What is described is an electrical module with a microphone integrated therein.
A microphone module with an encapsulated MEMS microphone (MEMS=Micro Electromechanical System) is known from the publication J. J. Neumann, Jr., and K. J. Gabriel, “A fully-integrated CMOS-MEMS audio microphone,” 12th International Conference on Solid State Sensors, Actuators and Microsystems, 2003 IEEE, pp. 230-233. Described therein is a module having a volume for pressure equalization (back volume).
An electrical module with a built-in MEMS piezoresistive microphone is known from the publication D. P. Arnold et al., “A directional acoustic array using silicon micromachined piezoresisitive microphones,” J. Acoust. Soc. Am., vol. 113(1), 2003, pp. 289-298.
In the publication Mang-Nian Niu and Eun Sok Kim, “Piezoelectric Bimorph Microphone Built on Micromachined Parylene Diaphragm,” Journal of Microelectromechanical Systems, vol. 12, 2003 IEEE, pp. 892-898, a piezoelectric microphone having two piezoelectric layers of ZnO and a floating electrode arranged therebetween is described.
Described herein is an electrical module with a built-in MEMS microphone that has a high signal-to-noise ratio.
An electrical module with a built-in microphone is described. The module comprises a base plate with an acoustic channel formed therein. One embodiment includes a first cavity connected via a sound inlet opening to the exterior, with a MEMS microphone chip arranged therein, and a second cavity, suitable as an acoustic back volume and connected to the acoustic channel. The microphone chip may be connected to the base plate, arranged above an opening formed in the base plate, and connected via this opening to the acoustic channel buried in the base plate.
The first cavity can coincide with the exterior. The diaphragm of the microphone chip separates the first cavity from the acoustic channel, which opens into a second cavity. The second cavity may be alongside the first cavity. The acoustic channel may run at least in part beneath the two cavities.
A pressure balance between the second cavity and the acoustic channel is possible by air interchange. A fast air interchange between the first and the second cavity—i.e., an air interchange in a period on the order of the oscillation period of the microphone diaphragm in the operating frequency range—may be prevented by the diaphragm of the microphone chip. A slow air interchange (in a period that is longer than the largest oscillation period of the microphone diaphragm in the operating frequency range) between the two cavities is nevertheless possible via a ventilation opening whose cross-sectional size is clearly smaller than the cross-sectional size of the diaphragm.
The acoustic channel may be at least sufficiently large in cross section that the pressure change in the proximity of the diaphragm of the microphone chip can be rapidly compensated. The cross-sectional size of the acoustic channel or the channel openings may be at least 5% of the diaphragm surface area.
Microphones that detect sound pressure via diaphragms are dependent on a large diaphragm excursion in reaction to the sound intensity in order to obtain the desired characteristics regarding sensitivity and noise behavior. For small components with built-in microphones, the attainable excursion is limited by the small diaphragm surface area. For this reason, only weak electrical signals can be obtained when the diaphragm excursion is transformed into an electrical variable. The compliance of a diaphragm manufactured in a separate procedure can be worsened by a high internal mechanical stress caused by a biasing of the diaphragm.
MEMS microphones described here have an air chamber (first cavity) connected to a sound input opening as well as a back volume formed by the acoustic channel and the second area. Back volume refers to enclosed air volumes, with which an acoustic short-circuit—an undesired pressure balance between front and back of the vibrating diaphragm—is prevented. For each diaphragm deflection, this air volume produces a restoring force in addition to the restoring force caused by the flexible diaphragm characteristics.
In the microphone specified here, the back volume may be formed by a horizontal acoustic channel formed in the carrier substrate below the two side-by-side cavities, and by the volume of the other cavity. With this particularly large back volume, the relative pressure changes in the back volume, caused by the diaphragm vibrations, and the associated restoring force affecting the diaphragm can be kept small.
In an embodiment, the module comprises a cover that has a separation ridge connecting two opposite side faces of the cover and sealing to the base plate. Between the base plate and the cover, for instance, the first cavity connected via a sound inlet opening to the exterior and the second cavity isolated from it by the separation ridge of the cover are formed. The sound inlet opening may be arranged in the cover.
The acoustic channel and the second cavity together form a back volume. An advantage of this embodiment is that the back volume is arranged partly in the base plate and partly thereabove. Thus a large portion of the module volume is used as the acoustic back volume.
A microphone chip comprises a carrier substrate, with a diaphragm capable of vibrating. The microphone chip may have a piezoelectric layer as well metal layers and/or electrode structures connected thereto, clamped therein above a recess or an opening.
There may be an adhesion-promoting and/or sealing mechanism, e.g., a glue layer or an epoxy resin layer, between the cover and the plate.
The microphone chip is arranged above a first opening provided in the base plate, which opens into the acoustic channel and the first cavity. The base plate has a second opening, through which the acoustic channel is connected to the second cavity. The cross-sectional size of the first opening may correspond to roughly the cross-sectional size of the microphone chip's diaphragm. The cross-sectional size of the second opening may be selected in such a way that a fast air interchange between the acoustic channel and the second cavity is possible.
With the microphone, the restoring force acting on the diaphragm can be reduced and the diaphragm excursion increased.
In an embodiment, the base plate comprises a first layer with a recess associated with the acoustic channel formed in it, and a second layer arranged above the first layer, which partly covers the recess for forming an acoustic channel up to the above-mentioned openings. The separation ridge of the cover may seal to the second layer.
The first layer of the base plate can optionally be a glass-fiber reinforced organic laminate, or contain ceramics. The first layer of the base plate can comprise several homogeneous or different dielectric sublayers arranged one above another, between which structured metal layers are arranged. The sublayers can be formed from a glass-fiber reinforced organic laminate or ceramics. The second layer of the base plate is formed with a first layer, which may include another material such as ceramic, formed like a solder stop mask (of acrylate or epoxy resin in one embodiment).
The second cavity can house at least one chip element, e.g., a resistor, a capacitor, an inductor, a filter, an impedance transformer and an amplifier. The chip element may be suitable for surface mounting.
The microphone chip can also be mounted with a flip-chip construction method and electrically connected by bumps to electrical contacts arranged on the upper side of the base plate. In another embodiment, the microphone chip can be electrically connected by bonding wires to electrical contacts arranged on the upper side of the base plate. The interfaces formed by the opposing mounting surfaces of the chip and the base plate may be sealed by adhesion, underfilling or soldering, for example. A solder frame or a frame made of potting compound may be arranged between the chip and base plate. In the case of a solder frame, it is expedient to form a solderable metallization, whose outline corresponds to the form of the frame in the lateral plane, on the upper side of the base plate and the lower surface of the microphone chip.
In one embodiment, the cover comprises a cap of plastic or ceramic coated with a conductive layer. The cover can also be formed from metal.
In case of a large acoustic pressure, such large peak-to-peak oscillation amplitudes of the diaphragm can occur that a nonlinearity in the electroacoustic transformation of the diaphragm oscillation into an electrical signal, and therefore signal distortion, results. This problem is remedied in one embodiment, in which a negative-feedback compensation circuit is connected to a diaphragm. Deflection of the diaphragm provoked by the compensation circuit opposes the deflection of the diaphragm caused by the acoustic pressure, and compensates it to a large extent, so that the diaphragm oscillates with a reduced amplitude or does not oscillate at all. The electrical parameter produced by the compensation circuit, for example, a potential, is proportional to the acoustic pressure or the signal to be detected. Any desired electrical circuit suitable for negative feedback is applicable as the compensation circuit.
According to another embodiment of the microphone, the diaphragm is clamped to the carrier substrate only at one side, while its end opposite the clamped end can oscillate freely above an opening formed in the carrier substrate when an acoustic signal is applied. Clamping on both sides is also possible, in which case only two opposite diaphragm ends are arranged above the carrier substrate. A diaphragm carrier capable of oscillation that is sealed to the carrier substrate on all sides, e.g., a flexible film, may be stretched over the opening in the carrier substrate. The diaphragm is located on the diaphragm carrier.
The following materials are suitable as a piezoelectric layer in all embodiments: ZnO, lead zirconate titanate (PZT) and aluminum nitride.
It is proposed that a diaphragm with at least one piezoelectric layer be to a large extent symmetrical regarding its layer succession and layer thickness. In particular, bending moments that develop due to different coefficients of expansion of sequential layers are compensated even for substantial temperature discontinuities. Warping of the diaphragm can therefore be avoided over a broad temperature range. This measure is particularly applicable to a bimorph diaphragm structure.
A microphone will be described in detail below on the basis of embodiments and the related figures. The figures show embodiments of different versions of the microphone on the basis of schematic representations, not drawn to scale. Identical or identically functioning parts are labeled with the same reference symbols.
Microphone chip MCH is arranged on a base plate BP above an opening formed therein—sound opening IN in
A closed cavity, which is used as an acoustic back volume, is formed between microphone chip MCH, the upper side of the base plate and cover CAP. In addition, a chip component BE1 electrically connected to microphone chip MCH is arranged in this cavity. Additional chip components BE2 are located on the base plate BP outside of the closed cavity. The electrical connections between the module components just mentioned are buried in part in multilayered base plate BP.
Base plate BP comprises a lower layer S2 and an upper layer S1 arranged thereon. In layer S2, an acoustic channel AK is provided in the form of a blind hole or a trench extending in a longitudinal direction. As viewed from above, layer S1 may cover this blind hole completely, up to a first opening W1 and a second opening W2. Layer S1 can be formed, for instance, as a solder stop mask.
A cover CAP, which has a separation ridge TS that interconnects two opposing sides of the cover, is arranged on layer S1. Cover CAP may be sealed tightly on all sides to the upper side of base plate BP or to its upper layer S1. A glue layer KS can be arranged between them for adhesion promotion or sealing.
A microphone chip MCH, which is sealed tightly on all sides to layer S1, is arranged above first opening W1 of layer S1. A sealing frame KS1 is arranged between microphone chip MCH and layer S1. Sealing frame KS1 can be formed from potting compound in one embodiment. In another embodiment, sealing frame KS1 can be formed as a solder frame.
Two cavities HR1, HR2, which are connected by acoustic channel AK and isolated from one another by microphone chip MCH arranged in first cavity HR1, are formed between the S1 and cover CAP by separation ridge TS of the cover. First cavity HR1 is connected via sound inlet opening IN to the outside.
Chip components BE1, BE2, which are electrically connected via contacts K1-K3 arranged on the base plate to one another and to microphone chip MCH, are arranged in second cavity HR2.
On the upper side of microphone chip MCH, a contact surface AF is arranged, which is electrically connected, e.g., to the first electrode of the microphone, and to an electrical contact K1 located on layer S1 via a bonding wire. The contact K2 shown in
The acoustic back volume is formed by an air volume enclosed in acoustic channel AK and second cavity HR2. The essential point is that acoustic channel AK connects the remote cavity HR2 to the rear side of microphone chip MCH and thus makes available an expanded back volume.
Opening W2 connecting acoustic channel AK to second cavity HR2 is formed in that a part of layer S2, in the area of the recess formed therein, is not covered by layer S1.
In an embodiment, layer S1 is completely covered by the cover CAP, wherein separation ridge TS rests upon on this layer and is fixedly connected thereto by glue layer KS. In this example, the height of separation ridge TS is less than the height of the external walls of the cover.
Microphone chip MCH is fixedly connected to layer S1 by a frame-like glue layer KS1 (or solder layer) arranged in the peripheral area of microphone chip MCH. Thus, opening W1 of the acoustic channel is isolated from first cavity HR1. Layer KS1 serves to seal off the interface between microphone chip MCH and layer S1.
A bimorph diaphragm structure has the advantage over a diaphragm with only one piezoelectric layer in that it is possible to obtain twice as large an electrical signal for the same diaphragm curvature, since the potentials of the two piezoelectric layers are additive.
The layer thicknesses of the layers forming diaphragm M1 may be chosen to be symmetrical relative to metal layer ML2. The piezoelectric layers have the same thickness and the same orientation of their piezoelectric axes. The two outside metal layers ML1, ML3 may be formed with equal thickness.
On the upper side of carrier substrate SU, electrical contacts AE1, AE2 are arranged, which are electrically connected on the one hand via electrical leads to electrodes formed in metal layers ML1 and ML2, and on the other hand, via plated-through holes DK to contact surfaces AF arranged on the lower surface of the carrier substrate SU.
In an embodiment, a ventilation opening, which is small in relation to the cross-sectional size of the diaphragm and serves for a slow pressure equalization in the range of ≧100 ms, can be provided to connect the enclosed air volume (back volume of the microphone) to the outside. The pressure is equalized slowly in relation to the period of an acoustic signal with the largest wavelength in the operating range of the microphone. This opening can be arranged in the diaphragm or in a wall of the container enclosing the acoustic back volume.
The module is not limited to the number or the special form of the elements, microphones and/or microphone chips shown in the figures, or to the audible acoustic range from 20 Hz to 20 kHz. Additional piezoelectric acoustic sensors, such as distance sensors operating with ultrasound, are also possible. A microphone chip can be used in any desired signal processing module. Different embodiments can be combined.
It is possible to form the carrier substrate as a multilayer structure with structured printed conductors integrated therein to realize, for instance, electrical leads, inductors, capacitors and resistors.
Number | Date | Country | Kind |
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10 2005 008 512 | Feb 2005 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2006/001116 | 2/8/2006 | WO | 00 | 1/8/2008 |
Publishing Document | Publishing Date | Country | Kind |
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WO2006/089638 | 8/31/2006 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
2105010 | Sawyer | Jan 1938 | A |
3447217 | Kumada | Jun 1969 | A |
3587322 | Lobdell et al. | Jun 1971 | A |
3726002 | Greenstein et al. | Apr 1973 | A |
3735211 | Kapnias | May 1973 | A |
3980917 | Kakizaki et al. | Sep 1976 | A |
4127840 | House | Nov 1978 | A |
4222277 | Kurtz | Sep 1980 | A |
4277814 | Giachino et al. | Jul 1981 | A |
4314226 | Oguro et al. | Feb 1982 | A |
4424419 | Chaput et al. | Jan 1984 | A |
4454440 | Cullen | Jun 1984 | A |
4456796 | Nakagawa et al. | Jun 1984 | A |
4504703 | Schneiter et al. | Mar 1985 | A |
4533795 | Baumhauer | Aug 1985 | A |
4545440 | Treadway | Oct 1985 | A |
4558184 | Busch-Vishniac et al. | Dec 1985 | A |
4628740 | Ueda et al. | Dec 1986 | A |
4641054 | Takahata et al. | Feb 1987 | A |
4691363 | Khanna | Sep 1987 | A |
4737742 | Takoshima et al. | Apr 1988 | A |
4776019 | Miyatake | Oct 1988 | A |
4816125 | Muller et al. | Mar 1989 | A |
4817168 | Fidi | Mar 1989 | A |
4825335 | Wilner | Apr 1989 | A |
4866683 | Phillips | Sep 1989 | A |
4908805 | Sprenkels et al. | Mar 1990 | A |
4910840 | Sprenkels et al. | Mar 1990 | A |
4984268 | Brown et al. | Jan 1991 | A |
5059848 | Mariani | Oct 1991 | A |
5091051 | Greer | Feb 1992 | A |
5101543 | Cote et al. | Apr 1992 | A |
5146435 | Bernstein | Sep 1992 | A |
5151763 | Marek et al. | Sep 1992 | A |
5153379 | Guzuk et al. | Oct 1992 | A |
5178015 | Loeppert et al. | Jan 1993 | A |
5184107 | Maurer | Feb 1993 | A |
5216490 | Greiff et al. | Jun 1993 | A |
5257547 | Boyer | Nov 1993 | A |
5357807 | Guckel et al. | Oct 1994 | A |
5394011 | Yamamoto et al. | Feb 1995 | A |
5408731 | Berggvist et al. | Apr 1995 | A |
5449909 | Kaiser et al. | Sep 1995 | A |
5452268 | Bernstein | Sep 1995 | A |
5459368 | Onishi et al. | Oct 1995 | A |
5465008 | Goetz et al. | Nov 1995 | A |
5477008 | Pasqualoni et al. | Dec 1995 | A |
5490220 | Loeppert | Feb 1996 | A |
5506919 | Roberts | Apr 1996 | A |
5531787 | Lesinski et al. | Jul 1996 | A |
5545912 | Ristic et al. | Aug 1996 | A |
5573435 | Grabbe et al. | Nov 1996 | A |
5592391 | Muyshondt et al. | Jan 1997 | A |
5593926 | Fujihira | Jan 1997 | A |
5650685 | Kosinski et al. | Jul 1997 | A |
5659195 | Kaiser et al. | Aug 1997 | A |
5712523 | Nakashima et al. | Jan 1998 | A |
5739585 | Akram et al. | Apr 1998 | A |
5740261 | Loeppert et al. | Apr 1998 | A |
5748758 | Menasco, Jr. et al. | May 1998 | A |
5821665 | Onishi et al. | Oct 1998 | A |
5831262 | Greywall et al. | Nov 1998 | A |
5838551 | Chan | Nov 1998 | A |
5852320 | Ichihashi | Dec 1998 | A |
5870482 | Loeppert et al. | Feb 1999 | A |
5872397 | Diffenderfer et al. | Feb 1999 | A |
5886876 | Yamaguchi | Mar 1999 | A |
5889872 | Sooriakumar et al. | Mar 1999 | A |
5901046 | Ohta et al. | May 1999 | A |
5923995 | Kao et al. | Jul 1999 | A |
5939968 | Nguyen et al. | Aug 1999 | A |
5990418 | Bivona et al. | Nov 1999 | A |
5999821 | Kaschke | Dec 1999 | A |
6012335 | Bashir et al. | Jan 2000 | A |
6052464 | Harris | Apr 2000 | A |
6057222 | Pahl et al. | May 2000 | A |
6075867 | Bay et al. | Jun 2000 | A |
6078245 | Fritz et al. | Jun 2000 | A |
6108184 | Minervini et al. | Aug 2000 | A |
6118881 | Quinlan et al. | Sep 2000 | A |
6136175 | Stelzl et al. | Oct 2000 | A |
6136419 | Fasano et al. | Oct 2000 | A |
6150753 | DeCastro | Nov 2000 | A |
6157546 | Petty et al. | Dec 2000 | A |
6163071 | Yamamura | Dec 2000 | A |
6178249 | Hietanen et al. | Jan 2001 | B1 |
6182342 | Sawin | Feb 2001 | B1 |
6187249 | Lewellin | Feb 2001 | B1 |
6191928 | Rector et al. | Feb 2001 | B1 |
6242842 | Pahl et al. | Jun 2001 | B1 |
6282072 | Minervini et al. | Aug 2001 | B1 |
6310420 | Pahl et al. | Oct 2001 | B1 |
6324907 | Halteren et al. | Dec 2001 | B1 |
6398943 | Arens-Fischer et al. | Jun 2002 | B1 |
6400065 | Toda et al. | Jun 2002 | B1 |
6413408 | Berger et al. | Jul 2002 | B1 |
6433412 | Ando et al. | Aug 2002 | B2 |
6437449 | Foster | Aug 2002 | B1 |
6439869 | Seng et al. | Aug 2002 | B1 |
6449828 | Pahl et al. | Sep 2002 | B2 |
6492194 | Bureau et al. | Dec 2002 | B1 |
6519822 | Stelzl et al. | Feb 2003 | B1 |
6522762 | Mullenborn | Feb 2003 | B1 |
6528924 | Stelzl et al. | Mar 2003 | B1 |
6530515 | Glenn et al. | Mar 2003 | B1 |
6555758 | Stelzl et al. | Apr 2003 | B1 |
6566672 | Schlough et al. | May 2003 | B1 |
6594369 | Une | Jul 2003 | B1 |
6613605 | Pace | Sep 2003 | B2 |
6614911 | Watson et al. | Sep 2003 | B1 |
6621392 | Volant et al. | Sep 2003 | B1 |
6625031 | Sano et al. | Sep 2003 | B2 |
6649446 | Goetz et al. | Nov 2003 | B1 |
6674159 | Peterson et al. | Jan 2004 | B1 |
6685168 | Stelzl et al. | Feb 2004 | B1 |
6710840 | Umemoto | Mar 2004 | B2 |
6722030 | Stelzl et al. | Apr 2004 | B1 |
6732588 | Mullenborn et al. | May 2004 | B1 |
6781231 | Minervini | Aug 2004 | B2 |
6800987 | Toda | Oct 2004 | B2 |
6809413 | Peterson et al. | Oct 2004 | B1 |
6829131 | Loeb et al. | Dec 2004 | B1 |
6838739 | Stelzl et al. | Jan 2005 | B2 |
6838972 | Minervini | Jan 2005 | B1 |
6904155 | Yonehara et al. | Jun 2005 | B2 |
6909183 | Feiertag et al. | Jun 2005 | B2 |
6924429 | Kasai et al. | Aug 2005 | B2 |
6924974 | Stark | Aug 2005 | B2 |
6930364 | Bruner | Aug 2005 | B2 |
6982380 | Hoffmann et al. | Jan 2006 | B2 |
7003127 | Sjursen | Feb 2006 | B1 |
7053456 | Matsuo | May 2006 | B2 |
7072482 | Van Doorn et al. | Jul 2006 | B2 |
7080442 | Kawamura et al. | Jul 2006 | B2 |
7092539 | Sheplak et al. | Aug 2006 | B2 |
7094626 | Stelzl et al. | Aug 2006 | B2 |
7146016 | Pedersen | Dec 2006 | B2 |
7166910 | Minervini | Jan 2007 | B2 |
7242089 | Minervini | Jul 2007 | B2 |
7259041 | Stelzl et al. | Aug 2007 | B2 |
7298856 | Tajima et al. | Nov 2007 | B2 |
7381589 | Minervini | Jun 2008 | B2 |
7388281 | Krueger et al. | Jun 2008 | B2 |
7434305 | Minervini | Oct 2008 | B2 |
7439616 | Minervini | Oct 2008 | B2 |
7492019 | Carley | Feb 2009 | B2 |
7518201 | Stelzl et al. | Apr 2009 | B2 |
7518249 | Krueger et al. | Apr 2009 | B2 |
7537964 | Minervini | May 2009 | B2 |
7544540 | Bauer et al. | Jun 2009 | B2 |
7608789 | Kruger et al. | Oct 2009 | B2 |
7692288 | Zhe | Apr 2010 | B2 |
7903831 | Song | Mar 2011 | B2 |
8018049 | Minervini | Sep 2011 | B2 |
20010010444 | Pahl et al. | Aug 2001 | A1 |
20020067663 | Loeppert et al. | Jun 2002 | A1 |
20020074239 | Berger et al. | Jun 2002 | A1 |
20020076910 | Pace | Jun 2002 | A1 |
20020102004 | Minervini | Aug 2002 | A1 |
20020110256 | Watson et al. | Aug 2002 | A1 |
20030010530 | Scheel et al. | Jan 2003 | A1 |
20030034536 | Scheeper et al. | Feb 2003 | A1 |
20030035558 | Kawamura et al. | Feb 2003 | A1 |
20030047806 | Stelzl et al. | Mar 2003 | A1 |
20030124829 | Pace | Jul 2003 | A1 |
20030133588 | Pedersen | Jul 2003 | A1 |
20030151133 | Kinayman et al. | Aug 2003 | A1 |
20030153116 | Carley et al. | Aug 2003 | A1 |
20040032705 | Ma | Feb 2004 | A1 |
20040046245 | Minervini | Mar 2004 | A1 |
20040058473 | Feiertag et al. | Mar 2004 | A1 |
20040064941 | Dozier et al. | Apr 2004 | A1 |
20040118595 | Flammer et al. | Jun 2004 | A1 |
20040150939 | Huff | Aug 2004 | A1 |
20040161530 | Stark | Aug 2004 | A1 |
20040231872 | Arnold et al. | Nov 2004 | A1 |
20040237299 | Stelzl et al. | Dec 2004 | A1 |
20040239449 | Stelzl et al. | Dec 2004 | A1 |
20050018864 | Minervini | Jan 2005 | A1 |
20050034888 | Hoffman et al. | Feb 2005 | A1 |
20050069164 | Muthuswamy et al. | Mar 2005 | A1 |
20050121785 | Stelzl et al. | Jun 2005 | A1 |
20050185812 | Minervini | Aug 2005 | A1 |
20050218488 | Matsuo | Oct 2005 | A1 |
20050242420 | Matsuda et al. | Nov 2005 | A1 |
20060151203 | Krueger et al. | Jul 2006 | A1 |
20060157841 | Minervini | Jul 2006 | A1 |
20060249802 | Stelzl et al. | Nov 2006 | A1 |
20070069354 | Dangelmaier et al. | Mar 2007 | A1 |
20070082421 | Minervini | Apr 2007 | A1 |
20070099327 | Hartzell et al. | May 2007 | A1 |
20070127982 | Bohlen et al. | Jun 2007 | A1 |
20070189558 | Ogura et al. | Aug 2007 | A1 |
20070201715 | Minervini | Aug 2007 | A1 |
20070202627 | Minervini | Aug 2007 | A1 |
20070222056 | Bauer et al. | Sep 2007 | A1 |
20080038577 | Kruger et al. | Feb 2008 | A1 |
20080048317 | Krueger et al. | Feb 2008 | A1 |
20080279407 | Pahl | Nov 2008 | A1 |
20090001553 | Pahl et al. | Jan 2009 | A1 |
20090071710 | Stelzl et al. | Mar 2009 | A1 |
20090080682 | Ogura et al. | Mar 2009 | A1 |
20090104415 | Schmajew et al. | Apr 2009 | A1 |
20090127697 | Pahl | May 2009 | A1 |
20110186943 | Pahl et al. | Aug 2011 | A1 |
20110210409 | Minervini | Sep 2011 | A1 |
Number | Date | Country |
---|---|---|
2315417 | Feb 2001 | CA |
198 06 818 | Nov 1999 | DE |
199 61 842 | Jul 2001 | DE |
101 45 100 | May 2002 | DE |
103 03 263 | Aug 2004 | DE |
202005001559 | Jun 2005 | DE |
10 2005 008 512 | Aug 2006 | DE |
0077615 | Apr 1983 | EP |
0774888 | May 1997 | EP |
0 742 643 | Feb 2002 | EP |
2 799 883 | Apr 2001 | FR |
55-134942 | Oct 1980 | JP |
57-100754 | Jun 1982 | JP |
57-207500 | Dec 1982 | JP |
61-033509 | Dec 1982 | JP |
58-030394 | Feb 1983 | JP |
58-203016 | Nov 1983 | JP |
62-230297 | Oct 1987 | JP |
03-116899 | May 1991 | JP |
04-281696 | Oct 1992 | JP |
06-334298 | Dec 1994 | JP |
07-212180 | Aug 1995 | JP |
07-212181 | Aug 1995 | JP |
10-321666 | Dec 1998 | JP |
11-508101 | Jul 1999 | JP |
2001-157298 | Jun 2001 | JP |
2001-339796 | Dec 2001 | JP |
2002-134875 | May 2002 | JP |
2003-078981 | Mar 2003 | JP |
2003-508998 | Mar 2003 | JP |
2003-304595 | Oct 2003 | JP |
2004-079776 | Mar 2004 | JP |
2004-229200 | Aug 2004 | JP |
2004-537182 | Dec 2004 | JP |
2005-198051 | Jul 2005 | JP |
2007-060661 | Mar 2007 | JP |
2007-524514 | Aug 2007 | JP |
WO9701258 | Jan 1997 | WO |
WO9943084 | Aug 1999 | WO |
WO9956390 | Nov 1999 | WO |
WO0042636 | Jul 2000 | WO |
WO0070630 | Nov 2000 | WO |
WO0119134 | Mar 2001 | WO |
WO0120948 | Mar 2001 | WO |
WO0126136 | Apr 2001 | WO |
WO0141497 | Jun 2001 | WO |
WO0215636 | Feb 2002 | WO |
WO0217364 | Feb 2002 | WO |
WO02045463 | Jun 2002 | WO |
WO03017364 | Feb 2003 | WO |
WO2004019490 | Mar 2004 | WO |
WO2005036698 | Apr 2005 | WO |
WO2005086532 | Sep 2005 | WO |
WO2005086535 | Sep 2005 | WO |
WO2006089638 | Aug 2006 | WO |
WO2006089641 | Aug 2006 | WO |
WO2007022249 | Feb 2007 | WO |
Number | Date | Country | |
---|---|---|---|
20080247585 A1 | Oct 2008 | US |