The present invention relates to electronic components having lead frames, and more particularly to solid electrolytic capacitors.
The capacitor element 2 comprises an anode body 20 which is a sintered body of a valve metal, a dielectric oxide coating 21 formed over the periphery of the anode body 20, and a cathode layer 5 provided over the coating 21.
The cathode layer 5 comprises a solid electrolyte layer 3 and a carbon-silver paste layer 6. An anode lead 22 in the form of a pin extends from one end of the anode body 20, and the anode lead frame 9 is joined to the anode lead 22 by resistance welding. The cathode lead frame 90 is attached to the cathode layer 5 with an electrically conductive adhesive 4.
The term “valve metal” refers to a metal which forms an extremely compacted and durable dielectric oxide coating when treated by electrolytic oxidation. Examples of such metals are Al (aluminum), Ta (tantalum), Ti (titanium), Nb (niobium), etc. Further solid electrolytes include manganese dioxide and like electrically conductive inorganic materials, and polythiophene-type and polypyrrole-type electrically conductive high polymers in addition to TCNQ complex salt.
The anode lead 22 is thinner than the anode lead frame 9, exhibits a low bond strength if attached to the frame 9 with the conductive adhesive 4 and is therefore joined thereto by resistance welding. On the other hand, if the cathode lead frame 90 is joined to the capacitor element 2 by resistance welding, the cathode layer 5 to be clamped by the resistance welding electrode (not shown) is likely to become thereby damaged, so that the conductive adhesive 4 is used for the layer 5.
In addition to being amenable to bonding with the conductive adhesive 4, the material of the lead frames 9, 90 must be diminished in surface oxidation, and needs to have mechanical characteristics such as ease of soldering.
As a material having such properties, an alloy is in use which consists mainly of Cu and contains Fe, Ni, Sn, Cr and Zr added thereto (see the publication of JP-A No. 1988-293147). Cu is lower in mechanical strength than Fe or the like and therefore given an enhanced mechanical strength by the addition of Fe and other elements.
However, the alloy is higher in coefficient of thermal expansion than the metals previously used for the lead frames 9, 90, such that the lead frame made from the alloy is liable to expand when exposed to the heat applied for making the housing 7 by injection molding. Such an alloy is of course higher than the conductive adhesive in coefficient of thermal expansion. After the solid electrolytic capacitor 1 has been fabricated, voltage of about 10 V is applied across the lead frames 9, 90 only for a specified period of time so as to pass overcurrent through a faulty portion of the dielectric oxide coating 21. The faulty portion becomes locally heated, releasing a dopant within the solid electrolyte layer therefrom to provide insulation and repair the faulty portion. This process is termed “aging.” During this aging, the faulty portion of the coating 21 will rise in temperature owing to the flow of overcurrent therethrough, and the heat will be delivered to the lead frames 9, 90.
Accordingly, the thermal expansion of the lead frames 9, 90 exerts pressure, causing the conductive adhesive 4 as cured to develop cracks. The cracking will then shift the position of the lead frames 9, 90 or make the frames removable easily. The shift of the position alters the areas of contact of the lead frames 9, 90 with the capacitor element 2, consequently producing variations in ESR (equivalent series resistance). This is likely to entail a lower yield when solid electrolytic capacitors 1 are produced in large quantities.
An object of the present invention is to provide an electronic component, especially a solid electrolytic capacitor having lead frames 9, 90 which are unlikely to be shifted in position relative to an element 2 or to be removed therefrom.
The present invention provides an electronic component wherein a lead frame 90 is attached to an element 2 with an electrically conductive adhesive 4.
The lead frame 90 has an adhesive filling portion 40 at a part thereof having a lower surface opposed to the element 2, and the filling portion 40 has inside thereof filled with the conductive adhesive 4. The adhesive filling portion 40 is one of a hole 8, cavity, cutout 80 and groove 6.
Since the conductive adhesive 4 as cured fills the interior of the filling portion 40, the lead frame 90 is correctly positioned in place on the capacitor element 2. Accordingly, even if the lead frame 90 thermally expands, causing the layer of adhesive 4 to develop cracks, the lead frame 90 remains unaltered in position within a horizontal plane relative to the capacitor element 2. Consequently, the area of contact of the cathode lead frame 90 with the capacitor element 2 remains unchanged, producing no variations, for example, in ESR and resulting in a higher yield when the solid electrolytic capacitor 1 is produced in large quantities.
a) is a bottom view of another cathode lead frame;
b) is a view in section taken along a plane containing the line B—B of
(First Embodiment)
The present invention is characterized in that the cathode lead frame 90 has adhesive filling portions 40 which are more specifically in the form of holes, bores or grooves and which are filled with an electrically conductive adhesive 4. As in the prior art, the cathode lead frame 90 is made from an alloy comprising Cu, and Fe and other elements which are added to the Cu. However, the material of the frame is not limited to this alloy.
Even if the lead frame 90 thermally expands, causing the layer of conductive adhesive 4 to develop cracks, the lead frame 90 remains unaltered in position within a horizontal plane relative to the capacitor element 2 since the holes are filled with the adhesive 4. Consequently, the area of contact of the cathode lead frame 90 with the capacitor element 2 remains unchanged, producing no variations, for example, in ESR and resulting in an improved yield when the solid electrolytic capacitor 1 is produced in large quantities. Further there is no need to apply an excess of adhesive 4 to give an enhanced bond strength, hence a production cost reduction.
Although the holes 8 are formed in the cathode lead frame 90 according to the above embodiment, semicircular, triangular or quadrilateral cutouts 80 may alternatively be formed in the side edges of the lead frame 90 as seen in
(Second Embodiment)
a) is a bottom view of a cathode lead frame 90 according to this embodiment, and
A plurality of grooves 6, 6 may be formed in a radial arrangement in the bottom surface of the lead frame 90 as shown in
Alternatively, a plurality of grooves 6, 60 may be so formed as to intersect one another as seen in
The bottom surface of the lead frame 90 is divided into a plurality of rectangular frame segments 91 by the intersecting grooves 6, 60. For the sake of convenience of illustration, it is assumed that four frame segments 91, 91 are provided widthwise of the frame 90. The conductive adhesive 4 is applied to the bottom surface and opposite side portions of the frame 90. Suppose the lead frame 90 has a width of L1, and the frame segments 91 have a width of L2.
When the unit frame 91 surrounded by the grooves 6, 60 (e.g., the portion C in
Further unless the grooves 6, 60 are provided, the conductive adhesive 4 applied to the bottom surface of the lead frame 90 will be drawn sideways by an amount of expansion corresponding to the widthwise dimension L1 of the lead frame 90, whereas with the lead frame 90 provided with the intersecting grooves 6, 60, the adhesive 4 applied to the bottom surface of the frame 90 is drawn sideways by an amount of expansion corresponding to the combined widthwise dimension of L2×4 of four frame segments 91. Since the widthwise dimensions have the relationship of L1>L2×4, the amount of adhesive 4 as cured and drawn sideways is smaller when the lead frame 90 is provided with the intersecting grooves 6, 60.
Further unless the grooves 6, 60 are provided, the adhesive 4 applied to the side portion of the lead frame 90 is pressed by an amount of expansion corresponding to the widthwise dimension L1 of the frame 90. On the other hand, with the lead frame 90 provided with the intersecting grooves 6, 60, the adhesive applied to the side portion of the frame 90 is pressed by an amount of expansion corresponding to the widthwise dimension L2 of the frame segment 91.
This reduces the likelihood of the adhesive 4 cracking, consequently preventing the shift of the position of the lead frame 90 within a horizontal plane and achieving a higher yield when the solid electrolytic capacitor 1 is produced in quantities.
The first grooves 6 and the second grooves 60 may be formed as inclined with respect to the widthwise direction of the lead frame 90 as shown in
Although the foregoing embodiments have been described with reference to the solid electrolytic capacitor as an electronic component having lead frames 9, 90, the invention may be embodied as other electronic components such as ICs. Anode leads 22 include those in the form of foil. When such an anode lead 22 is to be attached to the anode lead frame 9 with the conductive adhesive 4, holes or the like may be formed in the anode lead frame 9.
The lead frames 9, 90 become heated not only when the solid electrolytic capacitor 1 is fabricated but also when reflow soldering is performed for the solid electrolytic capacitor. The lead frames 9, 90 of the capacitor of the invention can be prevented from shifting in position also when this method of soldering is practiced.
Number | Date | Country | Kind |
---|---|---|---|
2002-360064 | Dec 2002 | JP | national |
2003-305365 | Aug 2003 | JP | national |
Number | Name | Date | Kind |
---|---|---|---|
6046902 | Nakagawa et al. | Apr 2000 | A |
6188566 | Aoyama | Feb 2001 | B1 |
6451622 | Sawai | Sep 2002 | B1 |
6473291 | Stevenson | Oct 2002 | B1 |
6751086 | Matsumoto | Jun 2004 | B2 |
6813141 | Kuroyanagi | Nov 2004 | B2 |
Number | Date | Country |
---|---|---|
8-148392 | Jun 1996 | JP |
WO 0055875 | Sep 2000 | WO |
Number | Date | Country | |
---|---|---|---|
20040113242 A1 | Jun 2004 | US |