The present patent application claims the priority benefit of French patent application FR16/62301 which is herein incorporated by reference.
The present invention generally concerns electronic devices and methods of manufacturing the same.
For certain applications, it is desirable to be able to form electrical insulation trenches in a semiconductor substrate of an electronic circuit to electrically insulate substrate portions from one another. An example of application corresponds to the forming of optoelectronic devices made up of semiconductor materials. The term “optoelectronic devices” is used to designate devices capable of converting an electric signal into an electromagnetic radiation or conversely, and especially devices dedicated to detecting, measuring, or emitting an electromagnetic radiation, or devices dedicated to photovoltaic applications.
Optoelectronic devices may comprise optoelectronic components, for example, light-emitting diodes, formed on the semiconductor substrate. The electrical insulation trenches may be formed in the substrate to electrically insulate a substrate portion for each optoelectronic component.
Electronic circuit 5 may further comprise, on surface 12, a layer 30 of a material promoting the forming of optoelectronic components, not shown. Layer 30 may be conductive and is, in this case, open at the level of trench 14. Electronic circuit 5 may further comprise an electrically-insulating layer or a stack of electrically-insulating layers covering surface 12 and/or surface 13 and trench 14. As an example, two electrically-insulating layers 32, 34 have been shown as an example in
Lateral walls 20 may be substantially parallel, as shown in
Width L and thickness E are determined according to the voltage behavior desired for trench 14, that is, the minimum voltage, called breakdown voltage, applied between portions 16 and 18 of substrate 10 at the level of the surface 12 for which trench 14 becomes electrically conductive. Dimensions L and E are generally determined by simulation.
However, in certain cases, the breakdown voltage really measured may be smaller than the breakdown voltage provided by simulation.
An object of an embodiment is to provide an electronic circuit comprising electrical insulation trenches overcoming all or part of the disadvantages of existing trenches.
Another object of an embodiment is to increase the breakdown voltage of electrical insulation trenches.
Another object of an embodiment is for the method of manufacturing electrical insulation trenches to comprise a small number of additional steps with respect to a method of manufacturing conventional electrical insulation trenches.
Another object of an embodiment is for the electrical insulation trenches to form neither bulged areas nor depressions on the upper surface of the substrate.
Thus, an embodiment provides an electronic device comprising a semiconductor substrate having first and second opposite surfaces and comprising an electrical insulation trench extending in the substrate from the first surface to the second surface, the electrical insulation trench comprising lateral walls, an electrically-insulating layer covering the lateral walls, and a core made of a filling material separated from the substrate by the insulating layer and comprising an electrically-insulating portion extending in the substrate from the first surface and covering the core.
According to an embodiment, the first surface is planar at the location of the electrical insulation trench.
According to an embodiment, the insulating portion is a thermal oxide.
According to an embodiment, the insulating portion is made of silicon oxide.
According to an embodiment, the filling material is polysilicon.
According to an embodiment, the electrically-insulating portion extends laterally in the substrate with respect to the rest of the electrical insulation trench.
According to an embodiment, the device comprises at least first and second optoelectronic components capable of emitting an electromagnetic radiation or of absorbing an electromagnetic radiation, the first optoelectronic component resting on a first portion of the substrate and the second optoelectronic component resting on a second portion of the substrate, the electrical insulation trench separating the first portion from the second portion.
An embodiment also provides a method of manufacturing an electronic device, such as previously defined, comprising the steps of:
(a) forming a first opening into the substrate from the first surface;
(b) forming a layer of the material of the electrically-insulating layer in the first opening and on the first surface;
(c) forming a layer of the filling material in the opening and on the first surface; and
(d) forming the insulating portion.
According to an embodiment, the step comprises a thermal oxidation step.
According to an embodiment, step (d) comprises a thermal oxidation step.
According to an embodiment, step (d) comprises a chemical vapor deposition step followed by a step of thermal anneal at more than 500° C.
According to an embodiment, the method further comprises a step (e) of etching the portions of the layer of the material of the electrically-insulating layer and of the layer of the filling material present on the first surface.
According to an embodiment, step (e) is carried out before step (d).
According to an embodiment, step (d) is carried out before step (e).
According to an embodiment, the method further comprises forming, before step (d), a second opening into the layer of the material of the electrically-insulating layer, the layer of the filling material on the first surface, and the substrate at the location of the insulation portion.
The foregoing and other features and advantages will be discussed in detail in the following non-limiting description of specific embodiments in connection with the accompanying drawings, among which:
The same elements have been designated with the same reference numerals in the various drawings and, further, the various drawings are not to scale. In the following description, when reference is made to terms qualifying the relative position, such as term “top”, “bottom”, “upper”, “lower”, etc., reference is made to the orientation of drawings or to an electronic device in a normal position of use.
For clarity, only those steps and elements which are useful to the understanding of the described embodiments have been shown and are detailed. In particular, the electronic components of an electronic circuit are well known in the art and are not described in detail hereafter. In the following description, expressions “substantially”, “around”, and “approximately” mean “to within 10%”, preferably to within 5%.
The inventors have shown that, for the electrical insulation trench structure 14 shown in
An embodiment provides increasing the electrical insulation at the top of the electrical insulation trench to avoid the forming of an electric arc in this area. This enables to increase the breakdown voltage of the electrical insulation trench, and thus the maximum voltage of the electronic circuit.
Substrate 10 may correspond to a monoblock structure or to a layer covering a support made of another material. Substrate 10 is preferably a semiconductor substrate, for example, a substrate made of silicon, of germanium, of silicon carbide, of a III-V compound, such as GaN or GaAs, or a ZnO substrate. Preferably, substrate 10 is a single-crystal silicon substrate. Preferably, it is a semiconductor substrate compatible with manufacturing methods implemented in microelectronics. Substrate 10 may correspond to a multilayer structure of silicon-on-insulator type, also called SOI. As a variation, substrate 10 may correspond to a BSOI (Bonded Silicon On Insulator) structure. As a variation, substrate 10 may correspond to a stack of a plurality of silicon layers having different dopant concentrations, for example, of type P. The thickness of substrate 10 of electronic circuit 45, obtained at the end of the method of manufacturing electronic circuit 45, which, as described in further detail hereafter, comprises a thinning step, may be in the range from 2 μm to 150 μm.
Substrate 10 may be heavily doped, lightly-doped, or non-doped. In the case where the substrate is heavily doped, semiconductor substrate 10 may be doped so as to lower the electric resistivity down to a resistivity close to that of metals, preferably lower than a few mohm·cm. Substrate 10 for example is a heavily-doped substrate having a dopant concentration in the range from 5*1016 atoms/cm3 to 2*1020 atoms/cm3. In the case where the substrate is lightly-doped of a first conductivity type, for example, with a dopant concentration smaller than or equal to 5*1016 atoms/cm3, preferably substantially equal to 1015 atoms/cm3, a doped region of the first conductivity type or of a second conductivity type, opposite to the first type, more heavily-doped than the substrate, which extends in substrate 10 from surface 12, may be provided. In the case of a silicon substrate 10, examples of P-type dopants are boron (B) or indium (In) and examples of N-type dopants are phosphorus (P), arsenic (As), or antimony (Sb).
When present, layer 30 may be made of a material favoring the growth of semiconductor elements, not shown. Layer 30 may correspond to a single layer or to a stack of at least two layers. As an example, layer 30 comprises a nitride, a carbide, or a boride of a transition metal from column IV, V, or VI of the periodic table of elements, or a combination of these compounds. As an example, layer 30 may be made of aluminum nitride (AlN), of aluminum oxide (Al2O3), of boron (B), of boron nitride (BN), of titanium (Ti), of titanium nitride (TiN), of tantalum (Ta), of tantalum nitride (TaN), of hafnium (Hf), of hafnium nitride (HfN), of niobium (Nb), of niobium nitride (NbN), of zirconium (Zr), of zirconium borate (ZrB2), of zirconium nitride (ZrN), of silicon carbide (SiC), of tantalum carbo-nitride (TaCN), of magnesium nitride in MgxNy form, where x is approximately equal to 3 and y is approximately equal to 2, for example, magnesium nitride in form Mg3N2. Layer 30 may be doped with the same conductivity type as substrate 10. Layer 30 for example has a thickness in the range from 1 nm to 300 nm, preferably in the range from 10 nm to 60 nm. As a variation, layer 30 may be replaced with pads, having a single-layer or multilayer structure, resting on surface 12 of substrate 10, each semiconductor element resting on one of the pads.
Each insulating layer 32, 34 of the stack of insulating layers may be made of a dielectric material, for example, of silicon oxide (SiO2), of silicon nitride (SixNy, where x is approximately equal to 3 and y is approximately equal to 4, for example, Si3N4), of silicon oxynitride (particularly of general formula SiOxNy, for example, Si2ON2), of hafnium oxide (HfO2), or of diamond. As an example, the thickness of the stack of insulating layers 32, 34 is in the range from 25 nm to 2 μm, for example, equal to approximately 150 nm. Each insulating layer 32, 34 may be formed by a deposition method, particularly a chemical vapor deposition (CVD) method, particularly a plasma-enhanced chemical vapor deposition (PECVD) method, for example, at temperatures in the range from 200° C. to 450° C., or a sub-atmospheric chemical vapor deposition (SACVD) method. However, other deposition methods may be implemented.
Insulating layer 35 may be made of a dielectric material, for example, of silicon oxide (SiO2), of silicon nitride (SixNy, where x is approximately equal to 3 and y is approximately equal to 4, for example, Si3N4), of silicon oxynitride (particularly of general formula SiOxNy, for example, Si2ON2), of hafnium oxide (HfO2), of diamond or of an electrically-insulating polymer. Insulating layer 35 may be formed by the methods previously described for layers 32 and 34.
Insulating layer 24 of trench 42 may be made of a dielectric material, for example, of silicon oxide (SiO2), of silicon nitride (SixNy, where x is approximately equal to 3 and y is approximately equal to 4, for example, Si3N4), of silicon oxynitride (particularly of general formula SiOxNy, for example, Si2ON2), of hafnium oxide (HfO2), or of diamond. Preferably, insulating layer 24 is made of silicon oxide. Preferably, insulating layer 24 is made of thermal silicon oxide. Insulating layer 24 may be formed by a deposition method, particularly a CVD-type method, particularly by PECVD-type deposition, for example, at temperatures in the range from 200° C. to 450° C., or of SACVD type. However, other deposition methods may be implemented. Insulating layer 24 may be formed by thermal oxidation, particularly at temperatures in the range from 900° C. to 1100° C. Dry or wet thermal oxidation methods may be used. Preferably, insulating layer 24 is formed by thermal oxidation.
Insulating portion 44 of trench 42 may be made of a dielectric material, for example, of silicon oxide (SiO2), of silicon nitride (SixNy, where x is approximately equal to 3 and y is approximately equal to 4, for example, Si3N4), of silicon oxynitride (particularly of general formula SiOxNy, for example, Si2ON2), of hafnium oxide (HfO2), or of diamond. Preferably, insulating portion 44 is made of silicon oxide. Preferably, insulating portion 44 is made of thermal silicon oxide. Insulating portion 44 may be formed by a deposition method, particularly a method of chemical vapor deposition (CVD) type, particularly by plasma-enhanced chemical vapor deposition (PECVD), for example, at temperatures in the range from 200° C. to 450° C. Insulating portion 44 may be formed by thermal oxidation, particularly at temperatures in the range from 900° C. to 1100° C. Dry or wet thermal oxidation methods may be used. Preferably, insulating portion 44 is formed by thermal oxidation. According to another embodiment, insulating portion 44 is formed by the deposition of a layer SiO2 followed by a high-temperature anneal (for example, between 700° C. and 1000° C.) to increase the oxide density. This advantageously enables to avoid the diffusion of dopants from substrate 10 and from core 26 into insulating portion 44, which might decrease the breakdown voltage of insulating portion 44.
Core 26 is preferably made of a semiconductor material, for example, made of silicon, of germanium, of silicon carbide, of a III-V compound, such as GaN or GaAs, or a II-VI compound such as ZnO. Preferably, core 26 is made of polysilicon. Preferably, it is a material compatible with manufacturing methods implemented in microelectronics. Core 26 may correspond to a multilayer structure of different semiconductor materials. Core 26 may be heavily doped, lightly doped, or non-doped.
Dimensions L, E, L′, P, and P′ vary according to the targeted applications. According to an embodiment, width L of trench 42 varies from 0.5 μm to 10 μm and preferably from 2 μm to 4 μm. According to an embodiment, thickness E of insulating layer 24 varies from 50 nm to 1000 nm. Thickness P of substrate 10 after the thinning varies from 2 μm to 150 μm. Aspect ratio P/L may be in the range from 1 to 40, for example, equal to approximately 25. According to an embodiment, depth P′ of insulating portion 44 varies from 50 nm to 1000 nm. In the embodiment shown in
The method further comprises at least subsequent steps of forming layers 30, 32, 34, a step of forming the optoelectronic components, a step of thinning substrate 10 on the side of the surface opposite to surface 12, the thickness of substrate 10 being decreased at least to reach insulating layer 24, and a step of forming layer 35 and possibly contacts pads through layer 35.
The initial steps of the method are the same as those previously described in relation with
The method further comprises at least subsequent steps of forming layers 30, 32, 34, a step of forming the optoelectronic components, a step of thinning substrate 10 on the side of the surface opposite to surface 12, the thickness of substrate 10 being decreased at least to reach insulating layer 24, and a step of forming layer 35 and possibly contacts pads through layer 35.
The embodiment of the method of manufacturing trench 42 previously described in relation with
The initial steps of the method are the same as those previously described in relation with
According to the conditions in which the thermal oxidation is performed, it is possible for insulating layer 52 not to stop the progression front of the oxidation reaction. Given that semiconductor layer 54 forms a recess opposite opening 50, during the progress of the oxidation edge of layer 54, the penetration of insulating layer 66 into opening 50 at the top thereof can be observed before the progression front reaches surface 12. In this case, insulating layer 66, which partly forms in opening 50, may laterally extend beyond opening 50.
The conditions of the thermal oxidation are defined so that insulating layer 66 penetrates into opening 50 down to a depth corresponding to the desired depth P′ of insulating portion 44.
The method further comprises at least subsequent steps of forming layers 30, 32, 34, a step of forming the optoelectronic components, a step of thinning substrate 10 on the side of the surface opposite to surface 12, the thickness of substrate 10 being decreased at least to reach insulating layer 24, and a step of forming layer 35 and possibly contacts pads through layer 35.
The embodiment of the method of manufacturing trench 42 previously described in relation with
The embodiments of the manufacturing method previously described in relation with
Advantageously, in the previously-described embodiments, insulating portion 44 is flush with the surface of substrate 10, that is, the upper surface of portion 44 is substantially coplanar with surface 12 of substrate 10. The forming of insulating portion 44 advantageously does not cause the forming of depressions or of raised portions on surface 12 of substrate 10. This eases the implementation of the subsequent steps of the electronic circuit manufacturing method.
Specific embodiments have been described. Although, in the previously-described embodiments, insulating portion 44 is formed by thermal oxidation, insulating portion 44 may be formed by any type of insulating layer forming method, particularly by deposition methods. However, insulating portion 44 is preferably formed by thermal oxidation since the obtained insulating material has good electronic properties, and particularly few electrically-active defects.
Number | Date | Country | Kind |
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1662301 | Dec 2016 | FR | national |
Filing Document | Filing Date | Country | Kind |
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PCT/FR2017/053421 | 12/6/2017 | WO | 00 |