Insulated semiconductor faceplate designs

Information

  • Patent Grant
  • 10170282
  • Patent Number
    10,170,282
  • Date Filed
    Thursday, January 23, 2014
    10 years ago
  • Date Issued
    Tuesday, January 1, 2019
    6 years ago
Abstract
An exemplary faceplate may include a conductive plate defining a plurality of apertures. The faceplate may additionally include a plurality of inserts, and each one of the plurality of inserts may be disposed within one of the plurality of apertures. Each insert may define at least one channel through the insert to provide a flow path through the faceplate.
Description
TECHNICAL FIELD

The present technology relates to semiconductor processes and equipment. More specifically, the present technology relates to processing system plasma components that are at least partially insulated.


BACKGROUND

Integrated circuits are made possible by processes which produce intricately patterned material layers on substrate surfaces. Producing patterned material on a substrate requires controlled methods for removal of exposed material. Chemical etching is used for a variety of purposes including transferring a pattern in photoresist into underlying layers, thinning layers, or thinning lateral dimensions of features already present on the surface. Often it is sought to have an etch process that etches one material faster than another facilitating, for example, a pattern transfer process. Such an etch process is said to be selective to the first material. As a result of the diversity of materials, circuits, and processes, etch processes have been developed with a selectivity towards a variety of materials.


Dry etches produced in local plasmas formed within the substrate processing region can penetrate more constrained trenches and exhibit less deformation of delicate remaining structures. However, local plasmas can damage the substrate through the production of electric arcs as they discharge. Plasmas additionally may sputter or otherwise degrade chamber components often requiring replacement of internal parts. Protecting chamber components can be performed by seasoning the chamber, which may increase process queue times and may be a disadvantage to adequate throughput.


Thus, there is a need for improved system components that can be used in plasma environments effectively while providing suitable degradation profiles. These and other needs are addressed by the present technology.


SUMMARY

Exemplary faceplates may include a conductive plate defining a plurality of apertures. The faceplates may additionally include a plurality of inserts, and each one of the plurality of inserts may be disposed within one of the plurality of apertures. Each insert may define at least one channel through the insert to provide a flow path through the faceplate. Each insert may also define more than one channel, and may for example define six channels through the insert arranged in a hexagonal pattern.


The faceplates may further include a plurality of o-rings positioned within annular channels, and each annular channel may be defined at least partially by each of the plurality of inserts. A portion of each o-ring of the plurality of o-rings may be seated within an annular groove defined along a region of a corresponding insert between a top and bottom of the insert. A second o-ring may also be seated within a second annular groove defined along a region of a corresponding insert between the top and bottom of the insert and vertically disposed from the first o-ring. The o-rings may be disposed within the inserts and the inserts may be housed within the respectively defined apertures of the conductive plate and may extend radially within each aperture to within at least 50 mils of the radius of each aperture. A portion of each aperture may be defined with a decreasing diameter from an upper region to a lower region to define a tapered region of the aperture. In exemplary faceplates the conductive plate may include a layer of material, such as dielectric material, on all surfaces of the conductive plate that may be exposed to plasma. Also, the layer of material may be located on all surfaces of the conductive plate including on all surfaces defining the plurality of apertures. The layer of material may be formed from a dielectric material, and may further be a ceramic material.


Exemplary faceplates of the technology may include a conductive plate defining a plurality of apertures. The faceplates may additionally include a plurality of inserts, and each one of the plurality of inserts may be disposed within one of the plurality of apertures. Each aperture may be defined with an upper portion and a lower portion of the aperture. The upper portion may be characterized by a cylindrical shape having a first diameter, and the lower portion may be characterized by a cylindrical shape having a second diameter less than the first diameter. A ledge may be defined by the conductive plate at the boundary between the upper portion and lower portion. The upper portion may be less than 10% of the length of the aperture in exemplary apertures. Each insert may be seated on the defined ledge of each corresponding aperture, and each insert may occupy at least a portion of both the upper portion and lower portion of each aperture. Each insert may also occupy only the upper portion or only the lower portion of each corresponding aperture in embodiments. Additionally, a plurality of o-rings may be positioned to form a seal between the inserts and the upper and/or lower portion of the apertures.


The inserts may also be formed from a dielectric material, and may further be a ceramic material. The ceramic may include one or more of aluminum oxide, zirconium oxide, and yttrium oxide. The plurality of inserts may be fixedly coupled to an insert plate in exemplary faceplates, and the insert may extend unidirectionally from a surface of the insert plate. The insert plate may be configured to be thermally fit to the conductive plate such that a surface of the insert plate covers a surface of the conductive plate, and the inserts may at least partially extend through the corresponding apertures.


Methods are also described forming exemplary faceplates. The methods may include forming a plurality of apertures through a conductive plate. The methods may include coating at least a portion of the conductive plate with a dielectric material, and the coating additionally may cover at least a portion of surfaces of the plate defining the plurality of apertures. The methods may further include disposing a plurality of inserts within the apertures such that each aperture includes at least one insert, and the inserts may each define at least one channel through the insert.


Such technology may provide numerous benefits over conventional systems and techniques. For example, degradation of the faceplate may be prevented or limited. An additional advantage is that improved uniformity of distribution may be provided from the channels of the inserts. These and other embodiments, along with many of their advantages and features, are described in more detail in conjunction with the below description and attached figures.





BRIEF DESCRIPTION OF THE DRAWINGS

A further understanding of the nature and advantages of the disclosed technology may be realized by reference to the remaining portions of the specification and the drawings.



FIG. 1 shows a top plan view of one embodiment of an exemplary processing system.



FIG. 2A shows a schematic cross-sectional view of an exemplary processing chamber.



FIG. 2B shows a detailed view of a portion of the processing chamber illustrated in FIG. 2A.



FIG. 3 shows a bottom plan view of an exemplary showerhead according to the disclosed technology.



FIG. 4 shows a plan view of an exemplary faceplate according to the disclosed technology.



FIG. 5 shows a simplified cross-sectional view of a faceplate according to the disclosed technology.



FIGS. 6A-6C show exemplary insert channel arrangements according to the disclosed technology.



FIGS. 7A-7C show exemplary cross-sectional aperture structures according to the disclosed technology.



FIG. 8A shows a cross-sectional view of an exemplary aperture and insert arrangement according to the disclosed technology.



FIG. 8B shows a top plan view of the arrangement of FIG. 8A.



FIG. 9 shows an exemplary conductive plate and insert plate according to the disclosed technology.



FIG. 10 shows a cross-sectional view of an exemplary conductive plate coupled with an insert plate according to the disclosed technology.



FIG. 11 shows a method of forming a faceplate according to the disclosed technology.





Several of the Figures are included as schematics. It is to be understood that the Figures are for illustrative purposes, and are not to be considered of scale unless specifically stated to be as such.


In the appended figures, similar components and/or features may have the same reference label. Further, various components of the same type may be distinguished by following the reference label by a letter that distinguishes among the similar components. If only the first reference label is used in the specification, the description is applicable to any one of the similar components having the same first reference label irrespective of the letter.


DETAILED DESCRIPTION

The present technology includes systems and components for semiconductor processing. When plasmas are formed in situ in processing chambers, such as with a capacitively coupled plasma (“CCP”) for example, exposed surfaces may be sputtered or degraded by the plasma or the species produced by the plasma. When dry etchant formulas that may include several radical species produced by the plasma are formed, the radical species produced may interact and affect the remote plasma chamber.


Conventional technologies have dealt with these unwanted side effects through regular maintenance and replacement of components, however, the present systems may at least partially overcome this need by providing components that may be less likely to degrade as well as components that may be easier to protect. By utilizing dielectric inserts within larger bore apertures, multiple benefits or advantages may be provided. The apertures of the plate may be of sufficient diameter to allow protective coatings to be applied to the plate, and the inserts may have channels specifically configured to produce more uniform flow patterns for precursors being delivered. Accordingly, the systems described herein provide improved performance and cost benefits over many conventional designs. These and other benefits will be described in detail below.


Although the remaining disclosure will routinely identify specific etching processes utilizing the disclosed technology, it will be readily understood that the systems and methods are equally applicable to deposition and cleaning processes as may occur in the described chambers. Accordingly, the technology should not be considered to be so limited as for use with etching processes alone.



FIG. 1 shows a top plan view of one embodiment of a processing system 100 of deposition, etching, baking, and curing chambers according to embodiments. In the figure, a pair of front opening unified pods (FOUPs) 102 supply substrates of a variety of sizes that are received by robotic arms 104 and placed into a low pressure holding area 106 before being placed into one of the substrate processing chambers 108a-f, positioned in tandem sections 109a-c. A second robotic arm 110 may be used to transport the substrate wafers from the holding area 106 to the substrate processing chambers 108a-f and back. Each substrate processing chamber 108a-f, can be outfitted to perform a number of substrate processing operations including the dry etch processes described herein in addition to cyclical layer deposition (CLD), atomic layer deposition (ALD), chemical vapor deposition (CVD), physical vapor deposition (PVD), etch, pre-clean, degas, orientation, and other substrate processes.


The substrate processing chambers 108a-f may include one or more system components for depositing, annealing, curing and/or etching a dielectric film on the substrate wafer. In one configuration, two pairs of the processing chamber, e.g., 108c-d and 108e-f, may be used to deposit dielectric material on the substrate, and the third pair of processing chambers, e.g., 108a-b, may be used to etch the deposited dielectric. In another configuration, all three pairs of chambers, e.g., 108a-f, may be configured to etch a dielectric film on the substrate. Any one or more of the processes described may be carried out in chamber(s) separated from the fabrication system shown in different embodiments. It will be appreciated that additional configurations of deposition, etching, annealing, and curing chambers for dielectric films are contemplated by system 100.



FIG. 2A shows a cross-sectional view of an exemplary process chamber system 200 with partitioned plasma generation regions within the processing chamber. During film etching, e.g., titanium nitride, tantalum nitride, tungsten, silicon, polysilicon, silicon oxide, silicon nitride, silicon oxynitride, silicon oxycarbide, etc., a process gas may be flowed into the first plasma region 215 through a gas inlet assembly 205. A remote plasma system (RPS) 201 may optionally be included in the system, and may process a first gas which then travels through gas inlet assembly 205. The inlet assembly 205 may include two or more distinct gas supply channels where the second channel (not shown) may bypass the RPS 201, if included.


A cooling plate 203, faceplate 217, ion suppressor 223, showerhead 225, and a substrate support 265, having a substrate 255 disposed thereon, are shown and may each be included according to embodiments. The pedestal 265 may have a heat exchange channel through which a heat exchange fluid flows to control the temperature of the substrate. The wafer support platter of the pedestal 265, which may comprise aluminum, ceramic, or a combination thereof, may also be resistively heated in order to achieve relatively high temperatures, such as from up to or about 100° C. to above or about 1100° C., using an embedded resistive heater element.


The faceplate 217 may be pyramidal, conical, or of another similar structure with a narrow top portion expanding to a wide bottom portion. The faceplate 217 may additionally be flat as shown and include a plurality of through-channels used to distribute process gases. Plasma generating gases and/or plasma excited species, depending on use of the RPS 201, may pass through a plurality of holes, shown in FIG. 2B, in faceplate 217 for a more uniform delivery into the first plasma region 215.


Exemplary configurations may include having the gas inlet assembly 205 open into a gas supply region 258 partitioned from the first plasma region 215 by faceplate 217 so that the gases/species flow through the holes in the faceplate 217 into the first plasma region 215. Structural and operational features may be selected to prevent significant backflow of plasma from the first plasma region 215 back into the supply region 258, gas inlet assembly 205, and fluid supply system 210. The faceplate 217, or a conductive top portion of the chamber, and showerhead 225 are shown with an insulating ring 220 located between the features, which allows an AC potential to be applied to the faceplate 217 relative to showerhead 225 and/or ion suppressor 223. The insulating ring 220 may be positioned between the faceplate 217 and the showerhead 225 and/or ion suppressor 223 enabling a capacitively coupled plasma (CCP) to be formed in the first plasma region. A baffle (not shown) may additionally be located in the first plasma region 215, or otherwise coupled with gas inlet assembly 205, to affect the flow of fluid into the region through gas inlet assembly 205.


The ion suppressor 223 may comprise a plate or other geometry that defines a plurality of apertures throughout the structure that are configured to suppress the migration of ionically-charged species out of the plasma excitation region 215 while allowing uncharged neutral or radical species to pass through the ion suppressor 223 into an activated gas delivery region between the suppressor and the showerhead. In embodiments, the ion suppressor 223 may comprise a perforated plate with a variety of aperture configurations. These uncharged species may include highly reactive species that are transported with less reactive carrier gas through the apertures. As noted above, the migration of ionic species through the holes may be reduced, and in some instances completely suppressed. Controlling the amount of ionic species passing through the ion suppressor 223 may advantageously provide increased control over the gas mixture brought into contact with the underlying wafer substrate, which in turn may increase control of the deposition and/or etch characteristics of the gas mixture. For example, adjustments in the ion concentration of the gas mixture can significantly alter its etch selectivity, e.g., TiNx:SiOx etch ratios, TiN:W etch ratios, etc. In alternative embodiments in which deposition is performed, it can also shift the balance of conformal-to-flowable style depositions for dielectric materials.


The plurality of apertures in the ion suppressor 223 may be configured to control the passage of the activated gas, i.e., the ionic, radical, and/or neutral species, through the ion suppressor 223. For example, the aspect ratio of the holes, or the hole diameter to length, and/or the geometry of the holes may be controlled so that the flow of ionically-charged species in the activated gas passing through the ion suppressor 223 is reduced. The holes in the ion suppressor 223 may include a tapered portion that faces the plasma excitation region 215, and a cylindrical portion that faces the showerhead 225. The cylindrical portion may be shaped and dimensioned to control the flow of ionic species passing to the showerhead 225. An adjustable electrical bias may also be applied to the ion suppressor 223 as an additional means to control the flow of ionic species through the suppressor.


The ion suppressor 223 may function to reduce or eliminate the amount of ionically charged species traveling from the plasma generation region to the substrate. Uncharged neutral and radical species may still pass through the openings in the ion suppressor to react with the substrate. It should be noted that the complete elimination of ionically charged species in the reaction region surrounding the substrate may not be performed in embodiments. In certain instances, ionic species are required to reach the substrate in order to perform the etch and/or deposition process. In these instances, the ion suppressor may help to control the concentration of ionic species in the reaction region at a level that assists the process.


Showerhead 225 in combination with ion suppressor 223 may allow a plasma present in chamber plasma region 215 to avoid directly exciting gases in substrate processing region 233, while still allowing excited species to travel from chamber plasma region 215 into substrate processing region 233. In this way, the chamber may be configured to prevent the plasma from contacting a substrate 255 being etched. This may advantageously protect a variety of intricate structures and films patterned on the substrate, which may be damaged, dislocated, or otherwise warped if directly contacted by a generated plasma. Additionally, when plasma is allowed to contact the substrate or approach the substrate level, the rate at which oxide species etch may increase. Accordingly, if an exposed region of material is oxide, this material may be further protected by maintaining the plasma remotely from the substrate.


The processing system may further include a power supply 240 electrically coupled with the processing chamber to provide electric power to the faceplate 217, ion suppressor 223, showerhead 225, and/or pedestal 265 to generate a plasma in the first plasma region 215 or processing region 233. The power supply may be configured to deliver an adjustable amount of power to the chamber depending on the process performed. Such a configuration may allow for a tunable plasma to be used in the processes being performed. Unlike a remote plasma unit, which is often presented with on or off functionality, a tunable plasma may be configured to deliver a specific amount of power to the plasma region 215. This in turn may allow development of particular plasma characteristics such that precursors may be dissociated in specific ways to enhance the etching profiles produced by these precursors.


A plasma may be ignited either in chamber plasma region 215 above showerhead 225 or substrate processing region 233 below showerhead 225. Plasma may be present in chamber plasma region 215 to produce the radical precursors from an inflow of, for example, a fluorine-containing precursor or other precursor. An AC voltage typically in the radio frequency (RF) range may be applied between the conductive top portion of the processing chamber, such as faceplate 217, and showerhead 225 and/or ion suppressor 223 to ignite a plasma in chamber plasma region 215 during deposition. An RF power supply may generate a high RF frequency of 13.56 MHz but may also generate other frequencies alone or in combination with the 13.56 MHz frequency.



FIG. 2B shows a detailed view 253 of the features affecting the processing gas distribution through faceplate 217. As shown in FIGS. 2A and 2B, faceplate 217, cooling plate 203, and gas inlet assembly 205 intersect to define a gas supply region 258 into which process gases may be delivered from gas inlet 205. The gases may fill the gas supply region 258 and flow to first plasma region 215 through apertures 259 in faceplate 217. The apertures 259 may be configured to direct flow in a substantially unidirectional manner such that process gases may flow into processing region 233, but may be partially or fully prevented from backflow into the gas supply region 258 after traversing the faceplate 217.


The gas distribution assemblies such as showerhead 225 for use in the processing chamber section 200 may be referred to as dual channel showerheads (DCSH) and are additionally detailed in the embodiments described in FIG. 3 as well as FIG. 4 herein. The dual channel showerhead may provide for etching processes that allow for separation of etchants outside of the processing region 233 to provide limited interaction with chamber components and each other prior to being delivered into the processing region.


The showerhead 225 may comprise an upper plate 214 and a lower plate 216. The plates may be coupled with one another to define a volume 218 between the plates. The coupling of the plates may be so as to provide first fluid channels 219 through the upper and lower plates, and second fluid channels 221 through the lower plate 216. The formed channels may be configured to provide fluid access from the volume 218 through the lower plate 216 via second fluid channels 221 alone, and the first fluid channels 219 may be fluidly isolated from the volume 218 between the plates and the second fluid channels 221. The volume 218 may be fluidly accessible through a side of the gas distribution assembly 225.



FIG. 3 is a bottom view of a showerhead 325 for use with a processing chamber according to embodiments. Showerhead 325 corresponds with the showerhead shown in FIG. 2A. Through-holes 365, which show a view of first fluid channels 219, may have a plurality of shapes and configurations in order to control and affect the flow of precursors through the showerhead 225. Small holes 375, which show a view of second fluid channels 221, may be distributed substantially evenly over the surface of the showerhead, even amongst the through-holes 365, and may help to provide more even mixing of the precursors as they exit the showerhead than other configurations.


An arrangement for a faceplate according to embodiments is shown in FIG. 4. As shown, the faceplate 400 may comprise a perforated plate or manifold. The assembly of the faceplate may be similar to the showerhead as shown in FIG. 3, or may include a design configured specifically for distribution patterns of precursor gases. Faceplate 400 may include an annular frame 410 positioned in various arrangements within an exemplary processing chamber, such as the chamber as shown in FIG. 2. On or within the frame may be coupled a plate 420, which may be similar in embodiments to ion suppressor plate 223 as previously described. In embodiments faceplate 400 may be a single-piece design where the frame 410 and plate 420 are a single piece of material.


The plate may have a disc shape and be seated on or within the frame 410. The plate may be a conductive material such as a metal including aluminum, as well as other conductive materials that allow the plate to serve as an electrode for use in a plasma arrangement as previously described. The plate may be of a variety of thicknesses, and may include a plurality of apertures 465 defined within the plate. An exemplary arrangement as shown in FIG. 4 may include a pattern as previously described with reference to the arrangement in FIG. 3, and may include a series of rings of apertures in a geometric pattern, such as a hexagon as shown. As would be understood, the pattern illustrated is exemplary and it is to be understood that a variety of patterns, hole arrangements, and hole spacing are encompassed in the design.


The apertures 465 may be sized or otherwise configured to allow inserts to be positioned or disposed within each one of the apertures such that each aperture includes a corresponding insert. An exemplary insert is illustrated in aperture 465n, and described further below in conjunction with FIG. 5. The apertures may be sized less than about 2 inches in various embodiments, and may be less than or about 1.5 inches, about 1 inch, about 0.9 inches, about 0.8 inches, about 0.75 inches, about 0.7 inches, about 0.65 inches, about 0.6 inches, about 0.55 inches, about 0.5 inches, about 0.45 inches, about 0.4 inches, about 0.35 inches, about 0.3 inches, about 0.25 inches, about 0.2 inches, about 0.15 inches, about 0.1 inches, about 0.05 inches, etc. or less. When the apertures have any of the profiles as will be described below, any of the sections or regions of the apertures may be of any of the sizes discussed herein.


Turning to FIG. 5 is shown a simplified cross-sectional view of a portion of a faceplate 500 according to the disclosed technology. As shown, the faceplate may include a plate 520 such as a conductive plate defining a plurality of apertures 565. The faceplate 500 may also include a plurality of inserts 515, where each one of the plurality of inserts 515 is disposed within one of the plurality of apertures 565. Each of the apertures 565 may have similar characteristics as the other apertures, or the apertures 565 may include a variety of patterns and shapes. The corresponding inserts 515 may have similar shapes as the apertures 565, or may be configured to be positioned within the various shapes that may characterize the corresponding apertures 565.


Each insert 515 may further define at least one channel 517 through the insert, and in embodiments may define a plurality of channels 517 within each insert 515, that may include at least 2, 3, 4, 5, 6, 7, 8, 9, 10, 12, 15, etc. or more channels defined by the insert. The channels may be a variety of sizes based on the number of channels, desired flow characteristics, etc., and in embodiments may be less than or about 1 inch. The channels may also be less than or about 0.8, about 0.75 inches, about 0.6 inches, about 0.5 inches, about 0.4 inches, about 0.3 inches, about 0.2 inches, about 0.1 inches, about 0.09 inches, about 0.08 inches, about 0.07 inches, about 0.06 inches, about 0.05 inches, about 0.04 inches, about 0.03 inches, about 0.02 inches, about 0.01 inches, about 0.005 inches, etc. or less. The channels may be defined along a parallel axis as the apertures, or may be angled towards or away from a central axis of the aperture in embodiments.


The inserts may be made of a variety of materials that include dielectrics, insulative materials, oxides, and ceramics or other inorganic or organic nonmetallic solids. The inserts may be made of material providing a resistance to physical bombardment as well as chemical inertness, among other properties. The ceramics may be whiteware or technical ceramics and may include one or more oxides including aluminum oxide, beryllium oxide, cerium oxide, zirconium oxide, yttrium oxide, etc. The ceramics may include nonoxides including carbide, boride, nitride, silicide, etc., as well as composite materials such as particulates or fibers to reinforce the material. The ceramics may also include one or more combinations of oxides and nonoxides, and in embodiments may include a combination of aluminum oxide and yttrium oxide. The ceramic may also include a combination of aluminum oxide, yttrium oxide, and zirconium oxide in a variety of proportions to provide specific properties. Each or any of the oxides may be at least about 0.1% of the composite, and may also be at least about 3%, 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 90%, 95%, etc. or more of the total amount of material in the composite up to 100% in which case the ceramic is essentially that material. The amount of each material may also be considered within a range of any of the disclosed percentages or numbers enclosed by any of the percentages listed.


The inserts may be disposed in the apertures in a variety of ways including press fitting, thermal shrinking, or with other clamping and fitting mechanisms as would be understood. For example, one or more devices 523 such as o-rings may be positioned along the inserts to provide a sealing between the plate 520 and the inserts 515. The o-rings 523 or other devices may be positioned within annular channels 524 defined at least partially by the plurality of inserts 515, and a portion of each o-ring 523 may be seated within an annular groove 525 defined along a region of a corresponding insert between the top and bottom of the insert. The annular channels may also be at least partially defined by the plate 520 as illustrated by the annular grooves 526. In embodiments more than one device such as multiple o-rings may be used in conjunction to provide stability and sealing of the insert. For example, a second o-ring may be seated within a second annular groove defined along a region of a corresponding insert between the top and bottom of the insert and vertically spaced from the first o-ring. The o-rings 523 may be disposed within the inserts such that the inserts are housed within the respectively defined apertures of the conductive plate and extend radially within each aperture to within at least about 0.5 inches of the radius of each aperture. In embodiments the inserts may extend radially within each aperture to within at least about 0.25 inches, about 0.1 inches, about 0.075 inches, about 0.05 inches, about 0.025 inches, about 0.015 inches, about 0.01 inches, about 0.005 inches, about 0.001 inches, etc. or less.



FIGS. 6A-6C show top plan views of exemplary insert and channel arrangements according to the disclosed technology. For example, FIG. 6A illustrates an insert 615a having four equal channels 617a defined therein. The channels 617 may be spaced in a variety of patterns and the channels may be characterized by equal dimensions or different dimensions in embodiments. FIG. 6B shows an additional arrangement where insert 615b defines six channels 617 through the insert arranged in a hexagonal pattern. As shown, channels 617f are characterized by a smaller diameter than are channels 617b. Any number of variations as would be understood are similarly encompassed by the technology. FIG. 6C shows another embodiment in which insert 615c includes a single channel 617c characterized by a larger diameter than other channels shown. The inserts 615 shown, or variations thereof, may be used in any combination across the plate to provide a more uniform distribution or flow of precursors through the inserts.


The flow capacity of each channel may also determine the number of apertures used. For example, if larger diameter channels are used, or a greater number of channels, less apertures with inserts may be required to deliver a certain flow of precursors or plasma effluents. Additionally, the number of channels and size of the channels will similarly affect the diameter of the inserts used. This may affect cost and manufacturing time associated with the faceplates and inserts. For example, larger inserts and/or larger channels may be less expensive to manufacture than smaller inserts or features. Certain inserts defining no channels may be used in select locations to further modify the flow patterns through the plate. For example, one of the rings of apertures as previously described may have each aperture or any number of apertures of the ring house or hold an insert having no channels defined therein in order to direct flow away from the particular apertures.


The apertures and inserts may also take on a variety of profiles that include cylindrical bodies as shown in FIG. 5, or in different shapes as shown in FIG. 7A-7C in which three exemplary cross-sectional views of apertures are shown. FIG. 7A shows a profile of an aperture 765a having an opening at a first diameter that tapers down to a cylindrical portion having a second smaller diameter. At least a portion of the aperture is thus defined with a decreasing diameter from an upper region to a lower region to define the tapered region. FIG. 7C illustrates an additional aperture 765c having a cylindrical upper portion over a smaller cylindrical lower portion such as a counterbore-type aperture. The aperture may alternatively have a countersink-type profile having a conical upper portion over a cylindrical lower portion. FIG. 7B shows an aperture with an upper cylindrical portion and lower cylindrical portion in which the upper portion has a depth that is less than about 10% of the overall length or depth of the aperture.


In embodiments the upper portion may have a depth that is greater than or about 90% of the overall depth of the aperture, less than about 90%, less than or about 85%, 80%, 75%, 70%, 65%, 60%, 55% 50%, 45%, 40%, 35%, 30%, 25%, 20%, 15%, 10%, 5%, 2%, or less and may have a profile similar to a spotface in which the upper portion accounts for only a small fraction of the overall length of the aperture. The aperture shape may provide additional support for the insert disposed therein, which may be seated on the defined ledge of the corresponding aperture, and occupy at least a portion of both the upper portion and lower portion of each aperture, such as shown in FIG. 7B. As illustrated, insert 715 is seated on the ledge formed between the upper and lower portions of aperture 765b and occupies a portion of both the upper portion and the lower portion. The insert 715 also defines channels 717 which provide access through the insert. Optional devices such as o-rings 723 may additionally be used to stabilize and position the insert within the aperture.



FIG. 8A shows a cross-sectional view of an exemplary aperture and insert arrangement 800 according to the disclosed technology. Aperture 865 may be characterized by an upper portion 867 and a lower portion 869. The upper portion 867 may be characterized by a cylindrical shape having a first diameter, and the lower portion 869 may be characterized by a cylindrical shape having a second diameter less than the first diameter. This arrangement may define a ledge within each aperture at the boundary between the upper and lower portions. Insert 815 may be disposed within the aperture 865, and may be seated on the ledge such that each insert 815 occupies only the upper portion of each corresponding aperture 865. The insert may be press fit or thermally fit within the aperture, and may alternatively have one or more devices such as o-rings 823 seated within one or more annular grooves 825, 826 defined within the insert 815. In embodiments the annular grooves may be defined at least partially by the inserts, at least partially by the plate defining the apertures at annular grooves 824, and/or both. The o-rings 823 may be positioned to form a seal between the insert 815 and the plate defining the upper portion 867 of the aperture 865.


When using the plate as an electrode, such as with plasma operations as described previously in which the plate may comprise a lower electrode or ground electrode, areas having dielectric inserts, or gaps in the conductive material, may allow plasma leakage to occur in the processing region below the faceplate, as these regions may be relatively transparent to the RF. Although this may be desirable for certain operations, in embodiments, the operations may seek to minimize plasma in the processing region and thus large bore holes may provide access by which plasma ignition may occur below the faceplate. However, manufacturing costs may dictate that larger inserts are more economical under certain conditions. Accordingly, by forming apertures having an upper portion and a smaller lower portion, a larger and potentially more cost effective insert may be utilized, while plasma leakage through the plate may be minimized by having smaller gaps that actually penetrate the conductive plate, which may advantageously contain the plasma partially, substantially, or essentially above the faceplate. In embodiments the apertures may be configured to reduce or limit the leakage through the faceplate. As discussed previously, the faceplate may be coupled with a showerhead to form a single electrode, for example. In embodiments, the arrangement of holes in the showerhead and faceplate may be configured to limit direct through-paths for ignition in the processing region. For example, the first channels of the showerhead may be offset from the apertures of the faceplate in order to provide a consistent electrode region across the combined surfaces.



FIG. 8B shows a top plan view of the arrangement 800 of FIG. 8A. As shown, insert 815 includes channel 817 formed therethrough, and is disposed within aperture 865. O-ring 823 is visible forming a seal between the insert 815 and portion of the plate defining the aperture 865. Although shown with a defined gap, it is to be understood that the insert may be entirely or substantially flush with the portion of the plate defining the aperture.


The inserts may be made of a dielectric material as previously described, and in embodiments an additional material such as a layer of material may coat or cover all surfaces of the conductive plate that are exposed or facing plasma. For example, if only one side of the plate is plasma-facing, then in embodiments only that face of the plate may be coated with the layer of material. The coating may also cover the walls of the plate defining the apertures. Additionally, the layer of material may be located on all surfaces of the conductive plate including on all surfaces defining the plurality of apertures. In this way, the plate may be protected from radical species, such as fluorine species, that may interact with the plate. In such embodiments, o-rings or other devices may be used to ease the inserts into the material, although press fitting or thermal fitting may similarly be employed. If a ceramic material is utilized as the coating, the coating may be temperature limited for subsequent operations or else the material might crack or otherwise produce defects. Accordingly, if thermal operations are subsequently performed, such as to fit the inserts into the conductive plate, the operations may be required to occur at temperatures below a threshold temperature affecting the coating. This temperature may be less than or about 500° C. in embodiments, and may also be less than or about 450° C., about 400° C., about 350° C., about 300° C., about 250° C., about 200° C., about 150° C., about 100° C., about 50° C., etc. or less. The material may be a dielectric or insulative material, and may be similar to or different from the material used for the inserts. For example, the material may include one or more of aluminum oxide, yttrium oxide, or zirconium oxide as previously discussed. For example, the material may be a ceramic coating that is plasma sprayed or otherwise applied to the surfaces of the plate. Such processes may be limited for certain aperture diameters, and as such, the apertures may be sized to accommodate and ensure complete coating of the surfaces with the dielectric material.


Turning to FIG. 9 is another exemplary structure including conductive plate 920 defining apertures 965 therethrough. Inserts 915 may be fixedly or otherwise coupled with an insert plate 930 for use as a coating or protection of the conductive plate 920. The inserts may extend unidirectionally from a surface of the insert plate, or may extend through the insert plate in embodiments. The insert plate 930 and inserts 915 may be formed as a single component and may be cast or molded to the desired shape. The inserts may be located or positioned on the insert plate so as to match with the configuration of the apertures defined within the conductive plate. The inserts 915 may alternatively be formed separately and coupled with or otherwise attached to the insert plate 930. FIG. 10 shows a cross-sectional view 1000 of the insert plate when coupled with the conductive plate 1020. As illustrated, insert plate 1030 may coat or otherwise cover conductive plate 1020. Conductive plate apertures 1065 may include the disposed inserts 1015, and channels 1017 formed through inserts 1015 may be accessible through the insert plate 1030. The insert plate may be thermally fixed to the conductive plate as previously discussed or other devices or operations may be similarly used or performed. In this way, the insert plate may be configured to be thermally fit to the conductive plate such that a surface of the insert plate covers a surface of the conductive plate, and the inserts at least partially extend into or through the corresponding apertures defined in the conductive plate. An additional plate of dielectric material may be coupled with the bottom and or sides of the conductive plate in embodiments and may be coupled, fixed, or combined with the insert plate 1030.



FIG. 11 shows a method of forming a faceplate according to the disclosed technology. The method may include forming a plurality of apertures through a conductive plate at operation 1110. The apertures may be drilled, cut, or otherwise formed in a variety of patterns. Once formed the resulting perforated plate may be coated with a material on at least a portion of the conductive plate at operation 1120. The coating may be an insulative coating, or a dielectric coating such as a plasma sprayed ceramic coating that forms a complete barrier to the underlying conductive surface. A plurality of inserts may be disposed within the apertures at operation 1130. The inserts may have channels defined or formed through the material in order to provide access through the conductive plate. The plate and inserts may include any of the features or characteristics as previously described. The plate may be coupled with a grounding source or an electrical source to operate as an electrode at least partially defining a space in which a plasma is formed. For example, the faceplate may be coupled within the system as described above with respect to FIG. 2, for example with regard to the ion suppressor. The faceplate may be electrically coupled with a showerhead to act together as the electrode. The faceplate and showerhead may be aligned to provide a continuous or substantially continuous electrode surface. This may be accomplished by offsetting the apertures of the components so that a portion of the apertures or a majority of the apertures do not align providing space through which plasma leakage may occur.


In the preceding description, for the purposes of explanation, numerous details have been set forth in order to provide an understanding of various embodiments of the present technology. It will be apparent to one skilled in the art, however, that certain embodiments may be practiced without some of these details, or with additional details.


Having disclosed several embodiments, it will be recognized by those of skill in the art that various modifications, alternative constructions, and equivalents may be used without departing from the spirit of the embodiments. Additionally, a number of well-known processes and elements have not been described in order to avoid unnecessarily obscuring the present technology. Accordingly, the above description should not be taken as limiting the scope of the technology.


Where a range of values is provided, it is understood that each intervening value, to the smallest fraction of the unit of the lower limit, unless the context clearly dictates otherwise, between the upper and lower limits of that range is also specifically disclosed. Any narrower range between any stated values or unstated intervening values in a stated range and any other stated or intervening value in that stated range is encompassed. The upper and lower limits of those smaller ranges may independently be included or excluded in the range, and each range where either, neither, or both limits are included in the smaller ranges is also encompassed within the technology, subject to any specifically excluded limit in the stated range. Where the stated range includes one or both of the limits, ranges excluding either or both of those included limits are also included.


As used herein and in the appended claims, the singular forms “a”, “an”, and “the” include plural references unless the context clearly dictates otherwise. Thus, for example, reference to “an aperture” includes a plurality of such apertures, and reference to “the plate” includes reference to one or more plates and equivalents thereof known to those skilled in the art, and so forth.


Also, the words “comprise(s)”, “comprising”, “contain(s)”, “containing”, “include(s)”, and “including”, when used in this specification and in the following claims, are intended to specify the presence of stated features, integers, components, or operations, but they do not preclude the presence or addition of one or more other features, integers, components, operations, acts, or groups.

Claims
  • 1. A semiconductor processing chamber faceplate comprising: a conductive plate defining a plurality of apertures; anda plurality of inserts, wherein each aperture of the plurality of apertures contains an insert of the plurality of inserts, wherein each insert of the plurality of inserts defines at least two channels there through, wherein each channel of the at least two channels independently extends vertically from a first end of an associated insert to a second end of the associated insert, wherein each channel of the at least two channels is radially offset from a central axis through the insert defining the at least two channels, and wherein the at least two channels are radially offset from one another about the central axis;a plurality of first o-rings positioned within annular channels at least partially defined by the conductive plate within the plurality of aperture;wherein a portion of each first o-ring of the plurality of first o-rings is seated within a first annular groove defined along a region of a corresponding insert between a top and bottom of the corresponding insert.
  • 2. The faceplate of claim 1, wherein the at least two channels defines six channels through the corresponding insert arranged in a hexagonal pattern.
  • 3. The faceplate of claim 1, wherein a second o-ring is seated within a second annular groove defined along the region of the corresponding insert between the top and bottom of the corresponding insert.
  • 4. The faceplate of claim 1, wherein the plurality of first o-rings are disposed within the plurality of inserts, wherein the plurality of inserts are housed within respectively defined apertures of the plurality of apertures of the conductive plate and extend radially within each aperture to within at least 50 mils of a radius of each aperture.
  • 5. The faceplate of claim 1, wherein at least a portion of each aperture of the plurality of apertures is defined with a decreasing diameter from an upper region to a lower region to define a tapered region.
  • 6. The faceplate of claim 1, further comprising a layer of dielectric material on all surfaces of the conductive plate configured to be exposed to a plasma.
  • 7. The faceplate of claim 6, wherein the layer of dielectric material is located on all surfaces of the conductive plate including on all surfaces defining the plurality of apertures.
  • 8. The faceplate of claim 1, wherein the plurality of first o-rings are each positioned radially outward from each insert of the plurality of inserts.
  • 9. The faceplate of claim 1, wherein each channel of the annular channels is partially defined by the conductive plate within an individual aperture of the plurality of apertures defined within the conductive plate, and wherein each channel of the annular channels is partially defined by the insert contained within each individual aperture.
  • 10. A semiconductor processing chamber faceplate comprising: a conductive plate defining a plurality of apertures; anda plurality of inserts, wherein each insert of the plurality of inserts is disposed within a separate aperture of the plurality of apertures, wherein each aperture of the plurality of apertures is defined with an upper portion and a lower portion within the conductive plate, wherein a ledge is defined by the conductive plate at a boundary between the upper portion and the lower portion, wherein the upper portion is characterized by a cylindrical shape having a first diameter extending from a first end of the aperture to the ledge, and the lower portion is characterized by a cylindrical shape having a second diameter extending from the ledge to a second end of the aperture, wherein the second diameter is less than the first diameter, wherein each insert of the plurality of inserts defines a channel there through, and wherein the channel is characterized by a diameter less than or equal to the second diameter;wherein each insert is seated on the defined ledge of each corresponding aperture, and wherein each insert occupies at least a portion of both the upper portion and lower portion of each aperture;wherein a plurality of o-rings are positioned to form a seal between the plurality of inserts and a portion of the plate defining the upper portion of the aperture.
  • 11. The faceplate of claim 10, wherein each insert of the plurality of inserts comprises a dielectric material.
  • 12. The faceplate of claim 11, wherein the dielectric material comprises a ceramic including one or more of aluminum oxide (AI2O3), zirconium oxide (ZrO2), and yttrium oxide (Y2O3).
  • 13. The faceplate of claim 10, wherein the ledge defines a transition from the first diameter to the second diameter.
CROSS-REFERENCES TO RELATED APPLICATIONS

This Application claims the benefit of U.S. Provisional Application No. 61/774,963, filed Mar. 8, 2013, entitled “Insulated Semiconductor Faceplate Designs,” the entire disclosure of which is hereby incorporated by reference for all purposes.

US Referenced Citations (747)
Number Name Date Kind
2369620 Sullivan et al. Feb 1945 A
3451840 Hough Jun 1969 A
3937857 Brummett et al. Feb 1976 A
4006047 Brummett et al. Feb 1977 A
4209357 Gorin et al. Jun 1980 A
4214946 Forget et al. Jul 1980 A
4232060 Mallory, Jr. Nov 1980 A
4234628 DuRose Nov 1980 A
4265943 Goldstein et al. May 1981 A
4364803 Nidola et al. Dec 1982 A
4368223 Kobayashi et al. Jan 1983 A
4397812 Mallory, Jr. Aug 1983 A
4468413 Bachmann Aug 1984 A
4512283 Bonifield Apr 1985 A
4565601 Kakehi et al. Jan 1986 A
4571819 Rogers et al. Feb 1986 A
4579618 Celestino et al. Apr 1986 A
4585920 Hoog et al. Apr 1986 A
4625678 Shloya et al. Dec 1986 A
4632857 Mallory, Jr. Dec 1986 A
4656052 Satou et al. Apr 1987 A
4690746 McInerney et al. Sep 1987 A
4714520 Gwozdz Dec 1987 A
4715937 Moslehi et al. Dec 1987 A
4749440 Blackwood et al. Jun 1988 A
4753898 Parrillo et al. Jun 1988 A
4786360 Cote et al. Nov 1988 A
4793897 Dunfield et al. Dec 1988 A
4807016 Douglas Feb 1989 A
4810520 Wu Mar 1989 A
4816638 Ukai et al. Mar 1989 A
4820377 Davis et al. Apr 1989 A
4851370 Doklan et al. Jul 1989 A
4865685 Palmour Sep 1989 A
4872947 Wang et al. Oct 1989 A
4878994 Jucha et al. Nov 1989 A
4886570 Davis et al. Dec 1989 A
4892753 Wang et al. Jan 1990 A
4894352 Lane et al. Jan 1990 A
4904341 Blaugher et al. Feb 1990 A
4904621 Lowenstein et al. Feb 1990 A
4913929 Moslehi et al. Apr 1990 A
4951601 Maydan et al. Aug 1990 A
4960488 Law et al. Oct 1990 A
4980018 Mu et al. Dec 1990 A
4981551 Palmour Jan 1991 A
4985372 Narita et al. Jan 1991 A
4992136 Tachi et al. Feb 1991 A
4994404 Sheng et al. Feb 1991 A
5000113 Wang et al. Mar 1991 A
5013691 Lory et al. May 1991 A
5030319 Nishino et al. Jul 1991 A
5061838 Lane et al. Oct 1991 A
5089441 Moslehi Feb 1992 A
5089442 Olmer Feb 1992 A
5147692 Bengston Sep 1992 A
5156881 Okano et al. Oct 1992 A
5186718 Tepman et al. Feb 1993 A
5198034 deBoer et al. Mar 1993 A
5203911 Sricharoenchalkit et al. Apr 1993 A
5215787 Homma Jun 1993 A
5228501 Tepman et al. Jul 1993 A
5231690 Soma et al. Jul 1993 A
5235139 Bengston et al. Aug 1993 A
5238499 van de Ven et al. Aug 1993 A
5240497 Shacham et al. Aug 1993 A
5248527 Uchida et al. Sep 1993 A
5252178 Moslehi Oct 1993 A
5266157 Kadomura Nov 1993 A
5270125 America et al. Dec 1993 A
5271972 Kwok et al. Dec 1993 A
5275977 Otsubo et al. Jan 1994 A
5279865 Chebi et al. Jan 1994 A
5288518 Homma Feb 1994 A
5290382 Zarowin et al. Mar 1994 A
5300463 Cathey et al. Apr 1994 A
5302233 Kim et al. Apr 1994 A
5306530 Strongin et al. Apr 1994 A
5314724 Tsukune et al. May 1994 A
5316804 Tomikawa et al. May 1994 A
5319247 Matsuura Jun 1994 A
5326427 Jerbic Jul 1994 A
5328218 Lowrey et al. Jul 1994 A
5328558 Kawamura et al. Jul 1994 A
5334552 Homma Aug 1994 A
5345999 Hosokawa Sep 1994 A
5352636 Beinglass Oct 1994 A
5356478 Chen et al. Oct 1994 A
5362526 Wang et al. Nov 1994 A
5368897 Kurihara et al. Nov 1994 A
5380560 Kaja et al. Jan 1995 A
5382311 Ishikawa et al. Jan 1995 A
5384284 Doan et al. Jan 1995 A
5385763 Okano et al. Jan 1995 A
5399237 Keswick et al. Mar 1995 A
5399529 Homma Mar 1995 A
5403434 Moslehi Apr 1995 A
5413967 Matsuda et al. May 1995 A
5415890 Kloiber et al. May 1995 A
5416048 Blalock et al. May 1995 A
5420075 Homma et al. May 1995 A
5429995 Nishiyama et al. Jul 1995 A
5439553 Grant et al. Aug 1995 A
5451259 Krogh Sep 1995 A
5468342 Nulty et al. Nov 1995 A
5474589 Ohga et al. Dec 1995 A
5478403 Shinigawa et al. Dec 1995 A
5478462 Walsh Dec 1995 A
5483920 Pryor Jan 1996 A
5500249 Telford et al. Mar 1996 A
5505816 Barnes et al. Apr 1996 A
5510216 Calabrese et al. Apr 1996 A
5516367 Lei et al. May 1996 A
5534070 Okamura et al. Jun 1996 A
5536360 Nguyen et al. Jun 1996 A
5531835 Fodor et al. Jul 1996 A
5549780 Koinuma et al. Aug 1996 A
5558717 Zhao et al. Sep 1996 A
5560779 Knowles et al. Oct 1996 A
5563105 Dobuzinsky et al. Oct 1996 A
5571576 Qian et al. Nov 1996 A
5578130 Hayashi et al. Nov 1996 A
5578161 Auda Nov 1996 A
5580421 Hiatt et al. Dec 1996 A
5591269 Arami et al. Jan 1997 A
5599740 Jang et al. Feb 1997 A
5624582 Cain Apr 1997 A
5626922 Miyanaga et al. May 1997 A
5635086 Warren, Jr. Jun 1997 A
5645645 Zhang et al. Jul 1997 A
5648125 Cane Jul 1997 A
5648175 Russell et al. Jul 1997 A
5656093 Burkhart et al. Aug 1997 A
5661093 Ravi et al. Aug 1997 A
5674787 Zhao et al. Oct 1997 A
5679606 Wang et al. Oct 1997 A
5688331 Aruga et al. Nov 1997 A
5695810 Dubin et al. Dec 1997 A
5712185 Tsai et al. Jan 1998 A
5716500 Bardos et al. Feb 1998 A
5716506 Maclay et al. Feb 1998 A
5719085 Moon et al. Feb 1998 A
5733816 Iyer et al. Mar 1998 A
5746875 Maydan May 1998 A
5747373 Yu May 1998 A
5755859 Brusic et al. May 1998 A
5756400 Ye et al. May 1998 A
5756402 Jimbo et al. May 1998 A
5772770 Suda et al. Jun 1998 A
5781693 Ballance et al. Jul 1998 A
5786276 Brooks et al. Jul 1998 A
5789300 Fulford Aug 1998 A
5800686 Littau et al. Sep 1998 A
5804259 Robles Sep 1998 A
5812403 Fong et al. Sep 1998 A
5820723 Benjamin et al. Oct 1998 A
5824599 Schacham-Diamand et al. Oct 1998 A
5830805 Schacham-Diamand et al. Nov 1998 A
5838055 Kleinhenz et al. Nov 1998 A
5843538 Ehrsam et al. Dec 1998 A
5844195 Fairbairn et al. Dec 1998 A
5846332 Zhao et al. Dec 1998 A
5846375 Gilchrist et al. Dec 1998 A
5846598 Semkow et al. Dec 1998 A
5849639 Molloy et al. Dec 1998 A
5850105 Dawson et al. Dec 1998 A
5855681 Maydan et al. Jan 1999 A
5856240 Sinha et al. Jan 1999 A
5858876 Chew Jan 1999 A
5872052 Iyer Feb 1999 A
5872058 Van Cleemput et al. Feb 1999 A
5882424 Taylor et al. Mar 1999 A
5882786 Nassau et al. Mar 1999 A
5885404 Kim et al. Mar 1999 A
5885749 Huggins et al. Mar 1999 A
5888906 Sandhu et al. Mar 1999 A
5891349 Tobe et al. Apr 1999 A
5891513 Dubin et al. Apr 1999 A
5897751 Makowiecki Apr 1999 A
5899752 Hey et al. May 1999 A
5904827 Reynolds May 1999 A
5907790 Kellam May 1999 A
5910340 Uchida et al. Jun 1999 A
5913140 Roche et al. Jun 1999 A
5913147 Dubin et al. Jun 1999 A
5915190 Pirkle Jun 1999 A
5918116 Chittipeddi Jun 1999 A
5920792 Lin Jul 1999 A
5932077 Reynolds Aug 1999 A
5933757 Yoshikawa et al. Aug 1999 A
5935334 Fong et al. Aug 1999 A
5937323 Orczyk et al. Aug 1999 A
5939831 Fong et al. Aug 1999 A
5942075 Nagahata et al. Aug 1999 A
5944902 Redeker et al. Aug 1999 A
5951601 Lesinski et al. Sep 1999 A
5951776 Selyutin et al. Sep 1999 A
5953591 Ishihara et al. Sep 1999 A
5953635 Andideh Sep 1999 A
5968610 Liu et al. Oct 1999 A
5969422 Ting et al. Oct 1999 A
5976327 Tanaka Nov 1999 A
5990000 Hong et al. Nov 1999 A
5990013 Berenguer et al. Nov 1999 A
5993916 Zhao et al. Nov 1999 A
6004884 Abraham Dec 1999 A
6010962 Liu et al. Jan 2000 A
6013191 Nasser-Faili et al. Jan 2000 A
6013584 M'Saad Jan 2000 A
6015724 Yamazaki et al. Jan 2000 A
6015747 Lopatin et al. Jan 2000 A
6020271 Yanagida Feb 2000 A
6030666 Lam et al. Feb 2000 A
6030881 Papasouliotis et al. Feb 2000 A
6035101 Sajoto et al. Mar 2000 A
6037018 Jang et al. Mar 2000 A
6037266 Tao et al. Mar 2000 A
6039851 Iyer Mar 2000 A
6053982 Halpin et al. Apr 2000 A
6059643 Hu et al. May 2000 A
6063683 Wu et al. May 2000 A
6063712 Gilton et al. May 2000 A
6065424 Shacham-Diamand et al. May 2000 A
6072227 Yau et al. Jun 2000 A
6077780 Dubin Jun 2000 A
6080529 Ye et al. Jun 2000 A
6083344 Hanawa et al. Jul 2000 A
6083844 Bui-Le et al. Jul 2000 A
6086677 Umotoy et al. Jul 2000 A
6087278 Kim et al. Jul 2000 A
6093594 Yeap et al. Jul 2000 A
6099697 Hausmann Aug 2000 A
6107199 Allen et al. Aug 2000 A
6110530 Chen et al. Aug 2000 A
6110836 Cohen et al. Aug 2000 A
6110838 Loewenstein Aug 2000 A
6113771 Landau et al. Sep 2000 A
6117245 Mandrekar et al. Sep 2000 A
6136163 Cheung et al. Oct 2000 A
6136685 Narwankar et al. Oct 2000 A
6136693 Chan et al. Oct 2000 A
6140234 Uzoh et al. Oct 2000 A
6144099 Lopatin et al. Nov 2000 A
6147009 Grill et al. Nov 2000 A
6149828 Vaartstra Nov 2000 A
6150628 Smith et al. Nov 2000 A
6153935 Edelstein et al. Nov 2000 A
6165912 McConnell et al. Dec 2000 A
6167834 Wang et al. Jan 2001 B1
6169021 Akram et al. Jan 2001 B1
6170428 Redeker et al. Jan 2001 B1
6171661 Zheng et al. Jan 2001 B1
6174812 Hsuing et al. Jan 2001 B1
6176198 Kao et al. Jan 2001 B1
6177245 Ward et al. Jan 2001 B1
6179924 Zhao et al. Jan 2001 B1
6180523 Lee et al. Jan 2001 B1
6182602 Redeker et al. Feb 2001 B1
6189483 Ishikawa et al. Feb 2001 B1
6190233 Hong et al. Feb 2001 B1
6191026 Rana et al. Feb 2001 B1
6194038 Rossman Feb 2001 B1
6197181 Chen Mar 2001 B1
6197364 Paunovic et al. Mar 2001 B1
6197680 Lin et al. Mar 2001 B1
6197688 Simpson Mar 2001 B1
6197705 Vassiliev Mar 2001 B1
6203863 Liu et al. Mar 2001 B1
6204200 Shieh et al. Mar 2001 B1
6217658 Orczyk et al. Apr 2001 B1
6228233 Lakshmikanthan et al. May 2001 B1
6228751 Yamazaki et al. May 2001 B1
6228758 Pellerin et al. May 2001 B1
6235643 Mui et al. May 2001 B1
6238513 Arnold et al. May 2001 B1
6238582 Williams et al. May 2001 B1
6241845 Gadgil et al. Jun 2001 B1
6242349 Nogami et al. Jun 2001 B1
6245396 Nogami Jun 2001 B1
6245670 Cheung et al. Jun 2001 B1
6251236 Stevens Jun 2001 B1
6251802 Moore et al. Jun 2001 B1
6258220 Dordi et al. Jul 2001 B1
6258223 Cheung et al. Jul 2001 B1
6258270 Hilgendorff et al. Jul 2001 B1
6261637 Oberle Jul 2001 B1
6277733 Smith Aug 2001 B1
6277752 Chen Aug 2001 B1
6277763 Kugimiya et al. Aug 2001 B1
6281135 Han et al. Aug 2001 B1
6291282 Wilk et al. Sep 2001 B1
6291348 Lopatin et al. Sep 2001 B1
6303418 Cha et al. Oct 2001 B1
6312995 Yu Nov 2001 B1
6313035 Sandhu et al. Nov 2001 B1
6319387 Krishnamoorthy et al. Nov 2001 B1
6323128 Sambucetti et al. Nov 2001 B1
6335261 Natzle et al. Jan 2002 B1
6335288 Kwan et al. Jan 2002 B1
6340435 Bjorkman et al. Jan 2002 B1
6342733 Hu et al. Jan 2002 B1
6344410 Lopatin et al. Feb 2002 B1
6350320 Sherstinsky et al. Feb 2002 B1
6351013 Luning et al. Feb 2002 B1
6352081 Lu et al. Mar 2002 B1
6364949 Or et al. Apr 2002 B1
6364954 Umotoy et al. Apr 2002 B2
6364957 Schneider et al. Apr 2002 B1
6372657 Hineman et al. Apr 2002 B1
6375748 Yudovsky et al. Apr 2002 B1
6379575 Yin et al. Apr 2002 B1
6383951 Li May 2002 B1
6387207 Janakiraman et al. May 2002 B1
6391753 Yu May 2002 B1
6395150 Van Cleemput et al. May 2002 B1
6403491 Liu et al. Jun 2002 B1
6416647 Dordi et al. Jul 2002 B1
6427623 Ko Aug 2002 B2
6432819 Pavate et al. Aug 2002 B1
6436816 Lee et al. Aug 2002 B1
6440863 Tsai et al. Aug 2002 B1
6441492 Cunningham Aug 2002 B1
6446572 Brcka Sep 2002 B1
6448537 Nering Sep 2002 B1
6458718 Todd Oct 2002 B1
6461974 Ni et al. Oct 2002 B1
6462371 Weimer et al. Oct 2002 B1
6465366 Nemani et al. Oct 2002 B1
6477980 White et al. Nov 2002 B1
6479373 Dreybrodt et al. Nov 2002 B2
6488984 Wada et al. Dec 2002 B1
6494959 Samoilov et al. Dec 2002 B1
6499425 Sandhu et al. Dec 2002 B1
6500728 Wang Dec 2002 B1
6503843 Xia et al. Jan 2003 B1
6506291 Tsai et al. Jan 2003 B2
6516815 Stevens et al. Feb 2003 B1
6518548 Sugaya et al. Feb 2003 B2
6527968 Wang et al. Mar 2003 B1
6528409 Lopatin et al. Mar 2003 B1
6531377 Knorr et al. Mar 2003 B2
6537733 Campana et al. Mar 2003 B2
6541397 Bencher Apr 2003 B1
6541671 Martinez et al. Apr 2003 B1
6544340 Yudovsky Apr 2003 B2
6547977 Yan et al. Apr 2003 B1
6551924 Dalton et al. Apr 2003 B1
6565729 Chen et al. May 2003 B2
6569773 Gellrich et al. May 2003 B1
6573030 Fairbairn et al. Jun 2003 B1
6573606 Sambucetti et al. Jun 2003 B2
6586163 Okabe et al. Jul 2003 B1
6596602 Iizuka et al. Jul 2003 B2
6596654 Bayman et al. Jul 2003 B1
6602434 Hung et al. Aug 2003 B1
6603269 Vo et al. Aug 2003 B1
6605874 Leu et al. Aug 2003 B2
6616967 Test Sep 2003 B1
6627532 Gaillard et al. Sep 2003 B1
6635578 Xu et al. Oct 2003 B1
6638810 Bakli et al. Oct 2003 B2
6645301 Sainty et al. Nov 2003 B2
6645550 Cheung et al. Nov 2003 B1
6656831 Lee et al. Dec 2003 B1
6656837 Xu et al. Dec 2003 B2
6663715 Yuda et al. Dec 2003 B1
6677242 Liu et al. Jan 2004 B1
6677247 Yuan et al. Jan 2004 B2
6679981 Pan et al. Jan 2004 B1
6717189 Inoue et al. Apr 2004 B2
6720213 Gambino et al. Apr 2004 B1
6740585 Yoon et al. May 2004 B2
6743473 Parkhe et al. Jun 2004 B1
6743732 Lin et al. Jun 2004 B1
6756235 Liu et al. Jun 2004 B1
6759261 Shimokohbe et al. Jul 2004 B2
6762127 Boiteux et al. Jul 2004 B2
6762435 Towle Jul 2004 B2
6764958 Nemani et al. Jul 2004 B1
6765273 Chau et al. Jul 2004 B1
6772827 Keller et al. Aug 2004 B2
6794290 Papasouliotis et al. Sep 2004 B1
6794311 Huang et al. Sep 2004 B2
6796314 Graff et al. Sep 2004 B1
6797189 Hung et al. Sep 2004 B2
6800830 Mahawili Oct 2004 B2
6802944 Ahmad et al. Oct 2004 B2
6808564 Dietze Oct 2004 B2
6808748 Kapoor et al. Oct 2004 B2
6821571 Huang Nov 2004 B2
6823589 White et al. Nov 2004 B2
6830624 Janakiraman et al. Dec 2004 B2
6835995 Li Dec 2004 B2
6846745 Papasouliotis et al. Jan 2005 B1
6852550 Tuttle et al. Feb 2005 B2
6858153 Bjorkman et al. Feb 2005 B2
6867141 Jung et al. Mar 2005 B2
6869880 Krishnaraj et al. Mar 2005 B2
6878206 Tzu et al. Apr 2005 B2
6879981 Rothschild et al. Apr 2005 B2
6886491 Kim et al. May 2005 B2
6892669 Xu et al. May 2005 B2
6893967 Wright et al. May 2005 B1
6897532 Schwarz et al. May 2005 B1
6903031 Karim et al. Jun 2005 B2
6903511 Chistyakov Jun 2005 B2
6908862 Li et al. Jun 2005 B2
6911112 An Jun 2005 B2
6911401 Khandan et al. Jun 2005 B2
6921556 Shimizu et al. Jul 2005 B2
6924191 Liu et al. Aug 2005 B2
6942753 Choi et al. Sep 2005 B2
6951821 Hamelin et al. Oct 2005 B2
6958175 Sakamoto et al. Oct 2005 B2
6958286 Chen et al. Oct 2005 B2
6974780 Schuegraf Dec 2005 B2
7017269 White et al. Mar 2006 B2
7018941 Cui et al. Mar 2006 B2
7030034 Fucsko et al. Apr 2006 B2
7049200 Arghavani et al. May 2006 B2
7078312 Sutanto et al. Jul 2006 B1
7081414 Zhang et al. Jul 2006 B2
7084070 Lee et al. Aug 2006 B1
7115525 Abatchev et al. Oct 2006 B2
7122949 Strikovski Oct 2006 B2
7148155 Tarafdar et al. Dec 2006 B1
7166233 Johnson et al. Jan 2007 B2
7183214 Nam et al. Feb 2007 B2
7196342 Ershov et al. Mar 2007 B2
7205240 Karim et al. Apr 2007 B2
7223701 Min et al. May 2007 B2
7226805 Hallin et al. Jun 2007 B2
7235137 Kitayama et al. Jun 2007 B2
7253123 Arghavani et al. Aug 2007 B2
7256370 Guiver Aug 2007 B2
7288482 Panda et al. Oct 2007 B2
7341633 Lubomirsky et al. Mar 2008 B2
7365016 Ouellet et al. Apr 2008 B2
7390710 Derderian et al. Jun 2008 B2
7396480 Kao et al. Jul 2008 B2
7416989 Liu et al. Aug 2008 B1
7465358 Weidman et al. Dec 2008 B2
7484473 Keller et al. Feb 2009 B2
7488688 Seung-Pil et al. Feb 2009 B2
7494545 Lam et al. Feb 2009 B2
7575007 Tang et al. Aug 2009 B2
7581511 Mardian et al. Sep 2009 B2
7628897 Mungekar et al. Dec 2009 B2
7709396 Bencher et al. May 2010 B2
7722925 White et al. May 2010 B2
7785672 Choi et al. Aug 2010 B2
7807578 Bencher et al. Oct 2010 B2
7871926 Xia et al. Jan 2011 B2
7910491 Soo Kwon et al. Mar 2011 B2
7915139 Lang et al. Mar 2011 B1
7939422 Ingle et al. May 2011 B2
7968441 Xu Jun 2011 B2
7981806 Jung Jul 2011 B2
8008166 Sanchez et al. Aug 2011 B2
8058179 Draeger et al. Nov 2011 B1
8071482 Kawada Dec 2011 B2
8074599 Choi et al. Dec 2011 B2
8083853 Choi et al. Dec 2011 B2
8133349 Panagopoulos Mar 2012 B1
8187486 Liu et al. May 2012 B1
8211808 Sapre et al. Jul 2012 B2
8309440 Sanchez et al. Nov 2012 B2
8328939 Choi et al. Dec 2012 B2
8435902 Tang et al. May 2013 B2
8491805 Kushibiki et al. Jul 2013 B2
8642481 Wang et al. Feb 2014 B2
8772888 Jung et al. Jul 2014 B2
8956980 Chen et al. Feb 2015 B1
20010008803 Takamatsu et al. Jul 2001 A1
20010015261 Kobayashi et al. Aug 2001 A1
20010020365 Kubo Sep 2001 A1
20010028922 Sandhu Oct 2001 A1
20010030366 Nakano et al. Oct 2001 A1
20010034121 Fu et al. Oct 2001 A1
20010041444 Shields et al. Nov 2001 A1
20010053585 Kikuchi et al. Dec 2001 A1
20010054381 Umotoy et al. Dec 2001 A1
20010055842 Uh et al. Dec 2001 A1
20020000202 Yuda et al. Jan 2002 A1
20020011210 Satoh et al. Jan 2002 A1
20020016080 Khan et al. Feb 2002 A1
20020016085 Huang et al. Feb 2002 A1
20020028582 Nallan et al. Mar 2002 A1
20020028585 Chung et al. Mar 2002 A1
20020029747 Powell et al. Mar 2002 A1
20020033233 Savas Mar 2002 A1
20020036143 Segawa et al. Mar 2002 A1
20020040764 Kwan et al. Apr 2002 A1
20020045966 Lee et al. Apr 2002 A1
20020054962 Huang May 2002 A1
20020069820 Yudovsky Jun 2002 A1
20020070414 Drescher et al. Jun 2002 A1
20020074573 Takeuchi et al. Jun 2002 A1
20020079088 Agonafer Jun 2002 A1
20020098681 Hu et al. Jul 2002 A1
20020124867 Kim et al. Sep 2002 A1
20020129769 Kim et al. Sep 2002 A1
20020177322 Li et al. Nov 2002 A1
20020187280 Johnson et al. Dec 2002 A1
20020187655 Tan et al. Dec 2002 A1
20020197823 Yoo et al. Dec 2002 A1
20030003757 Naltan et al. Jan 2003 A1
20030010645 Ting et al. Jan 2003 A1
20030019428 Ku et al. Jan 2003 A1
20030019580 Strang Jan 2003 A1
20030029566 Roth Feb 2003 A1
20030029715 Yu et al. Feb 2003 A1
20030032284 Enomoto et al. Feb 2003 A1
20030038127 Liu et al. Feb 2003 A1
20030038305 Wasshuber Feb 2003 A1
20030054608 Tseng et al. Mar 2003 A1
20030072639 White et al. Apr 2003 A1
20030075808 Inoue et al. Apr 2003 A1
20030077909 Jiwari Apr 2003 A1
20030079686 Chen et al. May 2003 A1
20030087531 Kang et al. May 2003 A1
20030091938 Fairbairn et al. May 2003 A1
20030098125 An May 2003 A1
20030109143 Hsieh et al. Jun 2003 A1
20030116087 Nguyen et al. Jun 2003 A1
20030116439 Seo et al. Jun 2003 A1
20030121608 Chen et al. Jul 2003 A1
20030124465 Lee et al. Jul 2003 A1
20030124842 Hytros et al. Jul 2003 A1
20030129106 Sorensen et al. Jul 2003 A1
20030129827 Lee et al. Jul 2003 A1
20030132319 Hytros et al. Jul 2003 A1
20030148035 Lingampalli Aug 2003 A1
20030173333 Wang et al. Sep 2003 A1
20030173347 Guiver Sep 2003 A1
20030181040 Ivanov et al. Sep 2003 A1
20030183244 Rossman Oct 2003 A1
20030190426 Padhi et al. Oct 2003 A1
20030199170 Li Oct 2003 A1
20030221780 Lei et al. Dec 2003 A1
20030224217 Byun et al. Dec 2003 A1
20030224617 Baek et al. Dec 2003 A1
20040005726 Huang Jan 2004 A1
20040033678 Arghavani et al. Feb 2004 A1
20040050328 Kumagai et al. Mar 2004 A1
20040069225 Fairbairn et al. Apr 2004 A1
20040070346 Choi Apr 2004 A1
20040072446 Liu et al. Apr 2004 A1
20040101667 O'Loughlin et al. May 2004 A1
20040110354 Natzle et al. Jun 2004 A1
20040115876 Goundar et al. Jun 2004 A1
20040129224 Yamazaki Jul 2004 A1
20040137161 Segawa et al. Jul 2004 A1
20040144490 Zhao et al. Jul 2004 A1
20040154535 Chen et al. Aug 2004 A1
20040175929 Schmitt et al. Sep 2004 A1
20040182315 Laflamme et al. Sep 2004 A1
20040192032 Ohmori et al. Sep 2004 A1
20040194799 Kim et al. Oct 2004 A1
20040211357 Gadgil et al. Oct 2004 A1
20040219789 Wood et al. Nov 2004 A1
20040245091 Karim et al. Dec 2004 A1
20050001276 Gao et al. Jan 2005 A1
20050003676 Ho et al. Jan 2005 A1
20050009358 Choi et al. Jan 2005 A1
20050026430 Kim et al. Feb 2005 A1
20050026431 Kazumi et al. Feb 2005 A1
20050035455 Hu et al. Feb 2005 A1
20050048801 Karim et al. Mar 2005 A1
20050073051 Yamamoto et al. Apr 2005 A1
20050090120 Hasegawa et al. Apr 2005 A1
20050098111 Shimizu et al. May 2005 A1
20050112901 Ji et al. May 2005 A1
20050121750 Chan et al. Jun 2005 A1
20050181588 Kim Aug 2005 A1
20050199489 Stevens et al. Sep 2005 A1
20050205110 Kao et al. Sep 2005 A1
20050214477 Hanawa et al. Sep 2005 A1
20050218507 Kao et al. Oct 2005 A1
20050221552 Kao et al. Oct 2005 A1
20050230350 Kao et al. Oct 2005 A1
20050236694 Wu et al. Oct 2005 A1
20050266622 Arghavani et al. Dec 2005 A1
20050266691 Gu et al. Dec 2005 A1
20050287771 Seamons et al. Dec 2005 A1
20060000802 Kumar et al. Jan 2006 A1
20060000805 Todorow et al. Jan 2006 A1
20060011298 Lim et al. Jan 2006 A1
20060019456 Bu et al. Jan 2006 A1
20060019486 Yu et al. Jan 2006 A1
20060024954 Wu et al. Feb 2006 A1
20060024956 Zhijian et al. Feb 2006 A1
20060033678 Lubomirsky et al. Feb 2006 A1
20060046419 Sandhu et al. Mar 2006 A1
20060046484 Abatchev et al. Mar 2006 A1
20060051966 Or et al. Mar 2006 A1
20060051968 Joshi et al. Mar 2006 A1
20060054184 Mozetic et al. Mar 2006 A1
20060093756 Rajagopalan et al. May 2006 A1
20060102076 Smith et al. May 2006 A1
20060130971 Chang et al. Jun 2006 A1
20060162661 Jung et al. Jul 2006 A1
20060166107 Chen et al. Jul 2006 A1
20060166515 Karim et al. Jul 2006 A1
20060178008 Yeh et al. Aug 2006 A1
20060185592 Matsuura Aug 2006 A1
20060191637 Zajac et al. Aug 2006 A1
20060207504 Hasebe et al. Sep 2006 A1
20060210723 Ishizaka Sep 2006 A1
20060211260 Tran et al. Sep 2006 A1
20060216923 Tran et al. Sep 2006 A1
20060226121 Aoi Oct 2006 A1
20060240661 Annapragada et al. Oct 2006 A1
20060246717 Weidman et al. Nov 2006 A1
20060251800 Weidman et al. Nov 2006 A1
20060251801 Weidman et al. Nov 2006 A1
20060252252 Zhu et al. Nov 2006 A1
20060261490 Su et al. Nov 2006 A1
20060264003 Eun Nov 2006 A1
20060264043 Stewart et al. Nov 2006 A1
20060266288 Choi Nov 2006 A1
20070071888 Shanmugasundram et al. Mar 2007 A1
20070072408 Enomoto et al. Mar 2007 A1
20070090325 Hwang et al. Apr 2007 A1
20070099428 Shamiryan et al. May 2007 A1
20070099431 Li May 2007 A1
20070099438 Ye et al. May 2007 A1
20070107750 Sawin et al. May 2007 A1
20070108404 Stewart et al. May 2007 A1
20070111519 Lubomirsky et al. May 2007 A1
20070117396 Wu et al. May 2007 A1
20070123051 Arghavani et al. May 2007 A1
20070163440 Kim et al. Jul 2007 A1
20070181057 Lam et al. Aug 2007 A1
20070193515 Jeon et al. Aug 2007 A1
20070197028 Byun et al. Aug 2007 A1
20070210717 Smith Sep 2007 A1
20070232071 Balseanu et al. Oct 2007 A1
20070238321 Futase et al. Oct 2007 A1
20070243685 Jiang et al. Oct 2007 A1
20070269976 Futase et al. Nov 2007 A1
20070281106 Lubomirsky et al. Dec 2007 A1
20080044990 Lee Feb 2008 A1
20080075668 Goldstein Mar 2008 A1
20080081483 Wu Apr 2008 A1
20080085604 Hoshino et al. Apr 2008 A1
20080099431 Kumar et al. May 2008 A1
20080115726 Ingle et al. May 2008 A1
20080124919 Huang et al. May 2008 A1
20080124937 Xu et al. May 2008 A1
20080142483 Hua et al. Jun 2008 A1
20080142831 Hua et al. Jun 2008 A1
20080153306 Cho et al. Jun 2008 A1
20080160210 Yang et al. Jul 2008 A1
20080162781 Haller et al. Jul 2008 A1
20080182381 Kiyotoshi Jul 2008 A1
20080182382 Ingle et al. Jul 2008 A1
20080182383 Lee et al. Jul 2008 A1
20080202892 Smith et al. Aug 2008 A1
20080230129 Davis Sep 2008 A1
20080230519 Takahashi Sep 2008 A1
20080233709 Conti et al. Sep 2008 A1
20080261404 Kozuka et al. Oct 2008 A1
20080268645 Kao et al. Oct 2008 A1
20080282979 Chen Nov 2008 A1
20080292798 Huh et al. Nov 2008 A1
20090004849 Eun Jan 2009 A1
20090017227 Fu et al. Jan 2009 A1
20090045167 Maruyama Feb 2009 A1
20090104738 Ring et al. Apr 2009 A1
20090104764 Xia et al. Apr 2009 A1
20090104782 Lu et al. Apr 2009 A1
20090170221 Jacques et al. Jul 2009 A1
20090189246 Wu et al. Jul 2009 A1
20090202721 Nogami et al. Aug 2009 A1
20090255902 Satoh et al. Oct 2009 A1
20090275205 Kiehlbauch et al. Nov 2009 A1
20090275206 Katz et al. Nov 2009 A1
20090277874 Rui et al. Nov 2009 A1
20090280650 Lubomirsky et al. Nov 2009 A1
20100048027 Cheng et al. Feb 2010 A1
20100055917 Kim Mar 2010 A1
20100059889 Gosset et al. Mar 2010 A1
20100075503 Bencher et al. Mar 2010 A1
20100093151 Arghavani et al. Apr 2010 A1
20100098884 Balseanu et al. Apr 2010 A1
20100099236 Kwon et al. Apr 2010 A1
20100099263 Kao et al. Apr 2010 A1
20100101727 Ji Apr 2010 A1
20100105209 Winniczek et al. Apr 2010 A1
20100144140 Chandrashekar et al. Jun 2010 A1
20100173499 Tao et al. Jul 2010 A1
20100178755 Lee et al. Jul 2010 A1
20100187534 Nishi et al. Jul 2010 A1
20100187588 Gil-Sub et al. Jul 2010 A1
20100187694 Yu et al. Jul 2010 A1
20100190352 Jaiswal Jul 2010 A1
20100207205 Grebs et al. Aug 2010 A1
20100330814 Yokota et al. Dec 2010 A1
20110008950 Xu Jan 2011 A1
20110011338 Chuc et al. Jan 2011 A1
20110034035 Liang et al. Feb 2011 A1
20110053380 Sapre et al. Mar 2011 A1
20110081782 Liang et al. Apr 2011 A1
20110124144 Schlemm et al. May 2011 A1
20110143542 Feurprier et al. Jun 2011 A1
20110151674 Tang et al. Jun 2011 A1
20110151676 Ingle et al. Jun 2011 A1
20110151677 Wang et al. Jun 2011 A1
20110151678 Ashtiani et al. Jun 2011 A1
20110155181 Inatomi Jun 2011 A1
20110159690 Chandrashekar et al. Jun 2011 A1
20110165771 Ring et al. Jul 2011 A1
20110180847 Ikeda et al. Jul 2011 A1
20110195575 Wang Aug 2011 A1
20110217851 Liang et al. Sep 2011 A1
20110226734 Sumiya et al. Sep 2011 A1
20110230052 Tang et al. Sep 2011 A1
20110266252 Thadani et al. Nov 2011 A1
20110294300 Zhang et al. Dec 2011 A1
20120003782 Byun et al. Jan 2012 A1
20120009796 Cui et al. Jan 2012 A1
20120068242 Shin et al. Mar 2012 A1
20120135576 Lee et al. May 2012 A1
20120164839 Nishimura Jun 2012 A1
20120196447 Yang et al. Aug 2012 A1
20120211462 Zhang et al. Aug 2012 A1
20120238102 Zhang et al. Sep 2012 A1
20120238103 Zhang et al. Sep 2012 A1
20120285621 Tan Nov 2012 A1
20120292664 Kanike Nov 2012 A1
20120309204 Kang et al. Dec 2012 A1
20130005140 Jeng et al. Jan 2013 A1
20130034968 Zhang et al. Feb 2013 A1
20130045605 Wang et al. Feb 2013 A1
20130052827 Wang et al. Feb 2013 A1
20130052833 Ranjan et al. Feb 2013 A1
20130059440 Wang et al. Mar 2013 A1
20130089988 Wang et al. Apr 2013 A1
20130119483 Alptekin et al. May 2013 A1
20130187220 Surthi Jul 2013 A1
20130260533 Sapre et al. Oct 2013 A1
20130284369 Kobayashi et al. Oct 2013 A1
20130284370 Kobayashi et al. Oct 2013 A1
20130302980 Chandrashekar et al. Nov 2013 A1
20140147126 Linnartz et al. May 2014 A1
20140263272 Duan et al. Sep 2014 A1
Foreign Referenced Citations (32)
Number Date Country
1375575 Oct 2002 CN
1412861 Apr 2003 CN
101465386 Jun 2009 CN
0329406 Aug 1989 EP
0376252 Jul 1990 EP
0475567 Mar 1992 EP
0 496 543 Jul 1992 EP
0 658 928 Jun 1995 EP
0697467 Feb 1996 EP
0913498 May 1999 EP
1099776 May 2001 EP
1107288 Jun 2001 EP
1496542 Jan 2005 EP
1568797 Aug 2005 EP
2285174 Jun 1995 GB
2058836 Feb 1990 JP
02256235 Oct 1990 JP
7297543 Nov 1995 JP
09153481 Jun 1997 JP
09-205140 Aug 1997 JP
11124682 May 1999 JP
04-239723 Aug 2004 JP
1020000008278 Feb 2000 KR
10-2001-0058774 Jul 2001 KR
1020030096140 Dec 2003 KR
10-2004-0096365 Nov 2004 KR
1020050042701 May 2005 KR
1020080063988 Jul 2008 KR
10-2010-0074508 Jul 2010 KR
1020110126675 Nov 2011 KR
1020120082640 Jul 2012 KR
1999026277 May 1999 WO
Non-Patent Literature Citations (80)
Entry
Abe et al., “Developments of plasma etching technology for fabricating semiconductor devices,” Jpn. J. Appl. Phys., vol. 47, No. 3R, Mar. 2008, 21 pgs.
Cho et al., “Dual Discharge Modes Operation of an Argon Plasma Generated by Commercial Electronic Ballast for Remote Plasma Removal Process,” IEEE Transactions on Plasma Science, vol. 42, No. 6, , Jun. 2014, 4 pages.
Cho et al., “Dielectric-barrier microdischarge structure for effic ient positive-column plasma using a thick-film ceramic sheet,” IEEE Trans. Plasma Sci., vol. 37, No. 8, Aug. 2009, 4 pgs.
Cho et al., “Three-dimensional spatiotemporal behaviors of light emission from discharge plasma of alternating current plasma display panels,” Appl. Phys. Lett. , vol. 92, No. 22, Jun. 2008, 3pgs.
Cho et al., “Analysis of address discharge modes by using a three-dimensional plasma display panel,” IEEE Trans. Plasma Sci. , vol. 36, Oct. 2008, 4 pgs.
C.K. Hu, et al. “Reduced Electromigration of Cu Wires by Surface Coating” Applied Physics Letters, vol. 81, No. 10, Sep. 2, 2002—pp. 1782-1784.
Derwent 2006-065772, Formation of multilayer enscapulating film over substrate, e.g. displace device, comprising delivering mixture precursors and hydrogen gas into substrate processing system, 2006.
European Search Report dated May 23, 2006 for EP Application No. 05251143.3.
European Examination Report dated Nov. 13, 2007 for EP Application No. 05251143.3.
EP Partial Search Report, Application No. 08150111.601235/1944796, dated Aug. 22, 2008.
Eze, F. C., “Electroless deposition of CoO thin films,” J. Phys. D: Appl. Phys. 32 (1999), pp. 533-540.
Galiano et al. “Stress-Temperature Behavior of Oxide Films Used for Intermetal Dielectric Applications”, VMIC Conference, Jun. 9-10, 1992, pp. 100-106.
Goebels, F.J. et al. “Arbitrary Polarization from Annular Slot Planar Antennas.” Ire Transactions on Antennas and Propagation, Jul. 1961, 8 pgs.
Iijima, et al., “Highly Selective SiO2 Etch Employing Inductively Coupled Hydro-Fluorocarbon Plasma Chemistry for Self Aligned Contact Etch”, Jpn. J. Appl. Phys., Sep. 1997, pp. 5498-5501, vol. 36, Part 1, No. 9A.
International Search Report of PCT/US2009/059743 dated Apr. 26, 2010, 4 pages.
International Search Report of PCT/US2012/061726 dated May 16, 2013, 3 pages.
International Search Report of PCT/2013/052039 dated Nov. 8, 2013, 9 pages.
International Search Report of PCT/2013/037202 dated Aug. 23, 2013, 11 pages.
Kim et al., “Pendulum electrons in micro hollow cathode di scharges,” IEEE Trans. Plasma Sci. , vol. 36, No. 4, pp. Aug. 2008, 2 pgs.
Lin, et al., “Manufacturing of Cu Electroless Nickel/Sn—Pb Flip Chip Solder Bumps”, IEEE Transactions on Advanced Packaging, vol. 22, No. 4 (Nov. 1999), pp. 575-579.
Lopatin, et al., “Thin Electroless barrier for copper films”, Part of the SPIE Conference of Multilevel Interconnect technology II, SPIE vol. 3508 (1998), pp. 65-77.
Musaka, “Single Step Gap Filling Technology fo Subhalf Micron Metal Spacings on Plasma Enhanced TEOS/O2 Chemical Vapor Deposition System,” Extended Abstracts of the 1993 International Conference on Solid State Devices and Materials pp. 1993, 510-512.
Pearlstein, Fred. “Electroless Plating,” J. Res. Natl. Bur. Stan., Ch. 31 (1974), pp. 710-747.
Redolfi et al., “Bulk FinFET fabrication with new approaches for oxide topography control using dry removal techniques,” Solid-State Electron., vol. 71, May 2012, 7 pgs.
Saito, et al., “Electroless deposition of Ni—B, Co—B and Ni—Co—B alloys using dimethylamineborane as a reducing agent,” Journal of Applied Electrochemistry 28 (1998), pp. 559-563.
Schacham-Diamond, et al., “Electrochemically deposited thin film alloys for ULSI and MEMS applications,” Microelectronic Engineering 50 (2000), pp. 525-531.
Schacham-Diamond, et al. “Material properties of electroless 100-200 nm thick CoWP films,” Electrochemical Society Proceedings, vol. 99-34, pp. 102-110.
Schoenbach et al.,“High-pressure hollow cathode di scharges,” Plasma Sources Sci. Te chnol.,vol. 6, No. 4, Nov. 1997, 10 pgs.
Smayling, et al., “APF® Pitch-Halving for 2nm Logic Cells using Gridded Design Rules”, proceedings of the SPIE, 2008, 8 pages.
Vassiliev, et al., “Trends in void-free pre-metal CVD dielectrics,” Solid State Technology, Mar. 2001, pp. 129-136.
Weston, et al., “Ammonium Compounds,” Kirk-Othmer Encyclopedia of Chemical Technology, 2003,30 pages see pp. 717-718, John Wiley & Sons, Inc.
Yosi Shacham-Diamond, et al. “High Aspect Ratio Quarter-Micron Electroless Copper Integrated Technology”, Microelectronic Engineering 37/38 (1997) pp. 77-88.
Li, D. et al., “HDP-CVD dep/etch/dep Process for Improved Deposition into High Aspect Ratio Features,” U.S. Pat. No. 6,908,862 published Jun. 21, 2005.
Abraham, “Reactive Facet Tapering of Plasma Oxide for Multilevel Interconnect Applications”, IEEE, V-MIC Conference, Jun. 15-16, 1987, pp. 115-121.
Applied Materials, Inc., “Applied Siconi™ Preclean,” printed on Aug. 7, 2009, 8 pages.
Carlson, et al., “A Negative Spacer Lithography Process for Sub-100nm Contact Holes and Vias”, University of California at Berkeley, Jun. 19, 2007, 4 pp.
Chang et al. “Frequency Effects and Properties of Plasma Deposited Fluorinated Silicon Nitride”, J. Vac Sci Technol B 6(2), Mar./Apr. 1988, pp. 524-532.
Cheng, et al., “New Test Structure to Identify Step Coverage Mechanisms in Chemical Vapor Deposition of Silicon Dioxide,” Appl. Phys. Lett., 58 (19), May 13, 1991, p. 2147-2149.
Examination Report dated Jun. 28, 2010 for European Patent Application No. 05251143.3.
Fukada et al., “Preparation of SiOF Films with Low Dielectric Constant by ECR Plasma CVD,” ISMIC, DUMIC Conference, Feb. 21-22, 1995, pp. 43-49.
Hashim et al., “Characterization of thin oxide removal by RTA Treatment,” ICSE 1998 Proc. Nov. 1998, Rangi, Malaysia, pp. 213-216.
Hausmann, et al., “Rapid Vapor Deposition of Highly Conformal Silica Nanolaminates,” Science, Oct. 11, 2002, p. 402-406, vol. 298.
Hayasaka, N. et al. “High Quality Low Dielectric Constant SiO2 CVD Using High Density Plasma,” Proceedings of the Dry Process Symposium, 1993, pp. 163-168.
Hwang et al., “Smallest Bit-Line Contact of 76nm pitch on NAND Flash Cell by using Reversal PR (Photo Resist) and SADP (Self-Align Double Patterning) Process,” IEEE/SEMI Advanced Semiconductor Manufacturing Conference, 2007, 3 pages.
International Search Report and Written Opinion of the International Searching Authority dated Jul. 3, 2008 (PCT/US05/46226).
International Search Report and Written Opinion for PCT Application No. PCT/US2011/027221, dated Nov. 1, 2011, 8 pages.
International Search Report and Written Opinion of PCT/US2010/057676 dated Jun. 27, 2011, 9 pages.
International Search Report and Written Opinion of PCT/US2011/030582 dated Dec. 7, 2011, 9 pages.
International Search Report and Written Opinion of PCT/US2011/064724 dated Oct. 12, 2012, 8 pages.
International Search Report and Written Opinion of PCT/US2012/028952 dated Oct. 29, 2012, 9 pages.
International Search Report and Written Opinion of PCT/US2012/048842 dated Nov. 28, 2012, 10 pages.
International Search Report and Written Opinion of PCT/US2012/053329 dated Feb. 15, 2013, 8 pages.
International Search Report and Written Opinion of PCT/US2012/057294 dated Mar. 18, 2013, 12 pages.
International Search Report and Written Opinion of PCT/US2012/057358 dated Mar. 25, 2013, 10 pages.
International Search Report and Written Opinion of PCT/US2012/058818 dated Apr. 1, 2013, 9 pages.
International Search Report and Written Opinion of the International Searching Authority for PCT Application No. PCT/US2012/028957, dated Oct. 18, 2012, 9 pages.
International Search report and Written Opinion of PCT/CN2010/000932 dated Mar. 31, 2011, 8 pages.
Japanese Patent Office, Official Action for Application No. 2007-317207 dated Dec. 21, 2011, 2 pages.
International Search Report and Written Opinion of PCT/US2013/076217 dated Apr. 28, 2014, 11 pages.
Jung, et al., “Patterning with amorphous carbon spacer for expanding the resolution limit of current lithography tool”, Proc. SPIE , 2007, 9 pages, vol. 6520, 65201C.
Laxman, “Low ϵ Dielectrics: CVD Fluorinated Silicon Dioxides”, Semiconductor International, May 1995, pp. 71-74.
Lee, et al., “Dielectric Planarization Techniques for Narrow Pitch Multilevel Interconnects,” IEEE, V-MIC Conference Jun. 15-16, 1987, pp. 85-92 (1987).
Matsuda, et al. “Dual Frequency Plasma CVD Fluorosilicate Glass Deposition for 0.25 um Interlevel Dielectrics”, ISMIC, DUMIC Conference Feb. 21-22, 1995, pp. 22-28.
Meeks, Ellen et al., “Modeling of SiO2 deposition in high density plasma reactors and comparisons of model predictions with experimental measurements,” J. Vac. Sci. Technol. A, Mar./Apr. 1998, pp. 544-563, vol. 16(2).
Mukai, et al., “A Study of CD Budget in Spacer Patterning Process”, Toshiba, SPIE 2008, Feb. 26, 2008, 12 pages.
Nishino, et al.; Damage-Free Selective Etching of SI Native Oxides Using NH3/NF3 and SF6/H20 Down-Flow Etching, The Japanese Society of Applied Physics, vol. 74, No. 2, pp. 1345-1348, XP-002491959, Jul. 15, 1993.
Ogawa, et al., “Dry Cleaning Technology for Removal of Silicon Native Oxide Employing Hot NH3/NF3 Exposure”, Japanese Journal of Applied Physics, pp. 5349-5358, Aug. 2002, vol. 41 Part 1, No. 8.
Ota, et al., “Stress Controlled Shallow Trench Isolation Technology to Suppress the Novel Anti-Isotropic Impurity Diffusion for 45nm-Node High Performance CMOSFETs,” Symposium on VLSI Technology Digest of Technical Papers, 2005, pp. 138-139.
Qian, et al., “High Density Plasma Deposition and Deep Submicron Gap Fill with Low Dielectric Constant SiOF Films,” ISMIC, DUMIC Conference Feb. 21-22, 1995, 1995, pp. 50-56.
Robles, et al. “Effects of RF Frequency and Deposition Rates on the Moisture Resistance of PECVD TEOS-Based Oxide Films”, ECS Extended Abstracts, Abstract No. 129, May 1992, pp. 215-216, vol. 92-1.
S.M. Sze, VLSI Technology, McGraw-Hill Book Company, pp. 107, 108.
C.C. Tang and D. W. Hess, Tungsten Etching in CF4 and SF6 Discharges, J. Electrochem. Soc., 1984, 131 (1984) p. 115-120.
Usami, et al., “Low Dielectric Constant Interlayer Using Fluorine-Doped Silicon Oxide”, Jpn. J. Appl. Phys., Jan. 19, 1994. pp. 408-412, vol. 33 Part 1, No. 1B.
Wang et al.; Ultra High-selectivity silicon nitride etch process using an inductively coupled plasma source; J. Vac. Sci. Techno!. A 16(3),May/Jun. 1998, pp. 1582-1587.
Wolf et al.; Silicon Processing for the VLSI Era; vol. 1; 1986; Lattice Press, pp. 546, 547, 618, 619.
Yang, R., “Advanced in situ pre-Ni silicide (Siconi) cleaning at 65 nm to resolve defects in NiSix modules,” J. Vac. Sci., Technol. B, Microelectron. Nanometer Struct., vol. 28, No. 1, Jan. 2010, 6 pgs.
Yasaka, Y. et al. “Planar microwave discharges with active control of plasma uniformity”. Physics of Plasmas, vol. 9 No. 3, Mar. 2002, 7 pgs.
Yasuda et al., “Dual-function remote plasma etching/cleaning system applied to selective etching of Si02 and removal of polymeric residues,” J. Vac. Sci. Technol., A, vol. 11, No. 5, 1993, 12 pgs.
Yu, et al., “Step Coverage Study of Peteos Deposition for Intermetal Dielectric Applications,” abstract, VMIC conference, Jun. 12-13, 1990, 7 pages, No. 82.
Yutaka, et al., “Selective Etching of Silicon Native Oxide with Remote-Plasma-Excited Anhydrous Hydrogen Fluoride,” Japanese Journal of Applied Physics, 1998, vol. 37, pp. L536-L538.
Related Publications (1)
Number Date Country
20140252134 A1 Sep 2014 US
Provisional Applications (1)
Number Date Country
61774963 Mar 2013 US