The present invention relates to the field of semiconductors. More specifically, it relates to a semiconductor structure comprising a first semiconductor layer, a bulk semiconductor layer, an insulation layer between the first semiconductor layer and the bulk semiconductor layer, a first implanted region and a second doped region.
Silicon on oxide (SOI) or ultra-thin buried oxide (UTBOX) wafers are advantageously characterized by small variations of the threshold-voltage and, thus, of growing interest in present and future CMOS technology. In particular, the fully depleted CMOS technology enables low-voltages and low-power circuits operating at high speeds. Moreover, fully depleted SOI devices are considered as the most promising candidates for enabling reduced short channel effects (SCE), particularly with the nodes below 22 nm.
Silicon on Insulator (SOI) wafers form the basis for the high-performance MOSFET and CMOS technology. The control of the SCE is mainly facilitated by the thinness of the active silicon layer formed above the insulator, i.e., buried oxide (BOX) layer. In order to reduce the coupling effect between source and drain and, furthermore, with respect to the scalability of thin film devices for future technologies, the provision of very thin BOX layers is mandatory. The control of the threshold voltage also depends on the thinness of the BOX layers. An appropriate implantation of the substrate below the BOX layer leads to the formation of back gate and enables an accurate adjustment of the threshold voltage by back gate biasing.
Accordingly, in order to provide a reliable and performing double-gate transistor on a SOI wafer, it is important to achieve a good control over the back gate, and over the BOX layer.
a-5d illustrate semiconductor structures 5100-5300 according to the prior art.
As can be seen in
The first semiconductor layer 5101 could be, for instance, Silicon. The insulation layer 5102 could be, for instance, Silicon Oxide. The bulk semiconductor layer 5103 could be, for instance, Silicon. With this exemplary arrangement, the semiconductor structure 5100 would be a SOI wafer, the insulation layer 5102 would be the BOX, and the bulk semiconductor layer 3013 could act as a back gate for transistors formed on the first semiconductor layer 5101.
In order to provide a better conductivity of the bulk semiconductor layer 5103, the semiconductor structure 5100 is doped via a doping step S51, as illustrated in
During the doping step S51, a doping material 5204 is implanted in the semiconductor structure 5100 so as to obtain the semiconductor structure 5200, illustrated in
However, pure Boron implants are not optimal since Boron has a tendency to diffuse and could segregate in the BOX, that is, in the insulation layer 5102.
For instance, as illustrated in
Additionally, during a diffusing step S52, resulting in the semiconductor structure 5300 of
Such a diffusion of Boron into the insulation layer 5102 may adversely affect the electrical properties of the insulation layer 5102 because boron penetration increases charge trapping in SiO2 and degrades SiO2/Si interface properties, as disclosed in non-patent document “Impact Of Boron Penetration On Gate Oxide Reliability And Device Lifetime In P+-poly PMOSFETs” published in the Proceedings of Technical Papers of 1997 International Symposium on VLSI Technology, Systems, and Applications.
It is, therefore, the object of the present invention to improve the process such that the diffusion can be reduced or prevented.
This object is achieved with the semiconductor structure comprising a first semiconductor layer; a bulk semiconductor layer; an insulation layer between the first semiconductor layer and the bulk semiconductor layer; a first implanted region that is at least partially within the insulation layer; and a second doped region that is at least partially within the bulk semiconductor layer; wherein the first implanted region has an implant profile that shows a maximum within the insulation layer and a tail extending within the bulk semiconductor layer so as to inhibit the diffusion of a second doping material of the second doped region within the insulation layer.
Thanks to such approach, it is possible to form a structure in which the insulation layer has good electrical characteristics.
In some embodiments the second doping material of the second doped region can be any of Boron, and/or BF2, and/or B18H22, and/or other boron-containing molecular species.
Thanks to such approach, a good electrical conductivity of the bulk semiconductor layer can be obtained.
In some embodiments, a first material of the first implanted region can be Fluorine, and/or Chlorine. In some embodiments, the first implanted region can have a thickness in the range of 40 nm to 80 nm, preferably of 75 nm.
Thanks to such approach, it is possible to effectively inhibit or at least reduce the diffusion of the second doping material and to improve the electrical characteristics of the insulation layer.
In some embodiments the second doped region can have a thickness in the range of 150 nm to 400 nm, preferably of 200 nm.
Thanks to such approach, a good electrical conductivity of the bulk semiconductor layer can be obtained.
In some embodiments, the first semiconductor layer can have a thickness in the range of 8 nm to 20 nm, preferably 12 nm, and/or the bulk semiconductor layer has a thickness (T3) in the range of 750 μm to 800 μm, preferably 775 μm, and/or the insulation layer has a thickness (T2) in the range of 8 nm to 40 nm, preferably 25 nm.
Thanks to such approach, good electrical characteristics of transistors formed on the first semiconductor layer can be achieved.
In some embodiments, the semiconductor structure can further comprise a transistor formed on the first semiconductor layer, wherein the bulk semiconductor layer can act as a back gate for the transistor.
Thanks to such approach, it is possible to achieve a good control over the channel of the transistors.
In some embodiments, the first semiconductor layer can be any of Si, and/or strained Si, and/or SiGe, and/or Ge, and/or III-V layers and/or the bulk semiconductor layer can be Si, and/or the insulation layer can be Silicon Oxide.
Thanks to such approach, it is possible to form a semiconductor structure with standard processes, thereby reducing the manufacturing costs. Also, it is possible to achieve good performances of transistors formed on the first semiconductor layer.
Moreover, the object of the present invention is also achieved by the method for manufacturing a semiconductor structure, the semiconductor structure comprising a first semiconductor layer; a bulk semiconductor layer; and an insulation layer between the first semiconductor layer and the bulk semiconductor layer; comprising the steps of a first implant carried out in a first implanted region that is at least partially within the insulation layer; and a second doping implant in a second doped region that is at least partially within the bulk semiconductor layer; wherein the first implant step is carried out so that the first implanted region has an implant profile that shows a maximum within the insulation layer and a tail extending within the bulk semiconductor layer so as to inhibit the diffusion of a second doping material of the second doped region within the insulation layer.
Thanks to such approach, it is possible to manufacture the semiconductor structure having good electrical characteristics, while minimizing the number of steps.
In some embodiments, the first implant step can comprise an ion-implant with an energy in the range of 5 keV to 15 keV, preferably 10 keV, and a dose in the range of 1013/cm2 to 104/cm 2, preferably 3.1013/cm2, and/or the second doping implant step can comprise an ion-implant with an energy in the range of 20 keV to 60 keV, preferably 30 keV, and a dose in the range of 1013/cm2 to 2.1014/cm2, preferably 5.1013/cm2.
Thanks to such approach, the desired doping profiles for obtaining good electrical characteristics of the semiconductor structure can be obtained.
The invention will be described in more detail by way of examples hereinafter using advantageous embodiments and with reference to the drawings. The described embodiments are only possible configurations in which the individual features may, however, as described above, be implemented independently of each other or may be omitted. Equal elements illustrated in the drawings are provided with equal reference signs. Parts of the description relating to equal elements illustrated in the different drawings may be left out. In the drawings:
a to 1f are schematic views of a semiconductor structure and a method for manufacturing of a semiconductor structure in accordance with the present invention;
a and 3b are schematic illustrations of implant profiles in accordance with further embodiments of the present invention;
a to 5d are schematic views of a semiconductor structure in accordance with the state of the art.
A semiconductor structure and a manufacturing method in accordance with the present invention will now be described with reference to
As can be seen in
The first semiconductor layer 1101 has a thickness T1 in the range of 8 nm to 20 nm, preferably 12 nm. The insulation layer 1102 has a thickness T2 in the range of 8 nm to 40 nm, preferably 25 nm. The bulk semiconductor layer 1103 has a thickness T3 in the range of 750 μm to 800 μm, preferably 775 μm. Although not illustrated in
The thicknesses of the first semiconductor layer 1101 and the insulation layer 1102 are such to provide improved electrical parameters for the fabricated devices. Based on these thickness values, the parameters of the subsequent B and F implants, such as energies and doses, are adjusted accordingly.
The semiconductor structure 1100 may, e.g., be obtained by a SMARTCUT® process. More specifically, this implies providing the semiconductor structure by forming a first intermediate insulating layer above the bulk semiconductor layer 1103; forming a second intermediate insulation layer above a semiconductor substrate; bonding the first and the second intermediate insulation layers, thereby obtaining the insulation layer 1102, within a wafer transfer process and removing part of the semiconductor substrate, thereby obtaining the first semiconductor layer 1101.
As illustrated in
The first material 1207 is Fluorine or, as an alternative, Chlorine. When the first material is inserted by ion implantation, Fluorine is more advantageous since it is lighter than Chlorine.
The first material 1207 is implanted in a first implanted region 1220 at least partially extending within the insulation layer 1102 and having a thickness T4, measured from the top of the semiconductor structure 1200, of 40 nm to 80 nm, preferably 75 nm.
In this manner, as will be discussed below, the first material 1207 prevents the diffusion of a second doping material 1304 within the insulation layer 1102. This is beneficial, since the second doping material could have a negative impact on the electrical characteristics of the insulation layer 1102. Additionally, this is further beneficial since the first material 1207 has a positive beneficial effect on the insulation layer 1102. More specifically, the reliability of the metal-oxide-silicon system is improved by the incorporation of the first material 1207 into the insulation layer 1102. A generation of interface states and an accumulation of positive oxide charges during electrical stressing or irradiation are, in fact, generally reduced by using this approach.
As illustrated in
The second doping material 1304 is any of Boron, and/or BF2, and/or B18H22 and/or other boron-containing molecular species. Atomic Boron is preferred since it has the lowest mass compared to other boron-containing molecular species. The second doping material 1304 is implanted in a second doped region 1310 at least partially extending within the bulk semiconductor layer 1303 and having a thickness T5, measured from the top of the semiconductor structure 1200, of 150 nm to 400 nm, preferably 200 nm.
As illustrated in
However, the diffusion of the second doping material 1304 is limited by the presence of the first material 1207. Accordingly, the degradation of the electrical characteristics of the insulation layer 1102 due to the diffusion of the second doping material 1304 from the bulk semiconductor layer 1103 into the insulation layer 1102 is prevented by the presence of the first material 1207.
Even more specifically, the tail of the first material 1207 extending from the insulation layer 1102 to the bulk semiconductor layer 1103 prevents the diffusion.
Additionally, the presence of the first material 1207 within the insulation layer 1102 improves the electrical characteristics of the insulation layer 1102 as discussed above.
Accordingly, the first implanted region 1220 achieves a synergetic effect in
With reference to
As can be seen in
Two solid lines in the profile chart illustrate the profile of the first implanted region 1220 and of the second doped region 1310. The dashed lines extending from the semiconductor structure 1300 into the profile chart represent the depth levels of the first semiconductor layer 1101, the insulation layer 1102 and the bulk semiconductor layer 1103. The dot and dash lines represent different values of the two solid lines.
More specifically, the first solid line 2008 illustrates the material concentration profile of the first implanted region 1220. As can be seen, the first implanted region 1220 has a first low concentration value 2005 and a first high concentration value 2007. More specifically, the first low concentration 2005 is the concentration of the first implanted region 1220 at the top surface of the first semiconductor layer 1101. The profile of the first implanted region 1220 then gradually rises, as the depth into the semiconductor structure 1300 increases to a value corresponding to the first high concentration 2007. From there on, as the depth increases, the concentration of the first implanted region 1220 gradually decreases to a value corresponding to 1017 at/cm3, at a depth corresponding to a first implanted region thickness 2003, substantially corresponding to thickness T4 in
Thus, the first implanted region 1220 has an implant profile that shows a maximum, that is to say the first high concentration 2007, within the insulation layer 1102, and a tail extending within the bulk semiconductor layer 1103.
The maximum of the implant profile can be advantageously located in the median plane of the insulation layer 1102.
The first low concentration 2005 could have a value in the range of 1017 at/cm3 to 3.1018 at/cm3, preferably 1018 at/cm3. The first high concentration 2007 could have a value in the range of 1018 at/cm3 to 1019 at/cm3, preferably 5.1018 at/cm3. The first implanted region thickness 2003 could have a value in the range of 40 nm to 80 nm, preferably 75 nm.
For an insulation layer 1102 having a thickness of 25 nm, a first semiconductor layer 1101 having a thickness of 10 nm and a sacrificial oxide having a thickness of 2 nm, this could be achieved by a first implant step S11 having an energy in the range of 5 keV to 15 keV, preferably 10 keV, and a dose in the range of 1013/cm2 to 1014/cm2, preferably 3.1013/cm2.
Second solid line 2009 illustrates the doping profile of the second doped region 1310. As can be seen, the second doped region 1310 has a second dopant low concentration value 2004 and a second dopant high concentration value—2006. More specifically, the second dopant low concentration 2004 is the dopant concentration of the second doped region 1310 at the top surface of first semiconductor layer 1101. The dopant profile of the second doped region 1310 then gradually rises, as the depth into semiconductor structure 1300 increases, to a value corresponding to the second dopant high concentration 2006. From there on, it decreases gradually, as the depth into semiconductor structure 1300 increases.
The second dopant low concentration 2004 could have a value in the range of 1016/cm3 to 5.1017/cm3, preferably 2.1017/cm3. The second dopant high concentration 2006 could have a value in the range of 1018 /cm3 to 1019/cm3, preferably 4.1018/cm3.
For an insulation layer 102 having a thickness of 25 nm, a first semiconductor layer 1101 having a thickness of 10 nm and a sacrificial oxide having a thickness of 2 nm, this could be achieved by a second doping step S12 having an energy in the range of 20 keV to 60 keV, preferably 30 keV, and a dose in the range of 1013/cm2 to 2.1014/cm2, preferably 5.1013/cm2.
The implant of the second doped region 1310 could be done after the implant of the first implanted region 1220.
As can be seen from
Thanks to such a profile, the concentration of the second doping material 1304 in the bulk semiconductor layer 1103 provides a beneficial doping profile for the bulk semiconductor layer 1103 to act as a back gate for transistors formed on the first semiconductor layer 1101. Moreover, the tail concentration of the first material 1207 in the bulk semiconductor layer 1103 provides a beneficial profile for inhibiting the diffusion of the second doping material 1304 into the insulation layer 1102, thereby preventing the degradation of the electrical characteristics of the insulation layer 1102 caused by a too high amount of the second doping material 1304. Still additionally, the concentration of the first material 1207 in the insulation layer 1102 provides a beneficial profile for improving the electrical characteristics of the insulation layer 1102.
Accordingly, a synergetic effect of the two profiles results in more than two beneficial effects.
a and 3b are schematic illustrations of further embodiments in accordance with the present invention. In particular, they illustrate concentration profiles resulting from steps S11 and S12 when using Fluorine as the first material 1207 and Boron as the second doping material 1304.
More specifically, they illustrate the case in which the insulation layer 1102 has a thickness of 25 nm, the, first semiconductor layer 1101 has a thickness of 10 nm and the sacrificial oxide has a thickness of 2 nm, while the bulk semiconductor layer 1103 is Silicon. In both
In both
Although the above embodiments have been described with reference to two implant steps S11 and S12, it has to be understood that the two implant steps S11 and S12 do not necessarily imply only two implants, but each could be performed by one or more sub-implant steps.
For instance, for step S12 including a Boron doping, chain implants, i.e., the combination of two Boron implants with different energies, can be advantageously used. This is illustrated in
More specifically,
Each curve is formed by a combination of two implants. In particular, along line 4001, from the bottom of the graph moving upward, each line is formed by the following implant combinations: 40 keV with a dose of 1013/cm2 and 60 keV with a dose of 4.1013/cm2, 35 keV with a dose of 2.1013/cm2 and 55 keV with a dose of 5.1013/cm2, 30 keV with a dose of 2.1013/cm2 and 50 keV with a dose of 8.1013/cm2, 30 keV with a dose of 4.1013/cm2 and 50 keV with a dose of 6.1013/cm2.
In addition, an additional implant step (not shown in the figures) with carbon and/or fluorine as an implant species could be realized, at a depth deeper than the first implanted region 1220. The carbon implant specie is preferred since its atomic mass is lower than that of fluorine. The implanted carbon profile should coincide with that of the boron profile, i.e., ion-implant with an energy in the range of 20 keV to 60 keV, preferably 30 keV. The dose range for carbon implants could be 5.1013/cm2 to 1014/cm2, preferably 1014/cm2. This would provide the beneficial advantage of further inhibiting the diffusion of the second doping material 1304.
Number | Date | Country | Kind |
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1161169 | Dec 2011 | FR | national |
This application is a national phase entry under 35 U.S.C. §371 of International Patent Application PCT/IB2012/002349, filed Nov. 13, 2012, designating the United States of America and published in English as International Patent Publication WO 2013/084035 A1 on Jun. 13, 2013, which claims the benefit under Article 8 of the Patent Cooperation Treaty and under 35 U.S.C. §119(e) to French Patent Application Serial No. 1161169, filed Dec. 5, 2011, the disclosure of each of which is hereby incorporated herein in its entirety by this reference.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/IB2012/002349 | 11/13/2012 | WO | 00 | 5/23/2014 |