1. Field of the Invention
The present invention relates to a process for manufacturing a memory device having selector transistors for storage elements and to a memory device fabricated thereby.
2. Description of the Related Art
As is known, memory devices comprise a plurality of memory cells or storage elements arranged in rows and columns, so as to form a memory array. Row and column decoders are used to selectively connect the storage elements to read/write circuits of the memory device for usual operation through. Moreover, in some cases it is necessary to provide further selection elements, which selectively activate and deactivate the storage elements for preventing disturbances caused by other adjacent storage elements.
To this aim, using bipolar transistors as selectors coupled to the storage elements is known as well. In particular, a bipolar selector transistor has a base terminal connected to a control line (e.g., a word line), an emitter terminal coupled to the storage element and a collector terminal normally connected to ground. It is clear that the way the emitter of the bipolar selector transistor and the storage element are coupled depends on the structure of the storage element itself.
For example, phase change memories are presently memory devices of increasing interest, which use bipolar transistors as selectors for storage elements.
Phase change memory cells utilize a class of materials that have the unique property of being reversibly switchable from one phase to another with measurable distinct electrical properties associated with each phase. For example, these materials may change between an amorphous disordered phase and a crystalline, or polycrystalline, ordered phase. A material property that may change and provide a signature for each phase is the material resistivity, which is considerably different in the two states.
Specific materials that may be suitably used in phase change cells are alloys of elements of the VI group of the periodic table as Te or Se, also called chalcogenides or chalcogenic materials. Therefore, hereinafter, the term “chalcogenic materials” is used to indicate all materials switchable between at least two different phases where they have different electrical properties (resistances) and include thus the elements of the VI group of the periodic table and their alloys.
In phase change memories, a thin film of chalcogenic material is employed as a programmable resistor, switching between a high and a low resistance condition.
Phase change is normally obtained by locally increasing the temperature. Under 150° C., both phases are stable. Over 200° C., nucleation of crystallites is fast and if the material is kept at the crystallization temperature for a sufficient time, it changes phase and becomes crystalline. In order to change the phase back to the amorphous state, its temperature is brought over the melting point (about 600° C.) and the calcogenide is rapidly cooled.
From an electrical point of view, it is possible to reach both critical temperatures (crystallization and melting temperatures) causing an electric current to flow through a resistive electrode in contact or close proximity with the chalcogenic material and heating the material by Joule effect. This goal is achieved by causing such a current flow to pass through a suitable neighboring series of resistors that operates as a heater.
The state of the chalcogenic material may be read by applying a sufficiently small voltage (or current) so as not to cause an appreciable heating and measuring the current passing through it (or voltage across it). Since the current is proportional to the conductance of the chalcogenic material (or voltage is proportional to the resistance), it is possible to discriminate between the two states.
There is always the need in the art for efficient and effective process for manufacturing memory devices and memory devices that provide, among others, high quality contacts between the selector and the storage element.
According to the present invention, one embodiment provides a process for manufacturing a memory device having selector transistors with raised contacts by forming a selector transistor having an embedded conductive region in a semiconductor body, forming one or more raised conductive regions on and electrically connected to the embedded conductive region, and forming a storage element that is stacked on and electrically connected to the embedded conductive region of the selector transistor.
Another embodiment of the present invention provides a memory device comprising a selector transistor and a storage element stacked on and electrically connected to the selector transistor, the selector transistor having a conductive region embedded in a semiconductor body, a plurality of raised conductive regions having sides and located on and electrically connected to the embedded conductive region, protective spacers positioned in contact with the sides of the raised conductive regions and covering areas of the embedded conductive region not in contact with the raised conductive layer, and a superficial layer of high conductivity on top of the raised conductive regions.
For the understanding of the present invention, preferred embodiments thereof are now described, purely as non-limiting example, with reference to the enclosed drawings, wherein:
As already mentioned, bipolar selector transistors are coupled to the chalcogenic storage elements. For the sake of clarity, reference is made to
According to known processes for fabricating phase change memories, the selector 4 is initially formed inside the epitaxial layer 5. Then, the lower dielectric layer 11 is deposited on the epitaxial layer 5 and the plugs 12, 13 are fabricated. More precisely, the lower dielectric layer 11 is anisotropically etched so as to form through openings, which are internally coated with a first conductive material and subsequently filled with a second conductive material.
The upper dielectric layer 10 is then deposited on the lower dielectric layer 11 and the heater 3 is made therein, by etching the upper dielectric layer 10, so as to open a cavity over the first plug 12, by coating the cavity with a material having a predetermined resistivity, thus contacting the first plug 12, and by filling the cavity again with dielectric material.
Thereafter, a delimiting layer 16 having an aperture is built on the upper dielectric layer 10; a chalcogenic layer is deposited on the delimiting layer 16 and fills the aperture, thereby forming the chalcogenic strip 2 and the storage element 8.
Finally, a metal line stack 18, second level plugs 19 and connection lines 20 are made, according to a required layout.
However, known processes have some limitations. First of all, a high number of fabrication steps are needed. For example, fabrication of the heater 3 preliminarily requires depositing the lower dielectric layer 11, for thermally insulating the selector 4 from the heater 3, forming the first plug 12 and the second plug 13 (i.e. etching the lower dielectric layer 11, internally coating and filling the openings), depositing and etching the upper dielectric layer 10; only at this stage of the process, resistive material can be deposited to form the heater 3.
Moreover, known processes can not provide high quality contacts between the terminals of the selector 4 and the storage element 8 or the connection lines. In fact, plugs 12, 13 land directly on doped epitaxial silicon of emitter region 4a and base contact region 4c, whereas further processing for making the surface of silicon contact regions highly conductive would be desirable.
It is clear that the above described drawbacks affect every type of memory cell using bipolar selector transistors coupled to the storage elements and not only phase change memories.
The present invention provides a process for manufacturing memory devices and a memory device that overcome the above described drawbacks. With reference to
A low-voltage gate oxide layer, hereinafter designed as LV oxide 30, is thermally grown on a whole surface 20a of the wafer 20 and is defined by a masked etch, so as to open emitter windows 31 and a base window 32, which partially expose corresponding contact areas of the base region 26. More precisely, the emitter windows 31 are formed at the ends of the base region 26 and are adjacent to the trench isolation structures 24, whereas the base window 32 exposes a central portion of the base region 26.
Subsequently, a polysilicon layer 33 of preferably 100-300 nm is deposited on the wafer 20 and entirely covers the LV oxide 30, as shown in
Thereafter (
At the same time, on a circuitry portion of the wafer 20, which is schematically shown on the left of
A protecting layer 43, e.g., of silicon dioxide, illustrated with a dotted line in
Subsequently, a P+ ion implantation and a N+ ion implantation are carried out (
After the ion implantations, the wafer 20 is heated for diffusing and activating the implanted ions, as illustrated in
Then, a self-aligned silicidation step is carried out (
With reference to
Subsequently, as shown in
With reference to
Thereafter, storage elements 65 are made over the heaters 60 (see also
Finally, an insulating layer 71 is deposited on the wafer 20; storage contacts 72 and a second level plug 73 are formed through insulating layer 71, so as to reach the storage elements 65 and the first level plug 61, respectively.
The advantages of the present invention are clear from the above. In particular, the process is quite simple with respect to the known processes. For example, in fact, silicidation step is self-aligned, since it is carried out exploiting the superficial conformation of the wafer and anti-silicidation mask is advantageously eliminated. Also, the heaters are made inside the dielectric layer which delimits the raised regions and therefore their fabrication does not require further deposition of dielectric layers.
Moreover, the present memory and manufacturing process allow a very efficient integration, completely compatible with CMOS technology and also with processes for the fabrication of chalcogenic storage elements with sublithographic dimension.
Also, selectors having raised emitter and/or base regions are provided, with high quality emitter and base contacts. In fact, raised regions can be easily silicided and the components that are coupled to the emitter and base contacts (i.e., heaters and first level plugs, respectively) land directly on silicide interfaces, which are much more conductive than polysilicon. Moreover, intermediate contacts are avoided.
A second embodiment of the present invention will be described hereinafter with reference to
In the early stages of the process, the selector 25 is formed inside a wafer 20′, which comprises the substrate 21, the epitaxial layer 22 and the trench isolation structures 24, as formerly described; moreover source regions 40a, 41a and drain regions 40b, 41b of transistors 40, 41 are formed in the substrate 22.
A LV oxide layer 80 and a polysilicon layer 81 are grown on the wafer 20′ and selectively etched for defining the gate oxide regions 38 and gate regions 39 of transistors 40, 41. The polysilicon layer 81 is removed from the base region 26.
A nitride layer 82 and a dielectric layer 83 are then deposited, planarized by CMP and etched, so as to open emitter apertures 85 and a base aperture 86 over the base region 26, and gate apertures 87 over the gate regions 39 of the transistors 40, 41 (
As illustrated in
After removing the hard mask 89 (
The process is then continued as already described. In particular, after a self-aligned silicidation step, the heaters 60, the storage elements 65 (see
Finally, it is clear that numerous variations and modifications may be made to process and to the memory device described and illustrated herein, all falling within the scope of the invention as defined in the attached claims.
First, the process can be exploited for manufacturing any kind of memories that require bipolar selector transistors coupled to the storage elements, and not only phase change memories.
The selector 25 can comprise either a single raised emitter or even more than two raised emitters. Moreover, the selector 25 could have only raised emitter regions, whereas the base contact is of a standard type. In this case, the LV oxide 30 is removed only to open emitter windows 31 and is left elsewhere over the base region 26. After building the spacers 45, a portion of the base region 26 is exposed, so that it first receives N+ type dopant ions, and then is coated by a silicide region during silicidation. Also in this case, silicidation is self-aligned and anti-silicidation mask is not required. A deeper first level plug is formed later, since it has to go through all the thickness of the thick dielectric layer 55; anyway the quality of the base contact is not impaired.
When standard base contacts are made, the LV oxide 30 can be completely etched over the base region 26, before depositing the polysilicon layer 33 directly on the base region 26 itself. The polysilicon layer 33 is then etched as described, for defining the raised emitter regions 35 over the base region 26 and the gate regions 39 in circuitry area; the etch of the polysilicon layer 33 is stopped as soon as the residual LV oxide 30 in the circuitry area is reached and a slight over-etch of the base region 26 is acceptable.
The first and second level plugs 61 and 73 can be replaced by a single level plug, thus simplifying the process.
At last, it is clear that the selector 25 can be also a bipolar NPN transistor.
All of the above U.S. patents, U.S. patent application publications, U.S. patent applications, foreign patents, foreign patent applications and non-patent publications referred to in this specification and/or listed in the Application Data Sheet, are incorporated herein by reference, in their entirety.
From the foregoing it will be appreciated that, although specific embodiments of the invention have been described herein for purposes of illustration, various modifications may be made without deviating from the spirit and scope of the invention. Accordingly, the invention is not limited except as by the appended claims.
Number | Date | Country | Kind |
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03425292.4 | May 2003 | EP | regional |