inside the chamber 105 between the integrally connected deposition regions 200, 300 using a displacement mechanism (not shown).
Depending on the specific process, the semiconductor wafer 190 can be heated to some desired temperature prior to material layer deposition. For example, wafer support 150 may be heated by an embedded heater element 170. The wafer support 150 may be resistively heated by applying an electric current from an AC power supply 106 to the heater element 170. The wafer 190 is, in turn, heated by the wafer support 150. The wafer support 150 may be an electrostatic chuck.
A temperature sensor 172, such as a thermocouple, may also be embedded in the wafer support 150 to monitor the temperature of the support in a conventional manner. The measured temperature can be used in a feedback loop to control the power supplied to the heater element 170, such that the wafer temperature can be maintained or controlled at a desired temperature which is suitable for the particular process application. The pedestal may optionally be heated using radiant heat (not shown).
A vacuum pump 102 is used to evacuate each of the deposition regions 200, 300 of the process chamber 105 and to maintain the proper gas flows and pressure inside the chamber 105. Orifices 120 provide process gases to each of the one or more deposition regions 200, 300. Each orifice 120 is connected to a gas panel 130 via a gas line 125, which controls and supplies various gases used in different steps of the deposition sequence.
Proper control and regulation of the gas flows through the gas panel 130 is performed by mass flow controllers (not shown) and the control unit 110. Illustratively, the control unit 110 comprises a central processing unit (CPU) 113, as well as support circuitry 114, and memories containing associated control software 116. The control unit 110 is responsible for automated control of the numerous steps required for wafer processing such as movement of the wafer support, gas flow control, temperature control, chamber evacuation, and other steps. Bi-directional communications between the control unit 110 and the various components of the ALD 100 are handled through numerous signal cables collectively referred to as signal buses 118, some of which are illustrated in
The central processing unit (CPU) 113 may be one of any form of general purpose computer processor that can be used in an industrial setting for controlling process chambers as well as sub-processors. The computer may use any suitable memory, such as random access memory, read only memory, floppy disk drive, hard drive, or any other form of digital storage, local or remote. Various support circuits may be coupled to the CPU for supporting the processor in a conventional manner. Process sequence routines as required may be stored in the memory or executed by a second CPU that is remotely located.
The process sequence routines are executed after the substrate 190 is positioned on the wafer support 150. The process sequence routines, when executed, transform the general purpose computer into a specific process computer that controls the chamber operation so that the deposition process is performed. Alternatively, the chamber operation may be controlled using remotely located hardware, as an application specific integrated circuit or other type of hardware implementation, or a combination of software and hardware.
Referring to
After the semiconductor wafer is positioned on the wafer support, a deposition gas is provided to each of the two or more deposition regions 200, 300, as indicated in step 360 of
Although embodiments described herein refer mainly to an atomic layer deposition chamber having two deposition regions, those skilled in the art will appreciate that, as described, embodiments of the present invention will also encompass deposition chambers having more than two deposition regions. For example,
Number | Name | Date | Kind |
---|---|---|---|
4058430 | Suntola et al. | Nov 1977 | A |
4389973 | Suntola et al. | Jun 1983 | A |
4413022 | Suntola et al. | Nov 1983 | A |
4415275 | Dietrich | Nov 1983 | A |
4423701 | Nath et al. | Jan 1984 | A |
4486487 | Skarp | Dec 1984 | A |
4664939 | Ovshinsky | May 1987 | A |
4761269 | Conger et al. | Aug 1988 | A |
4767494 | Kobayashi et al. | Aug 1988 | A |
4806321 | Nishizawa et al. | Feb 1989 | A |
4813846 | Helms | Mar 1989 | A |
4829022 | Kobayashi et al. | May 1989 | A |
4834831 | Nishizawa et al. | May 1989 | A |
4838983 | Schumaker et al. | Jun 1989 | A |
4838993 | Aoki et al. | Jun 1989 | A |
4840921 | Matsumoto | Jun 1989 | A |
4845049 | Sunakawa | Jul 1989 | A |
4859307 | Nishizawa et al. | Aug 1989 | A |
4859627 | Sunakawa | Aug 1989 | A |
4861417 | Mochizuki et al. | Aug 1989 | A |
4876218 | Pessa et al. | Oct 1989 | A |
4917556 | Stark et al. | Apr 1990 | A |
4927670 | Erbil | May 1990 | A |
4931132 | Aspnes et al. | Jun 1990 | A |
4951601 | Maydan et al. | Aug 1990 | A |
4960720 | Shimbo | Oct 1990 | A |
4975252 | Nishizawa et al. | Dec 1990 | A |
4993357 | Scholz | Feb 1991 | A |
5000113 | Wang et al. | Mar 1991 | A |
5013683 | Petroff et al. | May 1991 | A |
5027746 | Frijlink et al. | Jul 1991 | A |
5028565 | Chang et al. | Jul 1991 | A |
5082798 | Arimoto | Jan 1992 | A |
5085885 | Foley et al. | Feb 1992 | A |
5091320 | Aspnes et al. | Feb 1992 | A |
5130269 | Kitahara et al. | Jul 1992 | A |
5166092 | Mochizuki et al. | Nov 1992 | A |
5173327 | Sandhu et al. | Dec 1992 | A |
5173474 | Connell et al. | Dec 1992 | A |
5186718 | Tepman et al. | Feb 1993 | A |
5205077 | Wittstock | Apr 1993 | A |
5225366 | Yoder | Jul 1993 | A |
5234561 | Randhawa et al. | Aug 1993 | A |
5246536 | Nishizawa et al. | Sep 1993 | A |
5250148 | Nishizawa et al. | Oct 1993 | A |
5254207 | Nishizawa et al. | Oct 1993 | A |
5256244 | Ackerman | Oct 1993 | A |
5259881 | Edwards et al. | Nov 1993 | A |
5261959 | Gasworth | Nov 1993 | A |
5270247 | Sakuma et al. | Dec 1993 | A |
5278435 | Van Hove et al. | Jan 1994 | A |
5281274 | Yoder | Jan 1994 | A |
5286296 | Sato et al. | Feb 1994 | A |
5290748 | Knuuttila et al. | Mar 1994 | A |
5294286 | Nishizawa et al. | Mar 1994 | A |
5296403 | Nishizawa et al. | Mar 1994 | A |
5300186 | Kitahara et al. | Apr 1994 | A |
5311055 | Goodman et al. | May 1994 | A |
5316615 | Copel | May 1994 | A |
5316793 | Wallace et al. | May 1994 | A |
5330610 | Eres et al. | Jul 1994 | A |
5336324 | Stall et al. | Aug 1994 | A |
5338362 | Imahashi | Aug 1994 | A |
5338389 | Nishizawa et al. | Aug 1994 | A |
5348911 | Jurgensen et al. | Sep 1994 | A |
5374570 | Nasu et al. | Dec 1994 | A |
5384008 | Sinha et al. | Jan 1995 | A |
5395791 | Cheng et al. | Mar 1995 | A |
5438952 | Otsuka | Aug 1995 | A |
5439876 | Graf et al. | Aug 1995 | A |
5441703 | Jurgensen | Aug 1995 | A |
5443033 | Nishizawa et al. | Aug 1995 | A |
5443647 | Aucoin et al. | Aug 1995 | A |
5455072 | Bension et al. | Oct 1995 | A |
5458084 | Thorne et al. | Oct 1995 | A |
5469806 | Mochizuki et al. | Nov 1995 | A |
5480818 | Matsumoto et al. | Jan 1996 | A |
5483919 | Yokoyama et al. | Jan 1996 | A |
5484664 | Kitahara et al. | Jan 1996 | A |
5503875 | Imai et al. | Apr 1996 | A |
5518542 | Matsukawa et al. | May 1996 | A |
5521126 | Okamura et al. | May 1996 | A |
5527733 | Nishizawa et al. | Jun 1996 | A |
5532511 | Nishizawa et al. | Jul 1996 | A |
5540783 | Eres et al. | Jul 1996 | A |
5580380 | Liu et al. | Dec 1996 | A |
5601651 | Watabe | Feb 1997 | A |
5609689 | Kato et al. | Mar 1997 | A |
5616181 | Yamamoto et al. | Apr 1997 | A |
5637530 | Gaines et al. | Jun 1997 | A |
5641984 | Aftergut et al. | Jun 1997 | A |
5644128 | Wollnik et al. | Jul 1997 | A |
5667592 | Boitnott et al. | Sep 1997 | A |
5674786 | Turner et al. | Oct 1997 | A |
5693139 | Nishizawa et al. | Dec 1997 | A |
5695564 | Imahashi | Dec 1997 | A |
5705224 | Murota et al. | Jan 1998 | A |
5707880 | Aftergut et al. | Jan 1998 | A |
5711811 | Suntola et al. | Jan 1998 | A |
5730801 | Tepman et al. | Mar 1998 | A |
5730802 | Ishizumi et al. | Mar 1998 | A |
5747113 | Tsai | May 1998 | A |
5749974 | Habuka et al. | May 1998 | A |
5788447 | Yonemitsu et al. | Aug 1998 | A |
5788799 | Steger et al. | Aug 1998 | A |
5796116 | Nakata et al. | Aug 1998 | A |
5801634 | Young et al. | Sep 1998 | A |
5807792 | Ilg et al. | Sep 1998 | A |
5830270 | McKee et al. | Nov 1998 | A |
5835677 | Li et al. | Nov 1998 | A |
5851849 | Comizzoli et al. | Dec 1998 | A |
5855675 | Doering et al. | Jan 1999 | A |
5855680 | Soininen et al. | Jan 1999 | A |
5856219 | Naito et al. | Jan 1999 | A |
5858102 | Tsai | Jan 1999 | A |
5866213 | Foster et al. | Feb 1999 | A |
5866795 | Wang et al. | Feb 1999 | A |
5879459 | Gadgil et al. | Mar 1999 | A |
5882165 | Maydan et al. | Mar 1999 | A |
5882413 | Beaulieu et al. | Mar 1999 | A |
5904565 | Nguyen et al. | May 1999 | A |
5916365 | Sherman | Jun 1999 | A |
5923056 | Lee et al. | Jul 1999 | A |
5923985 | Aoki et al. | Jul 1999 | A |
5925574 | Aoki et al. | Jul 1999 | A |
5928389 | Jevtic | Jul 1999 | A |
5942040 | Kim et al. | Aug 1999 | A |
5947710 | Cooper et al. | Sep 1999 | A |
5972430 | DiMeo, Jr. et al. | Oct 1999 | A |
6001669 | Gaines et al. | Dec 1999 | A |
6015590 | Suntola et al. | Jan 2000 | A |
6025627 | Forbes et al. | Feb 2000 | A |
6026589 | Yao et al. | Feb 2000 | A |
6036773 | Wang et al. | Mar 2000 | A |
6042652 | Hyun et al. | Mar 2000 | A |
6043177 | Falconer et al. | Mar 2000 | A |
6051286 | Zhao et al. | Apr 2000 | A |
6062798 | Muka | May 2000 | A |
6071572 | Mosely et al. | Jun 2000 | A |
6071808 | Merchant et al. | Jun 2000 | A |
6084302 | Sandhu | Jul 2000 | A |
6086677 | Umotoy et al. | Jul 2000 | A |
6110556 | Bang et al. | Aug 2000 | A |
6113977 | Soininen et al. | Sep 2000 | A |
6117244 | Bang et al. | Sep 2000 | A |
6124158 | Dautartas et al. | Sep 2000 | A |
6130147 | Major et al. | Oct 2000 | A |
6139695 | Washburn et al. | Oct 2000 | A |
6139700 | Kang et al. | Oct 2000 | A |
6140237 | Chan et al. | Oct 2000 | A |
6140238 | Kitch | Oct 2000 | A |
6143082 | McInerney et al. | Nov 2000 | A |
6143659 | Leem | Nov 2000 | A |
6144060 | Park et al. | Nov 2000 | A |
6158446 | Mohindra et al. | Dec 2000 | A |
6174377 | Doering et al. | Jan 2001 | B1 |
6174809 | Kang et al. | Jan 2001 | B1 |
6178660 | Emmi et al. | Jan 2001 | B1 |
6183563 | Choi et al. | Feb 2001 | B1 |
6197683 | Kang et al. | Mar 2001 | B1 |
6200441 | Gornicki et al. | Mar 2001 | B1 |
6200893 | Sneh | Mar 2001 | B1 |
6203613 | Gates et al. | Mar 2001 | B1 |
6206967 | Mak et al. | Mar 2001 | B1 |
6207302 | Sugiura et al. | Mar 2001 | B1 |
6231672 | Choi et al. | May 2001 | B1 |
6248605 | Harkonen et al. | Jun 2001 | B1 |
6270572 | Kim et al. | Aug 2001 | B1 |
6271148 | Kao et al. | Aug 2001 | B1 |
6281098 | Wang et al. | Aug 2001 | B1 |
6287965 | Kang et al. | Sep 2001 | B1 |
6291876 | Stumborg et al. | Sep 2001 | B1 |
6302965 | Umotoy et al. | Oct 2001 | B1 |
6305314 | Sneh et al. | Oct 2001 | B1 |
6306216 | Kim et al. | Oct 2001 | B1 |
6316098 | Yitzchaik et al. | Nov 2001 | B1 |
6319553 | McInerney et al. | Nov 2001 | B1 |
6342277 | Sherman | Jan 2002 | B1 |
6365025 | Ting et al. | Apr 2002 | B1 |
6387185 | Doering et al. | May 2002 | B1 |
6432231 | Nielson et al. | Aug 2002 | B1 |
6447607 | Soininen et al. | Sep 2002 | B1 |
6451119 | Sneh et al. | Sep 2002 | B1 |
6455098 | Tran et al. | Sep 2002 | B1 |
6478872 | Chae et al. | Nov 2002 | B1 |
6481945 | Hasper et al. | Nov 2002 | B1 |
6497767 | Okase et al. | Dec 2002 | B1 |
6511539 | Raaijmakers | Jan 2003 | B1 |
6551406 | Kilpi | Apr 2003 | B1 |
6572705 | Suntola et al. | Jun 2003 | B1 |
6573182 | Sandhu et al. | Jun 2003 | B1 |
6578287 | Aswad | Jun 2003 | B1 |
6579372 | Park | Jun 2003 | B1 |
6579374 | Bondestam et al. | Jun 2003 | B1 |
6593484 | Yasuhara et al. | Jul 2003 | B1 |
6613656 | Li | Sep 2003 | B1 |
6630030 | Suntola et al. | Oct 2003 | B1 |
6630201 | Chiang et al. | Oct 2003 | B1 |
6656273 | Toshima et al. | Dec 2003 | B1 |
6660126 | Nguyen et al. | Dec 2003 | B1 |
6716287 | Santiago et al. | Apr 2004 | B1 |
6718126 | Lei | Apr 2004 | B1 |
6734020 | Lu et al. | May 2004 | B1 |
6772072 | Ganguli et al. | Aug 2004 | B1 |
6773507 | Jallepally et al. | Aug 2004 | B1 |
6777352 | Tepman et al. | Aug 2004 | B1 |
6778762 | Shareef et al. | Aug 2004 | B1 |
6815285 | Choi et al. | Nov 2004 | B1 |
6818094 | Yudovsky | Nov 2004 | B1 |
6821563 | Yudovsky | Nov 2004 | B1 |
6866746 | Lei et al. | Mar 2005 | B1 |
6868859 | Yudovsky | Mar 2005 | B1 |
20010000866 | Sneh et al. | May 2001 | A1 |
20010009140 | Bondestam et al. | Jul 2001 | A1 |
20010011526 | Doering et al. | Aug 2001 | A1 |
20010013312 | Soininen et al. | Aug 2001 | A1 |
20010014371 | Kilpi | Aug 2001 | A1 |
20010024387 | Raaijmakers et al. | Sep 2001 | A1 |
20010031562 | Raaijmakers et al. | Oct 2001 | A1 |
20010034123 | Jeon et al. | Oct 2001 | A1 |
20010041250 | Werkhoven et al. | Nov 2001 | A1 |
20010042523 | Kesala | Nov 2001 | A1 |
20010042799 | Kim et al. | Nov 2001 | A1 |
20010054377 | Lindfors et al. | Dec 2001 | A1 |
20010054769 | Raaijmakers et al. | Dec 2001 | A1 |
20020000196 | Park | Jan 2002 | A1 |
20020007790 | Park | Jan 2002 | A1 |
20020009544 | McFeely et al. | Jan 2002 | A1 |
20020041931 | Suntola et al. | Apr 2002 | A1 |
20020052097 | Park | May 2002 | A1 |
20020066411 | Chiang et al. | Jun 2002 | A1 |
20020073924 | Chiang et al. | Jun 2002 | A1 |
20020076481 | Chiang et al. | Jun 2002 | A1 |
20020076507 | Chiang et al. | Jun 2002 | A1 |
20020076508 | Chiang et al. | Jun 2002 | A1 |
20020086106 | Park et al. | Jul 2002 | A1 |
20020092471 | Kang et al. | Jul 2002 | A1 |
20020094689 | Park | Jul 2002 | A1 |
20020104481 | Chiang et al. | Aug 2002 | A1 |
20020108570 | Lindfors | Aug 2002 | A1 |
20020121241 | Nguyen et al. | Sep 2002 | A1 |
20020121342 | Nguyen et al. | Sep 2002 | A1 |
20020127745 | Lu et al. | Sep 2002 | A1 |
20020134307 | Choi | Sep 2002 | A1 |
20020144655 | Chiang et al. | Oct 2002 | A1 |
20020144657 | Chiang et al. | Oct 2002 | A1 |
20020146511 | Chiang et al. | Oct 2002 | A1 |
20020195056 | Sandhu et al. | Dec 2002 | A1 |
20030004723 | Chihara | Jan 2003 | A1 |
20030010451 | Tzu et al. | Jan 2003 | A1 |
20030017697 | Choi et al. | Jan 2003 | A1 |
20030022338 | Ruben et al. | Jan 2003 | A1 |
20030042630 | Babcoke et al. | Mar 2003 | A1 |
20030053799 | Lei | Mar 2003 | A1 |
20030057527 | Chung et al. | Mar 2003 | A1 |
20030072913 | Chou et al. | Apr 2003 | A1 |
20030075273 | Kilpela et al. | Apr 2003 | A1 |
20030075925 | Lindfors et al. | Apr 2003 | A1 |
20030079686 | Chen et al. | May 2003 | A1 |
20030089308 | Raaijmakers | May 2003 | A1 |
20030101927 | Raaijmakers | Jun 2003 | A1 |
20030101938 | Ronsse et al. | Jun 2003 | A1 |
20030105490 | Jallepally et al. | Jun 2003 | A1 |
20030113187 | Lei et al. | Jun 2003 | A1 |
20030116087 | Nguyen et al. | Jun 2003 | A1 |
20030121469 | Lindfors et al. | Jul 2003 | A1 |
20030121608 | Chen et al. | Jul 2003 | A1 |
20030140854 | Kilpi | Jul 2003 | A1 |
20030143328 | Chen et al. | Jul 2003 | A1 |
20030143747 | Bondestam et al. | Jul 2003 | A1 |
20030153177 | Tepman et al. | Aug 2003 | A1 |
20030172872 | Thakur et al. | Sep 2003 | A1 |
20030194493 | Chang et al. | Oct 2003 | A1 |
20030198754 | Xi et al. | Oct 2003 | A1 |
20030213560 | Wang et al. | Nov 2003 | A1 |
20030216981 | Tillman | Nov 2003 | A1 |
20030219942 | Choi et al. | Nov 2003 | A1 |
20030221780 | Lei et al. | Dec 2003 | A1 |
20030224107 | Lindfors et al. | Dec 2003 | A1 |
20030235961 | Metzner et al. | Dec 2003 | A1 |
20040011404 | Ku et al. | Jan 2004 | A1 |
20040011504 | Ku et al. | Jan 2004 | A1 |
20040013577 | Ganguli et al. | Jan 2004 | A1 |
20040014320 | Chen et al. | Jan 2004 | A1 |
20040015300 | Ganguli et al. | Jan 2004 | A1 |
20040016404 | Gregg et al. | Jan 2004 | A1 |
20040025370 | Guenther | Feb 2004 | A1 |
20040065255 | Yang et al. | Apr 2004 | A1 |
20040069227 | Ku et al. | Apr 2004 | A1 |
20040071897 | Verplancken et al. | Apr 2004 | A1 |
20040144308 | Yudovsky | Jul 2004 | A1 |
20040144311 | Chen et al. | Jul 2004 | A1 |
20040219784 | Kang et al. | Nov 2004 | A1 |
20040224506 | Choi et al. | Nov 2004 | A1 |
20040235285 | Kang et al. | Nov 2004 | A1 |
20050006799 | Gregg et al. | Jan 2005 | A1 |
20050059240 | Choi et al. | Mar 2005 | A1 |
20050095859 | Chen et al. | May 2005 | A1 |
20050104142 | Narayanan et al. | May 2005 | A1 |
Number | Date | Country |
---|---|---|
196 27 017 | Jan 1997 | DE |
198 20 147 | Jul 1999 | DE |
0 344 352 | Dec 1989 | EP |
0 429 270 | May 1991 | EP |
0 442 490 | Aug 1991 | EP |
0 497 267 | Aug 1992 | EP |
0 799 641 | Oct 1997 | EP |
1167569 | Jan 2002 | EP |
2 626 110 | Jul 1989 | FR |
2 692 597 | Dec 1993 | FR |
2 355 727 | May 2001 | GB |
58-098917 | Jun 1983 | JP |
58-100419 | Jun 1983 | JP |
60-065712 | Apr 1985 | JP |
61-035847 | Feb 1986 | JP |
61-210623 | Sep 1986 | JP |
62-069508 | Mar 1987 | JP |
62-091495 | Apr 1987 | JP |
62-141717 | Jun 1987 | JP |
62-167297 | Jul 1987 | JP |
62-171999 | Jul 1987 | JP |
62-232919 | Oct 1987 | JP |
63-062313 | Mar 1988 | JP |
63-085098 | Apr 1988 | JP |
63-090833 | Apr 1988 | JP |
63-222420 | Sep 1988 | JP |
63-222421 | Sep 1988 | JP |
63-227007 | Sep 1988 | JP |
63-252420 | Oct 1988 | JP |
63-266814 | Nov 1988 | JP |
64-009895 | Jan 1989 | JP |
64-009896 | Jan 1989 | JP |
64-009897 | Jan 1989 | JP |
64-037832 | Feb 1989 | JP |
64-082615 | Mar 1989 | JP |
64-082617 | Mar 1989 | JP |
64-082671 | Mar 1989 | JP |
64-082676 | Mar 1989 | JP |
01-103982 | Apr 1989 | JP |
01-103996 | Apr 1989 | JP |
64-090524 | Apr 1989 | JP |
01-117017 | May 1989 | JP |
01-143221 | Jun 1989 | JP |
01-143233 | Jun 1989 | JP |
01-154511 | Jun 1989 | JP |
01-236657 | Sep 1989 | JP |
01-245512 | Sep 1989 | JP |
01-264218 | Oct 1989 | JP |
01-270593 | Oct 1989 | JP |
01-272108 | Oct 1989 | JP |
01-290221 | Nov 1989 | JP |
01-290222 | Nov 1989 | JP |
01-296673 | Nov 1989 | JP |
01-303770 | Dec 1989 | JP |
01-305894 | Dec 1989 | JP |
01-313927 | Dec 1989 | JP |
02-012814 | Jan 1990 | JP |
02-014513 | Jan 1990 | JP |
02-017634 | Jan 1990 | JP |
02-063115 | Mar 1990 | JP |
02-074029 | Mar 1990 | JP |
02-074587 | Mar 1990 | JP |
02-106822 | Apr 1990 | JP |
02-129913 | May 1990 | JP |
02-162717 | Jun 1990 | JP |
02-172895 | Jul 1990 | JP |
02-196092 | Aug 1990 | JP |
02-203517 | Aug 1990 | JP |
02-230690 | Sep 1990 | JP |
02-230722 | Sep 1990 | JP |
02-246161 | Oct 1990 | JP |
02-264491 | Oct 1990 | JP |
02-283084 | Nov 1990 | JP |
02-304916 | Dec 1990 | JP |
03-019211 | Jan 1991 | JP |
03-022569 | Jan 1991 | JP |
03-023294 | Jan 1991 | JP |
03-023299 | Jan 1991 | JP |
03-044967 | Feb 1991 | JP |
03-048421 | Mar 1991 | JP |
03-070124 | Mar 1991 | JP |
03-185716 | Aug 1991 | JP |
03-208885 | Sep 1991 | JP |
03-234025 | Oct 1991 | JP |
03-286522 | Dec 1991 | JP |
03-286531 | Dec 1991 | JP |
04-031391 | Feb 1992 | JP |
04-031396 | Feb 1992 | JP |
04-031396 | Feb 1992 | JP |
04-100292 | Apr 1992 | JP |
04-111418 | Apr 1992 | JP |
04-132214 | May 1992 | JP |
04-132681 | May 1992 | JP |
04151822 | May 1992 | JP |
04-162418 | Jun 1992 | JP |
04-175299 | Jun 1992 | JP |
04-186824 | Jul 1992 | JP |
04-212411 | Aug 1992 | JP |
04-260696 | Sep 1992 | JP |
04-273120 | Sep 1992 | JP |
04-285167 | Oct 1992 | JP |
04-291916 | Oct 1992 | JP |
04-325500 | Nov 1992 | JP |
04-328874 | Nov 1992 | JP |
05-029228 | Feb 1993 | JP |
05-047665 | Feb 1993 | JP |
05-047666 | Feb 1993 | JP |
05-047668 | Feb 1993 | JP |
05-074717 | Mar 1993 | JP |
05-074724 | Mar 1993 | JP |
05-102189 | Apr 1993 | JP |
05-160152 | Jun 1993 | JP |
05-175143 | Jul 1993 | JP |
05-175145 | Jul 1993 | JP |
05-182906 | Jul 1993 | JP |
05-186295 | Jul 1993 | JP |
05-206036 | Aug 1993 | JP |
05-234899 | Sep 1993 | JP |
05-235047 | Sep 1993 | JP |
05-251339 | Sep 1993 | JP |
05-270997 | Oct 1993 | JP |
05-283336 | Oct 1993 | JP |
05-291152 | Nov 1993 | JP |
05-304334 | Nov 1993 | JP |
05-343327 | Dec 1993 | JP |
05-343685 | Dec 1993 | JP |
06-045606 | Feb 1994 | JP |
06-132236 | May 1994 | JP |
06-177381 | Jun 1994 | JP |
06-196809 | Jul 1994 | JP |
06-222388 | Aug 1994 | JP |
06-224138 | Aug 1994 | JP |
06-230421 | Aug 1994 | JP |
06-252057 | Sep 1994 | JP |
06-291048 | Oct 1994 | JP |
07-070752 | Mar 1995 | JP |
07-086269 | Mar 1995 | JP |
08-181076 | Jul 1996 | JP |
08-245291 | Sep 1996 | JP |
08-264530 | Oct 1996 | JP |
09-260786 | Oct 1997 | JP |
09-293681 | Nov 1997 | JP |
10-188840 | Jul 1998 | JP |
10-190128 | Jul 1998 | JP |
10-308283 | Nov 1998 | JP |
11-269652 | Oct 1999 | JP |
2000-031387 | Jan 2000 | JP |
2000-058777 | Feb 2000 | JP |
2000-068072 | Mar 2000 | JP |
2000-087029 | Mar 2000 | JP |
2000-138094 | May 2000 | JP |
2000-212752 | Aug 2000 | JP |
2000-218445 | Aug 2000 | JP |
2000-319772 | Nov 2000 | JP |
2000-340883 | Dec 2000 | JP |
2000-353666 | Dec 2000 | JP |
2001-020075 | Jan 2001 | JP |
2001-62244 | Mar 2001 | JP |
2001-152339 | Jun 2001 | JP |
2001-172767 | Jun 2001 | JP |
2001-189312 | Jul 2001 | JP |
2001-217206 | Aug 2001 | JP |
2001-220287 | Aug 2001 | JP |
2001-220294 | Aug 2001 | JP |
2001-240972 | Sep 2001 | JP |
2001-254181 | Sep 2001 | JP |
2001-284042 | Oct 2001 | JP |
2001-303251 | Oct 2001 | JP |
2001-328900 | Nov 2001 | JP |
2002 2060944 | Feb 2002 | JP |
9002216 | Mar 1990 | WO |
9110510 | Jul 1991 | WO |
9302111 | Feb 1993 | WO |
9617107 | Jun 1996 | WO |
9618756 | Jun 1996 | WO |
WO 9617107 | Jun 1996 | WO |
9806889 | Feb 1998 | WO |
9851838 | Nov 1998 | WO |
9901595 | Jan 1999 | WO |
WO 9901595 | Jan 1999 | WO |
9913504 | Mar 1999 | WO |
9929924 | Jun 1999 | WO |
9941423 | Aug 1999 | WO |
WO 9965064 | Dec 1999 | WO |
0011721 | Mar 2000 | WO |
0015865 | Mar 2000 | WO |
0015881 | Mar 2000 | WO |
0016377 | Mar 2000 | WO |
0054320 | Sep 2000 | WO |
WO 0054320 | Sep 2000 | WO |
0063957 | Oct 2000 | WO |
0079019 | Dec 2000 | WO |
0079576 | Dec 2000 | WO |
WO 0079576 | Dec 2000 | WO |
0115220 | Mar 2001 | WO |
0115220 | Mar 2001 | WO |
WO 0117692 | Mar 2001 | WO |
0127346 | Apr 2001 | WO |
0127346 | Apr 2001 | WO |
0127347 | Apr 2001 | WO |
0127347 | Apr 2001 | WO |
0129280 | Apr 2001 | WO |
0129891 | Apr 2001 | WO |
0129891 | Apr 2001 | WO |
0129893 | Apr 2001 | WO |
0129893 | Apr 2001 | WO |
0136702 | May 2001 | WO |
WO 0136702 | May 2001 | WO |
0140541 | Jun 2001 | WO |
0166832 | Sep 2001 | WO |
WO 0208488 | Jan 2002 | WO |
WO -245871 | Jun 2002 | WO |
WO 0323835 | Mar 2003 | WO |
Number | Date | Country | |
---|---|---|---|
20030023338 A1 | Jan 2003 | US |