Plasma process uniformity across a workpiece, such as a semiconductor wafer, is limited by non-uniformity of plasma ion distribution and process gas flow distribution. Efforts to improve process uniformity across the wafer can entail changing the radial distribution of the plasma source power and (or) changing the radial distribution of gas flow in the chamber. Such changes are typically carried out at or above the chamber ceiling, since the plasma source power applicator apparatus is generally at or on top of the ceiling and the process gas injection apparatus is typically a gas distribution plate in the ceiling. One problem is that the distance from the ceiling to the wafer is typically sufficient for diffusion effects to distort a desired distribution of plasma ions and (or) process gas flow between the ideal realized at the ceiling and the actual conditions at the wafer surface. Therefore, the extent to which plasma process uniformity can be improved is significantly limited due to the wafer-to-ceiling gap.
Plasma process control is affected by dissociation of chemical species in the plasma. The degree of dissociation is determined by (among other things) selection of RF plasma source power level, for example. Typically, the degree of dissociation affects all gas chemical species in the chamber, so that generally the same degree of dissociation is experienced by all species in the chamber, although the heavier or more complex molecular species may be somewhat less dissociated than the simpler ones. As a result, it is not generally possible to separately control the dissociation of different chemical species in the reactor chamber. For example, if a high degree of dissociation is desired for one chemical species, all species present in the chamber will experience a significant degree of dissociation. In such a case, for example, it may not be possible to highly dissociate one chemical species in the chamber without at least partially dissociating all species present in the chamber, even the more complex ones. Therefore, the ability to control an etch process is limited by the lack of any independent control over dissociation.
Plasma process control is also affected by the RF electric field at the wafer surface. Typically, the RF electric field at the wafer surface is controlled by the potential of the wafer relative to conductive surfaces of the chamber, such as the side wall or the ceiling. Such control is limited because the side wall is located closest to the wafer edge and furthest from the wafer center, and therefore can create non-uniformities. The ceiling, which presents a uniform conductive plane to the entire wafer, is displaced from the wafer by the wafer-to-ceiling gap which can allow unwanted distortions of what should be a uniform field over the wafer.
A method of processing a workpiece in a plasma reactor chamber is disclosed. In one aspect, the method includes providing an in-situ gas distribution plate between the workpiece and a ceiling of the chamber that divides the chamber into upper and lower chamber regions. The method further includes providing in the in-situ plate an array of feed-through openings with different opening sizes to present a non-uniform distribution of gas flow resistance for gas flow from the upper chamber region to the lower chamber region. A first process gas is introduced into the upper chamber region and a plasma is generated a plasma in the upper chamber region. A second process gas is introduced in the lower chamber region through gas injection orifices of the in-situ gas distribution plate.
In one aspect, a higher degree of dissociation is attained in the upper chamber region while a lower degree of dissociation is attained in the lower region, so that the first process gas is more highly dissociated while the second process gas is less dissociated, thereby attaining a greater range of process control.
In another aspect, the method can further couple a voltage source to a conductive electrode of the in-situ gas distribution plate. The method can also evacuate the lower chamber region with a vacuum pump while maintaining a pressure difference across the in-situ gas distribution plate in accordance with gas flow resistance of the in-situ plate so as to maintain the lower chamber region at lower chamber pressure than the upper chamber region.
So that the manner in which the exemplary embodiments of the present invention are attained and can be understood in detail, a more particular description of the invention, briefly summarized above, may be had by reference to the embodiments thereof which are illustrated in the appended drawings. It is to be appreciated that certain well known processes are not discussed herein in order to not obscure the invention.
To facilitate understanding, identical reference numerals have been used, where possible, to designate identical elements that are common to the figures. It is contemplated that elements and features of one embodiment may be beneficially incorporated in other embodiments without further recitation. It is to be noted, however, that the appended drawings illustrate only exemplary embodiments of this invention and are therefore not to be considered limiting of its scope, for the invention may admit to other equally effective embodiments.
The efficiency of the capacitively coupled power source applicator 116 in generating plasma ions increases as the VHF frequency increases, and the frequency range preferably lies in the VHF region for appreciable capacitive coupling to occur. As indicated symbolically in
The plasma ion density increases as the power applied by either the inductively coupled power applicator 114 or VHF capacitively coupled power applicator 116 is increased. However, they behave differently in that the inductively coupled power promotes more dissociation of ions and radicals in the bulk plasma and a center-low radial ion density distribution. In contrast, the VHF capacitively coupled power promotes less dissociation and a center high radial ion distribution, and furthermore provides greater ion density as its VHF frequency is increased.
The inductively and capacitively coupled power applicators may be used in combination or separately, depending upon process requirements. Generally, when used in combination, the inductively coupled RF power applicator 114 and the capacitively coupled VHF power applicator 116 couple power to the plasma simultaneously, while the LF and HF bias power generators simultaneously provide bias power to the wafer support electrode 130. The simultaneous operation of these sources enables independent adjustment of the most important plasma processing parameters, such as plasma ion density, plasma ion radial distribution (uniformity), dissociation or chemical species content of the plasma, sheath ion energy and ion energy distribution (width). For this purpose, a source power controller 140 regulates the source power generators 118, 122 independently of one another (e.g., to control their ratio of powers) in order to control bulk plasma ion density, radial distribution of plasma ion density and dissociation of radicals and ions in the plasma. The controller 140 is capable of independently controlling the output power level of each RF generator 118, 122. In addition, or alternatively, the controller 140 is capable of pulsing the RF output of either one or both of the RF generators 118, 122 and of independently controlling the duty cycle of each, or of controlling the frequency of the VHF generator 122 and, optionally, of the HF generator 118. In addition, a bias power controller 142 controls the output power level of each of the bias power generators 132, 134 independently in order to control both the ion energy level and the width of the ion energy distribution.
The in-situ electrode 10 in the reactor of
Referring to
Referring now to
The reactor of
The presence of the in-situ electrode 10 creates different process conditions in the two regions 15a, 15b above and below the in-situ electrode 10 respectively. The upper chamber region 15a has a higher chamber pressure, due to the gas flow resistance through the in-situ electrode passages 72, which favorable for an inductively coupled plasma source. The plasma density and the electron temperature is greater in the upper chamber region 15a, which leads to greater dissociation of chemical species in the upper chamber 15a. The dissociation in the lower chamber is much less because the electron temperature is lower, the plasma ion density is lower and the pressure is lower. Moreover, because of the lower pressure of the bottom chamber region 15b, there are less collisions, so that the ion trajectory is more narrowly distributed about the vertical direction near the wafer surface, a significant advantage.
In accordance with one aspect, the reactor of
Because the in-situ electrode/gas distribution plate 10 is closer to the workpiece or wafer 102 than the ceiling gas distribution plate 108b, the radial distribution of active species across the workpiece surface is far more responsive to changes gas flow apportionment between the inner and outer gas manifolds 62, 64, because the diffusion is so minimal. The close proximity of the in-situ electrode 10 to the workpiece 102 also causes the distribution of plasma ions across the workpiece surface to be highly responsive to the distribution of plasma flow through the axial openings 72 of the in-situ electrode 10. Thus, the radial distribution of etch rate across the workpiece surface may be improved (e.g., to a more uniform distribution) by apportioning process gas flow to the inner and outer manifolds 62, 64 of the in-situ electrode and by providing a non-uniform distribution of opening sizes of the axial openings 72 across the in-situ electrode 10.
The volume or height of each of the upper and lower chamber regions 15a, 15b can be adjusted, for example, by raising or lowering either the in-situ electrode 10 or the support pedestal 103 using the actuator 105. By reducing the distance from the wafer 102 to the in-situ electrode 10, the electrode-to-wafer path length is reduced to reduce collisions that would deflect ions from a desired vertical trajectory established by the electric field between the workpiece and the in-situ electrode 10. The volume of the upper chamber region 15a can be adjusted to optimize the operation of the inductively coupled plasma source power applicator 114. In this way, the two chamber regions 15a, 15b can have entirely different process conditions. The upper region 15a can have maximum ion density and maximum volume for maximum dissociation, high pressure and its own set of process gas species (e.g., lighter or simpler fluorocarbons) while the lower region 15b can have minimal ion density, lower pressure, less volume and minimal dissociation.
In accordance with an alternative aspect, the entire in-situ electrode 10 can be rendered conductive by forming it entirely of a semiconductive material or ceramic such as doped aluminum nitride.
The in-situ electrode 10 has different modes of use: One set of process gases may be introduced through the ceiling gas distribution plate 108b into the plasma generation region of the upper chamber 15a, while simultaneously a different set of processes gas may be introduced into the chamber region 15b below the plasma generation region through the in-situ electrode 10 much closer to the workpiece 102.
The gases in the upper and lower regions 15a, 15b may be subject to different process conditions: in the upper region, the ion density and pressure may be higher for greater dissociation of species, while in the lower region, the ion density is less and the pressure is less, for a narrower ion velocity distribution about the true vertical and less dissociation.
The inner and outer gas manifolds or zones 62, 64 of the in-situ electrode 10 may be controlled independently to adjust the radial distribution of process gases introduced through the in-situ electrode 10, the active species distribution at the workpiece surface being much more responsive to such changes because of the closer proximity of the in-situ electrode 10 to the workpiece 102.
The range of dissociated species can be significantly increased by generating highly dissociated species in the upper chamber region 15a and introducing heavier species through the in-situ electrode 10 into the lower region 15b which experience little or no dissociation.
Uniformity of the bias RF electrical field at the workpiece surface can be achieved by employing the conductive layer 44 of the in-situ electrode 10 as a ground reference or as an electrical potential reference, by connecting the conductive layer 44 either to ground or to an RF (HF or LF) potential source 80. The close proximity of the in-situ electrode 10 offers a close uniform plane for establishing a more uniform RF bias field at the workpiece. In one aspect, the RF bias generator 132 or 134 can be coupled across the workpiece support pedestal electrode 130 and the in-situ electrode conductive layer 44.
The gas flow distribution through the axial passages 72 of the in-situ electrode can be rendered non-uniform to compensate for a chamber design that otherwise would produce a center-high or center-low distribution of plasma ion density. This feature may be realized by providing the different passages 72 with differing areas or opening sizes, and distributing those sizes according (e.g., larger opening nearer the center and smaller openings nearer the periphery, or vice versa.
A D.C. voltage source 11 (shown in
In this case, the electrode 10 may be formed entirely of a conductive or semi-conductive material (e.g., doped aluminum nitride), and the conductive layer 44 may be eliminated.
The volumes of the upper and lower chamber regions 15a, 15b may be adjusted to optimize conditions in those two regions, for example by raising or lowering the pedestal 103. For example, if an inductively coupled source power applicator 14 is employed to generate the plasma in the upper chamber region 15a, then its performance may be enhanced by increasing the volume of the upper chamber region. This change would also tend to increase the residency time of gases in the plasma in the upper chamber region 15a, thereby increasing dissociation. The volume of lower chamber region 15b may be decreased in order to reduce ion collisions in that region and thereby achieve a narrower distribution of ion velocity profile about the vertical direction. This feature may improve plasma process performance in regions of the workpiece surface having deep high aspect ratio openings.
A low density capacitively coupled plasma source could be established in the lower chamber region 15a by coupling a VHF power generator 80 to the conductive layer 44 (of the in-situ electrode 10). The RF return terminal of the VHF generator can be connected to the support pedestal electrode 130 to establish a VHF electric field in the lower chamber region 15b. In this case, RF filters can be employed to avoid conduction between the HF and VHF power sources 132, 80. For example, if the in-situ electrode 10 (e.g., its conductive layer 44) functions as a ground plane for the HF bias source 132, then the VHF generator 80 could be coupled to the in-situ electrode through a narrow VHF bandpass filter (not shown), for example. Similarly, if the pedestal electrode 130 is to be a ground plane for the VHF generator 80, then the pedestal electrode 130 may be coupled to ground through a narrow VHF bandpass filter (now shown) to avoid diverting power from the HF or LF generators 132, 134, for example.
In the implementation depicted in
Referring to
While the foregoing is directed to embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
This application claims benefit of U.S. Provisional Application Ser. No. 60/873,103, filed Dec. 5, 2006.
Number | Date | Country | |
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60873103 | Dec 2006 | US |