1. Field of the Invention
This invention relates to the fabrication of interposers used in probing wafers for semiconductor manufacturing.
2. Prior Art
One of the final stages in the fabrication of integrated circuits on semiconductor wafers is the testing and sorting of the functionality of the circuits. The purpose of testing chips is to determine if the chips function as it was designed for; meaning that for given inputs, desirable outputs result. Sorting of chips is similar, but chips are specifically ranked in terms of how well each chip functions, for example, with respect to speed. Based on random variables, different chips will function at different speeds.
There are a variety of techniques employed for testing chips. One key factor in determining what process to use to test a chip is the complexity of the chip. The number of input and output (I/O) pads present on a chip are often representative of the complexity of the chip, wherein higher I/O numbers are attributed to higher chip complexity.
Low I/O chips with linear arrays of pads can be tested using probe stations where individual leads are brought into contact with each pad mechanically to provide power and signals, and to measure the outputs. For mid-range I/O chips, probe cards with many leads can be generated wherein the leads are arranged to correspond to each pad on the mid-range chip. The probe cards may also be wired and plugged into electronics for driving and measuring the performance of the chip. For high I/O chips, i.e., those having hundreds to thousands of I/O, with pads in aerial array rather than in linear array, connections to the testing electronics is impractical and expensive, and in some instances impossible.
Where testing or measuring of the chips is impractical, it is often advantageous to use packaging mounts, e.g., ceramic or organic modules in which the chips are mounted, in order to measure the chips. In this way, the wiring from the chip to electronics-compatible pins are already available. Temporary connections of the chips to the packaging mounts is preferred in order to avoid de-bonding a chip determined to be defective upon testing.
Interposers are devices commonly used for temporary connections in manufacturing for the probing of semiconductor wafers.
Current interposers used in probe technologies may be electrolytic plated flexible interposers designed to probe rigid, non-even surfaces such as those commonly associated with ceramic packaging modules. Current interposers may also be flexible interposers that, while easily implemented in a manufacturing environment, are difficult and cost-prohibitive to fabricate requiring unusual processing techniques that are not readily practiced. The variety of current interposers commercially available in the probe technologies tend to target rigid substrates, such as silicon chips. Thus in addition to the deficiencies cited above with respect to interposers used to probe rigid substrates, current interposers also fail to facilitate the probing of flexible substrates that are becoming more and more common in organic semiconductors.
The present invention comprises systems and methods for fabricating interposer probes in a cost-effective and convenient manner for use with rigid or flexible substrates.
Some embodiments of the present invention comprise systems and methods for fabricating flexible interposers while reducing external power supply needs. These embodiments of the invention further comprise systems and methods for fabricating flexible interposer probes while reducing precious metals waste. These embodiments of the present invention further comprise systems and methods for fabricating flexible interposer probes with minimal nodule formations. These embodiments of the invention further comprises systems and methods for fabricating electrolessly plated flexible interposer probes using commercially available electroless metal baths.
Other embodiments of the present invention comprise systems and methods for fabricating flexible interposers using standard semiconductor processes improve yield and reduce costs. These embodiments of the invention provide for tighter pitches in the interposers than do current technologies, and better facilitate the probing of nonuniform substrate surfaces.
Still other embodiments of the present invention comprise systems and methods of fabricating a rigid interposer. The rigid interposer of these embodiments of the systems and methods of the present invention better facilitates the probing of flexible substrates.
The artisan should appreciate that interposers can be designed to reduce oxidation of components, to increase flexibility of components, and to overcome mismatch between connected components. Accordingly, the interposers fabricated by the systems and methods of the present invention, as described herein, are understood to accommodate these aspects as well.
The above and other features of the present invention, including various novel details of construction and combination of parts, will be more particularly described with reference to the accompanying drawings and claims. It will be understood that the various embodiments of the invention described herein are shown by way of illustration only and not as a limitation thereof. The principles and features of the invention may be employed in various alternative embodiments without departing from the scope of the invention.
These and other features, aspects and advantages of the systems and methods of the invention will become better understood with regard to the following description, drawings, and appended claims, wherein:
Electroless plating refers to the autocatalytic reduction of a metal ion at a cathodic surface. The metal ion in solution reduces at the surface of the workpiece through a parallel oxidation reaction. For example, a hypophosphite anion can be oxidized according to the following reaction:
Equation 1 renders hydrogen evolution as a result of the plating process. Excess hydrogen production can interfere with the quality of the plated film, however, and should be avoided by proper bath agitation. Commercially available electroless solutions contain stabilizers to control the reaction rates of Equation 1. Electroless plating baths also contain various metal salts, reducing agents and organics to buffer and maintain the solution as well as to adjust properties such as hardness and the appearance of deposits in the plating film. The advantage of the reaction of Equation 1 is that is does not rely on an external supply of electrons to reduce the metal ions. As a result, conformal depositions may occur on any active surface.
Some embodiments of this invention comprise an electroless plating process for fabricating flexible interposer probes. According to these embodiments, the electroless plating process uses conformal metal coatings without external power supplies or complicated commoning methods. Because no external power source is used, nodule formations are minimized. Such nodule formations tend to occur at points of high current densities, e.g., at sharp edges, when forming flexible interposer probes using standard electrolytic plating techniques. Further, because the electroless plating solutions of the invention contact all parts of the interposer probe, electrically isolated regions need not be attached to one another by a commoning layer, such as a thin film deposition of Cu, for example. Further still, the electroless plating techniques described herein improve the manufacturability and reduce the cost of interposers as compared to known interposer fabricating technologies.
Electroless plating, according to the present invention, begins by forming a surface that is clean and catalytic. The artisan will appreciate that numerous techniques exist for creating an autocatalytic surface with a variety of chemicals, though for brevity the discussion herein focuses on those chemicals most suited for electroless deposition on copper as most probe panels use copper as its plating surface. The standard method of creating a catalytic surface is by utilizing an immersion, or displacement, deposit of a more noble and catalytic metal such as zinc (Zn), palladium (Pd), or tin (Sn).
Displacement deposits occur when a metal surface with a lower free energy, i.e., less noble, is placed into a solution containing metal ions that are at a higher free energy, i.e., more noble. The difference in the thermodynamic free energies drives the reaction that replaces the metal atom on the surface with the metal atoms from the solution. The kinetics of the reaction are governed by the fractional surface coverage of the replacement atom on the surface. As the fractional coverage of the surface increases, the reaction slows down. A typical example of this reaction is that of a Cu metal surface being displaced by Pd atoms from an acidic solution. The reaction is described by Equation 2 below:
In the above reaction described by Equation 2, the Cu atoms on the plating surface are displaced by the Pd atom because of a reaction potential of −1.293 V driving the Pd atom to cover the surface. The pH of the solution is adjusted to be acidic by the addition of sulfuric acid, for example. The acid helps to prevent oxidation at the Cu surface and favors the removal of Cu metal as copper sulfate. The reaction of Equation 2 will cease once the surface has been fully covered with Pd atoms. Immersion deposits can range from a few hundreds of angstroms to a few microns in thickness depending on the metal systems used.
Table 1 below illustrates chemistries and processes used in the production of electroless plated probes according to some embodiments of the invention.
There are five primary steps to the electroless plating process according to the invention. The steps generally are:
1. pre-cleaning the sample
2. seeding the sample
3. depositing an electroless layer on the sample
4. immersion seeding the sample
5. depositing the electroless on the sample,
for example, wherein the initial seeding is Pd seeding, the initial electroless layer Ni, the immersion seeding is Au, and last electroless layer is Au.
The electroless deposition process starts with a probe panel produced according to a standard process recipe except that a Ni/Au bump plating step is omitted. Protection of the Cu bumps from greyscale etching solution is important and may be achieved by applying some spin-on photoresist or dry film laminate. Probes are individually cut from the four-up panel configurations and loaded onto a custom designed, Delrin® probe holder. The probe holder is made completely of polymer materials to avoid plating onto any metal parts. The sample is fixed by its dowel pin holes and held in a semi-rigid manner. Holding the sample in this manner helps keep the probe in a steady position in the baths.
Experimentation of the processes according to the present invention has determined that a clean Cu surface is required for proper Pd seeding and electroless Ni deposition. It is also preferable to strip any organics from the Cu surfaces because the probes are treated with a benzotriazole solution and other organic chemicals during their production. Panels are stripped of any photoresist, soaked in ethyl alcohol and rinsed in de-ionized (DI) water. The parts are then be oxygen ashed prior to plating to remove any residual organic compounds. A Branson® barrel asher operating at a frequency of 13.56 MHz and 100 W of power for 10 minutes in a flowing oxygen atmosphere at a pressure of 650 mTorr. The probe is then dipped into a 25% sulfuric acid solution for 2 minutes to remove any oxidized copper. The part is then rinsed in flowing DI water for 30 seconds and dipped into an acidic palladium sulfate seeding bath (0.1 g/L PdSO4 in 20 mL/L H2SO4 aqueous solution) for 5 minutes. This tends to produce a dark tarnish of Pd atoms on the Cu surfaces. Finally, the parts are rinsed in DI water for 30 seconds to remove any excess Pd seed or acid.
The Cu surfaces should now be active and ready to be immersed into the electroless nickel (EN) bath. The EN bath used in the experimentation of the invention was ENPLATE NI426, which is a low phosphorus plating bath produced by Enthone Corporation. Operating conditions of the EN bath are given in Table 1. According to these conditions, a Ni—P phase diagram should indicate that no solid solubility of phosphorus in Ni at the plating temperature exists and that only a mixture of pure Ni and the intermetallic Ni3P exists. However, because of the plating rate, it is kinetically impossible for the intermetallic phase to form. Therefore the plated film is a supersaturated alloy of Ni and P. This results in a very hard (650 HK100) deposit with a microcrystalline grain structure (grain sizes 2 to 6 nm).
The electroless plating bath is operated under constant agitation and filtration to ensure uniform and smooth deposits. Custom plating tanks and bath heaters were fabricated to accommodate the panels. At a pH of 6.2 and a bath temperature of 83 degrees C., the plating rate is between 15 and 18 μm/hr. Parts were left in the bath for 10 minutes to achieve a 2.5 μm film. The film thicknesses were confirmed using optical microscopy and SEM imaging. Conformal coverage of the underlying Cu produced a coherent and smooth Ni:P film.
After deposition of the Ni diffusion barrier, it is necessary to deposit a similar thickness of gold (Au) to ensure good electrical contact for testing. The gold layer is a two-step process where a first layer of immersion gold is deposited to a thickness of 0.3 μm followed by an electroless gold deposition of 2.2 μm. The immersion Au chemistry used is Oromerse MN® from Techinc Incorporated, and the electroless Au bath is the GoBright TMS-21® bath from Uyemura International Corporation. Both baths come premixed and ready to use. The operating details are given in Table 1 above.
A simple modification of the current probe fabrication process replaces the two-step bump/greyscale plating with a single electroless plating process. The new process can be broken down into three components: pre-plating bump and pin formation, probe removal and cleaning, and electroless deposition of Ni/Au layers.
The first stage of the probe fabrication process is the formation of copper bumps and greyscale pins. These should be formed using the standard process as a template with the following modifications. First, only Cu bump plating is required. The bump is formed with a standard height and width, as dictated by the original process. After Cu bump plating, the Cu film is cleaned and coated with a resist, as required for greyscale lithography and etching. Before greyscale etching, the bumps are protected with a thick resist coat applied by a brush method and air dried. The standard etch procedure is used to form greyscale pins. The final product is a four-up panel with Cu bumps on the Kapton side and greyscale pins on the opposite side.
At this point, the individual probes are cut from the four-up panel to reduce Ni and Au plating waste. Each probe is then cut from the panel and cleaned to ensure that all organics are removed before electroless plating begins. The electroless deposition of Ni and Au is then performed.
The following process and solutions, for example, may be used to produce flexible interposers according to the invention:
The above described processes offer several advantages over other fabrication methods. For example, the underside of the probe that contacts the Kapton® film is plated with a protective Ni/Au layer. In standard electrolytic plating, this part of the probe would not be coated, and would therefore be subject to corrosion and other degradation. Acidic agents are typically used to clean currently available probes according to strict cleaning schedules in order to remove lead and tin deposits, for example. Such acidic agents are often a primary cause of corrosion on an underside of the probes. Eliminating the need for these acidic agents renders the probes fabricated by the processes described herein more reliable and more convenient as well.
The probes fabricated by the electroless plating processes described herein are more easily repaired than currently available probes as well, particularly where the probes have already been used and/or have suffered damage to the Ni/Au surface layer. Once a damaged probe is identified, it can be cleaned and re-plated with Ni/Au as the original Ni/Au layer wears thin or wears out. This process of repair can significantly increase the lifetime of an interposer, and can lower the cost of use as well.
Further, the probes fabricated by the electroless plating processes described herein may be produced in less steps than currently available interposers:. For example, where standard electrolytic plating methods are used, the front side of the interposer and the back side of the interposer are each separately plated. Thus, the electrolytic plating process requires two separate plating procedures. On the other hand, the electroless plating processes described herein coats both sides of the interposer at once, thereby saving a significant amount of processing steps.
According to various embodiments of the invention, vias are produced through a silicon, or other type of semiconductor wafer. The vias are filled with a conductive material, for example, to permit a front-to-back connection between the vias and the underlying wafer substrate and a seed layer or other substrate surface. The via structure thus acts as an interposer to connect two substrates. Depending on the application, the via structures can be built on both sides of the wafer in order to better facilitate probing.
For example, when connecting to a solder pad a pin can be formed on one side of the interposer to connect to the filled via with a flexible lead. The flexible lead is rigid enough to puncture through oxides on the surface of a solder ball to accommodate any non-uniformity in heights. To create the pins, micromolds are first created by using silicon or other micro-machining techniques. These molds ate filled with a material, such as a metal, up to a prescribed thickness to create sharp pins. This molding technique provides advantages such as:
The flexible leads are preferably created using either a flexible organic material coated with a conductive metal, or a metal with good electrical properties while possessing high tensile strength such as, for example, 450-620 MPa and most preferably 550 MPa. For example, copper beryllium could be used as the material for the flexible leads, or an elastic polymer having a metal or metallic coating could be used, although other flexible organic materials known in the art could as well be used as will be appreciated by the skilled artisan. Of course, the artisan will also readily appreciate that the leads could as well be comprised of a rigid material such as, Si or Si3N4, for example. This entire structure could then be transferred to the silicon interposer.
More specifically,
The micro-molded interposer structures formed by the processes described above with respect to
In
As shown in
As shown in
To further enhance the ability of the probe pin 412 to puncture oxides on the surface of the solder pads of the chip, the probe pin 412 may be coated with a hard material. The hard material may be tungsten or titanium, for example, or other materials that can be electroplated, such as palladium-cobalt or palladium-nickel, for example.
Although the probes 410 may be comprised of other than silicon wafers according to the invention, the use of silicon wafers for the probes 410 minimizes expense as silicon wafers are readily available and understood in the semiconductor manufacturing industry. Likewise, the use of silicon wafers provides additional flexibility to the probes as additional structures such as wiring structures or other active devices, for example, may be provided on either side of the probes. Such additional structures can provide for advanced probing techniques including speed sorting.
Building the probes 410 on rigid substrates enable simplified alignment techniques relative to the solder pads of chips being tested or the packaging modules holding said chips. Additional and/or wider guide holes could be drilled along with the vias to enhance the mechanical alignment of the probes 410 with the chips and package modules. These holes would align the probe pattern with nanometer accuracy to capture dowel pins connected to the substrate, for example, for very fast and accurate alignment of the probe with the chip and packaging module.
While there has been shown and described what is considered to be preferred embodiments of the invention, it will, of course be understood that various modifications and changes in form or detail could readily be made without departing from the spirit and scope of the invention. It is therefore intended that the invention be not limited to the exact forms described and illustrated herein, but should be construed to cover all modifications that may fall within the scope of the appended claims.