Not Applicable
The present invention relates to a multi-layer polymeric electronic device or component and a method of manufacturing it. Specifically, the present invention relates (a) to a method of manufacturing multi-layer polymeric electronic devices using a process that employs plated through-hole vias to create conductive paths between selected laminar electrodes; and (b) to a multi-layer polymeric electronic device made in accordance with the method of the invention. More specifically, the invention relates to a laminar electronic device comprising two or more polymeric active elements laminated between laminar metal (e.g., foil) layers that form electrodes, wherein the device includes a first conductive path that provides electrical connections between a first plurality of metal layers that form a first set of electrodes, and a second conductive path that provides electrical connections between a second plurality of metal layers that form a second set of electrodes. Correspondingly, the first conductive path is physically and electrically isolated from the second plurality of metal layers, while the second conductive path is physically and electrically isolated from the first plurality of metal layers.
Electronic devices or components employing conductive polymer elements, especially elements exhibiting positive temperature coefficient of resistivity (PTC) behavior, are well-known in the art. Typically, such devices comprise a laminated structure formed from a layer of conductive polymer material laminated between metal foil layers that function as electrodes. Terminations are then formed on the device for electrical connection to a circuit board, usually in a surface-mount configuration. For the purposes of both electrical efficiency and space-saving, multi-layer components are becoming increasingly common. Such multi-layer components typically comprise at least two discrete laminar polymeric elements, separated by laminar foil electrodes, and terminated by conductive terminations for connection to a circuit board. Such devices are preferably vertically and laterally symmetrical; that is, they have no distinct “right side up,” “upside down,” or “end-to-end” orientations, for more efficient installation on a circuit board by “pick-and-place” machinery. Exemplary prior art devices and methods of manufacturing them are disclosed in the following patent publications: U.S. Pat. No. 6,640,420; U.S. Pat. No. 6,172,591; U.S. Pat. No. 6,020,808; U.S. Pat. No. 6,429,533; and U.S. Pat. No. 6,242,997.
For maximum cost-savings, such devices must be easily mass-produced, typically with hundreds of such devices being formed simultaneously from a single laminated sheet structure. Heretofore, however, the need to create inter-layer conductive paths has presented challenges in reducing manufacturing costs, and thus more cost-efficient manufacturing methods are continually being sought. Furthermore, there has been a desire in the industry to apply multi-layer manufacturing techniques to a wider variety of electrical components and devices.
Broadly, the present invention is an electronic device or component comprising multiple, alternating layers of non-metallic (e.g., polymeric) material and metal foil electrodes, in which electrical connections between selected electrodes are provided by cross-conductors formed by plated through-hole vias. More specifically, the invention relates to a laminar electronic device comprising two or more non-metallic (e.g., polymeric) laminar elements laminated between metal foil layers that form electrodes, wherein the device includes a first cross-conductor, passing through a first through-hole via, that provides electrical connections between a first plurality of metal layers that form a first set of electrodes, and a second cross-conductor, passing through a second through-hole via, that provides electrical connections between a second plurality of metal layers that form a second set of electrodes. Correspondingly, the first cross-conductor is electrically and physically isolated from the second plurality of metal layers, while the second cross-conductor is electrically and physically isolated from the first plurality of metal layers.
The electrodes are formed by metal foil layers that are etched to form an isolation gap in each foil layer that isolates that layer from either of the first or second vias. The first and second cross-conductors, in turn, are formed by plating the through-hole vias, so as to establish electrically-conductive contact with those electrodes not separated from the via by an isolation gap. Thus, a device may be formed with N non-metallic (e.g. polymeric) layers and N+1 electrodes, where N is an integer greater than 1, wherein a first cross-conductor through a first via establishes electrical contact with a first set of N electrodes, and a second cross-conductor through a second via establishes electrical contact with a second set of N−1 electrodes, whereby the non-metallic layers are connected in series or parallel.
In a preferred embodiment, the plating that forms the cross-conductors through the vias also forms terminals or contact pads on the opposed major external surfaces of the device. The contact pads allow the device to be surface-mounted on a circuit board.
In the preferred embodiments, at least one of the non-metallic layers is made of a conductive polymer, such as a carbon-filled polymer that exhibits PTC behavior, as disclosed in, for example, U.S. Pat. No. 5,849,129; U.S. Pat. No. 4,237,441; and U.S. Pat. No. 5,174,924, the disclosures of which are incorporated by reference. Some embodiments may include one or more non-conductive (dielectric) polymeric layers, or conductive polymeric layers that have a fixed resistance, or ferromagnetic polymeric layers. Other embodiments may include still other types of laminar elements, such as, for example, a metal oxide varistor (MOV). Thus, the cross-conductors may be formed so as to create a device that comprises one or more elements that may include, for example, PTC elements, ferromagnetic elements, capacitive elements, fixed resistive elements, or non-polymeric active elements, connected in series or in parallel.
As will be appreciated from the detailed description below, the present invention provides a cost-efficient method of manufacturing multi-layer laminar electronic components that are also highly space-efficient. Moreover, the method of the invention offers a great deal of flexibility in manufacturing devices of a wide variety of electrical properties and characteristics in a single, space-saving package that is, preferably, vertically and/or laterally symmetrical, thereby resulting in advantages in installing the devices on circuit boards using conventional pick-and-place machinery. These and other advantages will be more fully understood from the following detailed description.
The various embodiments of the present invention are made with one or more laminated sheet structures, of the type shown in
As an alternative to laminating a layer of polymeric material between upper and lower foil sheets, it may be advantageous, for certain applications, to metallize directly the upper and lower surfaces of a sheet of polymeric material. The metallization may be accomplished by a metal plating process, vapor deposition, screen-printing, or any other suitable process that may suggest itself to those skilled in the pertinent arts. The preferred embodiments of the invention, however, use the laminated structure described above, and the ensuing description will be based on the use of the lamination process.
The laminated sheet structure 10 is typically sized to provide a multitude of electronic devices. Thus, as shown in
The devices described below are advantageously mass-produced while interconnected in a matrix formed by the lamination of two or more sheet structures into a laminated structure, which is then singulated (e.g., along the lines 20, 22) to form individual devices. The discussion below will be set forth with reference to the illustration of a single device, but it is to be understood that the process steps described below are performed on a matrix of such devices while they are interconnected in such a matrix. Thus, each step is performed simultaneously at a plurality of pre-defined locations on the matrix. As a final step in the manufacturing processes described below, the individual devices are separated from the matrix (singulated) by cutting, breaking, or dicing the matrix along the singulation lines 20, 22, or along a grid of separation lines defined by the singulation apparatus (if the singulation lines are not pre-formed).
Referring now to
A second sheet structure 10′ is provided, having a second upper metal layer 14′ on top of a second non-metallic (e.g., polymeric) layer 16′. The second sheet structure 10′ may be formed by laminating the second non-metallic layer 16′ between the second upper metal layer 14′, and a second lower metal layer 12′, but, after its lamination, the second lower metal layer 12′ (shown in phantom outline) of the second sheet structure 10′ is removed, by a conventional process, leaving only the second polymer layer 16′ and the second upper metal layer 14′, as shown in
It is understood that the second sheet structure 10′ may alternatively be made by directly metallizing the top surface of a sheet of polymeric material by any of the conventional methods mentioned above with respect to the first sheet structure 10.
After the multi-layer laminated structure 30 is formed, a plurality of through-hole vias is formed at pre-defined via locations in the structure 30. The plurality of vias includes a first subset of vias 32, each of which passes through one of the isolation areas 26, as mentioned above. The plurality of vias includes a second subset of vias 34, each of which passes through the multi-layer structure 30 at a pre-defined distance from one of the first subset of vias 32, such as may be defined, for example, by a singulation line 22 (
Using conventional photo-resist masking and etching techniques, or any other suitable process known in the art, metal is removed from the lower metal layer 12 and the second upper metal layer 14′ to form a set of transverse top isolation gaps 38 across the entire width of the second upper metal layer 14′ and a set of transverse bottom isolation gaps 38′ across the entire width of the lower metal layer 12. Each of the isolation gaps 38, 38′ is formed at a relatively short, pre-defined distance from one of the vias 34 in the second subset of vias, and they have a width (i.e., the dimension parallel to the longer dimension of the device) that is preferably approximately equal to the thickness of the polymer layers 16, 16′.
A solder mask 40, which is preferably a dielectric material, is screen-printed, or otherwise applied, to the lower metal layer 12 and to the second upper metal layer 14′, so as to fill in the isolation gaps 38, 38′, but leaving an exposed metal area surrounding each of the vias 32, 34. Specifically, the areas of the lower metal layer 12 and second upper metal layer 14′ between the respective isolation gaps 38, 38′ and the end of each device that is closer to the isolation gaps 38, 38′ are left exposed, as are the approximately equal-sized areas of the lower metal layer 12 and the second upper metal layer 14′ at the opposite end of each device. The exposed metal areas are coated (as by plating), first with nickel, and then with a solderable metal (e.g., gold), in accordance with standard industry practices, thereby forming a first pair of terminal pads 42a, 44a at each end of the lower surface of the device, and similar second pair of terminal pads 42b, 44b at each end of the upper surface of the device. The same plating layers are applied at the same time to the through-hole vias 32, 34. As mentioned above, the through-hole vias 32, 34 may have been previously metallized before the formation of the isolation gaps 38, 38′, and if so, the vias 32, 34 are metallized a second time when the exposed areas of the second upper metal layer 14′ and the lower metal layer 12 are metallized.
After completion of the above-mentioned metallization step, it can be seen that a first set of terminals is formed, each of which comprises a first lower terminal pad 42a, a first upper terminal pad 42b, and the electrical connection or cross-conductor therebetween provided by a metallized first through-hole via 32. In each device in the matrix, each of these first terminals thus electrically connects the lower metal layer 12 (which now defines a lower electrode) and the second upper metal layer 14′ (which now defines an upper electrode). Each of the first terminals is isolated, however, from the intermediate metal layer 14 (which now defines an intermediate electrode) by the polymer-filled isolation area 26. Likewise, a second set of terminals is formed, each of which comprises a second lower terminal pad 44a, a second upper terminal pad 44b, and the electrical interconnection or cross-conductor formed therebetween by a metallized second through-hole via 34. This second terminal is in electrical contact with the intermediate electrode (intermediate or second metal layer) 14, but it is isolated from the upper and lower electrodes by the isolation gaps 38, 38′, respectively (both of which are filled by the solder mask material 40).
In this configuration, each device is formed with a first arcuate isolation area 126a at one end of the first intermediate metal layer 114a, and a second arcuate isolation area 126b at the opposite end of the second intermediate metal layer 114b. The isolation areas 126a, 126b are formed in their respective metal layers 114a, 114b before the lower and upper sheet structures 10, 10′ are laminated together with the intermediate polymer layer 116c between them to form a laminated structure. The lamination of the sheet structures 10, 10′ causes polymeric material to flow into and fill the isolation areas 126a, 126b. After the two complete sheet structures 10, 10′ are laminated together with the intermediate polymer layer 116c between them, first and second subsets of through-hole vias 132, 134 are formed through the entire thickness of the laminated structure and metallized, as described above.
At each of a plurality of pre-defined locations in the laminated structure, a set of bottom isolation gaps 136 is formed in the lower metal layer 112, and a set of top isolation gaps 138 is formed in the upper metal layer 118. The bottom isolation gaps 136 are adjacent to, and on either side of, each of the second subset of vias 134, while the top isolation gaps 138 are adjacent to, and on either side of, each of the first subset of vias 132. A layer of solder mask material 140 (e.g., a dielectric material) is applied to both the lower metal layer 112 and the upper metal layer 118, filling in the isolation gaps 136, 138, and leaving exposed metal areas on the lower and upper metal layers 112, 118 surrounding each of the vias 132, 134. The exposed metal areas are then plated (or otherwise metallized), first with nickel, and then with a solderable metal, such as gold, to form first and second lower terminal pads 142a, 144a and first and second upper terminal pads 142b, 144b. The through-hole vias 132, 134 are metallized (e.g., plated) with the nickel and the solderable metal at the same time as the exposed metal end areas.
Thus, each of the devices 100 has a first terminal formed by the first lower terminal pad 142a, the first upper terminal pad 142b, and the electrical interconnection or cross-conductor formed between them by the plated first through-hole via 132. Likewise, a second terminal is formed by the second lower terminal pad 144a, the second upper terminal pad 144b, and the electrical interconnection or cross-conductor formed between them by the plated second through-hole via 134. The first terminal provides electrical connection to the lower metal layer 112 (which may now be defined as a lower external electrode) and to the second intermediate metal layer 114b (which may now be defined as a second intermediate electrode or a second internal electrode). Similarly, the second terminal provides electrical connection to the upper metal layer 118 (which may now be defined as an upper external electrode) and to the first intermediate metal layer 114a (which may now be defined as a first intermediate electrode or a first internal electrode). The first terminal is electrically isolated from the first internal electrode 114a by the polymer-filled first isolation area 126a, and from the upper electrode 118 by the second isolation gap 138. Similarly, the second terminal is electrically isolated from the lower electrode 112 by the first isolation gap 136, and from the second internal electrode 114b by the polymer-filled second isolation area 126b.
First and second sets of through-hole vias 232, 234 are then respectively drilled or otherwise formed at matrix locations that will correspond to opposite ends of each device 200 in the matrix. A first micro-via 270 may advantageously be formed through the bottom external foil layer 266 and the adjacent first insulating layer 262 at the end of each device 200 opposite the fourth isolation area 126d, and a second micro-via 272 may advantageously be formed through the top external foil layer 268 and the second insulating layer 264 at the end of each device opposite the third isolation area 126c. The first micro-via 270 extends to the surface of the lower metal layer (lower electrode 212), while the second micro-via 272 extends to the surface of the upper metal layer (upper electrode 218). The through-hole vias 232, 234, and the micro-vias 270, 272 are plated, first with a copper seed layer, then with a nickel layer, and then with a solderable metal, such as gold.
The bottom external foil layer 266 and the top external foil layer 268 are masked and etched to define a pair of lower terminal pads 242a, 244a, and a pair of upper terminal pads 242b, 244b. The upper terminal pads 242b, 244b are connected to their respective lower terminal pads 242a, 244a by the plated through-hole vias 232, 234, respectively, which also make contact with the metal layers that form the electrodes, whereby first and second terminals are formed. Specifically, a first terminal comprises the first lower terminal pad 242a, the first upper terminal pad 242b, and a first cross-conductor formed by the first plated through-hole via 232; while a second terminal comprises the second lower terminal pad 244a, the second upper terminal pad 244b, and a second cross-conductor formed by the second plated through-hole via 234. The first terminal makes contact with a second internal metal layer 214b that serves as a second intermediate electrode, and with the lower metal layer 212 that serves as a lower electrode. The second terminal makes contact with a first internal metal layer 214a that serves as a first intermediate electrode, and with the upper metal layer 218 that serves as an upper electrode. Furthermore, the first plated through-hole via 232 is insulated from the first intermediate electrode 214a by the polymer-filled first isolation area 126a (as explained above with respect to
The embodiment of
A plurality of vias 316, 316′, 316″ is formed in each of the substructures 302, 304, 306, respectively. With three substructures as shown, the vias 316 in the upper substructure 302 and the vias 316′ in the lower substructure 304 are in vertical alignment, while the via 316″ in the intermediate substructure 306 is spaced from the other vias 316, 316′ by a predetermined distance that is slightly greater than the length of the electrodes to be formed in the device by the first top foil layer 310 and the bottom foil layers 312, 312′, 312″, as will be described below.
The upper surface of the first top metal layer 310 and the lower surface of the second bottom foil layer 312′ are masked with a suitable insulative or (preferably) dielectric material 315, which fills in the isolation gaps 313, 313′, leaving exposed areas around each via 316 in the top surface of the upper substructure 302 and around each via 316′ in the lower substructure 304, and at the above-defined predetermined distance from each of the vias 316, 316′. These exposed areas are plated with a conductive metal plating to form terminal pads 319a, 319b, 319c, 319d. Each of the vias 316, 316′, 316″ is also internally plated to provide a metal-plated cross-conductor 317 between each of the top foil layers 310, 310′, 310″ and its respective bottom foil layer 312, 312′, 312″. Preferably, a first plating layer of copper is applied, followed by a second plating layer of a solderable metal, such as nickel or gold. Alternatively, a layer of nickel can be plated, followed by a separate layer of gold. It will be appreciated that these masking and plating steps can be performed either while the laminated substructures 302, 304, 306 are separated, or after they are laminated together, as described below. As shown, one of the terminal pads 319a on the upper substructure 302 surrounds the opening of the via 316 through that substructure; likewise, one of the terminal pads 319c on the lower substructure 304 surrounds the opening of the via 316′ through that substructure.
Referring now to
At a location that would be in registry (vertical alignment) with the protrusion 318 on the adjacent substructure so as to allow the three substructures 302, 304, 306 to be vertically stacked, first and second apertures 320, 322 are respectively formed in each of the first and second bottom foil sheets 312, 312′and in the corresponding polymer layers 308 using mechanical or etching techniques common in the industry. Thus, the first aperture 320 is a blind aperture that terminates at the bottom surface of the first top foil layer 310, while the second aperture 322 forms a passage extending all the way through the intermediate substructure 306. A third aperture 324 is formed in the lower substructure 304, near the end opposite the protrusion 318 of the lower substructure. The third aperture 324 passes through the plated terminal pad 319d, the second bottom foil layer 312′, and the adjacent polymeric layer 308.
The radius of each of the first and second apertures 320, 322 is greater than that of the protrusions 318, preferably by an amount that is approximately equal to the thickness of the polymeric layer 308, thereby allowing the protrusion 318 of the adjacent substructure to fit into the aperture of the adjoining substructure with a substantial annular space surrounding the protrusion. This annular space, as will be shown below, provides an isolation gap between the protrusion and the metal layer through which it passes. With each protrusion 318 seated in its respective aperture 320, 322, the three substructures 302, 304, 306 are vertically stacked, as shown in
During lamination, the solder layer 314 on top of the protrusion 318 extending from the lower substructure 304 is reflowed and bonds to the portion of the underside of the first bottom foil layer 312 on the upper substructure 302 that is exposed through the aperture 322 in the intermediate substructure 306, thereby forming a mechanical bond and an electrical connection with the first bottom foil layer 312. Similarly, during lamination, the solder layer 314 on top of the protrusion 318 extending from the intermediate substructure 306 is re-flowed and bonds to the portion of the underside of the first top foil layer 310 of the upper substructure 302 that is exposed through the aperture 320 in the upper substructure 302, thereby forming a mechanical bond and an electrical connection with the first top foil layer 310. Alternatively, a conductive epoxy may be used instead of the solder layer 314, in which case the pressure and heat of the lamination process cause the formation of the mechanical bond and the electrical connection.
As a result of the lamination process, the material of the polymer layers 308 flows into and substantially fills the annular spaces formed in the apertures 320 and 322 around the respective protrusions 318, thereby isolating protrusions 318 from the adjacent metal foil layers (i.e., first bottom foil layer 312 and the third bottom foil layer 312″). Also, as shown in
After the lamination of the three substructures, the third aperture 324 is used to form a connection between the second bottom foil layer 312′ and the third (interior) bottom foil layer 312″. The interior surfaces of the third aperture 324 are plated with a conductive metal to form an electrical contact element 326 that provides electrical connection between the terminal pad 319d, the third bottom foil layer 312″, and the adjacent plated via 316″. Thus, the plating of the interior of the third aperture 324 and the exposed bottom area of the third bottom foil layer 312″ provides a mechanical and electrical connection from the terminal pad 319d through the third aperture 324 to the third foil layer 312″. Each of the plated vias 316, 316′, 316″ provides a conductive path or cross-conductor 317 between the lower terminal pads 319c, 319d and the upper terminal pads 319a, 319b, respectively, and each of the cross-conductors 317 makes electrical contact with two selected metal layers, while being isolated from the remaining metal layers.
Thus, after singulation, (as described above), which may be centered on the vias 316, 316′, 316″, each device 300 includes first and second terminals, each of which includes a respective lower terminal pad 319c, 319d, a plated via cross-conductor 317, and a respective upper terminal pad 319a, 319b. Furthermore, each singulated device includes an upper electrode 310 formed from the first upper metal foil layer of the upper substructure 302, a lower electrode 312′ formed from the second lower metal foil layer 312′ of the lower substructure 304, and first and second interior electrodes 312, 312″, respectively formed from the first lower metal foil layer of the upper substructure 302 and the third lower metal foil layer of the intermediate substructure 306. The first terminal makes contact with the first interior electrode 312 and lower electrode 312′, while being isolated from the second interior electrode 312″ and the upper electrode 310. The second terminal makes contact with the second interior electrode 312″ and the upper electrode 310 while being isolated from the first interior electrode 312 and lower electrode 312′. It will be appreciated that the method used to manufacture device 300 shown in
Other types of devices constructed in accordance with the present invention are shown in
Alternatively, a first PPTC terminal may be formed at one end of the lower PPTC electrode 510 by not applying the bottom prepreg insulation layer 526 to that portion of the lower PPTC electrode 510, thereby eliminating the need for the second bottom terminal pad 522 and the first plated micro-via 524. A similarly-formed terminal at one end of the upper PPTC electrode 508 would eliminate the for the upper planar termination element 529 and the second plated micro-via 530.
A first plated through-hole via 606 (
The lower PPTC device electrode 609 is electrically connected to a first bottom PPTC terminal pad 611, on the bottom surface of the PPTC component 602, by means of a first plated micro-via 613 that extends through a bottom insulating prepreg layer 615 (applied to the bottom surface of the lower PPTC device electrode 609). The upper PPTC device electrode 618 is electrically connected to a first PPTC device top terminal pad 619, on the top surface of the PPTC component 602, by a plated micro-via 622 that extends through a top insulating prepreg layer 624 (applied to the top surface of the upper PPTC device electrode 618).
The PPTC device 602 and the second polymer device 604 are connected in series as follows: A first electrical connection is made between the first PPTC device top terminal pad 619 and a first terminal 620 of the second polymer device 604 through a re-flowed solder bonding layer 616 that bonds the PPTC device 602 to the second polymer device 604. Similarly, a second electrical connection is made between a second PPTC device top terminal pad 608, on the top surface of the PPTC component 602, and a second terminal 614 of the second polymer device 604. A third plated through-hole via 626 (
It will be appreciated that the embodiments of the invention described above with reference to
In the devices described above, the uppermost and lowermost layers of the polymer devices may be trimmed by any suitable means, such as by mechanical trimmers, lasers, chemical agents, etc., to improve the tolerances of the devices. This trimming might be performed while the devices are attached in matrix form, if the devices are electrically isolated. Alternatively, trimming can be performed after singulation.
It will be appreciated that the polymer structures discussed above may be made as PTC devices, fixed resistors, capacitors, ferromagnetic devices (e.g., inductors), negative temperature coefficient (NTC) devices, batteries, etc. For example, one or more resistive devices (fixed, PTC, or NTC) can be combined with one or more capacitive or inductive devices, in series, in parallel, or in series/parallel combinations.
It will also be appreciated that the metal foil layers described above may include fired cermet resistors or capacitors. Once fired, these components can be assembled into modules using the manufacturing methods described above.
Finally, it will be understood that the devices described above may be produced, using the methods of the invention, in a variety of packages, either leaded, leadless. Such packages may employ such termination designs as ball grid array (BGA), pad grid array (PGA), single in-line pin (SIP), or dual in-line pin (DIP).
This application claims the benefit, under 35 U.S.C. Section 119(e), of co-pending U.S. Provisional Application No. 60/454,754, filed Mar. 14, 2003, the disclosure of which is incorporated herein by reference.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US04/07764 | 3/15/2004 | WO | 9/13/2005 |
Number | Date | Country | |
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60454865 | Mar 2003 | US |