Embodiments described herein relate generally to a semiconductor device, a method of manufacturing the same and a nonvolatile semiconductor memory device.
Recently, as a candidate for a large-capacity and high-speed memory device similar to a dynamic memory (DRAM), there has been proposed a resistance-change memory in which electric current is used to change the resistance of elements.
In general, according to one embodiment, there is provided a semiconductor device, comprising a semiconductor substrate, a first semiconductor layer formed on a main surface of the semiconductor substrate, the first semiconductor layer containing carbon, a second semiconductor layer formed on the first semiconductor layer, the second semiconductor layer containing impurities diffused, a groove part arranged so as to pass through the second semiconductor layer, and a gate electrode embedded in the groove part via a gate insulating film.
One example of a resistance-change memory is a 1T/1R type. This type has the important problem as to how a large current is supplied from a transistor to a resistance-change element in a predetermined cell area.
Also, when a MOSFET is used as a cell transistor, the contact area for a source/drain electrode is decreased as the cell area is reduced. It is expected that the increase of a so-called parasitic resistance (contact resistance) greatly affects the deterioration of a current drive. Further, a certain resistor is connected to either of the source or drain electrode of a MOSFET in a 1T/1R type, which can work as a parasitic resistance.
Thus, a 1T/1R-type resistance-change memory conventionally needs to have a transistor capable of supplying sufficient currents bi-directionally in a structure where a parasitic resistance can be small, and a circuit configuration in which the transistor is used. In addition, as for memory characteristic, the characteristic variation of each cell transistor needs to be reduced to the minimum to secure a large operation margin of reading out and writing.
Therefore, in the present embodiments, regarding the cell transistor of the above-mentioned resistance-change memory, there is proposed a device structure where sufficient bi-directional currents can be supplied by decreasing a parasitic resistance and the characteristic variation is small, and a method of manufacturing the same.
Hereinafter, semiconductor devices according to embodiments will be described with reference to the accompanying drawings.
As shown in the plan view of
That is, as shown in
The structure of a transistor unit used for the resistance-change memory of the first embodiment is shown in
On the Si epitaxial layer 20, a groove part 32 configured to form a gate portion of a MOS transistor is formed. In the groove part 32, a gate electrode 34 is embedded and formed in the groove part 32 via a gate insulating film 33. The gate electrode 34 is embedded halfway in the groove part 32. A cap layer (gate protection insulating film) 35 is embedded and formed thereabove. The top face of the cap layer 35 is positioned higher than the substrate surface (the top face of the Si epitaxial layer 20).
Also, an interlayer insulating film 36 is formed on the substrate on which the transistor unit is formed. A contact plug 37 is embedded and formed in the interlayer insulating film 36 so as to be connected to the drain of the transistor unit. An MTJ element 50 is formed on the interlayer insulating film 36. The MTJ element 50 is structured so that a nonmagnetic tunnel barrier layer 52 is sandwiched by a ferromagnetic recording layer 51 whose magnetization direction is variable and a ferromagnetic reference layer 53 whose magnetization direction is fixed. The recording layer 51 is connected to the contact plug 37.
An interlayer insulating film 41 is formed so as to cover the MTJ element 50. A contact plug 42, which is connected to the reference layer 53 of the MTJ element 50, is embedded and formed in the interlayer insulating film 41. Also, a contact plug 43, which is connected to the source of the transistor unit, is embedded and formed by passing through the interlayer insulating film 41 and the interlayer insulating film 36. On the interlayer insulating film 41, an interconnect (BL) 61 connected to the connecter plug 42 and an interconnect (SL) 62 connected to the contact plug 43 are formed.
In a cell transistor of a DRAM and a resistance-change memory, a contact area needs to be enlarged so as to reduce a contact resistance with a source/drain. In the first embodiment, it is possible to reduce the width of a gate electrode sidewall part and the height of a gate electrode (including a gate cap material) from the substrate surface by using an embedded-gate transistor as shown in
Also, an embedded gate structure has the important feature of being insulated from a contact plug since the upper portion is capped by an insulating film. This leads to an advantage that even if a contact hole is widened in lithography processing, the contact hole can be etched and opened without taking the misalignment into account.
In the assumption of cell layout, the size of a contact radius usually needs to be made extremely small if the size variation and misalignment of lithography are taken into account. However, in an embedded-gate cell transistor, a part of a contact hole is allowed to be on the gate since the upper portion of the gate is insulated by gate capping insulator film. A certain amount of contact area is thereby achieved.
Further, in the first embodiment, a source/drain region of the embedded-gate cell transistor is formed by growing the Si epitaxial layer 20 while doping impurities into the Si substrate 10. Furthermore, the first embodiment has a feature that carbon is doped in the vicinity between the original Si substrate 10 and an epitaxially-grown portion.
It is thereby possible to maintain to a certain size the relationship between the depth of the groove part 32 and the height of the S/D portion for forming a gate, which inflicts no damage on ion implantation in high energy. It is also possible to uniform the impurity distribution in the doped layers 21 and 22 and to steepen the impurity distribution at the boundary between the doped layers 21 and 22 and at the boundary between the p-doped layer 21 and the Si substrate 10.
As shown in
Under such an impurity concentration profile, while a region equivalent to an S/D extension part in a planar MOSFET is formed by phosphorus on a desired position in a longitudinal direction, high-concentration arsenic exists on the substrate surface. A low-resistance contact region is thereby formed.
Since a so-called BOX impurity of phosphorus and arsenic can be formed on an arbitrary position with each other, it is possible to reduce a spreading resistance and a sheet resistance as compared to when an impurity profile is formed by ion implantation. Therefore, it is possible to improve performance and reduce the short channel effect at the same time.
Also, since the film thickness of the epitaxial growth can be controlled easily, it is possible to control the height of the S/D precisely and to minimize the characteristic variation arising from size variation as compared to forming by conventional etching.
Further, it is possible to make carbon function as a reducer of dopant diffusion for phosphorus and as a stopper/detector for BG etching. The latter can function as an etching stopper by arranging to stop a reactive ion etching (RIE) device upon detection of carbon when BG etching is formed by RIE.
Next, the processes of manufacturing the first embodiment will be explained with reference to
First, as shown in
Then, as shown in
Since carbon reduces dopant diffusion for phosphorus, the existence of the C-doped layer 11 can reduce impurity diffusion from the Si epitaxial layer 20 to the Si substrate 10.
As shown in
When the phosphorus and arsenic to be added during the growth of the doped layers 21 and 22 are switched, it is possible either to add arsenic while adding a certain amount of phosphorus or to start adding arsenic at the same time of stopping adding phosphorus halfway. In
In addition, in order to further reduce the resistance of the Si epitaxial layer 20, it may be possible that the surface of the Si epitaxial layer 20 is silicided by depositing Ni, Ti, Co and the like and adding an appropriate heating process.
Subsequently, as shown in
By etching while monitoring carbon in the C-doped layer 11, it is possible to determine the depth of the groove part 32 with excellent controllability. Note that over-etching can be performed after detection of carbon to prevent the Si epitaxial layer 20 from remaining.
Then, as shown in
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Then, as shown in
Thereafter, the MTJ element 50 is formed by depositing with sequential sputter or the like the ferromagnetic recording layer 51, which function as a resistance-change element, the nonmagnetic tunnel barrier layer 52 and the ferromagnetic reference layer 53 and by processing them in a necessary pattern. Further, the structure shown in
Thus, according to the first embodiment, since the C-doped layer 11 is formed on the surface of the Si substrate 10 and then the Si epitaxial layer 20 of dopes impurities is grown thereon, it is possible to form a semiconductor layer in good quality without generating crystal defects as compared to forming an impurity diffusion layer by ion implantation. Further, since the thickness of epitaxial growth can be precisely controlled, it is possible to determine the depth of the source/drain region exactly as compared to the conventional ion implant process. Furthermore, there is no possibility that a junction leakage current is increased by a heating process after ion implantation. Therefore, it is possible to realize an element structure that inhibits the generation of crystal defects while reducing the variation in transistor characteristics.
Also, by forming the groove part 32 of an embedded gate after the source/drain region, it is possible to reduce the variation in their sizes (variation in height and depth). Furthermore, by using the C-doped layer 11 as an end point monitor of etching, it is possible to determine the depth of the groove part 32 for embedding a gate with excellent controllability. Therefore, it is possible to stably and precisely control the shape (height) of the source/drain region and that of the gate electrode region of the embedded-gate MOSFET and to form an element having a size that varies to a lesser extent. Accordingly, it is possible to realize a cell transistor having high capability, small leakage current and less characteristic variation.
In addition, there is an advantage of preventing short circuit between the gate and contact since a gate cap material can be arranged by protruding a bit from the groove part 32.
The second embodiment differs from the first embodiment in that an oxide film and a nitride film are used instead of a high-k film as a gate insulating film 73. The cap layer (gate protection insulating film) 35 is embedded on the gate electrode 34 of the groove part 32. The cap layer 35 is formed only in the groove part 32 without protruding outside the groove part 32.
In the second embodiment, in the process shown in
Next, as shown in
Subsequently, as shown in
Thereafter, the structure shown in
Even under such a structure, it is possible to enlarge an area of an S/D exposed on the substrate surface as well as to obtain the same effect as the first embodiment. This is effective when no short circuit occurs between the gate and contact.
The third embodiment differs from the first embodiment in that the amount of over-etching performed after detection of carbon in the C-doped layer 11 is increased at the time of forming a groove for forming a gate part.
By increasing the amount of over-etching, the C-doped layer 11 is passed through to partially eliminate the surface part of the substrate 10. The subsequent processes are conducted in the same way as the first embodiment.
Under such a structure, it is possible to prevent the C-doped layer 11 from remaining in the channel as well as to obtain the same effect as the first embodiment. Therefore, it is possible to reduce mobility due to the existence of the C-doped layer 11 and to curb the increase of an S factor due to the increase of interface level density.
As shown in
As shown in
On the other hand, as shown in
Thus, according to the fourth embodiment, the Si epitaxial 20 formed on the Si substrate 10 by epitaxial growth is treated as a source/drain in an embedded-gate transistor formed in the memory cell region 80. Therefore, even when the surface of the same uppermost interlayer insulating layer is flattened in the memory cell region 80 and the periphery circuit region 90, it is possible to reduce the aspect ratio of the contact in the memory cell region 80. This has the advantage of facilitating manufacture.
Note that the present invention is not limited to the above-mentioned embodiments.
While a magnetic resistance effect element such as MTJ is used as a resistance-change element in the embodiments, it is preferable that the resistance be changed by a magnetic field or an electric field.
While a resistance-change memory is taken as an example in the above explanation in the embodiments, it is applicable to a DRAM, not limited thereto. Further, a semiconductor device having an embedded gate electrode as well as a semiconductor having a memory is applicable.
Furthermore, the material of a gate electrode, a gate insulating film and a protection insulating film are not limited to the embodiments; they are appropriately applicable in accordance with a specification.
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
This application claims the benefit of U.S. Provisional Application No. 61/951,422, filed Mar. 11, 2014, the entire contents of which are incorporated herein by reference.
Number | Date | Country | |
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61951422 | Mar 2014 | US |