The present disclosure relates to solder preforms used for ceramic package hermetic sealing applications. More specifically, processes for making solder preforms which increase the usage of raw material, reduce defects, and result in shorter lead times are described herein, as are the solder preforms formed thereby and electronic packages including such solder preforms.
Solder preforms are typically made by a stamping tool which stamps out solder preforms of a given size from a ribbon of raw material. The stamping tool is also known as a compound die. The compound die performs two actions concurrently, such as cutting an inner peripheral line and an outer peripheral line of the annular preform.
When the solder preform is formed with a stamping tool, only a small amount of the ribbon of raw material is used for production. The raw material adjacent the solder preform and the inner center cutout section of the preform are unused and must be refined or re-melted prior to being sent through the stamping tool again. This adds to additional cost. Furthermore, accurate molds with tight tolerances and adequate alignment are required to make stamping tools capable of producing acceptable solder preforms. The stamping tool also requires periodic maintenance that takes the production line out of service. This adds to production costs and reduces the manufacturing efficiency of solder preforms.
Some additional issues can arise when stamping tools are used to form solder preforms. First, when a solder preform having a new or different size is requested, a new stamping tool generally has to be fabricated. The lead time to fabricate each stamping tool can be as long as six to eight weeks. If the dimensions of a stamping tool are incorrect after fabrication, a new tool has to be refabricated, resulting in a loss of time and cost. Second, stamping tools can create raised edges or small pieces of material known as burrs which remain attached to the edges of the solder preform after stamping. Burrs can interfere with the sealing efficacy of the solder preform and may cause cracks to form in the solder. Deburring processes undesirably add to productions costs for forming solder preforms. It would be desirable to provide methods that minimize these problems.
The present disclosure relates to methods of making solder preforms for use in hermetic sealing of electronic packages. A ribbon of raw material is provided. A first annular solder preform is formed by laser cutting the ribbon, with an exterior peripheral cutting edge defining an outer perimeter of the first annular solder preform and an interior peripheral cutting edge defining an inner perimeter of the first annular solder preform. The exterior peripheral cutting edge and the interior peripheral cutting edge of the first annular solder preform can then be cleaned.
In some embodiments, the ribbon of raw material is formed from a gold-tin alloy having about 80 wt % gold and about 20 wt % tin.
In further embodiments, the cleaning is performed by ultrasonically removing carbon on the exterior peripheral cutting edge and the interior peripheral cutting edge of the annular solder preform.
As desired, additional annular solder preforms can be laser cut from an inner cutout section of the first annular preform. The inner cutout section typically has an outer perimeter defined by the interior peripheral cutting edge of the first annular solder preform. The annular solder preforms can be in the shape of a square, rectangle, or disc.
Also disclosed in various embodiments are annular solder preforms prepared by: receiving a ribbon of raw material; laser cutting the ribbon along an exterior peripheral cutting edge and an interior peripheral cutting edge; and cleaning the exterior peripheral cutting edge and the interior peripheral cutting edge to obtain the annular solder preform.
The raw material can be a gold-tin alloy. An outer perimeter of the annular solder preform can be in the shape of a square having a length and a width of about 0.3 inches, and an inner perimeter of the annular solder preform is in the shape of a square having a length and a width of about 0.25 inches. The annular solder preform can be in the shape of a square, rectangle, or disc.
The methods may further include a method of using an annular solder preform in a frame lid assembly. An annular solder preform is tack welded to a cover lid having a first surface, a second surface, and a sidewall joining the first surface and second surface together. The annular solder preform is melted to fuse the cover lid to an insulating base that is shaped to include a cavity. The annular solder preform is made by laser cutting a ribbon of raw material in the appropriate shape and size. An exterior peripheral cutting edge defines an outer perimeter of the annular solder preform and an interior peripheral cutting edge defines an inner perimeter of the annular solder preform.
The cover lid can be made from beryllium-copper, molybdenum, bronze, glass, an iron-nickel-cobalt alloy, or a ceramic selected from the group consisting of alumina (Al2O3), beryllia (BeO), aluminum nitride (AlN), zirconia toughened alumina (ZTA), SiC, and Si3N4.
A second annular solder preform can be laser cut from the inner cutout section of the first annular solder preform. That second annular solder preform can be tack welded to a second cover lid having a first surface, a second surface, and a sidewall joining the first surface and second surface together. The second annular solder preform is then heated and melted. The second annular solder preform can then fuse the second cover lid to a second insulating base shaped to include a cavity.
Also disclosed herein are annular solder preforms which include a laser cut exterior peripheral cutting edge defining an outer perimeter of the annular solder preform and a laser cut interior peripheral cutting edge defining the inner perimeter of the first annular solder preform. The annular solder preform is formed from an alloy having about 80 wt % gold and about 20 wt % tin.
A second annular solder preform can be laser cut from the inner cutout section of the first annular solder preform. The annular solder preforms can be in the shape of a square, rectangle, or disc.
Also disclosed herein are methods of making multiple solder preforms from a single ribbon, comprising: receiving a ribbon of raw material formed from an alloy having about 80 wt % gold and about 20 wt % tin; forming a first annular solder preform by laser cutting the ribbon along an exterior peripheral cutting edge and an interior peripheral cutting edge, the interior peripheral cutting edge defining an outer perimeter of an inner cutout section; and laser cutting a second annular solder preform from the inner cutout section of the first annular solder preform.
These and other non-limiting characteristics of the disclosure are more particularly disclosed below.
The following is a brief description of the drawings, which are presented for the purposes of illustrating the exemplary embodiments disclosed herein and not for the purposes of limiting the same.
A more complete understanding of the processes and apparatuses disclosed herein can be obtained by reference to the accompanying drawings. These figures are merely schematic representations based on convenience and the ease of demonstrating the existing art and/or the present development, and are, therefore, not intended to indicate relative size and dimensions of the assemblies or components thereof.
The present disclosure may be understood more readily by reference to the following detailed description of desired embodiments and the examples included therein. In the following specification and the claims which follow, reference will be made to a number of terms which shall be defined to have the following meanings.
The singular forms “a,” “an,” and “the” include plural referents unless the context clearly dictates otherwise.
Numerical values in the specification and claims of this application should be understood to include numerical values which are the same when reduced to the same number of significant figures and numerical values which differ from the stated value by less than the experimental error of conventional measurement technique of the type described in the present application to determine the value.
All ranges disclosed herein are inclusive of the recited endpoint and independently combinable (for example, the range of “from 2 grams to 10 grams” is inclusive of the endpoints, 2 grams and 10 grams, and all the intermediate values).
As used herein, approximating language, such as “about” and “substantially,” may be applied to modify any quantitative representation that may vary without resulting in a change in the basic function to which it is related. The modifier “about” should also be considered as disclosing the range defined by the absolute values of the two endpoints. For example, the expression “from about 2 to about 4 ” also discloses the range “from 2 to 4.” The term “about” may refer to plus or minus 10% of the indicated number.
The term “room temperature” refers to a range of from 20° C. to 25° C.
The terms “annular” or “annulus” refer to a planar shape formed by the area between two concentric shapes whose edges are parallel to each other. These terms can refer, for example to the ring shape bounded by two concentric circles, or to the shape contained between two squares with a common center whose sides are parallel to each other.
A conventional stamping method 100 for forming an annular solder preform is illustrated in
The conventional method of stamping the ribbon into solder preforms results in the ribbon portion 106 (outside of the solder preforms) and inner cutout portions 108 (from the center of each solder preform) being unused after the stamping process. These portions 106, 108 can be refined or re-melted to form a new ribbon of material which can then be passed through the stamping tool/die again to produce more annular solder preforms.
The usage of the gold-tin ribbon in this conventional stamping method for forming annular solder preforms can be calculated. Referring again to
The conventional stamping process illustrated in
Advantageously, the preforms should not be deformed, damaged, or melted during the cutting process. The precise laser cutting process maintains the original composition of the gold-tin alloy without changing the alloy's chemical phase. In addition, the laser cutting produces burr-free cutting edges without compromising alloy quality.
The present disclosure is not limited to laser cutting only two annular preforms 110, 118 out of the ribbon as shown in
In
A second annular solder preform is then formed from the inner cutout section 116. Again, any additional solder preforms fabricated from the inner cutout section 116 will necessarily be smaller than the first annular solder preform. This can be done with the inner cutout section 116 still located within the first annular preform 110, or the inner cutout section 116 can be removed from the first annular preform and then processed.
To form the second annular preform 118, as seen in
It is contemplated that sometimes the interior peripheral cutting edge 114 of the first annular solder preform could also serve as the second exterior peripheral cutting edge 120. However, it is believed that such situations will rarely occur.
The first annular solder preform 110 and the second annular solder preform 118 are then removed from the ribbon 102. The annular solder preforms 110, 118 can then be cleaned to remove carbon which may build up on their inner perimeter and outer perimeter. The unused ribbon portion 134 and remaining cutout section 116 can be collected for refining/re-melting/re-processing.
In some particular embodiments as illustrated in
It should be noted that the solder preforms 110, 118 are very thin, and are depicted here as being in the shape of a two-dimensional square annulus. However, it should be understood that the solder preforms are actually three-dimensional objects, albeit with a very small thickness. As illustrated in
Again, the annular preform may be of any desired shape. It is particularly contemplated that the annular preform may be in the shape of a square, a rectangle, or a disc. A square has four sides of equal length and four right angles, while a rectangle has four right angles, and the lengths of adjacent sides can vary. A disc is formed from two concentric circles.
A second annular solder preform is then formed from the inner cutout section 216. As seen in
The first annular solder preform 210 and the second annular solder preform 218 are then removed from the ribbon 202. The annular solder preforms 210, 218 can then be cleaned to remove carbon which may build up on their inner perimeter and outer perimeter. The unused ribbon portion 234 and remaining cutout section 216 can be collected for refining/re-melting/re-processing.
The ribbons of raw material 102, 202 and annular solder preforms 110, 118, 210, 218 formed therefrom can be made from a metal alloy such as a lead-based alloy or a lead-free alloy. In particular embodiments, the metal alloy is a gold-tin alloy. Most desirably, the gold-tin alloy is a eutectic composition of about 80 wt % gold and about 20 wt % tin (i.e., 80Au-20Sn). The preforms have a thickness of greater than about 0.001 inches, including about 0.006 inches and up to about 0.010 inches. The preforms can have an outer diameter or outer width of up to 2.500 inches. The solder preforms desirably have a melting temperature of from about 200° C. to about 350° C. In some embodiments, indium is added to the 80Au-20Sn composition to raise its melting point, providing protection against secondary reflow, loss of hermeticity, or critical component shift during the soldering process.
Laser cutting can be performed by any suitable method known in the art, such as with a carbon dioxide laser, a YAG laser or an excimer laser. In some particular embodiments, laser cutting is performed with a carbon dioxide laser. Carbon dioxide lasers typically utilize a gas mixture in which light is amplified by carbon dioxide molecules. Laser cutting is generally achieved by mixing gases (e.g., carbon dioxide, nitrogen, and helium) and feeding the mixture into a first end of a discharge tube. The gas is pumped out a second end of the discharge tube with a mechanical forepump. An electrical discharge is maintained between the first and second end of the tube. Various optic lenses (i.e., mirrors) are used to focus and direct the laser through a nozzle and onto the work piece to be cut. The focused laser beam melts, burns, vaporizes, or blows away the material which comes into contact with the laser beam, resulting in a cutting edge with a high-quality surface finish. The cutting edge is substantially free of raised edges or small pieces of material attached to the cutting edge, commonly referred to as burrs. An ultraviolet (UV) laser can be used.
A computer numerical control (CNC) machine can be used to move the raw material with respect to the generated laser beam or vice versa. A motion control system can also be employed to follow a CNC or G-code of the pattern to be cut from the material. In this regard, any number of various patterns can advantageously be cut to form solder preforms having complex geometries.
The cleaning of the annular solder preforms can be performed by any suitable method such as ultrasonic cleaning, pressure washing, high-temperature outgassing, ultra-pure water rinsing, or drying with compressed clean air. In particular embodiments, the cleaning is performed by ultrasonic cleaning. Ultrasonic cleaning generally refers to a process that uses ultrasound at an appropriate frequency and an appropriate cleaning solvent to clean the preform. The cleaning acts to remove residual debris and contamination which may remain after laser cutting, such as carbon, thereby increasing cleanliness and improving sealing performance of the preform. The ultrasonic frequency can be from about 30 kHz to about 50 kHz. The ultrasonic cleaning may be performed for a period of about 20 minutes to about 40 minutes, including about 30 minutes.
The results of an ultrasonic cleaning process can be seen in
Next, in
Generally, the annular solder preform can be tack welded to a seal ring on the second surface of the cover lid.
Referring first to
In some desirable embodiments, the seal ring can be formed from a set of sublayers. In such embodiments, there may be two sublayers or three sublayers. In specific embodiments, a nickel sublayer can be laid down first, then a gold sublayer can be laid down over the nickel sublayer. The nickel sublayer serves as a barrier to corrosion, while the gold sublayer provides a readily solderable surface. Each sublayer may have a thickness/depth of 0.001 mm to 0.01 mm (i.e. 1 μm to 10 μm). The seal ring may have a thickness/depth of 0.001 mm to 0.04 mm (i.e. 1 μm to 40 μm).
Next, as illustrated in
As previously mentioned, the solder preform is tack welded to a seal ring located on the second surface of the cover lid/plate. The first annular solder preform is then heated to melt the first annular solder preform and fuse the cover lid to the base. The cover lid 336 is made from a non-metallic material. Exemplary non-metallic materials include beryllium-copper, molybdenum, bronze, glass, an iron-nickel-cobalt alloy (e.g. KOVAR™), an iron-nickel binary alloy (e.g. Alloy 42), or a ceramic selected from the group consisting of alumina (Al2O3), beryllia (BeO), aluminum nitride (AlN), zirconia toughened alumina (ZTA), SiC, and Si3N4. The plate has a thickness (measured between the first surface and the second surface) of about 0.5 millimeters (mm) to about 1 millimeter. In particular embodiments, the plate is made from a non-magnetic material. This may be useful in certain applications where electrical signals/noise can interfere with the electronic component in the package, e.g. in medical imaging applications.
Many advantages accrue in the presently-described methods. Tool and die fabrications are not required, which not only reduces the cost of producing solder preforms, but also saves manpower. In addition, the need to store and maintain tools and dies is eliminated. Laser cutting permits complex cutting designs compared with conventional stamping methods and the lead time is improved. The quality of cuts produced by laser cutting reduces post refining processes, especially deburring since the laser produces burr-free cuts. Moreover, utilization of the ribbon of raw material is maximized.
The present disclosure has been described with reference to exemplary embodiments. Obviously, modifications and alterations will occur to others upon reading and understanding the preceding detailed description. It is intended that the present disclosure be construed as including all such modifications and alterations insofar as they come within the scope of the appended claims or the equivalents thereof.
This application claims priority to U.S. Provisional Patent Application Ser. No. 62/297,258, filed on Feb. 19, 2016, which is fully incorporated by reference herein.
Number | Date | Country | |
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62297258 | Feb 2016 | US |