The present invention relates to methods of forming a semiconductor structure, and particularly to methods of extending the depth of a via opening to enable exposure of an underlying metal line and formation of a contact thereupon.
Manufacture of a semiconductor chip employs formation of an interconnect structure in back-end-of-line (BEOL) processing steps. The interconnect structure comprises multiple levels of metal lines and metal vias. The metal lines provide horizontal conduction paths within the same interconnect level, while the metal vias provide vertical conduction paths between neighboring interconnect levels. Typically, the interconnect structure further comprises metal pads at a top level of the interconnect structure to provide electrical paths for communicating signals into and out of the semiconductor chip. For this purpose, the metal pads may be employed as wirebond pads.
Formation of a functional interconnect structure requires sequential performance of multiple proper processing steps on a semiconductor substrate. The sequence of the processing steps is termed in the art as “routing,” or “process integration.” Maintaining variations of an individual process within allowable limits, or “process specifications,” which is typically set by yield considerations, is termed in the art as “process control.” Proper routing and process control are essential in the manufacture of the functional interconnect structure.
A prior art interconnect structure for formation of a metal pad is described herein to illustrate a particular example of routing and process control issues involved in the manufacture of interconnect structures. Referring to
Referring to
Referring to
The exemplary prior art structure of
An increase of the total thickness of the dielectric cap layer 20, the first dielectric layer 30, and the second dielectric layer 32 may be caused by failure in process control or by erroneous routing such as repeated deposition of any one of the dielectric cap layer 20, the first dielectric layer 30, and the second dielectric layer 32. Such an increase in the total thickness may result in an incomplete via opening VO that does not expose a top surface of the metal lines 14 and/or a metal pad (40, 50) that does not contact the metal lines 14. Absent intervention at this point, a resulting semiconductor chip is a non-functional chip due to the electrically disconnected metal pad (40, 50).
In view of the above, there exists a need for integration schemes that enables proper formation of a metal pad that contacts a metal line within an interconnect level dielectric layer after formation of an incomplete via opening that does not expose the metal line.
In general, formation of the incomplete via opening may be detected at any of the various processing steps thereafter including a step after removal of the photoresist 47 and prior to formation of the at least one metallic liner layer, a step after formation of the metal layer and prior to patterning of the metal layer, or a step after patterning of the metal pad (40, 50). Therefore, there is a need for integration schemes for forming a proper metal pad contacting the metal line within the interconnect level dielectric layer from interconnect structures at various steps after the formation of the incomplete via opening.
The present invention addresses the needs described above by providing integration schemes for forming a proper metal pad contacting a metal line within an interconnect level dielectric layer from interconnect structures at various steps after the formation of an incomplete via opening.
In the present invention, an interconnect structure having an incomplete via opening that does not expose a top surface of a metal line underneath is processed to deepen the via opening and to expose the metal line. In case the interconnect structure comprises a metal pad or a blanket metal layer, the metal pad or the metal layer is removed selective to an underlying dielectric layer to expose the incomplete via opening. Another dielectric layer is formed within the incomplete via opening to compensated for differences in the total dielectric thickness above the metal line relative to an optimal dielectric stack. A photoresist is applied thereupon and patterned. An anisotropic etch process for formation of a normal via opening may be employed with no or minimal modification to form a proper via opening and to expose the metal line. A metal pad is formed upon the metal line so that electrical contact is provided between the metal pad and the metal line.
According to an aspect of the present invention, a method of modifying a first interconnect structure is provided, which comprises:
providing an interconnect structure comprising:
removing the metal pad selective to the at least one dielectric layer and exposing the via opening;
forming a supplementary dielectric layer in the via opening, wherein the sum of a thickness of the supplementary dielectric layer and a thickness of the at least one dielectric layer directly above the metal line is substantially equal to a predefined target thickness; and
patterning the supplementary dielectric layer and the at least one dielectric layer directly above the metal line to expose the metal line.
According to another aspect of the present invention, a method of modifying a second interconnect structure is provided, which comprises:
providing an interconnect structure comprising:
removing the metal layer and the at least one metallic liner selective to the at least one dielectric layer and exposing the via opening;
forming a supplementary dielectric layer in the via opening, wherein the sum of a thickness of the supplementary dielectric layer and a thickness of the at least one dielectric layer directly above the metal line is substantially equal to a predefined target thickness; and
patterning the supplementary dielectric layer and the at least one dielectric layer directly above the metal line to expose the metal line.
According to yet another aspect of the present invention, a method of modifying a third interconnect structure is provided, which comprises:
providing an interconnect structure comprising:
forming a supplementary dielectric layer in the via opening, wherein the sum of a thickness of the supplementary dielectric layer and a thickness of the at least one dielectric layer directly above the metal line is substantially equal to a predefined target thickness; and
patterning the supplementary dielectric layer and the at least one dielectric layer directly above the metal line to expose the metal line.
In one embodiment, the above methods further comprise forming at least one metallic liner layer directly on the metal line after the metal line is exposed.
In another embodiment, the at least one metallic layer comprises at least one of a TaN layer, a Ti layer, and a TiN layer.
In yet another embodiment, the at least one metallic layer comprises a stack, from bottom to top, of a TaN layer, a Ti layer, and a TiN layer.
In still another embodiment, the above methods further comprise forming a metal layer directly on the at least one metallic layer.
In still yet another embodiment, the metal layer comprise Al and has a thickness from about 0.8 μm to about 5.0 μm.
In a further embodiment, the at least one dielectric layer comprises:
a dielectric cap layer abutting the metal line and the interconnect level dielectric layer;
a first dielectric layer abutting the dielectric cap layer; and
a second dielectric layer abutting the first dielectric layer.
In an even further embodiment, the second dielectric layer and the supplementary dielectric layer comprise a same material.
In a yet further embodiment, the first dielectric layer comprises silicon oxide and the second dielectric layer comprises silicon nitride.
As stated above, the present invention relates to methods of extending the depth of a via opening to enable exposure of an underlying metal line and formation of a contact thereupon, which is now described in detail with accompanying figures. It is noted that like and corresponding elements are referred to by like reference numerals.
Referring to
A dielectric cap layer 20, a first dielectric layer 30, and a second dielectric layer 34, which is herein collectively referred to as “at least one dielectric layer” (20, 30, 34), are sequentially formed on the metal lines 14 and the interconnect level dielectric layer 10. The dielectric cap layer 20 typically comprises silicon nitride such as ultraviolet treated silicon nitride formed by plasma enhanced chemical vapor deposition (PECVD) followed by ultraviolet treatment or high density plasma silicon nitride formed by high density plasma chemical vapor deposition (HDPCVD). The dielectric cap layer typically has a thickness from about 5 nm to about 80 nm, although lesser and greater thicknesses are also contemplated herein. The first dielectric layer 30 and the second dielectric layer 34 may comprise the same material, or different materials. For example, the first dielectric layer 30 may comprise silicon oxide and the second dielectric layer 34 may comprise silicon nitride. The thickness of the first dielectric layer 30 may be from about 200 nm to about 700 nm, and thickness of the second dielectric layer 34 may be greater than 600 nm.
The total dielectric thickness t of the first exemplary interconnect structure exceeds the standard total dielectric thickness t0 of the exemplary prior art interconnect structure of
A photoresist (not shown) is applied to the top surface of the second dielectric layer 34 and lithographically patterned. The pattern in the photoresist is transferred into the second dielectric layer 34, the first dielectric layer 30, and the dielectric cap layer 20 by an anisotropic etch which is substantially the same as the anisotropic etch in the prior art processing steps of
Thereafter, at least one metallic liner layer and a metal layer are deposited within the via opening and lithographically patterned to form a metal pad comprising a pad liner portion 40 and a pad metal portion 50. The pad liner portion 40 typically comprises a stack of a TaN layer, a Ti layer, and a TiN layer, from bottom to top. For example, the thickness of the TaN layer may be about 70 nm, the thickness of the Ti layer may be about 25 nm, and the thickness of the TiN layer may be about 25 nm, although variations in the thicknesses of the various metallic liner layers may vary depending on application. The pad metal portion 50 comprises Al and has a thickness from about 0.8 μm to about 5.0 μm. The pad metal portion 50 and the pad liner portion 40 collectively constitute the metal pad (40, 50), which may function as a wirebond pad. The metal pad (40, 50) is disjoined from the metal lines 14, i.e., electrical contact is not provided between the metal pad (40, 50) and the metal lines 14.
While two dielectric layers are formed above the dielectric cap layer 20 for the purposes of description of the present invention in the first exemplary interconnect structure, the present invention is applicable irrespective of the number of dielectric layers above the dielectric cap layer 20 as long as the total dielectric thickness t exceeds a maximum allowed thickness for the standard total dielectric thickness t0 so that the via opening does not expose the metal lines 14. The number of dielectric layer(s) may be any positive integer including 1 in the present invention.
Electrical isolation of the metal pad (40, 50) from the metal lines 14 causes functional failure of the first exemplary interconnect structure. Further processing of the first exemplary interconnect structure only produces a non-functional semiconductor chip. The present invention provides remedy for this situation.
Referring to
A second wet etch employing sulfuric peroxide is then employed to remove the metal pad (40, 50), which includes the pad metal portion 50 comprising Al and the pad liner portion 40, selective to the at least one dielectric layer (20, 30, 34). In case the pad liner portion 40 comprises a stack, from bottom to top, of a TaN layer, a Ti layer, and a TiN layer, the second wet etch may remove the entirety of the pad metal portion 50, the TiN layer, and the Ti layer. A touch up etch, which may be a reactive ion etch, may be employed to removed the remainder of the pad liner portion 40, which may comprise the TaN layer.
A via opening VO is thus within the second dielectric layer 34. The first dielectric layer 30 may, or may not, be exposed at the bottom of the via opening VO. Typically, the dielectric cap layer 20 is not exposed at this point. A portion of the at least one dielectric layer (20, 30, 34) is thus present between the bottom surface of the via opening VO and the top surface of the metal lines 14. The bottom surface of the via opening VO may be located in the first dielectric layer 30, or the second dielectric layer 34.
Referring to
The predetermined target thickness may substantially match the standard total dielectric thickness t0 if the material of the supplementary dielectric layer 36 has a similar level of etch resistance as the material of the first dielectric layer 30 and/or the second dielectric layer 34. The total etch resistance of the supplementary dielectric layer 36 and the portion of the at least one dielectric layer (20, 30, 34) directly beneath the recessed area of the supplementary dielectric layer 36 may substantially match the total etch resistance of the at least one dielectric layer (20, 30, 32) of
Preferably, the supplementary dielectric layer 36 and the second dielectric layer 34 comprise the same material. For example, the supplementary dielectric layer 36 and the second dielectric layer 34 may comprise silicon nitride and the first dielectric layer 30 may comprise silicon oxide. The stack of the supplementary dielectric layer 36 and the portion of the at least one dielectric layer (20, 30, 34) directly beneath the recessed area of the supplementary dielectric layer 36 closely matches a normal dielectric stack of
Processing steps intended to provide a clean surface may be performed at this step. Exemplary cleaning process that may be employed include an O2 plasma clean that removes foreign material from the surface of the supplementary dielectric layer 36.
Referring to
An anisotropic etch process that is substantially the same as the anisotropic etch process employed to form the via opening VO in the exemplary prior art interconnect structure of
Further, the composition and the total thickness of the stack of the supplementary dielectric layer 36 and the portion of the at least one dielectric layer (20, 30, 34) in the recessed portion of the supplementary dielectric layer 36 may match the composition of the entirety of the at least one dielectric layer (20, 30, 32) of
Referring to
The replacement pad liner portion 60 typically comprises a stack of a TaN layer, a Ti layer, and a TiN layer, from bottom to top. For example, the thickness of the TaN layer may be about 70 nm, the thickness of the Ti layer may be about 25 nm, and the thickness of the TiN layer may be about 25 nm, although variations in the thicknesses of the various metallic liner layers may vary depending on application. The replacement pad metal portion 70 comprises Al and has a thickness from about 0.8 μm to about 5.0 μm. The replacement pad metal portion 70 and the replacement pad liner portion 60 collectively constitute the replacement metal pad (60, 70), which may function as a wirebond pad. The replacement metal pad (60, 70) is electrically connected to the metal lines 14.
It is noted that the label “replacement” that is assigned to the replacement pad liner portion 60, the replacement metal pad portion 70, and the replacement metal pad (60, 70) only denotes the characteristics of these elements as replacement elements for each of the pad liner portion 40, the metal pad portion 50, and the metal pad (40, 50), and that these elements may be properly termed without the label “replacement” when such characteristics are not considered.
The first embodiment of the present invention thus provides a method, or an integration scheme, for removing a metal pad (40, 50) that is not electrically connected to metal lines 14 within a top level interconnect layer 8 and subsequently forming a replacement metal pad (60, 70) that is electrically connected to the metal lines 14, thus repairing a critical structural problem that would have resulted in a non-functional semiconductor chip and providing a functional electrical contact between the metal lines 14 and the replacement metal pad (60, 70).
Referring to
At least one metallic liner layer 40L and a metal layer 50L are deposited within the via opening. The at least one metallic liner layer 40L may have the same vertical stack as the pad liner portion 40 of
Referring to
A via opening VO is thus within the second dielectric layer 34. The first dielectric layer 30 may, or may not, be exposed at the bottom of the via opening VO. Typically, the dielectric cap layer 20 is not exposed at this point. A portion of the at least one dielectric layer (20, 30, 34) is thus present between the bottom surface of the via opening VO and the top surface of the metal lines 14. The bottom surface of the via opening VO may be located in the first dielectric layer 30, or the second dielectric layer 40.
Referring to
The thickness and composition of the supplementary dielectric layer 36 may be the same as in the first embodiment, and determined based on the same consideration employed in the first embodiment. Processing steps intended to provide a clean surface may be performed thereafter. Exemplary cleaning process that may be employed include an O2 plasma clean that removes foreign material from the surface of the supplementary dielectric layer 36.
Referring to
As in the first embodiment, the same anisotropic etch as one employed to form the exemplary prior art interconnect structure of
Referring to
The second embodiment of the present invention thus provides a method, or an integration scheme, for removing at least one metallic liner layer 40L and a metal layer 50L that is not electrically connected to metal lines 14 within a top level interconnect layer 8 and subsequently forming a replacement metal pad (60, 70) that is electrically connected to the metal lines 14, thus repairing a critical structural problem that would have resulted in a non-functional semiconductor chip and providing a functional electrical contact between the metal lines 14 and the replacement metal pad (60, 70).
Referring to
Processing steps of the second embodiment corresponding to
The third embodiment of the present invention thus provides a method, or an integration scheme, for modifying an interconnect structure containing a via opening VO that does not expose metal lines 14, while not containing any metallic liner layer or a metal layer. The via opening VO is extended downward to form an extended via opening EVO that exposes metal lines 14 within a top level interconnect layer 8. A replacement metal pad (60, 70) that is electrically connected to the metal lines 14 is subsequently formed, thus repairing a critical structural problem that would have resulted in a non-functional semiconductor chip and providing a functional electrical contact between the metal lines 14 and the replacement metal pad (60, 70).
While the invention has been described in terms of specific embodiments, it is evident in view of the foregoing description that numerous alternatives, modifications and variations will be apparent to those skilled in the art. Accordingly, the invention is intended to encompass all such alternatives, modifications and variations which fall within the scope and spirit of the invention and the following claims.