The present disclosure relates generally to a semiconductor device and a method of fabricating the same, and more particularly to a semiconductor device including a dielectric layer, and a method of fabricating the same.
An integrated circuit (IC) is constructed by various active components and interconnection structures formed on a substrate or in different films. Generally speaking, the fabrication of the interconnection structures is firstly carried out by etching a dielectric layer to form a through hole or a circuit pattern in the dielectric layer, and filling in the through hole or the circuit pattern with a conductive material such as copper following by planarizing the conductive material. In the back-end processes of the semiconductor devices, the frequent use of plasma easily leads to accumulation of redundant charges on the conductive material filled in the through hole or the circuit pattern, and the excessive charges often results in unnecessary currents which may enters the circuit from the conductive material, penetrates the gate oxide and leads to a threshold voltage shift. The aforementioned issues will damage to the components in the front-end process, referring to a plasma induced damage (PID) caused by Antenna effect.
In the advanced semiconductor industry, as the continuously shrinking dimension and the continuously increasing integration, the operation performance of semiconductor devices is deeply affected by the Antenna effect. Accordingly, the layout of the circuit is requested to meet the appropriate Antenna ratio (AR), that is, the ratio between the exposed area of the metal wire and the area of the gate dielectric layer. The semiconductor device is less affected by the Antenna effect if the AR is smaller, and the yield and reliability of the semiconductor device may be probably improved thereby. However, the existing AR limitation leads to the increasing difficulty and complexity of the circuit design and manufacturing process, there is still a certain chance that the current will concentrate on the transistor with smaller resistance when using the improved design such as transistor parallel connection, which still cannot effectively solve the problems caused by Antenna effect. Therefore, the improvement of the existing technology is still a crucial subject to people in the related arts.
An object of the present disclosure is to provide a semiconductor device and a method of fabricating the same, where a carbon-rich dielectric layer is additionally disposed within a dielectric layer, to dramatically improve the Antenna effect under an increasing Antenna ratio (AR). Through these manners, the semiconductor device of the present disclosure is allowable to achieve a better reliability and yield, thereby gaining an optimized operating performance.
To achieve the aforementioned objects, the present disclosure provides a semiconductor device including a first dielectric layer and a first conductive structure. The first dielectric includes a stacked structure having a low-k dielectric layer, an etching stop layer, and a carbon-rich dielectric layer between the low-k dielectric layer and the etching stop layer, wherein a carbon concentration within the carbon-rich dielectric layer is above 15%. The first conductive structure is disposed in the first dielectric layer.
To achieve the aforementioned objects, the present disclosure provides a method of fabricating a semiconductor device including the following steps. Firstly, a first dielectric layer is formed, and the first dielectric layer includes a stacked structure having a low-k dielectric layer, an etching stop layer, and a carbon-rich dielectric layer between the low-k dielectric layer and the etching stop layer, wherein a carbon concentration within the carbon-rich dielectric layer is above 15%. Next, a first conductive structure is formed in the first dielectric layer.
These and other objectives of the present invention will no doubt become obvious to those of ordinary skill in the art after reading the following detailed description of the preferred embodiment that is illustrated in the various figures and drawings.
To provide a better understanding of the presented disclosure, preferred embodiments will be described in detail. The preferred embodiments of the present disclosure are illustrated in the accompanying drawings with numbered elements. In addition, the technical features in different embodiments described in the following may be replaced, recombined, or mixed with one another to constitute another embodiment without departing from the spirit of the present disclosure.
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Precisely speaking, the carbon concentration of the carbon-rich dielectric layer 124 is in the range from 15% to 90%, and preferable being 15% to 50%, but is not limited thereto. While forming the carbon-rich dielectric layer 124, a relative higher carbon concentration is positively correlated to a relative greater precursor generated accordingly at the same time, and then, which enables to have a stronger ability to neutralize unstable charges and to achieve a better function in stabilizing charges. The carbon-rich dielectric layer 124 includes a greater carbon concentration than that of the low-k dielectric layer 126, for example being about 3% to 10% greater than that of the low-k dielectric layer 126, and preferably being about 5% greater than that of the low-k dielectric layer 126, but is not limited thereto. In one embodiment, the low-k dielectric layer 126 for example includes a dielectric material having a dielectric constant lower than 3, and preferably lower than 2.5 to 2.9, like fluorinated silica glass (FSG), silicon carbide oxide (SiCOH), porous carbon oxide or spin-coated silicon glass, but is not limited thereto. In another embodiment, the carbon-rich dielectric layer 124 for example includes a dielectric material having a dielectric constant lower than that of the low-k dielectric layer 126, preferably includes a dielectric material having a dielectric constant lower than 2.5, and more preferably lower than 2 to 2.4, like a carbon-rich organic component such as terpinene, but is not limited to. The etching stop layer 122 for example includes a dielectric material having a dielectric constant greater than that of the low-k dielectric layer 126, like nitrogen doped carbide, but not limited thereto.
In the present embodiment, the etching stop layer 122, the carbon-rich dielectric layer 124, and the low-k dielectric layer 126 are for example stacked sequentially from bottom to top on the substrate 100, as shown in
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According to the semiconductor device 10 of the present embodiment, as the carbon-rich dielectric layer 124 is disposed within the inter-metal dielectric layer (namely the first dielectric layer 120), with the precursors in the carbon-rich dielectric layer 124 neutralizing the free radicals and the charged substances generated in the back-end process or in the etching process, the unstable charges will not be accumulated on the metal interconnection such as the first conductive structure 130, thereby effectively reducing the possibility of structural damages caused by plasma used in the back-end process. In this way, the semiconductor device 10 of the present embodiment enables to improve the Antenna effect, and the Antenna ratio (AR) of the semiconductor device 10 is no longer requested to meet the existing AR limitation like AR2000, wherein the AR referring to a ratio between an exposing area of the metal wires to a surface area of the gate dielectric layer 142. The smaller AR results in fewer influences by the Antenna effect. For example, in the semiconductor device 10 of the present embodiment, a ratio (R2+R3/R1) between the sum of a surface area R2 of the plug 112 and a surface area R3 of the first concoctive structure 130 to a surface area R1 of the gate electrode 144 (or the gate dielectric layer 142) reaches to more than AR5000, and less than AR100000, preferably between AR5000 and AR100000, but not limited thereto. In addition, a ratio (R2/R1) between the surface area R2 of the first conductive structure 130 to the surface area R1 of the gate electrode 144 (or the gate dielectric layer 142) may also reach to more than AR5000, and less than AR100000, preferably between AR5000 and AR100000. Accordingly, the semiconductor device 10 of the present embodiment is allowable to gain improved reliability and yield, to achieve better functions and performances.
In order to make people skilled in the art of the present disclosure easily understand the semiconductor device 10 of the present disclosure, the fabricating method of the semiconductor device 10 in the present disclosure will be further described below.
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People well known in the arts should easily realize the semiconductor device and the fabricating method thereof in the present disclosure are not limited to the aforementioned embodiment, and may further include other examples. The following description will detail the different embodiments of the semiconductor device and the fabricating method thereof in the present disclosure. To simplify the description, the following description will detail the dissimilarities among the different embodiments and the identical features will not be redundantly described. In order to compare the differences between the embodiments easily, the identical components in each of the following embodiments are marked with identical symbols.
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Precisely speaking, each of the second conductive structures 330 for example includes any components being made of a conductive material such as a conductive line, a plug, a metal line or a RDL, but is not limited thereto. Each of the second dielectric layers 320 respectively includes an etching stop layer 322, a carbon-rich dielectric layer 324, and a low-k dielectric layer 326 stacked sequentially, wherein the carbon-rich dielectric layer 324 has the carbon concentration above 15%, for example in the range of about 15%-90%, and preferably about 15%-50%, but not limited thereto. It is noted that, the carbon-rich dielectric layer 324 includes a greater carbon concentration than that of t the low-k dielectric layer 326, for example being about 3% to 10% greater, and preferably being about 5% greater, but is not limited thereto. In addition, each of the second dielectric layer 320 may also include an adhesive layer 328 optionally disposed between the etching stop layer 322 and the carbon-rich dielectric layer 324, to strengthen the combination of the etching stop layer 322 and the carbon-rich dielectric layer 324, thereby avoiding peeling films or structural collapse. In one embodiment, the adhesive layer 328 for example includes an initiation layer 328a and a transition layer 328b stacked sequentially from bottom to top, with the initiation layer 328a and the transition layer 328b respectively including a dielectric material containing carbon, oxygen, hydrogen or silicon, but not limited thereto.
People skilled in the arts should easily realize the practical number of the second dielectric layers 320 and/or the precise pattern or the surface area R31, R32, R33, R34, R35 of the second conductive structures 330 in the present embodiment are only for exemplified, and which may be further adjusted based on practical product requirements and will not be limited by what is shown in
With these arrangements, the dielectric layer 110 is also configured as an ILD layer of the semiconductor device 30 when the plug 112 serving as a contact plug or an zero-layer metal interconnection of the semiconductor device 30, and the first dielectric layer 120 and each second dielectric layer 320 are respectively configured as an IMD layer of the semiconductor device 30 when the first conductive structure 130 serving as a M1 metal interconnection and the second conductive structures 330 sequentially serving as a second-layer metal interconnection (M2), a third-layer metal interconnection (M3) to a nth-layer metal interconnection (with n being a positive integer greater than 3). Accordingly, through arranging the carbon-rich dielectric layers 124, 324 inside each IMD layer of the semiconductor device 30, the semiconductor device 30 of the present embodiment enables not only to neutralize the free radicals and charged substances generated by the deposition process or the etching process at the back-end process, but also to prevent unstable charges from accumulating on each of the metal interconnections (such as the first conductive structure 130 and the second conductive structures 330), thereby increasing the tolerance of the semiconductor device 30 against to the Antenna effect, and further reducing the possibility to get structural damage caused by plasma in the back-end process in a more efficiency manner.
In this way, the semiconductor device 30 of the present embodiment is also allowable to gain a dramatically improved reliability and yield, and which is no longer required to meet the existing AR limitation like AR2000, wherein, a ratio ((R2+R31+R32+R33+R34+R35)/R1) between the sum (R2+R31+R32+R33+R34+R35) of the surface area R2 of the plug 112 and the surface areas (R31+R32+R33+R34+R35) of all of the metal interconnections to the surface area R1 of the gate electrode 144 (or the gate dielectric layer 142) reaches to more than AR5000, and less than AR100000, preferably between AR5000 and AR100000, but not limited thereto.
Please refer to
Precisely speaking, each of the second conductive structures 430 for example includes any components being made of a conductive material like a conductive line, a plug, a metal line or a RDL, but is not limited thereto. Each of the second dielectric layers 420, 420a respectively includes an etching stop layer 422, an adhesive layer 428 and a low-k dielectric layer 426 stacked sequentially. In one embodiment, the adhesive layer 428 for example includes an initiation layer 328a and a transition layer 328b stacked sequentially from bottom to top, or the adhesive layer 428 may also be omitted, but not limited thereto. It is noted that, a carbon-rich dielectric layer 424 is additionally disposed within at least one of the second dielectric layers 420, and preferably disposed in the second dielectric layer 420 over the second conductive structure 430 with a relative greater surface area R42, wherein the surface area R42 of the second conductive structure 430 is for example greater than the surface area R2 of the first conductive structure 130, but not limited thereto. In other words, there is no carbon-rich dielectric layer disposed within other second dielectric layers 420a. Otherwise, in another embodiment, the carbon-rich dielectric layer 124 disposed within the first dielectric layer 120 may also be omitted, to only remain the carbon-rich dielectric layer 424 in the dielectric layer (for example the second dielectric layer 420) on the metal interconnection (for example the second conductive structure 430) with a relative greatest surface area.
The carbon-rich dielectric layer 424 is precisely disposed between the etching stop layer 422 and the low-k dielectric layer 426, over the adhesive layer 428. The carbon-rich dielectric layer 424 includes a carbon concentration in above 15%, for example in the range of about 15%-90%, and preferably about 15%-50%, and the carbon-rich dielectric layer 424 includes a greater carbon concentration than that of the low-k dielectric layer 426, for example being about 3% to 10% greater, and preferably being about 5% greater, but is not limited thereto. In one embodiment, while the surface area R42 of the second conductive structure 430 is larger than the surface area R2 of the first conductive structure 130, the carbon concentration of the carbon-rich dielectric layer 424 within the second dielectric layer 420 surrounding the aforementioned second conductive structure 430 is preferably higher than the carbon concentration of the carbon-rich dielectric layer 124 within the first dielectric layer 120, but not limited thereto.
People well skilled in the arts should easily realize the practical number of the second dielectric layers 420, 420a and/or the precise pattern or the surface area R41, R42, R43, R44, R45 of the second conductive structure 430 in the present embodiment are only for exemplified, and which may be further adjusted based on practical product requirements and will not be limited by what is shown in
With these arrangements, the dielectric layer 110 is also configured as an ILD layer of the semiconductor device 40 when the plug 112 serving as a contact plug or an zero-layer metal interconnection of the semiconductor device 40, and the first dielectric layer 120 and each second dielectric layer 420, 420a are respectively configured as an IMD layer of the semiconductor device 40 when the first conductive structure 130 serving as a M1 metal interconnection and each second conductive structure 430 sequentially serving as a M2 metal interconnection, a M3 metal interconnection to a Mth-layer metal interconnection (with M being a positive integer greater than 4). Accordingly, through arranging the carbon-rich dielectric layers 124, 424 inside at least one IMD layer (such as the first dielectric layer 120 and/or the second dielectric layer 420) of the semiconductor device 40, preferably in an IMD dielectric layer on the metal interconnection with a relative greater surface area, for neutralizing the free radicals and charged substances generated by the deposition process or the etching process at the back-end process, and also, for preventing the unstable charges from accumulating on each of the metal interconnections (such as the first conductive structure 130 and/or the second conductive structures 430). Then, the tolerance of the semiconductor device 40 against to the Antenna effect will be dramatically increased, and also the possibility to get structural damage caused by plasma in the back-end process will be further reduced in a more efficiency manner.
In this way, the semiconductor device 40 of the present embodiment is also allowable to gain a dramatically improved reliability and yield, and which is no longer to meet the existing AR limitation like AR2000, wherein, a ratio ((R2+R41+R42+R43+R44+R45)/R1) between the sum (R2+R41+R42+R43+R44+R45) of the surface area R2 of the plug 112 and surface areas (R41+R42+R43+R44+R45) of all of the metal interconnections to the surface area R1 of the gate electrode 144 (or the gate dielectric layer 142) reaches to more than AR5000, and less than AR100000, preferably between AR5000 and AR100000, but not limited thereto.
Overall speaking, according to the semiconductor device and the fabricating method thereof, a carbon-rich dielectric layer having a carbon concentration above 15% and a dielectric constant lower than 2.5 is arranged in at least one IMD layer, and preferably disposed inside the IMD layer on the metal interconnection having the relative greater surface area, or disposed inside each IMD layer, to neutralize the free radicals and charged substances generated by the back-end process (for example the deposition process or the etching process), and to prevent unstable charges from accumulating on the metal interconnection, thereby dramatically reducing the possibility to get structural damage caused by plasma in the back-end process. Thus, the semiconductor device of the present disclosure enables to dramatically improve the Antenna effect under an increasing AR, and also, to gain an optimized reliability and yield.
Those skilled in the art will readily observe that numerous modifications and alterations of the device and method may be made while retaining the teachings of the invention. Accordingly, the above disclosure should be construed as limited only by the metes and bounds of the appended claims.
Number | Date | Country | Kind |
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112130613 | Aug 2023 | TW | national |