Claims
- 1. A dielectric green tape for forming a ceramic dielectric body having a dielectric constant less than 5.0 comprising a layer of a composition comprising an alkali-free mixture of finely divided particles consisting essentially of:
- (a) 70-85% by weight silica particles and
- (b) 15-30% by weight zinc borate flux particles dispersed in an organic medium comprising a polymeric binder.
- 2. The dielectric green tape of claim 1 wherein the zinc borate flux consists essentially of zinc oxide and boron oxide and the mole ratio of zinc oxice to boron oxide is in the range of 3/1 to 1/1.
- 3. The dielectric green tape of claim 2 wherein the mole ratio of zinc oxide to boron oxide is 2/1 in the zinc borate flux.
- 4. The dielectric green tape of claim 1 wherein the silica is alpha-quartz.
- 5. The dielectric green tape of claim 1 wherein the formed ceramic dielectric body has a thermal coefficient of expansion in the range of 1.5 to 8.5 ppm/.degree. C.
- 6. A multilayer capacitor comprising a plurality of layers of the green tape of claim 1 having a printed thick film copper electrode layer therebetween, the multilayer capacitor having been fired in an atmosphere having a low oxygen content to effect volatilization of the organic medium, sintering and densification of the alkali free mixture of finely divided particles.
- 7. The multilayer capacitor of claim 6 wherein the zinc borate flux consists essentially of zinc oxide and boron oxide and the mole ratio of zinc oxice to boron oxide is in the range of 3/1 to 1/1.
- 8. The multilayer capacitor of claim 7 wherein the mole ratio of zinc oxide to boron oxide is 2/1 in the zinc borate flux.
- 9. The multilayer capacitor of claim 6 wherein the silica is alpha-quartz.
- 10. The multilayer capacitor of claim 6 wherein the dielectric layers have a thermal coefficient of expansion in the range of 1.5 to 8.5 ppm/.degree. C.
- 11. A multilayer ceramic substrate comprising a plurality of layers of the green tape of claim 1 having interconnected copper conductor layers therebetween, the multilayer ceramic substrate having been fired in an atmosphere having a low oxygen content to effect volatilization of the organic medium, sintering and densification of the alkali free mixture of finely divided particles.
- 12. The multilayer ceramic substrate of claim 11 wherein the zinc borate flux consists essentially of zinc oxide and boron oxide and the mole ratio of zinc oxide is in the range of 3/1 to 1/1.
- 13. The multilayer ceramic substrate of claim 12 wherein the mole ratio of zinc oxide to boron oxide is 2/1 in the zinc borate flux.
- 14. The multilayer ceramic substrate of claim 11 wherein the silica is alpha-quartz.
- 15. The multilayer ceramic substrate of claim 11 wherein the dielectric layers have a thermal coefficient of expansion in the range of 1.5 to 8.5 ppm/.degree.C.
Cross Reference to Related Application
This application is a divisional of application Ser. No. 07/236,072, filed Aug. 23, 1988, now U.S. Pat. No. 4,879,261, which is a continuation-in-part of allowed copending U.S. patent application Ser. No. 07/003,259, filed Jan. 13, 1987, now U.S. Pat. No. 4,766,027.
US Referenced Citations (4)
Foreign Referenced Citations (2)
Number |
Date |
Country |
0099768 |
Aug 1988 |
JPX |
480659 |
Aug 1975 |
SUX |
Divisions (1)
|
Number |
Date |
Country |
Parent |
236072 |
Aug 1988 |
|