The present invention relates to a semiconductor device, a method of manufacturing a semiconductor device, and an SOI substrate.
Recently, in high frequency integrated circuits using a silicon substrate, it has been required to prevent signal attenuation caused by a dielectric loss of the silicon substrate.
Patent Document 1 (Japanese Unexamined Patent Publication No. 2008-227084) discloses a semiconductor device in which boron used as an acceptor is introduced into a region that comes into contact with a silicon oxide film on a silicon substrate. With such a configuration, a boron doping layer serves as a hole source, and charge compensation is performed on electrons collected in the vicinity of the interface. Therefore, it is possible to reduce the number of interface carriers that contribute to electrical conduction, and to realize a semiconductor device having low harmonics.
[Patent Document 1] Japanese Unexamined Patent Publication No. 2008-227084
However, as a result of examination by the inventor, it has been found, as disclosed in Patent Document 1, that in a method of doping the entire surface of the silicon oxide film interface with acceptors using an ion implantation, there is the possibility of high-frequency characteristics being deteriorated when due to the variations of interfacial electron density, doping amount, or the like.
According to the present invention, there is provided a semiconductor device including: a diffusion region which is provided in a silicon substrate, and into which acceptors are introduced; a non-diffusion region which is disposed in the silicon substrate alternately with the diffusion region, and into which the acceptors are not introduced; a first insulating layer which is provided so as to contact with the silicon substrate; and an interconnect which is provided over the first insulating layer.
According to the present invention, there is provided a method of manufacturing a semi conductor device, including: a first process of forming a first insulating layer over a silicon substrate, and forming a diffusion region into which acceptors are introduced and a non-diffusion region which is disposed alternately with the diffusion region and into which the acceptors are not introduced, in the silicon substrate; and forming an interconnect over the first insulating layer.
According to the present invention, there is provided an SOI substrate including: a diffusion region which is provided in a silicon substrate, and into which acceptors are introduced; a non-diffusion region which is disposed in the silicon substrate alternately with the diffusion region, and into which the acceptors are not introduced; a first insulating layer which is provided so as to contact with the top of the silicon substrate; and a silicon layer which is provided so as to contact with the top of the first insulating layer.
According to the present invention, a diffusion region into which acceptors are introduced and a non-diffusion region into which the acceptors are not introduced are alternately disposed in a silicon substrate. Here, the diffusion region into which the acceptors are introduced serves as a p-type region in the vicinity of the surface of the silicon substrate. On the other hand, the non-diffusion region into which the acceptors are not introduced serves as an n-type region due to interfacial electrons. In this manner, the p-type region and the n-type region are alternately formed. Thereby, electrons and holes generated in the vicinity of the surface of the silicon substrate are confined by a mutual potential barrier. Therefore, it is possible to effectively increase the resistivity of the silicon substrate. In addition, when the interfacial electron density varies in the plane, it is possible to reduce the influence thereof. As stated above, when a high frequency is applied, it is possible to suppress the influence of carriers generated in the vicinity of the surface of the silicon substrate.
According to the present invention, when a high frequency is applied, it is possible to suppress the influence of carriers generated in the vicinity of the surface of the silicon substrate.
The above-mentioned objects, other objects, features and advantages will be made clearer from the preferred embodiments described below, and the following accompanying drawings.
Hereinafter, embodiments of the invention will be described with reference to the accompanying drawings. In all the drawings, like elements are referenced by like reference numerals and descriptions thereof will not be repeated.
(First Embodiment)
Meanwhile,
Meanwhile, the silicon substrate 100 herein has a high resistivity of equal to or more than several kΩcm.
As shown in
In addition, the non-diffusion region 240 into which the acceptors are not introduced is disposed in the silicon substrate 100 alternately with the diffusion region 220.
Meanwhile, the non-diffusion region 240 is formed of an n-type region by interfacial electrons generated in the vicinity of the surface of the silicon substrate 100. Meanwhile, in the following description, a carrier generated in the vicinity of the surface of the silicon substrate 100 is represented as an “interface carrier”. Meanwhile, the term “vicinity of the surface of the silicon substrate 100” herein means the vicinity of the interface on the silicon substrate 100 side in the vicinity of the interface between the silicon substrate 100 and the first insulating layer 300.
In addition, the first insulating layer 300 is provided so as to contact with the silicon substrate 100. A high frequency signal is applied to the semiconductor device 10, and thus the first insulating layer 300 preferably has a low dielectric constant. The first insulating layer 300 is, for example, a silicon oxide film. Alternatively, the first insulating layer 300 may be a film which is a stack of plural kinds of insulating layers.
Further, the interconnect 620 is provided on the first insulating layer 300. The interconnect 620 is a transmission line to which a high frequency signal is applied. Here, a frequency F (GHz) of the high frequency signal applied to the interconnect 620 is, for example, equal to or more than 0.1 (GHz).
Next, the diffusion region 220 and the non-diffusion region 240 will be described in detail.
As shown in
In addition, for example, the diffusion regions 220 adjacent to each other are separated. That is, in a range where the interconnect 620 extends, there is no portion that adjacent diffusion regions 220 are connected, when seen in a plan view. Thereby, it is possible to prevent carrier transport from a diffusion region 220 to an adjacent diffusion region 220 due to a high frequency signal.
In addition, the diffusion region 220 and the non-diffusion region 240 are alternately disposed. Here, these regions are alternately disposed in a direction perpendicular to the extending direction of the interconnect 620. When a high frequency signal is applied to the interconnect 620, an electric field induced by the high frequency signal in an interface direction is generated in the vicinity of the surface of the silicon substrate 100. Therefore, in this manner, the diffusion region 220 and the non-diffusion region 240 are alternately disposed in the direction perpendicular to the extending direction of the interconnect 620, and thus it is possible to suppress the interface carrier transport.
In addition, when the frequency of the high frequency signal applied to the interconnect 620 is set to F (GHz), the length of the diffusion region 220 on the short side in a direction parallel or perpendicular to the extending direction of the interconnect 620 is equal to or less than 25/F (μm). On the other hand, the length of the non-diffusion region 240 on the short side in a direction parallel or perpendicular to the extending direction of the interconnect 620 is equal to or less than 25/F (μm).
The “length of the diffusion region 220 on the short side” in the first embodiment is a length (width of the stripe) in the direction perpendicular to the extending direction of the diffusion region 220. The “length of the non-diffusion region 240 on the short side” is the same as well.
Here, the electric field in the interface direction generated in the vicinity of the surface of the silicon substrate 100 alternates with a period of 1/(2F) seconds. On the assumption that a typical saturation velocity of the carriers in silicon is 1×107 cm/s, the distance in which the carrier can travel for 1/(2F) seconds is a maximum of 50/F μm. Therefore, according to the embodiment, the short side length of the diffusion region 220 and the short side length of the non-diffusion region 240 are set to ½ of the distance in which the above-mentioned carriers can travel, that is, equal to or less than 25/F μm. Thereby, it is possible to increase the probability of the carriers being confined by a potential barrier between the diffusion region 220 and the non-diffusion region 240. Meanwhile, the setting of the lengths to ½ of the distance in which the carriers can travel is because the carriers can be sufficiently confined even when the distance in which the carriers can travel is set to equal to or less than ½, as the above-mentioned confining effect.
For example, when the frequency F of the high frequency signal applied to the semiconductor device 10 is set to 1 (GHz), the distance in which the carriers can travel is 50 μm. At this time, the short side length of the diffusion region 220 and the short side length of the non-diffusion region 240 are preferably equal to or less than 25 μm. Specifically, the short side length of the diffusion region 220 and the short side length of the non-diffusion region 240 are, for example, 1.5 μm. Thereby, the lengths are set to be shorter than ½ of the distance in which the carriers can travel, and thus it is possible to confine the carriers. That is, it is possible to substantially increase the resistivity of the silicon substrate 100.
In addition, the dose amount of the acceptors in the diffusion region 220 is designed on the basis of an areal average value of the areal density of the acceptors in the diffusion region 220 and the non-diffusion region 240. Here, when the first insulating layer 300 is a silicon oxide film, the areal density of the interfacial electrons in the vicinity of the surface of the silicon substrate 100 is typically approximately between 5×1010 cm−2 to 1×1011 cm−2, inclusive. Therefore, the areal average value of the areal density of the acceptors obtained by summing up the diffusion region 220 and the non-diffusion region 240 is appropriately equal to or more than 1×1010 cm−2 and equal to or less than 1×1012 cm−2.
Meanwhile, when the dose amount of the acceptors in the diffusion region 220 is increased so that the areal average value of the areal density of the acceptors becomes equal to or more than 1×1012 cm−2, the holes of the diffusion region 220 increase, and thus penetrate to the non-diffusion region 240. In this case, hole conduction occurs in the entirety including the non-diffusion region 240, effective resistivity in the interface direction decreases.
On the other hand, when the dose amount of the acceptors in the diffusion region 220 is decreased so that the areal average value of the areal density of the acceptors becomes equal to or less than 1×1010 cm −2, it is not possible to compensate for interfacial electrons present in the silicon substrate 100, and electronic conduction is dominant even in the diffusion region 220.
On the other hand, in the first embodiment, the areal average value of the areal density of the acceptors is equal to or more than 1×1010 cm−2 and equal to or less than 1×1012 cm−2. By setting the value to the above-mentioned range, it is possible to prevent the holes from penetrating into the non-diffusion region 240 due to the excessively high dose amount of the acceptors in the diffusion region 220. In addition, it is possible to prevent the compensation for the interfacial electrons present in the silicon substrate 100 from being insufficient due to the excessively low dose amount of the acceptors in the diffusion region 220. In other words, it is possible to compensate for the interfacial electrons with an average of the diffusion region 220 and the non-diffusion region 240.
Here, the area ratio of the diffusion region 220 to the non-diffusion region 240 is considered so that the areal average value of the areal density of the acceptors mentioned above is satisfied, and the dose amount of the acceptors in the diffusion region 220 is determined. In the case of
As stated above, the interfacial electrons are compensated for in the vicinity of the surface of the silicon substrate 100, and thus it is possible to increase effective resistivity. Specifically, the resistivity of the region of both the diffusion region 220 and the non-diffusion region 240 in the silicon substrate 100 is equal to or more than 300Ωcm.
Next, a method of manufacturing the semiconductor device according to the first embodiment will be described with reference to
As shown in
Here, the diffusion region 220 into which the acceptors are introduced and the non-diffusion region 240 which is disposed alternately with the diffusion region 220 and into which the acceptors are not introduced are formed in the silicon substrate 100.
Next, as shown in
Next, heat treatment is performed in order to activate the introduced acceptors. The heat treatment is performed by, for example, lamp annealing or the like. An ion implantation region for forming the diffusion region 220 is designed in consideration of thermal diffusion with this heat treatment.
Next, as shown in
It is possible to obtain the semiconductor device 10 of the first embodiment through the above-mentioned processes.
Next, the effect of the first embodiment will be described in contradistinction to a comparative example.
In any of the results, the transfer coefficient becomes the maximum when the areal average value (effective dose amount) of the areal density of the acceptors is 6.4×10 10 cm−2. This shows that it is possible to compensate for the interfacial electrons optimally in a case of such a dose amount.
In the comparative example, it is known that the transfer coefficient decreases considerably when the areal average value of the areal density of the acceptors deviates from this optimum value. When the areal average value of the areal density of the acceptors is smaller than the optimum value, the interfacial electrons are present and a transmission loss increases. On the other hand, when the areal average value of the areal density of the acceptors is larger than the optimum value, the interfacial electrons are compensated, but the excess of acceptors brings holes and a transmission loss increases.
Meanwhile, in the actual silicon substrate 100, it is expected that a variation in the interfacial electron density occurs for each wafer or in the plane of the wafer. However, evaluating the interfacial electron density in advance is difficult because the mass productivity of the semiconductor device is significantly impaired. Therefore, in the comparative example, a constant dose amount is introduced into the entire surface of the wafer, without regard for a variation in the interfacial electron density. In such a case, as in the comparative example, when the acceptors are introduced into the entire surface of the silicon substrate 100, any one of the interface carriers as mentioned above is generated in a wafer or a portion of a wafer either of which is out of tune with the interfacial electron density, which leads to a transmission loss.
In addition, as in the comparative example, when the acceptors are introduced into the entire surface of the silicon substrate 100, it is also expected that the implanted acceptor dose itself may be varied. Similarly, in such a case, any one of the interface carriers is generated in the portion out of tune with the interfacial electron density, which leads to a transmission loss.
In this manner, as in the comparative example, when the acceptors are introduced into the entire surface of the silicon substrate 100, stable high-frequency characteristics may not be obtained.
On the other hand, in the two examples according to the first embodiment, even when the areal average value of the areal density of the acceptors deviates from the optimum value, the transfer coefficient shows a higher value than that in the comparative example.
In the two examples according to the first embodiment, the diffusion region 220 into which the acceptors are introduced and the non-diffusion region 240 into which the acceptors are not introduced are alternately disposed in the silicon substrate 100. Here, in the vicinity of the surface of the silicon substrate 100, the diffusion region 220 into which the acceptors are introduced serves as a p-type region. On the other hand, the non-diffusion region 240 into which the acceptors are not introduced serves as an n-type region due to the interfacial electrons. In this manner, the p-type region and the n-type region are alternately disposed. Thereby, electrons and holes generated in the vicinity of the surface of the silicon substrate 100 are confined by a mutual potential barrier. Therefore, it is possible to effectively increase the resistivity of the silicon substrate 100. In addition, when the interfacial electron density varies in the plane, it is possible to reduce the influence thereof. From the above-mentioned reason, in the two examples according to the first embodiment, it is considered that the transfer coefficient shows a higher value than that in the comparative example even when the areal average value of the areal density of the acceptors deviates from the optimum value.
As stated above, when a high frequency is applied, it is possible to suppress the influence of the carriers generated in the vicinity of the surface of the silicon substrate 100.
(Second Embodiment)
As shown in
As shown in
In this region, the diffusion region 220 is disposed, for example, in a quadrangular island shape. Thereby, in the vicinity of the surface of the silicon substrate 100, even when an electric field is generated in the above-mentioned two directions, it is possible to suppress the interface carrier transport in each of the directions. Therefore, it is possible to effectively increase the resistivity in the interface direction.
Here, in a photolithography process, the minimum size of a mask pattern is specified, and such a pattern that island portions of the diffusion regions 220 are brought into contact with each other in the corner is not permitted. Therefore, the island portions of the diffusion regions 220 are separated from each other in the vicinity of the corner. The distance by which the island portions are separated from each other in the vicinity of the corner is preferably a distance of the minimum size capable of being designed. Thereby, it is possible to minimize the interfacial electron transport in the non-diffusion region 240 through this gap.
Next, a method of manufacturing the semiconductor device according to the second embodiment will be described with reference to
As shown in
Next, as shown in
Meanwhile, when an ion implantation is used in the introduction of the acceptors, an acceleration voltage is adjusted so that the diffusion region 220 is formed in the vicinity of the surface of the silicon substrate 100.
Next, heat treatment is performed in order to activate the introduced acceptors. The heat treatment is the same as that in the first embodiment.
Next, as shown in
According to the second embodiment, either the diffusion region 220 or the non-diffusion region 240 is disposed in an island shape in a region in which the interconnect 620 is bent. In the region in which the interconnect 620 is bent, when a high frequency signal is applied to the interconnect 620, an electric field in the interface direction in the vicinity of the surface of the silicon substrate 100 is generated in directions perpendicular to each of the directions of the interconnect 620 on the front side and the backside of the bending point. For this reason, it is possible to suppress the interface carrier transport in each of the directions of the interconnect 620 on the front side and the back side of the bending point by disposing either the diffusion region 220 or the non-diffusion region 240 in an island shape, even when the electric field is generated as described manner. Therefore, in this case, it is also possible to effectively increase the resistivity of the silicon substrate 100.
According to the manufacturing method of the second embodiment, the first insulating layer 300 is formed in advance, and then the diffusion region 220 is formed by introducing the acceptors into the silicon substrate 100 through the first insulating layer 300. Thereby, the position of the diffusion region 220 can be adjusted in accordance with the pattern of the first insulating layer 300 formed in advance. In addition, the heat treatment for the activation of the acceptors is performed after the first insulating layer 300 is formed. Thereby, the acceptors are not diffused excessively.
Meanwhile, the configuration of the first embodiment may be created by the manufacturing method of the second embodiment. Alternatively, the configuration of the second embodiment may be created by the manufacturing method of the first embodiment.
(Third Embodiment)
The third embodiment is the same as the second embodiment, except for the following point. The semiconductor device includes the following configuration in addition to the second embodiment. A silicon layer 400 is provided so as to contact with the top of the first insulating layer 300. In addition, an element isolation region 420 is provided in the silicon layer 400. Further, a semiconductor element (40) is provided in the silicon layer 400. In addition, an insulating interlayer 500 is provided on the silicon layer 400, the element isolation region 420 and the semiconductor element (40). In addition, vias 540 are provided in the insulating interlayer 500. Further, the interconnects 620 are provided on the insulating interlayer 500, and are connected to the semiconductor elements (40) through the vias 540. Hereinafter, a detailed description will be given.
As shown in
As shown in
As shown in
In addition, the silicon layer 400 is provided so as to contact with the top of the first insulating layer 300. The silicon layer 400 is a so-called silicon on insulator (SOI) layer. Therefore, the above-mentioned first insulating layer 300 is a buried oxide (BOX) layer. The detailed description of a process for forming the silicon layer 400 will be given later.
In addition, the element isolation region 420 having an opening is provided in the silicon layer 400. The element isolation region 420 is, for example, a shallow trench isolation (STI). Here, the element isolation region 420 is a region in which an opening is formed by removing the silicon layer 400 once, and then is buried with an insulating layer. In addition, the element isolation region 420 is, for example, a silicon oxide film.
The semiconductor element 40 includes, for example, the following configuration. A source region 402 and a drain region 404 are provided in the vicinity in the interface of the silicon layer 400 on the insulating interlayer 500 side. A channel region (not shown) is formed between these regions. A gate insulating film 510 and a gate electrode 520 are provided on the channel region in the silicon layer 400. A sidewall insulating film 522 is provided at sidewalls on both sides of the gate insulating film 510 and the gate electrode 520.
In addition, as shown in
Meanwhile, the insulating interlayer 500 may consist of plural layers. A liner insulating film (not shown in the drawings) located below the insulating interlayer 500 in
In addition, the insulating interlayer 500 maybe formed with the same composition as that of the element isolation region 420. Further, an interface may not be formed between the insulating interlayer 500 and the element isolation region 420.
In addition, the vias 540 are provided in the insulating interlayer 500. Further, the interconnects 620 are provided on the insulating interlayer 500. The interconnects 620 are connected to the above-mentioned semiconductor elements 40 through the vias 540. Here, the via 540 is connected to, for example, the source region 402 or the drain region 404 in the semiconductor element 40. In addition, in a region which is not shown in
The insulating interlayer 600 is further provided in regions other than the interconnect 620. In addition, an insulating interlayer 700 is provided on the insulating interlayer 600 and the interconnect 620. Meanwhile, in a region which is not shown in
In addition, the interconnect 620 to which a high frequency signal is applied or the semiconductor element (40) is formed in a region within the dotted line of
Next, a method of manufacturing the semiconductor device according to the third embodiment will be described with reference to
First, as shown in
Next, a bonding silicon substrate (400) on which the first insulating layer 300 serving as a BOX layer on the substrate surface is formed is prepared. Next, H+ ions are implanted into a portion serving as the surface side of the silicon layer 400, described later, in the bonding silicon substrate (400).
Next, as shown in
Next, heat treatment is performed in order to activate the introduced acceptors. The heat treatment is performed by, for example, lamp annealing or the like.
Next, as shown in
Next, the semiconductor element (40) is formed in the silicon layer 400. The semiconductor element (40) is formed through the following processes, in a case of such a configuration as that in
Next, as shown in
Next, a via hole (not shown in the drawings) is formed in the insulating interlayer 500 by dry etching so as to be connected to the gate electrode 520, the source region (402) or the drain region (404) of the semiconductor element (40). Next, the inside of the via hole is buried with a conductive material by a plating method. Thereby, the via 540 connected to the gate electrode 520, the source region (402) or the drain region (404) is formed. The conductive material is, for example, Cu.
Next, the above-mentioned conductive material and the insulating interlayer 500 are planarized by chemical mechanical polishing (CMP).
Next, the insulating interlayer 600 and the interconnect 620 are formed by the same method as forming the via 540 mentioned above. Meanwhile, the interconnect 620 may be formed by a dual damascene method by forming an etching stopper film (not shown in the drawings) between the insulating interlayer 600 and the insulating interlayer 500.
Next, the insulating interlayer 700 is formed on the insulating interlayer 600 and the interconnect 620. Meanwhile, a via (not shown in the drawings) or an interconnect (not shown in the drawings) connected to the interconnect 620 may be formed in a region which is not shown in
According to the third embodiment, the silicon layer 400 which is an SOI layer is provided so as to contact with the top of the first insulating layer 300. In addition, the semiconductor element (40) is provided in a portion located within the opening of the element isolation region 420 in the silicon layer 400. In the region in which the semiconductor element (40) is formed, the diffusion region 220 and the non-diffusion region 240 are formed so as to be alternately disposed. In the region in which the semiconductor element (40) is formed, when a high frequency signal is applied to the interconnect 620, an electric field is generated in complicated directions, when seen in a plan view, in the interface direction in the vicinity of the surface of the silicon substrate 100. For this reason, it is possible to suppress the interface carrier transport in each direction by disposing the diffusion region 220 and the non-diffusion region 240, mentioned above, in the region in which the semiconductor element (40) is formed, even when an electric field is generated complicatedly. Therefore, it is possible to effectively increase the resistivity of the silicon substrate 100.
(Fourth Embodiment)
Next, a method of manufacturing a semiconductor device 10 according to a fourth embodiment will be described with reference to
As shown in
Next, as shown in
According to the manufacturing method of the fourth embodiment, the SOI substrate including the first insulating layer 300 and the silicon layer 400 is formed in advance, and then the diffusion region 220 is formed by introducing the acceptors into the silicon substrate 100 through the silicon layer 400 and the first insulating layer 300. In such a method, heat treatment for the activation of the acceptors is performed after the SOI substrate including the first insulating layer 300 and the silicon layer 400 is formed. Thereby, the acceptors are not diffused excessively by the heat treatment for the formation of the SOI substrate.
Meanwhile, the SOI substrate of
As stated above, in the third and fourth embodiments, the different methods for forming the silicon layer 400 (methods for forming the SOI substrate) are respectively used, but the other method may be used in any of the embodiments.
(Fifth Embodiment)
Next, a semiconductor device 10 according to a fifth embodiment will be described with reference to
For example, similarly to the first or third embodiment, the interconnect 620 which is a transmission line to which a high frequency signal is applied or the semiconductor element (40) is formed in regions within the dotted lines of
In the case of
In the case of
In the case of
In the case of
In this manner, the adjacent diffusion regions 220 are not connected to each other in directions perpendicular to directions in which the island portions of the diffusion region 220 are connected to each other and extend. Thereby, holes or electrons do not move in the directions.
In addition, the adjacent island portions of the diffusion region 220 are connected to each other by the connection portion at a distance of the minimum size capable of being designed. Thereby, it is also less likely that holes or electrons are transported in the directions in which the island portions of the diffusion region 220 are connected to each other and extend.
According to the case of
According to the cases of
(Sixth Embodiment)
Next, a semiconductor device 10 according to a sixth embodiment will be described with reference to
As shown in
In addition, the semiconductor device includes the bias generation circuit 800 that generate a power supply voltage and the control circuit 820 that controls a high frequency signal. In addition, the bias circuit 800 or the control circuit 820 is connected to the gate interconnect (660) in a layer which is not shown. The power supply voltage generated from the bias generation circuit 800 is supplied to a gate of the semiconductor element (40). In addition, the control circuit 820 is a logic circuit that controls a switch selection state of the high frequency signal in each branch by controlling a gate bias.
As shown in
According to the sixth embodiment, it is possible to obtain the same effect as that in the first to fifth embodiments. In addition, it is possible to provide a stable high-frequency switching circuit having a small transmission loss.
In the above-mentioned embodiments, a case has been described in which the diffusion region 220 is provided in the region where the interconnect 620 which is a transmission line or the semiconductor element (40) is formed. Furthermore, a region in which a spiral inductor, a resistive element or a capacitive element is formed may be used.
In addition, in the above-mentioned embodiments, a case has been described in which the patterns of the region where the diffusion region 220 is provided are the same as each other within the region, but the above-mentioned patterns can also be combined within the same region.
As described above, although the embodiments of the invention have been set forth with reference to the drawings, they are merely illustrative of the invention, and various configurations other than those stated above can be adopted.
This application claims priority from Japanese Patent Application No. 2011-67013 filed on Mar. 25, 2011, the content of which is incorporated herein by reference in its entirety.
Number | Date | Country | Kind |
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2011-067013 | Mar 2011 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2012/001161 | 2/21/2012 | WO | 00 | 9/23/2013 |