The present invention relates to the field of microelectronic and quantum electronics, in particular. It has, for example, a particularly advantageous application for producing back gates in quantum devices with quantum bits (called qubits), in particular for devices based on spin qubit or supraconductive qubit architectures.
Semiconductive devices, for example, transistors, integrated on a silicon on isolator (SOI) semiconductor-type substrate, generally have better performance than semiconductive devices integrated on a bulk substrate, in particular at the end of consumption. To improve the electrostatic control of these on-SOI integrated semiconductive devices, a conductive back gate can be formed under the buried isolator layer, preferably in vertical alignment with the active zone of the semiconductive device, which is formed in the superficial semiconductive layer located on the buried isolator layer. An electric contact on this back gate makes it possible to apply a variable voltage to the back gate and to thus modulate the electrostatic environment at the active zone of the semiconductive device.
For quantum applications, in particular, this back gate voltage is an additional parameter which is very useful for modulating the electrostatic environment of the quantum points.
To produce this conductive back gate, “back face” methods are complex and invasive, and not very suitable for the scale of a full wafer. Alternatively, front face ion implantation methods, which make it possible to very highly dope the substrate under the buried isolator layer, induce residual dopants in the superficial semiconductive layer. These residual dopants are not, in particular, compatible with the operation of quantum points.
Document FR2952472A1 describes an example of a method for producing a back gate under an on-SOI semiconductive device. In this example, each device is electrically isolated by isolation trenches passing through the superficial semiconductive layer and the buried isolator layer, and extending to the substrate. The method consists of forming an opening within an isolation trench by anisotropic etching, then extend this isotropic etching such that the opening opens into the buried isolator layer, under the superficial semiconductive layer. A removal of the material of the buried isolator layer, selectively at the materials of the substrate, from the superficial semiconductive layer and from the isolation trenches, is thus done through the opening. A cavity is thus formed under the semiconductive device. The cavity is then filled with a conductive material, so as to form the conductive back gate under the semiconductive device. The opening is also filled with the conductive material and thus forms an electric contact for the back gate. A disadvantage of this method, is that the opening made within the isolation trench is relatively wide, which limits the integration density of the devices. The minimum width to be provided for these isolation trenches must be relatively high to enable the formation of a back gate locally, under an individual device, without impacting the integrity of a neighbouring device.
Therefore, there remains a need to have a method for producing a back gate under an on-SOI semiconductive device, enabling a larger integration density. An aim of the invention is to respond to this need, and to overcome at least partially the disadvantages of the known solutions.
In particular, an aim of the invention is a method for producing a back gate under an on-SOI semiconductive device making it possible to increase the integration density. Another aim of the invention is a device coming from such a production method.
Other aims, features and advantages of the present invention will appear upon examining the description below and the accompanying drawings. It is understood that other advantages can be incorporated.
To achieve this aim, according to an embodiment, a method for producing a back gate under a semiconductive device is provided, said semiconductive device being formed on or from a semiconductive layer of a stack successively comprising a support layer, a sacrificial layer and the semiconductive layer.
The method comprises:
Advantageously, the formation of the isolation trenches comprises:
Advantageously, the partial etching of the isolation trenches comprises:
Thus, only one part localised on the flanks of the trench pattern is etched during the partial etching of the isolation trench. This makes it possible to confine the partial etching between the flank of the trench pattern and the isolating material for filling the isolation trench.
Contrary to the solution disclosed by document FR 2952472 A1 wherein the partial etching of the isolation trench is not confined, the sizing of the isolation trench is thus better controlled. This makes it possible to increase the integration density of the semiconductive devices.
It is further possible to perform a partial etching of the isolation trench at one single flank of the trench pattern. This makes it possible to access a sacrificial layer located on the side of this flank only, by preserving the other flank of the trench pattern. Different semiconductive devices can thus be cointegrated, densely and easily. In particular, a semiconductive device comprising a back gate can be formed directly in the vicinity of a semiconductive device without a back gate, without it being necessary to increase the width of the isolation trench, separating them from one another, contrary to the solution disclosed by document FR 2952472 A1. The method according to the invention thus offers an improved solution for the production of back gates localised under one or more semiconductive devices, with an increased integration density.
Another aspect of the invention relates to a semiconductive device comprising a back gate formed by the method, according to the invention.
The aims, objectives, as well as the features and advantages of the invention will best emerge from the detailed description of an embodiment of the latter, which is illustrated by the following accompanying drawings, wherein:
The drawings are given as examples and are not limiting of the invention. They constitute principle schematic representations, intended to facilitate the understanding of the invention and are not necessarily to the scale of practical applications. In particular, on the principle diagrams, the thicknesses and/or the dimensions of the different layers, patterns and raised parts are not representative of reality. For reasons of clarity, all the alphanumeric references are not systematically repeated from one figure to the other. It is understood that the elements already described and referenced, when they are reproduced in another figure, typically have the same alphanumeric references, even if these are not explicitly mentioned, a person skilled in the art will identify, without difficulties, one same element reproduced in different figures.
Before starting a detailed review of embodiments of the invention, optional features are stated below, which can optionally be used in association or alternatively:
According to an example, the semiconductive device is a quantum device and the electrically conductive material is metal. A conductive metal material makes it possible to obtain a back gate, which is operational even at a low temperature, typically for operating temperatures of a quantum device. Contrary to a doped or highly doped-type semiconductive-type conductive material, a metal material is not sensitive to the gel of the carriers which occurs at a low temperature. The metal back gate thus remains operational at a low temperature.
According to an example, the semiconductive device is adjacent to a second semiconductive device separated from the semiconductive device by an isolation trench having a first flank on the side of the semiconductive device and a second flank on the side of the second semiconductive device, said isolation trench comprising a first sacrificial coating layer portion on the first flank and a second sacrificial coating layer portion on the second flank.
According to an example, the partial etching of said isolation trench comprises a simultaneous removal of the first and second sacrificial coating layer portions, so as to form a first back gate under the semiconductive device and a second back gate under the second semiconductive device. The method thus makes it possible to simultaneously form several back gates for adjacent devices, by preserving an operational isolation trench between the adjacent devices, thanks to the isolating material inserted between the first and second sacrificial coating layer portions in the isolation trench.
According to an alternative example, the partial etching of said isolation trench comprises a removal of the first sacrificial coating layer portion only, without removal of the second sacrificial coating layer portion, so as to form the back gate only under the semiconductive device, by preserving a sacrificial layer portion under the second semiconductive device. The method thus makes it possible to form a back gate for only one of the adjacent devices, by preserving an operational isolation trench between the adjacent devices, thanks to the isolating material and to the second sacrificial coating layer portion in the isolation trench.
According to an example, the formation of the sacrificial coating layer is done by compatible deposition on the flanks and the bottom of the at least one trench pattern.
According to an example, the removal of the sacrificial coating layer is only partial and configured to preserve a portion of the sacrificial coating layer located on the bottom of the at least one trench pattern. The number of steps of the method for forming the isolation trench and the openings to the sacrificial layer is thus limited.
According to an example, the formation of the sacrificial coating layer comprises a compatible deposition on the flanks and the bottom of the at least one trench pattern, followed by an anisotropic etching configured to remove a portion of the sacrificial coating layer located on the bottom of the at least one trench pattern, such that the sacrificial coating layer only covers the flanks of the at least one trench pattern, before filling the at least one trench pattern with the isolating material.
According to an example, the removal of the sacrificial coating layer is total. The formation of the openings to the sacrificial layer is thus facilitated. It is not necessary to specifically control the stopping of etching during the removal of the sacrificial coating layer.
According to an example, the sacrificial coating layer is chosen with the basis of a first dielectric material, for example, SiN or SiC. This makes it possible to preserve sacrificial coating layer portions in the isolation trench without weakening or compromising the isolation function of the isolation trench.
According to an example, the formation of the sacrificial coating layer is configured, such that the sacrificial coating layer has a thickness e15 in a direction transverse to the flanks of the at least one trench pattern, and the filling of the at least one trench pattern by the isolating material is configured, such that the isolating material has a thickness e16 in said transverse direction, such that e15<e16/3. This makes it possible to size the isolation trench according to proportions balancing the isolation function by the isolating material and the function of access to the sacrificial layer of the stack by the sacrificial coating layer. The isolation between adjacent devices and the access to the sacrificial layer of the stack are thus optimised.
According to an example, the method further comprises after removal of the sacrificial layer and before filling the cavity with an electrically conductive material, a compatible deposition of a layer made of a second dielectric material on exposed walls of the cavity, for example, by chemical vapour deposition (CVD). This makes it possible to insulate the back gate with respect to the support layer and/or with respect to the superficial semiconductive layer.
According to an example, the layer made of a second dielectric material has a thickness e51, the sacrificial coating layer has a thickness e15, the electrically conductive material has a thickness e5, such that e51<e15/3 and e51<e5/3, and preferably such that e51<e15/4 and e51<e5/4. This makes it possible to size the back gate and the contact via on this back gate according to balanced proportions. The bias of the back gate and the isolation of the back gate with respect to the support layer and/or with respect to the superficial semiconductive layer are thus optimised.
According to an example, the isolating material of the isolation trenches is chosen with the basis of SiO2. The isolating material of the isolation trenches is different from the first dielectric material of the sacrificial coating layer.
According to an example, the first dielectric material of the sacrificial coating layer has, with respect to the isolating material of the isolation trenches, a selectivity to the etching S≥5:1.
According to an example, the sacrificial layer is formed on the support layer by epitaxy, said sacrificial layer being, for example, SiGe-based.
Unless incompatible, it is understood that all the optional features above can be combined, so as to form an embodiment, which is not necessarily illustrated or described. Such an embodiment is clearly not excluded from the invention. The features and the advantages of an aspect of the invention, for example, the device or the method, can be adapted mutatis mutandis to the other aspect of the invention.
The invention is generally based on a method for manufacturing a back gate for a semiconductive device, and on such a device equipped with a back gate. This back gate can also be called back electrode. A semiconductive device according to the invention typically comprises a semiconductive layer, wherein charge carriers or quantum states travel and/or are confined. For example, and in a non-limiting manner, this semiconductive layer can thus form a transistor channel, or be integrated in a spin qubit architecture for quantum devices with quantum bits (called qubits).
It is specified that, in the scope of the present invention, the terms “on”, “surmounts”, “covers”, “underlying”, “opposite” and their equivalents do not necessarily mean “in contact with”. Thus, for example, the deposition, the transfer, the adhering, the assembly or the application of a first layer on a second layer, does not compulsorily mean that the two layers are directly in contact with one another, but means that the first layer covers at least partially the second layer, by being either directly in contact with it, or by being separated from it by at least one other layer or at least one other element.
By a substrate, a film, a layer, “with the basis” of a material A, this means a substrate, a film a layer comprising this material A only, or this material A and optionally other materials, for example doping elements or alloy elements.
Several embodiments of the invention implementing successive steps of the manufacturing method are described below. Unless explicitly mentioned, the adjective “successive” does not necessarily imply, even if this is generally preferred, that the steps follow one another immediately, intermediate steps being able to separate them.
Moreover, the term “step” means the carrying out of a part of the method, and can mean a set of substeps.
Moreover, the term “step” does not compulsorily mean that the actions carried out during a step are simultaneous or immediately successive. Certain actions of a first step can in particular be followed by actions linked to a different step, and other actions of the first step can then be resumed. Thus, the term “step” does not necessarily mean single and inseparable actions over time and in the sequence of phases of the method.
By “selective etching with respect to” or “etching having a selectivity with respect to”, this means an etching configured to remove a material A or a layer A with respect to a material B or a layer B, and having an etching speed of the material A greater than the etching speed of the material B. The selectivity is the ratio between the etching speed of the material A over the etching speed of the material B. It is referenced SA:B. A selectivity SA:B of 10:1 means that the etching speed of the material A is 10 times greater than the etching speed of the material B.
By “extends within” a layer, this means the action of penetrating into this layer, directly or indirectly. In particular, a structure or a material extending within a layer means that the structure or the material are extended between the two faces defining said layer, typically between the two upper and lower faces. Thus, a filling material which extends at least to within the sacrificial layer of the stack means that the filling material has a portion or a lower face located between the planes defined by the upper and lower faces of the sacrificial layer of the stack. A filling material which extends at least to within the support layer of the stack means that the filling material has a portion or a lower face located between the planes defined by the upper and lower faces of the support layer of the stack. In this case, a filling material extending to within the support layer totally passes through the sacrificial layer of the stack. This makes it possible to facilitate the isolation between two adjacent devices during the etching of the sacrificial coating layer followed by the filling of the cavity by an electrically conductive material to form the back gate(s) under one and/or the other of the adjacent devices. The tolerance on stopping the etching of the sacrificial coating layer is increased.
A preferably orthonormal system, comprising the axes x, y, z is represented in the accompanying figures. When one single system is represented in one same set of figures, this system applies to all the figures of this set.
In the present patent application, thickness will preferably be referred to, for a layer or a film, and height for a device or a structure. The thickness is taken in a direction normal to the main extension plane of the layer or of the film. Thus, an epitaxially grown superficial silicon layer typically has a thickness along z. A gate pattern formed on such a superficial layer has a height along z. The relative terms “on”, “surmounts”, “under”, “underlying” refer to positions taken in the direction z. A“lateral” dimension corresponds to a dimension in a direction of the plane xy. By a “lateral” extension or “laterally” means, an extension in one or more directions of the plane xy. The thicknesses e15, e16, e51, e5, etc. of the different layers are, naturally, strictly positive.
An element located “in vertical alignment with” or “to the right” of another element means that these two elements are both located on one same line perpendicular to a plane, wherein a lower or upper face of a substrate mainly extends, i.e. on one same line oriented vertically in the figures, as a cross-section.
The terms “substantially”, “about”, “around” mean close to 10%, and preferably close to 5%. Moreover, the terms “comprised between . . . and . . . ” and equivalent mean that the limits are inclusive, unless mentioned otherwise.
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After removal of the sacrificial layer 11, the walls of the cavity 50 are coated by a layer 51 made of a dielectric material, for example, SiN or SiO2, so as to electrically isolate the future back gate with respect to the support 10 and the topSi 12 layer. This layer 51 preferably has a thickness e51 of between 2 nm and 10 nm. It can be formed by a compatible deposition method of the plasma-enhanced chemical vapour deposition PECVD or of the low-pressure chemical vapour deposition LPCVD or PEALD (plasma-enhanced atomic layer deposition) type. The cavity 50 thus has a height e5. The sizing rules are preferably such that e51<e15/3 and e51<e5/3, and preferably such that e51<e15/4 and e51<e5/4. This makes it possible to preserve sufficiently large opening sections, between the openings 40b and the cavity 50 to enable the subsequent filling with a conductive material.
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In view of the description above, it clearly appears that the method proposed offers a particularly effective and versatile solution to form a back gate under a semiconductive device, by preserving or by improving the integration density of this semiconductive device.
The invention is not limited to the embodiments described above.
Number | Date | Country | Kind |
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22 14382 | Dec 2022 | FR | national |