Claims
- 1. A process for device fabrication comprising:
- forming a layer of an energy sensitive resist material on a substrate wherein the energy sensitive resist material comprises a radiation sensitive material and a polymer which is the polymerization product of monomers, wherein about 25 mole percent to about 50 mole percent of the monomers incorporated into the polymer have an alicyclic hydrocarbon moiety that is either incorporated into the polymer backbone or pendant to the polymer backbone via a saturated hydrocarbon linkage and about 25 mole percent to about 50 mole percent of the monomers incorporated into the polymer are a maleic anhydride monomer and wherein the polymer has at least one substituent that is selected from the group consisting of acid labile substituents, free acid substituents or both;
- exposing the layer of energy sensitive resist material to patterned radiation selected from the group consisting of ultraviolet radiation, x-ray radiation, and electron beam radiation thereby introducing an image of the pattern into the resist material;
- developing the image into a pattern; and
- transferring the pattern into the underlying substrate.
- 2. The process of claim 1 wherein the polymer is the polymerization product of the alicyclic hydrocarbon moiety-containing monomer, the maleic anhydride monomer and a third monomer that is selected from the group consisting of acrylic acids, methacrylic acids, acrylates, and methacrylates.
- 3. The process of claim 2 wherein the alicyclic hydrocarbon moiety-containing monomer is selected from the group consisting of norbornene, 1,5-dimethyl-1,5-cyclooctadiene, 5,6,-dihydrodicyclopentadiene, and 1,5-cyclooctadiene.
- 4. The process of claim 3 wherein the exposing radiation is ultraviolet radiation with a wavelength of about 193 nm.
- 5. The process of claim 4 wherein the third monomer is selected from the group consisting of acrylic acid and methacrylic acid and the polymer has the following structure ##STR5## wherein Y is the alicyclic hydrocarbon moiety-containing monomer, X is either hydrogen or methyl and wherein n is about 0.95 to about 0.5, m is about 0.05 to about 0.5 and n+m is equal to one.
- 6. The process of claim 5 wherein the resist material further comprising a dissolution inhibitor, wherein the amount of the radiation sensitive material in the resist material is about 0.5 to about 20 weight percent of the resist material and the amount of dissolution inhibitor in the resist material is about 10 to about 40 weight percent.
- 7. The process of claim 4 wherein the polymer is the polymerization product of norbornene, maleic anhydride, the third monomer, and a forth monomer wherein the polymer has the following structure: ##STR6## wherein n is about 0.95 to about 0.5, m+p is about 0.05 to about 0.5 and n+m+p is equal to one, wherein at least one of R and R' is an acid labile group and the other is either an acid labile group or hydrogen and the polymer is soluble in aqueous base solution.
- 8. The process of claim 7 wherein the resist material further comprising a dissolution inhibitor, wherein the amount of the radiation sensitive material in the resist material is about 0.5 to about 20 weight percent of the resist material and the amount of dissolution inhibitor in the resist material is about 10 to about 40 weight percent.
- 9. The process of claim 4 wherein the third monomer is selected from the group consisting of acrylates and methacrylates and the polymer has the following structure: ##STR7## wherein Y is the alicyclic hydrocarbon moiety-containing monomer, and wherein n is about 0.95 to about 0.5, m is about 0.05 to about 0.5 and n+m is equal to one, wherein R and R' are either acid labile groups or hydrogen and wherein at least one of R and R' is an acid labile group wherein the amount of the acid labile groups on the polymer is sufficient to render the polymer insoluble in aqueous base solution.
- 10. The process of claim 9 wherein the acid labile groups are selected from the group consisting of t-butyl, t-amyl, 1-methoxycyclohexyl, 3-oxocyclohexyl, and bis(2-trimethylsilyl)ethyl.
- 11. The process of claim 9 wherein the resist material further comprises a dissolution inhibitor, wherein the amount of the photoacid generator in the resist material is about 0.5 to about 20 weight percent the resist material and the amount of dissolution inhibitor in the resist material is about 10 to about 40 weight percent.
- 12. The process of claim 9 wherein n is about 0.85 to about 0.8 and m is about 0.15 to about 0.2.
- 13. The process of claim 4 wherein the polymer is the polymerization product of norbornene, maleic anhydride, the third monomer, and a forth monomer, wherein the third monomer is selected from the group consisting of acrylates and methacrylates and the polymer has the following structure ##STR8## wherein X is either hydrogen or methyl and wherein n is about 0.95 to about 0.5, m+p is about 0.05 to about 0.5 and n+m+p is equal to one, wherein R and R' are either acid labile groups or hydrogen and wherein at least one of R and R' is an acid labile group wherein the amount of the acid labile groups on the polymer is sufficient to render the polymer insoluble in aqueous base solution.
- 14. The process of claim 13 wherein the acid labile groups are selected from the group consisting of t-butyl, t-amyl, 1-methoxycyclohexyl, 3-oxocyclohexyl, and bis(2-trimethylsilyl)ethyl.
- 15. The process of claim 14 wherein the resist material further comprises a dissolution inhibitor, wherein the amount of the photoacid generator in the resist material is about 0.5 to about 20 weight percent the resist material and the amount of dissolution inhibitor in the resist material is about 10 to about 40 weight percent.
- 16. The process of claim 15 wherein n is about 0.85 to about 0.55 and m+p is about 0.15 to about 0.45.
- 17. The process of claim 1 wherein the alicyclic hydrocarbon moiety-containing monomer has substituent groups pendant thereto selected from the group consisting of alkyl groups, carbonyl groups, carboxylate groups and nitrile groups and wherein the substituent groups do not significantly absorb the exposing radiation.
- 18. The process of claim 17 wherein the alicyclic moiety-containing monomer has carboxylate groups pendant thereto and the amount of carboxylate groups pendant to the polymer is sufficient to render the polymer insoluble in aqueous base solution.
CLAIM OF PRIORITY
This application claims priority of Provisional Application Ser. No. 60/013,093 filed Mar. 8, 1996.
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