In metal-oxide-semiconductor field-effect transistors (hereinafter referred to as MOSFETs) included in a semiconductor device, the threshold voltages are controlled by introducing impurities into the channel regions below the gate electrodes. Impurities of a concentration corresponding to each threshold voltage are introduced into the channel regions.
When many impurities are introduced into a channel region to control the threshold voltage of a MOSFET, sub-threshold leakage current, gate-induced drain leakage (hereinafter referred to as GIDL), or junction leakage current may increase in the MOSFET in some cases.
Various embodiments of the present disclosure will be explained below in detail with reference to the accompanying drawings. The following detailed description refers to the accompanying drawings that show, by way of illustration, specific aspects and various embodiments of the present disclosure. The detailed description provides sufficient detail to enable those skilled in the art to practice these embodiments of the present disclosure. Other embodiments may be utilized, and structure, logical and electrical changes may be made without departing from the scope of the present disclosure. The various embodiments disclosed herein are not necessary mutually exclusive, as some disclosed embodiments can be combined with one or more other disclosed embodiments to form new embodiments.
Hereinafter, a semiconductor device 1 and a method of forming the same according to a first embodiment will be described with reference to
Also, each of the transistors Tr2 to Tr4 is set to have either a first threshold voltage Vt1 or a second threshold voltage Vt2 different from the first threshold voltage Vt1. In the following description, the first threshold voltage Vt1 is assumed to be a higher voltage value than the second threshold voltage Vt2. The transistors Tr2 and Tr4 have the first threshold voltage Vt1, while the transistor Tr3 has the second threshold voltage Vt2.
The gate electrode 7 is provided with gate electrode portions 7a to 7d that correspond to the transistors Tr1 to Tr4, respectively. The transistors Tr1 to Tr4 are respectively provided in formation regions N and P1 to P3 of the semiconductor substrate 10. The transistor Tr1 is provided with the source-drain SD1a, SD1b, the channel CH1, and the gate electrode portion 7a. The transistor Tr2 is provided with the source-drain SD2a, SD2b, the channel CH2, and the gate electrode portion 7b. The transistor Tr3 is provided with the source-drain SD3a, SD3b, the channel CH3, and the gate electrode portion 7c. The transistor Tr4 is provided with the source-drain SD4a, SD4b, the channel CH4, and the gate electrode portion 7d.
A first well 10a to a fourth well 10d are provided in the semiconductor substrate 10. The first well 10a to the fourth well 10d are respectively provided in the active regions 2 to 5 of the semiconductor substrate 10. The first well 10a contains a prescribed concentration of a P-type impurity such as boron, for example. The second well 10b to the fourth well 10d contain prescribed concentrations of N-type impurities such as phosphorus or arsenic, for example. The N-type impurity concentrations of the second well 10b to the fourth well 10d may be the same or different.
A channel doping region 12a is provided in the channel CH1 of the active region 2. A channel doping region 12b is provided in the channel CH2 of the active region 3. A channel doping region 12c is provided in the channel CH3 of the active region 4. A channel doping region 12d is provided in the channel CH4 of the active region 5. The channel doping regions 12a to 12d have prescribed concentrations of channel doping impurities. P-type or N-type impurities such as phosphorus, arsenic, or boron are used as the channel doping impurities. The impurity concentration of each of the channel doping regions 12a to 12d is adjusted in accordance with the desired threshold voltage. A first insulating film 13 and a second insulating film 14 are layered onto the upper surface of the channel doping regions 12a to 12d. The first insulating film 13 and the second insulating film 14 function as gate insulating films for the transistors Tr1 to Tr4. The first insulating film 13 contains an insulating material such as silicon dioxide or silicon oxynitride, for example. The second insulating film 14 contains an insulating material such as hafnium oxide, for example. The second insulating film 14 includes a high-k film. A high-k film has a relative permittivity higher than at least silicon dioxide.
The gate electrode 7 is provided with the gate electrode portions 7a to 7d that respectively correspond to the transistors Tr1 to Tr4. The gate electrode portion 7b of the transistor Tr2 and the gate electrode portion 7d of the transistor Tr4 have a layered structure in which a first conductive film 15, a second conductive film 16, a third conductive film 17, a fourth conductive film 18, a fifth conductive film 19, a sixth conductive film 20, a seventh conductive film 21, an eighth conductive film 22, and a third insulating film 23 are layered in order from the bottom up. The gate electrode portion 7c of the transistor Tr3 has a layered structure in which the second conductive film 16, the third conductive film 17, the fourth conductive film 18, the fifth conductive film 19, the sixth conductive film 20, the seventh conductive film 21, the eighth conductive film 22, and the third insulating film 23 are layered in order from the bottom up. The gate electrode portion 7a of the transistor Tr1 has a layered structure in which the fifth conductive film 19, the sixth conductive film 20, the seventh conductive film 21, the eighth conductive film 22, and the third insulating film 23 are layered in order from the bottom up. The first embodiment illustrates an exemplary configuration in which the gate electrode portions 7a to 7d are disposed in correspondence with the transistors Tr1 to Tr4 as a portion of the gate electrode 7, but the configuration is not limited thereto. Another configuration is possible in which independent gate electrodes are provided for each of the transistors Tr1 to Tr4.
The first conductive film 15, second conductive film 16, fourth conductive film 18, and sixth conductive film 20 contain a conductor such as titanium nitride or a titanium aluminum nitride alloy, for example. The third conductive film 17 contains a conductor such as aluminum, for example. The fifth conductive film 19 contains a conductor such as lanthanum, for example.
In the above configuration, the gate electrode portions 7b and 7d include the first conductive film 15, whereas the gate electrode portion 7c does not include the first conductive film 15. For this reason, the thickness of the conductive film between the second insulating film 14 and the third conductive film 17, or in other words the thickness of the titanium nitride, is greater in the transistors Tr2 and Tr4 than in the transistor Tr3.
Next,
Next, an insulating film is embedded into the isolation grooves 11a. The insulating film is formed by chemical vapor deposition (hereinafter referred to as CVD) or by an application method, for example. The insulating material contains silicon dioxide, for example. Next, chemical mechanical polishing (hereinafter referred to as CMP), for example, is performed on the insulating film to remove other portions while leaving the portions inside the isolation grooves 11a. With this arrangement, the isolation insulating film 11 is formed inside the isolation grooves 11a.
Next, in the semiconductor substrate 10, the wells 10a to 10d are formed in correspondence with the transistors Tr1 to Tr4. The wells 10a to 10d are formed by introducing impurities using known photolithography technology and ion implantation technology, for example, and then performing a heat treatment for impurity activation. Boron, for example, is introduced into the well 10a as a P-type impurity. Phosphorus or arsenic, for example, is introduced into the wells 10b to 10d as an N-type impurity. After the introduction of the impurities, a heat treatment at a temperature of approximately 1000° C., for example, is performed in a nitrogen atmosphere, for example.
Next, the first insulating film 13 and the second insulating film 14 are formed on the active regions 2 to 5 of the semiconductor substrate 10 and the isolation insulating film 11. The first insulating film 13 is formed by thermal oxidation or CVD, for example. The second insulating film 14 is formed by CVD, for example. Next, the first conductive film 15 is formed on the second insulating film 14. The first conductive film 15 is provided with titanium nitride, for example. The first conductive film 15 is formed by known sputtering technology or by atomic layer deposition (hereinafter referred to as ALD) technology, for example.
Next, a photoresist 30 provided with an opening 30a is formed in the formation region P2 by known photolithography technology. The upper surface of the first conductive film 15 is exposed in the opening 30a.
Next, known wet etching technology is performed using the photoresist 30 as a mask to etch the first conductive film 15 exposed in the opening 30a. In the wet etching, an etching solution such as ammonia hydrogen peroxide mixture (hereinafter referred to as APM) or hydrochloric hydrogen peroxide mixture (hereinafter referred to as HPM) is used, for example. Through the etching, the first conductive film 15 is removed and the upper surface of the second insulating film 14 is exposed in the opening 30a. Thereafter, the photoresist 30 is stripped. Through the above steps, the structure illustrated in
Next, as illustrated in
Next, a photoresist 31 provided with an opening 31a is formed in the formation region N by known photolithography technology. The upper surface of the fourth conductive film 18 is exposed in the opening 31a.
Next, the fourth conductive film 18, third conductive film 17, second conductive film 16, and first conductive film 15 exposed in the opening 31a are etched by known wet etching technology, for example, using the photoresist 31 as a mask. In the wet etching, an etching solution such as APM or HPM is used, for example. The etching removes the fourth conductive film 18, the third conductive film 17, the second conductive film 16, and the first conductive film 15 in the opening 31a and exposes the upper surface of the second insulating film 14. Thereafter, the photoresist 31 is stripped. Through the above steps, the structure illustrated in
Thereafter, annealing is performed. The annealing is performed in a nitrogen atmosphere or a nitrogen atmosphere with oxygen at a temperature of approximately 1000° C., for example. The annealing causes the conductor (in the present embodiment, aluminum) in the third conductive film 17 to move by thermal diffusion. At this time, the aluminum in the third conductive film 17 is more concentrated between the first insulating film 13 and the second insulating film 14 compared to other portions. The amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14 is controlled by adjusting the thickness of the conductive film(s) between the third conductive film 17 and the second insulating film 14, or in other words the thickness of the titanium nitride. The thinner the conductive film(s) between the third conductive film 17 and the second insulating film 14, or in other words the thinner the titanium nitride, the greater is the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14. Consequently, if gate electrodes with different thicknesses of the conductive film(s) between the third conductive film 17 and the second insulating film 14 are formed, gate electrodes with different amounts of aluminum concentrated between the first insulating film 13 and the second insulating film 14 can be formed.
In the formation regions P1 and P3 of the transistors Tr2 and Tr4, the first conductive film and the second conductive film 16 are provided between the third conductive film 17 and the second insulating film 14. In the formation region P2 of the transistor Tr3, the second conductive film 16 is provided between the third conductive film 17 and the second insulating film 14. Consequently, in the formation regions P1 and P3 of the transistors Tr2 and Tr4, the thickness of the conductive films between the third conductive film 17 and the second insulating film 14, or in other words the thickness of the titanium nitride, is greater than in the formation region P2 of the transistor Tr3. Consequently, the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14 in the formation region P2 is greater than the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14 in the formation regions P1 and P3.
Next, as illustrated in
Thereafter, the third insulating film 23, eighth conductive film 22, seventh conductive film 21, sixth conductive film 20, fifth conductive film 19, fourth conductive film 18, third conductive film 17, second conductive film 16, and first conductive film 15 are etched by known photolithography technology and anisotropic dry etching technology, for example, and the gate electrode 7 having the planar shape illustrated in
Through the above steps, the semiconductor device 1 according to the first embodiment is formed.
According to the semiconductor device 1 and the method for forming the same according to the first embodiment, the following effects are obtained.
In the P-channel transistors Tr2 to Tr4, the gate electrode portions 7b and 7d are provided with a layered structure different from the gate electrode portion 7c. The gate electrode portion 7c is provided with the second conductive film 16 between the third conductive film 17 and the second insulating film 14. The gate electrode portions 7b and 7d are provided with the first conductive film 15 and the second conductive film 16 between the third conductive film 17 and the second insulating film 14. For this reason, in the gate electrode portion 7c, the amount of conductive material, namely aluminum, in the third conductive film 17 concentrated between the first insulating film 13 and the second insulating film 14 is greater than in the gate electrode portions 7b and 7c.
The threshold voltage of a MOSFET is controlled through adjustment of the effective work function of the gate electrode and through adjustment of the channel doping impurity concentration. In the case where adjustment of the effective work function of the gate electrode is used, the channel doping impurity concentration necessary to obtain a target threshold voltage can be lowered compared to the case where adjustment of the effective work function of the gate electrode is not used.
In the first embodiment, the greater the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14, the greater is the amount of change in the effective work function. In the first embodiment, the greater the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14, the more effective work function of the gate electrode is adjusted to achieve a lower threshold voltage of the MOSFET. With this arrangement, the first threshold voltage Vt1 of the transistor Tr3 is lower than the second threshold voltage Vt2 of the transistors Tr2 and Tr4.
As above, in the first embodiment, by forming gate electrodes with different thicknesses of the conductor, or in other words the titanium nitride, between the third conductive film 17 and the second insulating film 14, gate electrodes with different amounts of aluminum concentrated between the first insulating film 13 and the second insulating film 14 can be formed. With this arrangement, gate electrodes with different effective work functions can be formed, thereby making it possible to form MOSFETs with different threshold voltages.
Additionally, in the first embodiment, by adjusting the thickness of the conductor, or in other words the titanium nitride, between the third conductive film 17 and the second insulating film 14, the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14 can be adjusted. By adjusting the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14, the effective work function of the gate electrode of the MOSFET can be adjusted, thereby making it possible to control the threshold voltage of the MOSFET. With this arrangement, the concentration of the impurities introduced into the channel doping regions 12b to 12d for controlling the threshold voltage can be lowered. Moreover, in the case of introducing impurities of the opposite conductivity type of the well to lower the threshold voltage, or in other words, in the case of counter doping, the doping with such impurities can be eliminated or the impurities used for the doping can be reduced in quantity. With this arrangement, increases in the sub-threshold leakage current, GIDL, and junction leakage current in the transistors Tr2 to Tr4 can be suppressed.
Next, a semiconductor device 100 and a method of forming the same according to a second embodiment will be described with reference to
The gate electrode 70 is provided with a gate electrode portion 7e that corresponds to the transistor Tr5. The gate electrode portion 7e has a layered structure in which a ninth conductive film 15a, the second conductive film 16, the third conductive film 17, the fourth conductive film 18, the fifth conductive film 19, the sixth conductive film 20, the seventh conductive film 21, the eighth conductive film 22, and the third insulating film 23 are layered in order from the bottom up. The ninth conductive film 15a is provided with the same conductor as the first conductive film 15 and is thinner than the first conductive film 15.
Next,
Next, as illustrated in
According to the semiconductor device 100 according to the second embodiment, effects similar to the semiconductor device 1 according to the first embodiment can be obtained. Also, according to the second embodiment, the semiconductor device 100 provided with the ninth conductive film 15a that is thinner than the first conductive film 15 in the gate electrode portion 7e can be formed. The thickness of the conductor (titanium nitride) between the third conductive film 17 and the second insulating film 14 in the gate electrode portion 7e is smaller than in the gate electrode portions 7b and 7d, and greater than in the gate electrode portion 7c in the first embodiment. Consequently, the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14 in the gate electrode portion 7e can be adjusted to be greater than in the gate electrode portions 7b and 7d, and less than the amount of aluminum concentrated between the first insulating film 13 and the second insulating film 14 in the gate electrode portion 7c in the first embodiment.
As above, by adjusting the thickness of the ninth conductive film 15a to be left behind in the step illustrated in
The above describes the semiconductor devices 1 and 100 according to the first and second embodiments by taking the example of a configuration including P-channel MOSFETs provided with a plurality of threshold voltages, but the configuration is not limited thereto. The embodiments may also be applied to a semiconductor device including N-channel MOSFETs provided with a plurality of threshold voltages. Furthermore, the embodiments may also be applied to a semiconductor device provided with either P-channel transistors or N-channel transistors.
As above, methods of forming the semiconductor devices 1 and 100 according to the first and second embodiments are described by taking the example of an annealing step performed before the formation of the fifth conductive film 19 of the gate electrode 7, but the annealing may also be performed after the formation of the fifth conductive film 19. For example, the annealing may also be performed after the formation of the seventh conductive film 21.
Although various embodiments have been disclosed in the context of certain preferred embodiments and examples, it will be understood by those skilled in the art that the scope of the present disclosure extends beyond the specifically disclosed embodiments to other alternative embodiments and/or uses of the embodiments and obvious modifications and equivalents thereof. In addition, other modifications which are within the scope of this disclosure will be readily apparent to those of skill in the art based on this disclosure. It is also contemplated that various combination or sub-combination of the specific features and aspects of the embodiments may be made and still fall within the scope of the disclosure. It should be understood that various features and aspects of the disclosed embodiments can be combined with or substituted for one another in order to form varying modes of the disclosed embodiments. Thus, it is intended that the scope of at least some of the present disclosure should not be limited by the particular disclosed embodiments described above.