The present disclosure relates to a silicon carbide (SiC) power device having an improved robustness, in particular in regard to thermomechanical stresses due to thermal cycles; the present disclosure moreover relates to a process for manufacturing the power device.
Integrated electronic devices are known, for example diodes or MOSFETs (Metal-Oxide Semiconductor Field-Effect Transistors) for power-electronic applications, made starting from a silicon carbide substrate.
Such devices are advantageous thanks, at least in part, to the favorable chemico-physical properties of silicon carbide. For instance, silicon carbide generally has a bandgap wider than that of silicon, that is the material commonly used in electronic power devices. Consequently, even with relatively small thicknesses, silicon carbide has a breakdown voltage higher than silicon and can therefore be advantageously used in high-voltage, high-power, and high-temperature applications.
Manufacturing of advanced silicon carbide power devices is, however, affected by some problems due to the dielectric properties of passivation layers used with insulating functions.
On account of the high operating temperature and dielectric rigidity, a polyimide layer (i.e., a polymer of imide monomers) is typically used as passivation and insulation material in current silicon carbide power devices, being for example formed via deposition using spin-coating techniques. Problems of adhesion of this passivation layer to the underlying silicon carbide substrate (or to some other layer of material), in particular after thermal cycles (both during operations of electrical testing and during the effective operating life) currently limit reliability of such power devices.
In particular, due to possible delamination of the passivation layer, caused by thermomechanical stresses after the aforesaid thermal cycles, so-called electrical arching phenomena may occur in reverse biasing, between metal-material regions of the power device, with consequent damage or breakdown of the same power device.
In various embodiments, the present disclosure provides an improved solution for a silicon carbide power device, allowing to overcome the disadvantages highlighted previously associated to known solutions and in particular providing a higher robustness in regard to thermomechanical stresses due to thermal cycles.
According to the present disclosure, a silicon carbide power device and a corresponding manufacturing process are therefore provided.
In one or more embodiments, an electronic power device is provided that includes a substrate of silicon carbide (SiC) having a front surface and a rear surface which lie in a horizontal plane and are opposite to one another along a vertical axis transverse to the horizontal plane. The substrate includes an active area, and a non-active edge area surrounding the active area, and a plurality of doped regions extending from the front surface into the substrate in the active area. A dielectric region is disposed over the front surface in at least the edge area. A passivation layer is disposed over the front surface of the substrate, and the passivation layer is in contact with the dielectric region in the edge area. The passivation layer includes at least one anchorage region that extends through a thickness of the dielectric region at the edge area and is configured to define a mechanical anchorage for the passivation layer.
In one or more embodiments, a process for manufacturing an electronic power device is provided that includes: forming a dielectric region on a front surface of a substrate of silicon carbide (SiC), at an edge area of the substrate, the substrate having the front surface and a rear surface which lie in a horizontal plane and are opposite to one another along a vertical axis transverse to said horizontal plane, said substrate including an active area and the edge area, which is not active, a plurality of doped regions extending from the front surface into the substrate in the active area; and forming a passivation layer over the front surface of said substrate, and in contact with said dielectric region in said edge area. The forming the passivation layer includes forming an anchorage region that extends through a thickness of said dielectric region at said edge area and is configured to define a mechanical anchorage for said passivation layer.
For a better understanding of the present disclosure, preferred embodiments thereof are now described, purely by way of non-limiting example, with reference to the attached drawings, wherein:
With initial reference to
The above manufacturing process envisages providing a wafer 1 comprising a silicon carbide substrate 2, having a front surface 2a and a rear surface 2b, which extend in a horizontal plane xy and are separate from and opposite to one another along a vertical axis z, transverse to the horizontal plane xy.
In the embodiment illustrated, where the power device is, by way of example, a power diode, a rear cathode contact is formed on the rear surface 2b of the substrate, constituted by a layer of conductive material 3, for example metal material.
Moreover, a plurality of anode wells 4, constituted by appropriately doped regions, are formed at the front surface 2a of the substrate 2, in an active area A′ of the power device. In a known manner, each of the aforesaid anode wells 4, which can have a strip-like conformation (in top view, in the horizontal plane xy), represents a cell of the power device.
At the front surface 2a of the substrate 2, in an edge area A″ of the power device (distinct and separate from the active area A′), an edge anode region 5 is moreover formed, which is also constituted by an appropriately doped region, having a side extension greater than that of the aforesaid anode wells 4 (in
In a known manner, the edge area A″ terminates at a scribe line SL, represented by a dashed line, along which dicing of the wafer 1 will be carried out, for the formation of dies of the power device, once the manufacturing process is completed.
The edge anode region 5 is arranged externally with respect to the active area A′ and to the anode wells 4, for example being shaped like a ring around the active area A′. In a way not shown, the aforesaid edge anode region 5 may be connected to a ring-shaped implanted region, which is also formed at the front surface 2a of the substrate 2, at the edge area A″ (having, in a known manner, functions of termination of the electrical field).
As shown in the aforesaid
As illustrated in
As illustrated in
In particular, definition of the overlying layer 10 leads to formation of a first overlying region 10a and a second overlying region 10b, at the edge area A″, which are spaced apart laterally (in the horizontal plane xy, in
For instance, the first and second overlying regions 10a, 10b may have a same width in the horizontal plane xy (in
In particular, the first overlying region 10a is located laterally at a distance (in the horizontal plane xy, in
As illustrated in
In a known way, here not shown, anode electrical-contact regions may then be formed, by surface implants in the aforesaid anode wells 4 and edge anode region 5, in order to improve the corresponding electrical contact properties.
As shown in
The front conductive layer 14 is then defined, as illustrated in
As illustrated in the aforesaid
The outer end of the aforesaid remaining portion 14a is in any case sufficiently far from the first overlying region 10a, so that the first overlying region 10a is located, as discussed previously, in a non-active area of the power device (for example, in the case where the electrical field lines terminate at a distance of approximately 20 μm from the outer end of the remaining portion 14a, the first overlying region 10a is arranged at a distance sufficiently higher than 20 μm from the same outer end of the remaining portion 14a).
With reference to
In particular, this etching operation is carried out via photolithographic process, with an etching mask 15, represented schematically by a dashed line in the aforesaid
During etching, the chemical-etching agent (in the example, HF) therefore penetrates through the access window 12 through the dielectric region 8a, removing the underlying material (etching stops on the front surface 2a of the substrate 2), without, however, involving the overlying regions 10a, 10b given the characteristics of selectivity of the etching process in regard to the material of the same overlying regions 10a, 10b.
In particular, given that wet etching is totally isotropic, an anchorage opening 16 is formed in the dielectric region 8a, extending vertically (along the vertical axis z) throughout the thickness of the dielectric region 8a, and which horizontally (in the horizontal plane xy, in
In detail, in the embodiment illustrated, the anchorage opening 16 is trapezium-shaped in cross-section, and the aforesaid dimension W1 has a larger extension, at the major base of the trapezium, facing the access window 12, comprised, for example, between 2 μm and 5 μm (in any case depending upon the thickness of the dielectric, the aforesaid wet etching being isotropic).
Basically, following upon etching, a respective end portion of the first and second overlying regions 10a, 10b, designated by 18a and 18b, respectively, facing the access window 12, is arranged suspended and protruding over the underlying anchorage opening 16.
As illustrated in
Following upon its formation, the passivation layer 20 has, in particular, an anchorage region 22, which extends in the anchorage opening 16, occupying it entirely, and has: a first portion 22a, within the aforesaid anchorage opening 16, which assumes a corresponding conformation (in the example, with trapezoidal cross-section); and a second portion 22b, within the access window 12, having a width smaller than that of the first portion (in
In particular, the aforesaid first portion 22a of the anchorage region 22 is located directly underneath, and in direct contact with, the end portions 18a, 18b of the first and second overlying regions 10a, 10b, and the aforesaid second portion 22b is arranged between the same end portions 18a, 18b.
The wafer 1 is then subjected to dicing along the scribe line SL, for formation of a die integrating the power device, here designated by 25 (in the example, a power diode).
The aforesaid power device 25 therefore has the passivation layer 20, arranged at least over the dielectric region 8 (of thick dielectric) in the edge area A″, that is appropriately anchored thanks to the presence of the corresponding anchorage region 22 and the associated mechanical anchorage within the anchorage opening 16.
Advantageously, this anchorage region 22 allows the passivation layer 20 to remain mechanically anchored, even after thermal cycles (during electrical testing or during effective operation of the power device 25), eliminating or in any case markedly reducing the possibility of delamination of the passivation layer 20 from the underlying material and of consequent electrical-arching phenomena.
In the embodiment illustrated, the active area A′ of the power device 25 has a substantially square conformation in the horizontal plane xy, corresponding to which is a substantially square conformation of the overlying anode electrical contact (constituted by the remaining portion 14a of the front conductive layer 14). The first and second overlying regions 10a, 10b have in this case the conformation of a square ring in the horizontal plane xy and entirely surround the active area A′. The passivation layer 20 extends above the front surface of the die 25′ and has, in particular, the anchorage region 22, which also has the shape of a square ring (in top view), being in fact arranged at the access window 12 defined between the aforesaid first and second overlying regions 10a, 10b.
In the variant embodiment illustrated in
In particular, the aforesaid second overlying region 10b has a further end 18b′, opposite to the end 18b facing the access window 12, which protrudes from the underlying dielectric region 8a. Consequently, the passivation layer 20, once formed, has a further anchorage area, designated by 22′, arranged directly underneath the aforesaid further end 18b′, which therefore contributes to anchoring the passivation layer 20 with respect to the underlying substrate 2 and to preventing delamination phenomena due to the thermomechanical stresses.
In an evident manner, also for this embodiment the configurations discussed previously with reference to
A further embodiment of the manufacturing process of the power device is now discussed.
In this case, as shown in
As illustrated in
The aforesaid doped portion 30′ is arranged at what constitutes, during operation, an electrically non-active area of the power device (in other words, it is arranged in an area external to the area involved by the electrical field lines due to operation of the power device).
Next, as shown in
In particular, following upon the aforesaid implantation, the doped portion 30′ has an etch rate higher than that of the material constituting the second dielectric layer 32; for example, the ratio between the etch rate of the doped portion 30′ and that of the second dielectric layer 32 is higher than or equal to two.
As illustrated in
As illustrated in
The above front conductive layer 14 is then defined, as illustrated in
As illustrated in the aforesaid
As shown in
In particular, etching is carried out through an appropriate etching mask 33 (represented schematically with dashed lines) so as to dig a vertical trench 34 throughout the thickness of the dielectric region 8a, centrally with respect to the corresponding doped portion 30′ (it is noted that the dry etch involves indistinctly the material of the dielectric region 8a, irrespective of doping, therefore without distinction as regards the corresponding doped portion 30′).
As shown in
On account of the different etch rate, the etch penetrates, in the horizontal plane xy, more into the doped portion 30′ than it does into the overlying material of the dielectric region 8a, thus causing removal (in the example, complete removal) of the same doped portion 30′, for formation of what is once again defined as the anchorage opening 16 and of the access window 12, overlying, and in fluidic communication with, the same anchorage opening 16, which is in this case also formed in the same dielectric region 8a. The anchorage opening 16 therefore has again, in the horizontal plane xy (in
It is noted that, in this embodiment, the end portions, once again designated by 18a, 18b, facing the access window 12 and suspended and protruding above the underlying anchorage opening 16 are the result of etching of the surface portion of the dielectric region 8a and are therefore constituted by the material of the same dielectric region 8a.
As illustrated in
After its formation, the passivation layer 20 has in particular the anchorage region 22, which extends in the anchorage opening 16, occupying it entirely, and once again has: the first portion 22a, within the same anchorage opening 16, having a corresponding conformation; and the second portion 22b, within the access window 12, having a dimension smaller than that of the first portion 22a in the horizontal plane xy (in
In particular, the aforesaid first portion 22a of the anchorage region 22 is located directly underneath, and in direct contact with, the end portions 18a, 18b of the dielectric region 8a, and the aforesaid second portion 22b is arranged between the same end portions 18a, 18b of the dielectric region 8a.
The wafer 1 is then subjected to dicing along the scribe line SL, for formation of the die containing the power device, once again designated by 25.
Also in this case, advantageously, the anchorage region 22 enables the passivation layer 20 to remain anchored and fixed, even following upon thermal cycles and the resulting electromechanical stresses.
In the embodiment illustrated, the active area A′ of the power device 25 has a substantially square conformation in the horizontal plane xy, corresponding to which is a substantially square conformation of the remaining overlying portion 14a of the front conductive layer 14 (which constitutes the anode electrical contact).
The anchorage opening 16 and the corresponding anchorage region 22 of the passivation layer 20 have the conformation of a square ring in the horizontal plane xy itself, entirely surrounding the active area A′.
In the embodiment illustrated in
A further embodiment of the process for manufacturing the power device is now discussed.
In this case, as illustrated in
The sacrificial region 40 is formed in a manner limited and confined to an external region of the power device, in the edge area A″ and in the proximity of the scribe line SL, therefore being arranged in what constitutes, during operation, an electrically non-active area of the power device (in other words, being arranged in an area external to the area involved by the electrical field lines due to operation of the power device).
The sacrificial region 40 has, for example, a width of approximately 30 μm (in particular, the width of the sacrificial region 40 in the horizontal plane xy, along the axis x in
Then (
As shown in
As illustrated in
In particular, etching is carried out using an appropriate etching mask 42 (represented schematically with a dashed line), so as to dig a trench 44 throughout the thickness of the dielectric region 8a, centrally with respect to the aforesaid sacrificial region 40.
As illustrated in
The anchorage opening 16 has in this case a substantially rectangular shape in cross-section, and the access window has a substantially trapezoidal section (with the minor base facing the aforesaid anchorage opening 16).
It is noted that, also in this embodiment, the end portions 18a, 18b, facing the access window 12 and suspended and protruding above the underlying anchorage opening 16, are the result of etching of the surface portion of the dielectric region 8a and are integral with the same dielectric region 8a.
As illustrated in
The front conductive layer 14 is then defined, as illustrated in
As illustrated in
Following upon its formation, the passivation layer 20 has in particular the anchorage region 22, which extends in the anchorage opening 16, occupying it entirely, and once again has: the first portion 22a, within the same anchorage opening 16, having a corresponding conformation (also in this case being rectangular in section); and the second portion 22b, within the access window 12, having a size smaller than that of the first portion 22a in the horizontal plane xy (in
In particular, the aforesaid first portion 22a of the anchorage region 22 is located also in this case directly underneath, and in direct contact with, the end portions 18a, 18b of the dielectric region 8a, and the aforesaid second portion 22b is arranged between the same end portions 18a, 18b of the dielectric region 8a.
The wafer 1 is then subjected to dicing along the scribe line SL, for formation of the die integrating the power device, once again designated by 25.
Also in this case, advantageously, the anchorage region 22 enables the passivation layer 20 to remain anchored in a fixed manner within the anchorage opening 16, even following upon thermal cycles and resulting electromechanical stresses.
The anchorage opening 16 and the corresponding anchorage region 22 of the passivation layer 20 have the conformation of a square ring in the horizontal plane xy, surrounding the active area A′ entirely.
In the embodiment illustrated in
The advantages of the present solution are clear from the foregoing description.
In particular, it is once again underlined that, thanks to the presence of the anchorage region 22, the passivation layer 20 is anchored and fixed in a reliable manner, thus preventing possible delamination thereof, i.e., its partial detachment from the underlying material, on account of thermomechanical stresses due to thermal cycles.
Consequently, the present solution enables maximization of the reliability and robustness of a resulting power device 25, in particular with respect to the corresponding edge termination (from which, in use, the aforesaid delamination phenomena start), which is obtained starting from the silicon carbide substrate 2.
The manufacturing process, in the embodiments described, is convenient and economically advantageous to implement, including processing steps that are in themselves standard in the semiconductor industry.
Finally, it is clear that modifications and variations may be made to what has been described and illustrated herein, without thereby departing from the scope of the present disclosure.
In particular, it is underlined that the present solution can find advantageous application in any electronic device, in particular for power applications, in which anchorage of a passivation layer to an underlying material is advantageous to prevent phenomena of delamination due, for example, to thermomechanical stresses.
Moreover, it is underlined that the present solution may envisage a desired number of anchorage regions 22, obtained in a way altogether corresponding to what has been discussed previously, in particular in the edge area A″ of the power device 25.
Provision of a plurality of anchorage regions 22 may in fact enable a further increase in the anchoring of the passivation layer 20 and therefore a further increase in the reliability of the resulting power device 25.
These anchorage regions 22 may have any desired arrangement; for example, they may be arranged according to a grid arrangement in the aforesaid edge area A″.
Purely by way of example,
The various embodiments described above can be combined to provide further embodiments. These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.
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Number | Date | Country | |
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20230092543 A1 | Mar 2023 | US |
Number | Date | Country | |
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Parent | 17039289 | Sep 2020 | US |
Child | 18052510 | US |