1. Field of the Invention
This invention relates generally to methods and systems for electroplating substrates, such as those utilized for damascene electroplating of write coils in magnetic heads.
2. Description of the Related Art
The demand for manufacturing semiconductor integrated circuit (IC) devices, such as computer chips with high circuit speed, high-packing density, and low power dissipation, requires the downward scaling of feature sizes in ultra-large-scale integration (ULSI) and very-large-scale integration (VLSI) structures. The trend to smaller chip sizes and increased circuit density requires the miniaturization of interconnect features which severely penalizes the overall performance of the structure because of increasing interconnect resistance and reliability concerns such as fabrication of the interconnects and electromigration. Magnetic heads with inductive write coils also feature miniaturization requirements to increase areal storage densities on magnetic disks and reduction of coil resistance.
Historically, such structures have utilized aluminum and aluminum alloys as the metallization on silicon wafers, with silicon dioxide being the dielectric material. In general, openings were formed in the silicon dioxide dielectric layer in the shape of vias and trenches which were then metallized to form the interconnects. Increased miniaturization, however, has required these openings to be at submicron sizes (e.g., 0.5μ and lower). To achieve such miniaturization, industries have moved to the use of copper instead of aluminum as the metal to form the connection lines and interconnects in the chip. Copper has a lower resistivity than aluminum and the thickness of a copper line for the same resistance can be thinner than that of an aluminum line. Copper-based interconnects therefore represent the most foreseeable future trend in the fabrication of such devices. Copper can be deposited on substrates by plating (such as electroless and electrolytic), sputtering, plasma vapor deposition (PVD), and chemical vapor deposition (CVD). It is generally recognized that a plating-based deposition is the best method to apply copper to the device since it can provide high deposition rates and low system costs.
Referring to
Plating system 100 further includes a plating solution holding tank 119 from which a plating solution 127 is drawn via a pump 122 through a plating solution inlet transport line 117, a flow measurement device 151, and an inlet valve 140 to an inlet 110a of cell 110. Plating solution 127 flows through cell 110 and thereby contacts wafer 112 and anode 113, filling the space therein between them with the solution. A rotor 130 holds wafer 112 in position and a rotor 131 holds anode 113 in place. Rotors 130 and 131 alternatively may be a flange, plate, or other similar device. Plating solution 127 exits cell 110 through an overflow weir 125 into outlet 110b and is recycled into tank 119 through a plating solution transport line 118. During operation of plating system 100 to plate wafer 112, plating solution 127 continuously flows through the system at a predetermined plating flow rate. The plating flow rate may be, for example, between 2 to 6 gallons per minute (g/m). This forms a substantially uniform electrolyte composition in the system and contributes to the overall effectiveness of the wafer plating. Flow of plating solution 127 through plating system 100 is controlled by a flow control mechanism which includes pump 122 and inlet valve 140. Additionally, the flow control mechanism includes a flow measurement device 151, such as a flow meter, and a closed feedback loop 150 for more precise control over the flow of plating solution 127.
During operation of plating system 100, copper metal is plated on wafer surface 112a when power supply 116 is energized. A pulse current, direct current (DC), reverse periodic current, or other suitable current may be employed. The electroplating process results in depletion of the copper concentration of plating solution 127. Copper deposits must be uniform and capable of filling the extremely small trenches and vias of the device. These important properties are typically achieved using multi-component plating solutions, which include organic and inorganic components. Typical plating solution 127 formulations use highly stable electrolytes containing copper sulfate and sulfuric acid. As an example, copper concentration in these electrolytes may be between 12-60 grams/liter (g/l) and sulfuric acid 1-240 g/l.
Other components added to the plating solution are present in relatively small amounts. These components are organic additives and chloride ions. The organic additives, depending on the concentration and chemical composition, affect the properties of the electrodeposited copper including uniformity, hardness, ductility, tensile strength, grain size, etc. These additives for enhancing electroplating properties, which react at the wafer surface during electroplating, fall into three major categories. Accelerators are compounds that contain pendant sulfur atoms that locally accelerate deposition where they are adsorbed. Suppressors are polymers, such as polyethylene glycols, which have the ability to form a current-suppressing film on the entire wafer surface. The third category of organic additives are levelers, which are secondary suppressors and work only on the protruding surfaces where mass transfer is most effective.
After completing the electroplating of one or more wafers, the flow through pump 122 is set and maintained at a reduced “idle flow” rate. This reduced idle flow rate may be, for example, between 1 to 1.5 g/m. During this time period, no wafers are being electroplated. At some point in time, however, subsequent wafers will be electroplated where pump 122 is once again set and maintained at the higher plating flow rate.
In addition to reacting at the surface of the wafer during electroplating, the additives of the plating solution undesirably react at the surface of anode 113 within cell 110 during electroplating and idle flow during non-plating periods. Further, there are other interactions between the additives and inorganic compounds which cause decomposition and modification of initial organic compounds. These breakdown products ideally need to be kept below a threshold level in order to provide the most uniform of copper deposition and highest capability of filling the extremely small trenches and vias of the device. Thus, monitoring these breakdown products must be performed at least once every four to six hours by analyzing the composition of the bath during idle flow. Also, replacement of up to 20% may be done daily to maintain the plating solution in steady state. Both of these requirements result in a large amount of time and labor for plating solution analysis and control. This is especially true when system utilization is less than 100%.
Accordingly, what are needed are improved methods for electroplating wafers as well as improved systems for performing such methods.
Improved methods and systems for electroplating wafers are described herein. The method includes the acts of introducing a wafer which is coupled to an electrode (e.g. a cathode) into an electroplating cell having a counter electrode (e.g. an anode); maintaining a flow of a plating solution through the cell for electroplating the wafer; removing the wafer from the cell; stopping the flow of the plating solution through the cell; maintaining a volume of plating solution within the cell sufficient to keep the counter electrode submerged during stoppage of flow; removing the plating solution within the cell; and repeating the above steps for a subsequent wafer.
By stopping the flow of plating solution after completion of plating one or more wafers, a consumption rate of additives enhancing electroplating properties is reduced, a production rate of breakdown products produced during electroplating is reduced, plating solution useable life is increased, and a need for plating solution analysis is reduced.
For a fuller understanding of the nature and advantages of the present invention, as well as the preferred mode of use, reference should be made to the following detailed description read in conjunction with the accompanying drawings:
In describing the preferred embodiment of the present invention, reference will be made herein to
Referring first to
Plating system 300 further includes a plating solution holding tank 119 from which a plating solution 127 is drawn via a pump 122 through a plating solution inlet transport line 117 and a plating solution inlet valve 140 into an inlet 110a of cell 110. Plating solution 127 flows through cell 110 and thereby contacts wafer 112 and counter electrode 113, filling the space between them with the solution. Rotor 130 holds wafer 112 in position and rotor 131 holds counter electrode 113 in place. Rotors 130 and 131 alternatively may be a flange, plate, or other similar device. Plating solution 127 exits cell 110 through overflow weir 125 into outlet 110b, flows through an adjacent plating solution outlet valve 341, and is recycled into tank 119 through plating solution transport line 118. During operation of plating system 100, plating solution 127 continuously flows through the system at a predetermined plating flow rate. The plating flow rate may be, for example, between 2 to 6 gallons per minute (g/m). Such flow forms a substantially uniform electrolyte composition in the system and contributes to the overall effectiveness of the wafer plating. Flow of plating solution 127 through plating system 300 is controlled by a flow control mechanism which includes pump 122, inlet valve 140, and outlet valve 341. Additionally, the flow control mechanism includes a flow measurement device 151, such as a flow meter, and a closed feedback loop 150 for more precise control over the flow of plating solution 127. Note that plating system 300 is similar to plating system 100 of
The composition of plating solution 127 may vary widely depending on the substrate to be electroplated and the type of copper deposition desired. Exemplary plating solutions include copper fluoborate, copper pyrophosphate, copper cyanide, copper phosphonate, and other copper metal chelates such as methane sulfonic acid. One preferred plating solution is copper sulfate in an acid solution. The concentration of copper and acid may vary over wide limits. For copper or copper ions, compositions generally vary up to 25 grams/liter (g/l) or more preferably 15 to 20 g/l. The acidic composition is typically sulfuric acid in an amount up to about 300 g/l or more, preferably 150 to 200 g/l. Chloride ions may be used in the plating solution at levels up to about 90 mg/l. Other components added to the plating solution are present in relatively small amounts. These components are organic additives and chloride ions. The additives for enhancing electroplating properties, depending on the concentration and chemical composition, affect the properties of the electrodeposited copper including uniformity, hardness, ductility, tensile strength, etc. A particularly desirable additive composition uses a mixture of aromatic or aliphatic quaternary amines, polysulfide compounds, polyimines and polyethers. Other additives include metaloids such as selenium, tellurium and sulfur compounds.
A method of electroplating wafer 112 of
Once the electroplating of the wafer(s) is completed as identified at step 210, flow of the solution through cell 110 is stopped by turning off or disengaging pump 122 as well as closing inlet valve 140 and outlet valve 341 (step 212 of
For the next set of wafers to be electroplated, the volume of the plating solution maintained within cell 110 is removed just prior to electroplating the next wafer (step 218 of
As indicated, the above method is applicable when electroplating different sets or batches of wafers. For a first set of wafers, steps 204, 206, 208 and 210 of
During operation of plating system 300 (e.g. step 206 of
In accordance with the present techniques, the flow of plating solution 127 is stopped but a volume of plating solution 127 is maintained within cell 110 sufficient to keep counter electrode 113 submerged between electroplating runs (see steps 212 and 214 of
Removing the plating solution from the system is performed and new plating solution is added to the system either simultaneously or after the recycling in substantially the same amount. The new solution is preferably a single liquid containing all the materials needed to maintain the electroplating system. The addition/removal mechanism maintains the plating solution in steady-state during operation of the plating system.
Referring now to
Note that the techniques for engaging/disengaging the pump, opening/closing of the valves, and identifying various conditions for change (e.g. wafer electroplating completed, new wafer set introduced, etc.), may be implemented in whole or in part manually by an end user(s) of the system or by computer control. If done by computer control, software instructions may be written in accordance with the described logic, stored in memory, and executed by a computer processor for performing the method.
Thus, a method of electroplating wafers of the present invention includes the steps of: for a first set of wafers: (a) introducing a wafer coupled to an electrode into an electroplating cell having a counter electrode; (b) maintaining a flow of a plating solution through the cell for electroplating the wafer; (c) removing the wafer from the cell; and (d) repeating steps a to c for electroplating additional wafers of the first set. The method continues with the steps of (e) stopping the flow of the plating solution through the cell after electroplating the first set of wafers; and (f) maintaining a volume of plating solution within the cell sufficient to keep the counter electrode submerged during stoppage of flow. For a subsequent set of wafers, the method continues with the steps of (g) removing the plating solution within the cell; and (h) reperforming steps a to d for electroplating the subsequent set of wafers.
A system of the present invention includes an electroplating cell for electroplating a wafer; a positioning mechanism to introduce and remove the wafer from the cell; and a flow control mechanism to maintain a flow of plating solution through the cell for electroplating the wafer and to stop the flow thereafter. The flow control mechanism also maintains a volume of plating solution within the cell sufficient to keep an electrode of the cell submerged during stoppage of flow, and removes the volume of plating solution from the cell prior to electroplating a subsequent wafer. The removal of plating solution may be done by draining the cell for recycling within a holding tank or for disposal via a drain/waste tank.
It is to be understood that the above is merely a description of preferred embodiments of the invention and that various changes, alterations, and variations may be made without departing from the true spirit and scope of the invention as set for in the appended claims. Few if any of the terms or phrases in the specification and claims have been given any special meaning different from their plain language meaning, and therefore the specification is not to be used to define terms in an unduly narrow sense.