The present disclosure relates to the processing of substrates. In particular, it provides a novel transistor fabrication process and method that protects a contact etch stop layer (CESL) from oxidation and thinning during subsequent processing steps of the transistor fabrication process. In one embodiment, the disclosed method may be utilized when forming field effect transistors (FETs) on semiconductor substrates.
As geometries in substrate processing continue to shrink, the technical challenges to forming structures and devices on substrates increase. Field effect transistors, or FETs, are one example of devices that may be formed on a semiconductor substrate using a variety of semiconductor processing techniques. The fabrication of FETs typically involves multiple steps of layer deposition, patterning and etching to define various structures on and/or within a substrate. For example, one type of FET may generally include a source region, a drain region, a channel region positioned between the source region and the drain region, and a gate structure (or simply “gate”) positioned over the channel region. In a planar FET, such as a metal-oxide-semiconductor field effect transistor (MOSFET), the source, drain and channel regions are formed within the substrate, and the gate structure is formed above the substrate over the channel region.
FinFET transistors were developed to improve the operating speed of transistors, while avoiding the deleterious effects often seen when the channel length is reduced in planar MOSFET designs (such as leakage currents that occur in a short channel device when the transistor is switched “off”). Unlike planar MOSFET transistors, FinFET transistors are three-dimensional (3D) transistor designs that use “fins” to form a raised channel between the source and drain regions of the FinFET. In a FinFET design, the gate structure wraps around the raised channel on multiple sides of the fin to form the gate structure. The greater surface area between the gate and the channel reduces leakage currents in the transistor “off” state and enables lower gate voltages to be used to turn the FinFET “on.” Thus, FinFETs typically provide better performance and reduced power consumption compared to planar MOSFET designs. Although FinFETs offer power, performance and scaling benefits, they are not without manufacturing challenges.
Each fin 12 includes a source region 14, a drain region 16 and a channel region 18 positioned between the source region and the drain region. As shown in
As noted above, FET fabrication methods typically involve multiple steps of layer deposition, patterning and etching to define the various transistor structures formed on and/or within the substrate. In some approaches, a contact etch stop layer (CESL) may be used within a FinFET fabrication process to protect one or more underlying layers, while selectively removing other layers. In some cases, subsequent processing steps may damage or diminish the CESL, resulting in damage to the protected underlying layer(s).
In one example prior art process (not shown), a CESL may be conformally deposited onto the FinFET 10 to protect underlying structures (e.g., the source region 14, drain region 16 and/or epitaxial features 22) during subsequent processing steps. After the CESL is deposited, an oxide layer may be deposited onto the CESL and annealed, before the oxide layer is etched to form contact openings to the source and drain regions. In the prior art process, uncontrolled oxidation of the CESL during the post-oxide anneal step may result in significant loss or thinning of the CESL during a subsequently performed oxide etch step and corresponding damage to underlying source and drain regions. For example, thinning of the CESL may cause the oxide etch to etch through the CESL and damage the source and drain regions and/or thinning of the CESL may result in the CESL removal etch over etching so much that the CESL removal etch damages the source and drain. Further, variations in the etch rate and selectivity of the oxide etch may also cause loss of the CESL and corresponding damage to the underlying source and drain regions. Thus, changes in thickness and/or chemical composition of the CESL caused by the substrate processing may lead to damaging the underlying structures, such as the source region 14, drain region 16 and/or the epitaxial features 22 formed thereon.
A need, therefore, remains for an improved transistor fabrication process that protects a contact etch stop layer (CESL) from oxidation and thinning during subsequent processing steps of the transistor fabrication process.
Improved process flows and methods are provided herein for fabricating a transistor, such as a field effect transistor (FET), on a substrate. More specifically, improved process flows and transistor fabrication methods, which utilize a contact etch stop layer (CESL) with improved etch stop capability.
In the disclosed process flows and methods, a CESL is conformally deposited directly onto a plurality of transistor structures, and a sacrificial layer is conformally deposited directly onto the CESL to protect the CESL from oxidation and thinning during subsequent processing step(s). In doing so, the sacrificial layer improves the etch stop capability of the CESL during a subsequently performed oxide etch process. By providing a CESL with improved etch stop capability, the disclosed process flows and methods provide a controlled CESL etch process, which in turn, reduces or avoids damage to underlying transistor structures, such as the source and drain regions and/or the epitaxial features formed as part of those regions.
According to one embodiment, a method for fabricating a transistor in accordance with the techniques described herein may generally include forming a plurality of transistor structures on and/or within the substrate, where the plurality of transistor structures comprise a gate structure, a source region and a drain region. After the transistor structures are formed, the method may include conformally depositing a contact etch stop layer (CESL) directly onto the plurality of transistor structures, and conformally depositing a sacrificial silicon layer directly onto the CESL, such that the sacrificial silicon layer is formed over the plurality of transistor structures. As described in more detail below, the sacrificial silicon layer protects the CESL from oxidation and thinning during subsequent processing step(s), particularly in the regions where contacts to source and drain regions are formed.
In one embodiment, a method for fabricating a transistor on a substrate is provided. The method may comprise forming a plurality of transistor structures on and/or within the substrate, wherein the plurality of transistor structures comprise a gate structure, a source region and a drain region. The method further comprises forming a contact etch stop layer (CESL) on the plurality of transistor structures. The method also comprises forming a sacrificial silicon layer on the CESL such that the sacrificial silicon layer is formed over the plurality of transistor structures, wherein formation of the sacrificial silicon layer includes forming the sacrificial silicon layer on the CESL in the source region where a source contact will be subsequently formed and in the drain region where a drain contact will be subsequently formed. The sacrificial silicon layer protects the CESL formed over the source region and the drain region from oxidation and thinning during subsequent processing steps, thereby preventing damage to the source region and the drain region during the subsequent processing steps.
In embodiments of the methods, the CESL comprises SiN, SiOCN, SiCN, SiBCN, AlN, and/or AlO and the sacrificial silicon layer comprises amorphous silicon or polycrystalline silicon. In some embodiments, forming the CESL comprises conformally depositing the CESL to a thickness ranging between 1 nm and 10 nm and forming the sacrificial silicon layer comprises conformally depositing to a thickness ranging between 1 nm and 5 nm. In some embodiments, the steps of forming the CESL and the forming the sacrificial silicon layer are performed in the same processing chamber using the same deposition process. In one embodiment, the method further comprises forming an oxide layer directly on the sacrificial silicon layer and performing an anneal process, wherein the sacrificial silicon layer protects the CESL from oxidation during said forming the oxide layer and performing the anneal process. In some embodiments, the methods further comprise performing a first etch process to form contact openings above the source region and the drain region, wherein by protecting the CESL from oxidation, the sacrificial silicon layer improves an etch stop capability of the CESL. In still other embodiments, the sacrificial silicon layer is oxidized during said forming the oxide layer and performing the anneal process, and wherein the sacrificial silicon layer is removed during the first etch process. In other embodiments, the methods further comprise, performing a second etch process to remove portions of the CESL overlying the source region and the drain region and to extend the contact openings to the source region and the drain region, wherein by protecting the CESL from thinning, the sacrificial silicon layer reduces or prevents damage to the plurality of transistor structures. In still another embodiment, the transistor is a Fin field effect transistor (FinFET), and the plurality of transistor structures comprise (1) one or more fins that extend vertically from the substrate, wherein the one or more fins comprise a channel region positioned between the source region and the drain region, and (2) the gate structure, wherein the gate structure is oriented orthogonal to the one or more fins.
In yet another embodiment, a method for fabricating a transistor on a substrate is provided. The method may comprises forming a plurality of transistor structures on and/or within the substrate, wherein the plurality of transistor structures comprise (1) one or more fins that extend vertically from the substrate, wherein the one or more fins comprise a source region, a drain region and a channel region positioned between the source region and the drain region, and (2) a gate structure oriented orthogonal to the one or more fins. The method further comprises forming a contact etch stop layer (CESL) on the plurality of transistor structures. The method also comprises forming a sacrificial layer directly on the CESL, such that the sacrificial layer is formed over the plurality of transistor structures, including over the source region and over the drain region. Forming the sacrificial layer protects the CESL in the source region and the drain region from oxidation and thinning during subsequent processing steps.
A more complete understanding of the present inventions and advantages thereof may be acquired by referring to the following description taken in conjunction with the accompanying drawings, in which like reference numbers indicate like features. It is to be noted, however, that the accompanying drawings illustrate only exemplary embodiments of the disclosed concepts and are therefore not to be considered limiting of the scope, for the disclosed concepts may admit to other equally effective embodiments.
Improved process flows and methods are provided herein for fabricating a transistor, such as a field effect transistor (FET), on a substrate. More specifically, improved process flows and transistor fabrication methods, which utilize a contact etch stop layer (CESL) with improved etch stop capability.
In the disclosed process flows and methods, a CESL is conformally deposited directly onto a plurality of transistor structures, and a sacrificial layer is conformally deposited directly onto the CESL to protect the CESL from oxidation and thinning during subsequent processing step(s). In doing so, the sacrificial layer improves the etch stop capability of the CESL during a subsequently performed oxide etch process. By providing a CESL with improved etch stop capability, the disclosed process flows and methods provide a controlled CESL etch process, which in turn, reduces or avoids damage to underlying transistor structures, such as the source and drain regions and/or the epitaxial features formed as part of the source and drain regions.
The process flows and methods disclosed herein may utilize a wide variety of CESL materials including, but not limited to, silicon nitride, silicon carbonitride (SiCN), silicon boron carbonitride (SiBCN) or other silicon materials for which good etch selectivity with oxide and source/drain silicon may be obtained. Although CESL materials containing nitride are disclosed herein in exemplary embodiments, the techniques described herein are extendible to other materials commonly used in etch stop layers. Thus, it will be recognized that a nitride CESL is merely exemplary and other CESL layers may be utilized. The process flows and methods disclosed herein may also utilize a wide variety of sacrificial layer materials including, but not limited to, amorphous silicon and polycrystalline silicon (polysilicon). Although sacrificial layer materials containing silicon are disclosed herein as examples, the techniques described herein are extendible to other sacrificial layer materials.
The process flows and methods disclosed herein may generally be used to fabricate a transistor on a substrate, such as a semiconductor substrate.
The improved process flow shown in
In some embodiments, the techniques described herein may be implemented in conjunction with a “gate last” or replacement metal gate (RMG) transistor fabrication process. A typical RMG process flow includes forming a temporary or sacrificial gate structure, forming additional transistor structures, and then removing the sacrificial gate structure to form a trench. After removing the sacrificial gate structure, various layers of material (e.g., gate dielectric, gate conductor and/or gate cap materials) are deposited within the trench to form a functional gate structure. Thus, the RMG process delays gate formation (i.e., forms the gate last) to avoid damaging gate materials during subsequent processing steps. Although the improved process flow shown in
As described in more detail below, each FinFET may generally include a gate structure and one or more fins 110. The cross-sectional views shown in
In the embodiment shown in
Base substrate 102 may be any substrate for which the use of patterned features is desirable. For example, base substrate 102 may be a semiconductor substrate having one or more semiconductor processing layers formed thereon. In one embodiment, base substrate 102 may be a substrate that has been subject to multiple semiconductor processing steps which yield a wide variety of structures and layers, all of which are known in the substrate processing art. Non-limiting examples of suitable materials for base substrate 102 include Si (silicon), strained Si, SiC (silicon carbide), Ge (germanium), SiGe (silicon germanium), SiGeC (silicon-germanium-carbon), Si alloys, Ge alloys, III-V materials (e.g., GaAs (gallium arsenide), InAs (indium arsenide), InP (indium phosphide), or aluminum arsenide (AlAs)), II-VI materials (e.g., CdSe (cadmium selenide), CdS (cadmium sulfide), CdTe (cadmium telluride), ZnO (zinc oxide), ZnSe (zinc selenide), ZnS (zinc sulfide), or ZnTe (zinc telluride)), or any combination thereof.
Similar to the one or more fins 12 shown in
Although not labeled in the figures, each fin 110 includes a source region, a drain region and a channel region positioned between the source region and the drain region. The one or more fins 110 may be formed from any of a wide variety of electrically conductive materials, as is known in the art. In one embodiment, the one or more fins 110 may be formed from a silicon material, though it will be recognized that the fins may be formed of materials similar to the wide variety of base substrate materials described above. In some embodiments, epitaxial features (not shown) may be formed as part of the source and drain regions of the one or more fins 110, similar to the epitaxial features 26 shown in
In the embodiment shown in
The sacrificial gate structures 106 may be formed from a wide variety of materials, as is known in the art. In one embodiment, the sacrificial gate structures 106 may be formed from polysilicon. However, other materials may also be used to implement the sacrificial gate structures 106 as is known in the art. The sacrificial gate structures 106 shown in
Sidewall spacers 108 are formed adjacent to the sacrificial gate structures 106 on either side of the gate structures, as is known in the art. The sidewall spacers 108 may be formed from a wide variety of dielectric materials, as is known in the art. In some embodiments, the sidewall spacers 108 may be formed from a low-k dielectric material. Other dielectric materials may also be used to implement the sidewall spacers 108, as is known in the art.
After the FinFET structures shown in
After the CESL 112 is deposited, a sacrificial silicon layer 114 is deposited onto the CESL 112, as shown in
The CESL 112 and sacrificial layer formed on the CESL 112 may each be formed from a wide variety of materials. In some embodiments, the CESL 112 may be formed from a etch stop material, such as silicon nitride (SiN), silicon oxynitride (SiON), silicon carbide (SiC), silicon carbonitride (SiCN), silicon oxycarbonitride (SiOCN), silicon boron carbonitride (SiBCN), silicon carbon oxide (SiOC), hydrogen doped silicon nitride carbide (SiNCH), aluminum oxide (AlO), aluminum nitride (AlN), and/or other dielectric materials or combinations of materials that show good etch selectivity to the overlying oxide and the underlying source/drain silicon. Other etch stop materials may also be used to implement the CESL 112, as is known in the art. To protect the CESL 112 from oxidation and potential overetch, the sacrificial layer may be formed from a silicon-containing material such as for example silicon (for example as shown with sacrificial silicon layer 114) or other silicon materials that easily oxidizes. In some embodiments, the sacrificial silicon layer 114 may comprise amorphous silicon or polysilicon. Further, the sacrificial silicon layer 114 need not be comprised of only silicon, but rather may merely be a silicon containing material. As mentioned, other oxidizable materials may also be used to implement the sacrificial layer.
A variety of deposition processes may be used to conformally deposit the CESL 112 and the sacrificial silicon layer 114. For example, the CESL 112 and the sacrificial silicon layer 114 may be deposited using chemical vapor deposition (CVD), plasma enhanced CVD (PECVD), physical vapor deposition (PVD), atomic layer deposition (ALD), and/or other deposition processes. In some embodiments, the CESL 112 and the sacrificial silicon layer 114 may be deposited in the same processing chamber using the same deposition process (e.g., CVD). In other embodiments, different deposition processes may be used to deposit the CESL 112 and the sacrificial silicon layer 114.
In one preferred embodiment, a silicon nitride CESL 112 may be deposited onto the FinFET structures shown in
After the sacrificial silicon layer 114 is deposited, a flowable oxide layer 116 is deposited onto the sacrificial silicon layer 114 to fill in the gaps between the sacrificial gate structures 106 (and sidewall spacers 108), as shown in
A variety of deposition processes may be used to deposit the flowable oxide layer 116 onto the sacrificial silicon layer 114. For example, a plasma assisted CVD process at low temperature (30 to 100 degrees C.) and a pressure of 0.1 to 1 Torr may be used to deposit the flowable oxide. In some embodiments, the flowable oxide layer 116 may be deposited to a thickness ranging between 50 nm and 200 nm. After the flowable oxide layer 116 is deposited, an anneal process may be used to increase the density of at least a portion of the flowable oxide layer 116. Suitable anneal processes include, but are not limited to, those involving exposure to a steam, thermal, ultraviolet (UV), electron-beam (e-beam), microwave, laser or plasma source in an oxidative or inert environment.
In the improved process flows and methods disclosed herein, sacrificial silicon layer 114 functions as a protective layer, which protects the CESL 112 from oxidation during the oxide deposition and anneal step shown in
Various processes may be performed after the oxide deposition and anneal step shown in
For example, the CESL 112 is preferably formed from a material having a much slower etch rate than the material used for the flowable oxide layer 116. Regardless of the particular material chosen, CESL 112 preferably exhibits different etch characteristics (e.g., etch rate, etch selectivity, etc.) than the flowable oxide layer 116. These different etch characteristics allow the CESL 112 to act as an etch stop during the oxide etch process shown in
In some embodiments, a replacement metal gate (RMG) process may be performed to remove the sacrificial gate structures 106 and replace them with functional gate structures, as shown in
After removing the sacrificial gate structures 106, the RMG process may utilize one or more deposition processes to deposit various materials within the trenches formed between each pair of the sidewall spacers 108. In some embodiments, a metal gate 118 and a gate cap 120 may be formed between each pair of sidewall spacers 108, as shown in
After performing the oxide etch and RMG process shown in
As noted above, prior art processes for fabricating FinFET transistors use contact etch stop layers to protect underlying FinFET structures during subsequent processing steps. In the prior art process discussed in the background section, a CESL is deposited onto the FinFET structures and an oxide layer (such as flowable oxide layer 116 of
The improved process flow shown in
By protecting the CESL 112 from oxidation, sacrificial silicon layer 114 improves the etch stop capability of the CESL 112 during the oxide etch step shown in
In some embodiments, forming a sacrificial silicon layer 114 on the CESL 112, as described herein, may also enable a thinner (e.g., 1 nm to 5 nm) CESL 112 to be used, compared to contact etch stop layers (e.g., 2 nm to 10 nm) typically used in prior art processes. Also, reducing the thickness of the CESL 112 on the gate sidewall (e.g., on sidewall surfaces of the sidewall spacers 108) reduces gate capacitance and improves the operational speed of the FinFET transistor.
Next, method 400 includes forming a contact etch stop layer (CESL) on the plurality of transistor structures (in step 420), and forming a sacrificial silicon layer on the CESL, such that the sacrificial silicon layer is formed over the plurality of transistor structures (in step 430). In this embodiment, the step of forming the sacrificial silicon layer includes forming the sacrificial silicon layer on the CESL in the source region where a source contact will be subsequently formed and in the drain region where a drain contact will be subsequently formed. In doing so, the sacrificial silicon layer protects the CESL formed over the source region and the drain region from oxidation and thinning during subsequent processing steps, thereby preventing damage to the source region and the drain region during the subsequent processing steps.
Next, method 500 includes forming a contact etch stop layer (CESL) on the plurality of transistor structures (in step 520), and forming a sacrificial layer directly on the CESL, such that the sacrificial layer is formed over the plurality of transistor structures, including over the source region and over the drain region (in step 530). In this embodiment, the sacrificial layer protects the CESL in the source region and the drain region from oxidation and thinning during subsequent processing steps.
It is noted that reference throughout this specification to “one embodiment” or “an embodiment” means that a particular feature, structure, material, or characteristic described in connection with the embodiment is included in at least one embodiment of the invention, but do not denote that they are present in every embodiment. Thus, the appearances of the phrases “in one embodiment” or “in an embodiment” in various places throughout this specification are not necessarily referring to the same embodiment of the invention. Furthermore, the particular features, structures, materials, or characteristics may be combined in any suitable manner in one or more embodiments. Various additional layers and/or structures may be included and/or described features may be omitted in other embodiments.
The term “substrate” as used herein means and includes a base material or construction upon which materials are formed. It will be appreciated that the substrate may include a single material, a plurality of layers of different materials, a layer or layers having regions of different materials or different structures in them, etc. These materials may include semiconductors, insulators, conductors, or combinations thereof. For example, the substrate may be a semiconductor substrate, a base semiconductor layer on a supporting structure, a metal electrode or a semiconductor substrate having one or more layers, structures or regions formed thereon. The substrate may be a conventional silicon substrate or other bulk substrate comprising a layer of semi-conductive material. As used herein, the term “bulk substrate” means and includes not only silicon wafers, but also silicon-on-insulator (“SOI”) substrates, such as silicon-on-sapphire (“SOS”) substrates and silicon-on-glass (“SOG”) substrates, epitaxial layers of silicon on a base semiconductor foundation, and other semiconductor or optoelectronic materials, such as silicon-germanium, germanium, gallium arsenide, gallium nitride, and indium phosphide. The substrate may be doped or undoped.
Process flows and methods for processing a substrate are described herein in various embodiments. The substrate may include any material portion or structure of a device, particularly a semiconductor or other electronics device, and may, for example, be a base substrate structure, such as a semiconductor substrate or a layer on or overlying a base substrate structure such as a thin film. Thus, substrate is not intended to be limited to any particular base structure, underlying layer or overlying layer, patterned or unpatterned layer, but rather, is contemplated to include any such layer or base structure, and any combination of layers and/or base structures.
It is noted that various deposition processes can be used to form one or more of the material layers shown and described herein. For example, one or more depositions can be implemented using chemical vapor deposition (CVD), plasma enhanced CVD (PECVD), physical vapor deposition (PVD), atomic layer deposition (ALD), and/or other deposition processes. It is further noted that various etch processes can be used to etch one or more of the material layers shown and described herein. For example, one or more etch processes can be implemented using plasma etch processes, discharge etch processes, and/or other desired dry or wet etch processes.
Other operating variables for process steps can also be adjusted to control the various deposition and/or etch processes described herein. The operating variables may include, for example, the chamber temperature, chamber pressure, flowrates of gases, types of gases, and/or other operating variables for the processing steps. Variations can also be implemented while still taking advantage of the techniques described herein.
One skilled in the relevant art will recognize that the various embodiments may be practiced without one or more of the specific details, or with other replacement and/or additional methods, materials, or components. In other instances, well-known structures, materials, or operations are not shown or described in detail to avoid obscuring aspects of various embodiments of the invention. Similarly, for purposes of explanation, specific numbers, materials, and configurations are set forth in order to provide a thorough understanding of the invention. Nevertheless, the invention may be practiced without specific details. Furthermore, it is understood that the various embodiments shown in the figures are illustrative representations and are not necessarily drawn to scale.
Further modifications and alternative embodiments of the described systems and methods will be apparent to those skilled in the art in view of this description. It will be recognized, therefore, that the described systems and methods are not limited by these example arrangements. It is to be understood that the forms of the systems and methods herein shown and described are to be taken as example embodiments. Various changes may be made in the implementations. Thus, although the inventions are described herein with reference to specific embodiments, various modifications and changes can be made without departing from the scope of the present inventions. Accordingly, the specification and figures are to be regarded in an illustrative rather than a restrictive sense, and such modifications are intended to be included within the scope of the present inventions. Further, any benefits, advantages, or solutions to problems that are described herein with regard to specific embodiments are not intended to be construed as a critical, required, or essential feature or element of any or all the claims.