The present disclosure relates to semiconductor devices.
Even though the size of semiconductor devices continues to scale down, the search continues for devices and methods of fabrication that will lead to even smaller scale devices. One technology that has shown promise is sometimes referred to as “nanometer-scale” technology because of the approximate size of the structures. A variety of structures such as nanocolumns, nanowires, nanorods, and nanotubes have been used to form various devices.
As one example, nanotube transistors have been proposed. Some proposals call for a transistor using a single carbon nanotube. However, the processes for fabricating such devices may be tedious, low-yield, and not amenable to high volume manufacturing. Moreover, since the lateral dimensions of a single nanotube are small, the ability to conduct large amounts of current may be limited. This makes such devices unsuitable for some applications such as power amplifiers. Even for applications where large currents are not needed, such as logic integrated circuits, fabricating single nanotube processing may be difficult.
Some proposals call for transistor devices using groups of nanocolumns or nanotubes. In these cases, the current carrying capacity of the group is much greater than that of a single nanocolumn or nanotube. However, the fabrication processes may not be suitable for high volume manufacturing of integrated circuits.
The approaches described in this section are approaches that could be pursued, but not necessarily approaches that have been previously conceived or pursued. Therefore, unless otherwise indicated, it should not be assumed that any of the approaches described in this section qualify as prior art merely by virtue of their inclusion in this section.
The present disclosure is illustrated by way of example, and not by way of limitation, in the figures of the accompanying drawings and in which like reference numerals refer to similar elements and in which:
In the following description, for the purposes of explanation, numerous specific details are set forth in order to provide a thorough understanding of the present invention. It will be apparent, however, that embodiments may be practiced without these specific details. In other instances, well-known structures and devices are shown in block diagram form in order to avoid unnecessarily obscuring the disclosure.
Transistors and methods for forming transistors from groups of nanostructures are disclosed herein. The nanostructures may be nanocolumns, nanowires, nanorods, nanotubes, etc. In some embodiments, the nanostructures in a single transistor are grouped in an array. For example, an array of nanostructures may be grown vertically on a substrate. However, the nanostructures could also be formed from the top down by patterning a stack of planar layers and subsequent etching. Because the transistor may include an array of nanostructures, the transistor may be able to conduct a large current. Therefore, embodiments are suitable for high power applications.
The nanostructures may be formed from a variety of materials. In some embodiments, the nanostructures are formed from one or more semiconductors. In some embodiments, the nanostructures have lower, middle and upper segments that may be formed with different materials and/or doping to achieve desired effects. Electrodes may be formed as planar metal structures that surround sidewalls of the nanostructures.
Many different types of transistors may be formed. The transistors may be Field Effect Transistors (FETS) or bipolar junction transistors (BJTs). In one embodiment, the transistor is a heterojunction bipolar junction transistor (HBT). In one embodiment, the transistor is a high electron mobility transistor (HEMT).
Techniques for fabricating the transistor may use planar type processes such that cost-effective high volume manufacturing may be achieved. In some embodiments, the nanostructure array is oriented vertically with respect to the substrate. Therefore, packing density may be higher than for conventional devices. Moreover, by increasing the number of transistors per unit area, manufacturing cost may be reduced.
Referring to
As will be discussed more fully below, the segments 99 may be formed from different materials and/or doped differently to achieve different effects. For example, the lower segments 99a could serve as an emitter, the middle segments 99b as a base and the upper segments 99c as a collector. In this case, the lower electrode 102 could be an emitter electrode, the middle electrode 104 could be a base electrode, and the upper electrode 106 could be a collector electrode. Thus, the structure could form a single transistor having many nanostructures 96. Therefore, current carrying capacity may be large.
In one embodiment, the lateral width of the nanostructures 96 may range from about 5 nm-500 nm. However, nanostructures 96 may have a lesser or greater lateral width. The entire range of widths may be present in a single device. Thus, there may be considerable variance in width of individual nanostructures 96. Also note that the width of an individual nanostructure 96 may vary from top to bottom. For example, a nanostructure 96 could be narrower, or wider, at the top. Also note that nanostructures 96 are not necessarily columnar in shape. As depicted, there are spaces or gaps between the nanostructures 96. These spaces may be filled with an insulator; however, the spaces may also be left open such that there may be an air gap between nanostructures 96. The nanostructures 96 are not coalesced, in some embodiments. That is to say, that individual nanostructures 96 are not required to be joined together laterally at some level. Note that although each nanostructure 96 is depicted in
The electrodes 102, 104, 106 may surround the sidewalls of the nanostructures 96. The electrodes 102, 104, 106 have a substantially planar structure in some embodiments. The plane may be oriented horizontally with respect to the substrate 108. However, note that the thickness of the electrodes 102, 104, 106 is allowed to vary. In some embodiments, the electrodes 102, 104, 106 are formed from metal. Example metals include, but are not limited to, nickel and aluminum.
Referring to
Note that in
Examples of suitable materials for the substrate 108 include, but are not limited to, silicon (Si), germanium (Ge), silicon carbide (SiC), zinc oxide (ZnO), and sapphire. If the substrate 108 is either Si, or Ge, the substrate 108 may be (111)- or (100)-plane oriented, as examples. If the substrate 108 is SiC, ZnO, or sapphire the substrate 108 may be (0001) plane oriented, as one example. The substrate 108 is doped with a p-type dopant, in one embodiment. An example of a p-type dopant for Si substrates includes, but is not limited to, boron (B). The p-type doping level may be p, p+ or, p++. The substrate 108 is doped with an n-type dopant, in one embodiment. Examples of n-type dopants for Si substrates include, but are not limited to, arsenic (As) and phosphorous (P). The n-type doping level may be n, n+ or, n++. Note that the substrate 108 is not required for device operation. In some embodiments, the substrate 108 on which the nanostructures 96 were grown is removed (e.g., by etching), which allows for a more flexible device.
The lower electrode 102 is depicted as being in contact with the sidewalls of the nanostructures in
Many different types of transistors may be formed with technology disclosed herein. In some embodiments, the lower, middle and upper segments that may be formed with different materials and/or doping to achieve desired effects. The transistor may be a field effect transistor (FET) or bipolar junction transistor (BJT). In one embodiment, the transistor is a heterojunction bipolar junction transistor (HBT). In one embodiment, the transistor is a high electron mobility transistor (HEMT).
For example, a BJT may be formed using any of the devices of
In one embodiment, the collector segments 299a are formed from (Al)GaN. The collector segments 299a may be doped with an n-type donor such as Si. In the present embodiment, the emitter segments 299c may be formed from (Al)GaN. The emitter segments 299a may be doped with an n-type donor such as Si. In the present embodiment, the base segments 299b may be formed from (In)GaN. The base segments 299a may be doped with a p-type donor such as Mg. However, different dopants could be used. Moreover, the nanostructures 96 could be formed with other materials.
With the foregoing example materials, the transistor 200 is a heterojunction transistor. For example, the material for the base has a different band gap than the materials for the collector and emitter. However, collector segments 299a, base segments 299b and emitter segments 299c could each be formed from materials having the same band gap. Thus, a heterojunction is not required. As mentioned above, a pnp transistor could be formed instead.
As mentioned above, the electrodes 102, 104, 106 may form an Ohmic contact with the nanostructures of the BJT 200. Given the example materials, the first electrode 102 and third electrode 106 may be formed from a metal that makes good Ohmic contact with (Al)GaN. The second electrode 104 may be formed from a metal that makes good Ohmic contact with (In)GaN. In some embodiments, the electrodes 102, 104, 106 that contact the n-type semiconductor regions may be made of a suitable material to form an Ohmic contact with an n-type semiconductor. Electrodes 102, 104, 106 that contact p-type semiconductor regions may be made of a suitable material to form an Ohmic contact with a p-type semiconductor. For example, aluminum may form an Ohmic contact with nanostructures formed from n-doped nitride semiconductors. Nickel may form an Ohmic contact with nanostructures formed from p-doped nitride semiconductors. Note that the first electrode 102 may also be referred to as a first emitter/collector electrode and the third electrode 106 may also be referred to as a second emitter/collector electrode.
Note that because of the compliant nature of nanocolumn growth, the indium (In) mole fraction of the base can be made high. The activation energy of the acceptor may be decreased as the In composition is increased; therefore, there may a great improvement in the conductivity of Mg-doped InGaN material of the base. This improvement in base conductivity may greatly improve overall device performance.
As noted, an FET may be formed using any of the devices of
In one embodiment, the drain segments 399a are formed from GaN. The drain segments 399a may be doped with an n-type donor such as Si. In the present embodiment, the source segments 399c may be formed from GaN. The source segments 399a may be doped with an n-type donor such as Si. In the present embodiment, the channel segments 399b may be formed from GaN. The channel segments 399b may be intrinsic or unintentionally doped or doped (e.g., n-type). In the present embodiment, GaN is used for all segments; however, the segments are not required to all be formed from the same material. Also, a material other than GaN may be used. Note that the source and drain could be p-doped instead.
As mentioned above, the lower and upper electrodes 102, 106 may form an Ohmic contact with the nanostructures of the FET 300. However, the middle electrode 104 may form a Schottky contact with the nanostructures. Note that the first electrode 102 may also be referred to as a first source/drain electrode and the third electrode 106 may also be referred to as a second source/drain electrode.
In step 402, nanostructures 96 having segments 99 are formed. In some embodiments first, second and third segments 99a, 99b, 99c are formed in the nanostructures 96. As noted these may be drain, channel, and source segments (399a, 399b, 399c) or collector, base and emitter segments (299a, 299b, 299c). However, a different number of segments could be formed. In one embodiment, an array of nanostructures 96 are grown vertically on a substrate 108. The nanostructures 96 may be grown either by self-assembly or by patterned growth using epitaxial growth techniques such as metalorganic chemical vapor deposition, molecular beam epitaxy and hydride vapor phase epitaxy. In patterned growth, a portion of the substrate surface which is not covered by mask material such as SiO2, SiNx, or metal is exposed to serve as nucleation sites for the nanostructures 96. The nanostructures 96 may also be grown using nanoparticles such as gold (Au) and nickel (Ni), which may act as nucleation sites for the nanostructures 96.
In some embodiments, the nanostructures 96 are formed by patterning and etching. For example, one or more planar layers of material for the nanostructures 96 is deposited. Each layer may be doped appropriately in situ or by implantation. After depositing and doping all layers, photolithography may be used to pattern and etch in order to form the nanostructures 96 having segments.
In some embodiments, step 402 includes forming the different segments having different materials from each other. However, each segment may be formed from the same material. In some embodiments, forming the different segments includes doping the nanostructures 96 with one or more impurities. That is, different doping may be used in the different segments. Intrinsic segments may also be formed. Note that the substrate 108 may be doped prior to forming the nanostructures 96.
In step 404, a first (or lower) electrode 102 that is in electrical contact with the first segments 99a is formed. In one embodiment, the lower electrode 102 surrounds the sidewalls of the nanostructures 96. In such embodiments, the lower electrode 102 may be formed by depositing a material over the substrate 108 (after the nanostructures 96 have been formed) and etching back the material. The material may be metal. In patterned growth employing conductive material (such as metal) as a mask material, the mask layer may serve as the lower electrode 102. However, it is not required that the lower electrode 102 surrounds the sidewalls of the nanostructures 96.
In step 406, a first insulator is formed around the sidewalls of the nanostructures 96 above the lower electrode 102. In one embodiment, spin-on-glass (SOG) is applied. In one embodiment, silicon dioxide is deposited. In another embodiment, photoresist is added. Note that more than one type of material could be used. For example, layers of different materials could be deposited or a single region could include multiple materials. After depositing, the insulator may be etched back to a suitable level.
In step 408, a second (or middle) electrode 104 that surrounds the sidewalls of the second segments 99b is formed. The middle electrode 104 may be formed by depositing a material over the insulator 125a and etching back the material. The material may be metal. In some embodiments, the middle electrode 104 forms an Ohmic contact with the second segments 99b. In some embodiments, the middle electrode 104 forms a Schottky contact with the second segments 99b.
In step 410, a second insulator is formed around the sidewalls of the nanostructures 96 above the middle electrode 104. In one embodiment, spin-on-glass (SOG) is applied. In one embodiment, silicon dioxide is deposited. In another embodiment, photoresist is added. Note that more than one type of material could be used. For example, layers of different materials could be deposited or a single region could include multiple materials. After depositing, the insulator may be etched back to a suitable level.
In step 412, a third (or upper) electrode 106 that is in electrical contact with the third segments 99c is formed. The upper electrode 106 may surround the sidewalls of the third segments 99c. The upper electrode 106 may be formed by depositing a material over the insulator 125b and etching back the material. The material may be metal.
In step 414, electrical contacts 132 are formed to the first, second, and third electrodes 102, 104, 106. In one embodiment, patterning and etching is performed to remove a portion of the third electrode 106 and the second insulation 125b to expose a portion of the second electrode 104. Likewise, patterning and etching may be performed to remove a portion of the second electrode 104 and the first insulation 125a to expose a portion of the first electrode 102. A stair case type structure may be formed, as depicted in
In one embodiment, the transistor is a high electron mobility transistor (HEMT). A HEMT may have a high energy bandgap region adjacent to the channel (which may have a lower bandgap than the high energy bandgap region). Free electrons may be able to transfer from the high bandgap material into the lower bandgap channel. In this way, high carrier concentration and high electron mobility can be achieved simultaneously. This leads to overall higher device performance.
Next, material for the high bandgap region 602 is grown around the nanostructures 96 at least for some portion of the channel segments 399b, in step 702. As one example, AlGaN is grown. In one embodiment, the mole fraction of Al is greater than 0.2. However, the mole fraction may be less than 0.2.
In step 704, metal is deposited for the second electrode 104.
One embodiment includes a transistor comprising an array of nanostructures, wherein nanostructures in the array of nanostructures include first segments, second segments, and third segments. The second segments are between the first and third segments. The transistor further includes a first electrode in electrical contact with the first segments of the nanostructures; a second electrode surrounding ones of the second segments of the nanostructures; and a third electrode in electrical contact with the third segments of the nanostructures.
One embodiment includes a method of forming a transistor comprising: forming an array of nanostructures, wherein nanostructures in the array of nanostructures include first segments, second segments, and third segments, the second segments are between the first and the third segments; forming a first electrode in electrical contact with the first segments of the nanostructures; forming a second electrode surrounding ones of the second segments of the nanostructures; and forming a third electrode in electrical contact with the third segments of the nanostructures.
One embodiment includes a field effect transistor comprising an array of nanostructures, wherein the nanostructures include lower segments, middle segments, and upper segments. The upper segments and the lower segments may be doped with a material having a first type of conductivity. The transistor may also include a first source/drain electrode in electrical contact with the lower segments of the array of nanostructures; a gate electrode surrounding ones of the middle segments of the plurality of nanostructures; and a second source/drain electrode in electrical contact with the upper segments.
One embodiment includes a bipolar junction transistor comprising an array of nanostructures, wherein the nanostructures having lower segments, middle segments, and upper segments. The upper segments and the lower segments may be doped with a material having a first type of conductivity; the middle segments may be doped with a material having a second type of conductivity. The transistor may also include a first emitter/collector electrode in electrical contact with the lower segments of the array of nanostructures; a base electrode in electrical contact with the middle segments of the plurality of nanostructures; and a second emitter/collector electrode in electrical contact with the upper segments.
In the foregoing specification, several examples have been provided in which example shapes of nanostructures having been depicted for illustrative purposes. However, other shapes are possible. Thus, embodiments are not to be limited to columnar shapes, for example.
In the foregoing specification, embodiments of the invention have been described with reference to numerous specific details that may vary from implementation to implementation. Thus, the sole and exclusive indicator of what is the invention, and is intended by the applicants to be the invention, is the set of claims that issue from this application, in the specific form in which such claims issue, including any subsequent correction. Any definitions expressly set forth herein for terms contained in such claims shall govern the meaning of such terms as used in the claims. Hence, no limitation, element, property, feature, advantage or attribute that is not expressly recited in a claim should limit the scope of such claim in any way. The specification and drawings are, accordingly, to be regarded in an illustrative rather than a restrictive sense.
The following applications are cross-referenced and incorporated by reference herein in their entirety: U.S. patent application Ser. No. 12/796,569, entitled “Nanostructure Optoelectronic Device having Sidewall Electrical Contact,” by Kim et al., filed on Jun. 8, 2010; U.S. patent application Ser. No. 12/796,589, entitled “Multi-Junction Solar Cell Having Sidewall Bi-Layer Electrical Interconnect,” by Kim et al., filed on Jun. 8, 2010; and U.S. patent application Ser. No. 12/796,600, entitled “Nanostructure Optoelectronic Device with Independently Controllable Junctions,” by Kim et al., filed on Jun. 8, 2010.