The present invention relates to a spectroscopic analysis device and an interfering light formation mechanism.
When light is applied to gas, liquid, solid, or the like (hereinafter simply referred to as “gas or the like”), the wavelength of the light transmitted through the gas or the like or the light reflected by the gas or the like (hereinafter referred to as “object light”) varies depending on the substances present in the gas or the like. In this situation, there is a technique using a spectroscopic technology as a method using the wavelength of the object light to discriminate and identify the substance present in the gas or the like. In the technique using the spectroscopic technology, the frequency spectrum and intensity of the object light is used to enable the substance present in the gas or the like to be discriminated and identified and the concentration of the substance to be grasped (hereinafter sometimes referred to as “discrimination and identification or the like of the substance”).
Known techniques using the spectroscopic technology include wavelength-dispersive spectroscopy and Fourier spectroscopy.
The wavelength-dispersive spectroscopy can perform discrimination and identification or the like of the substance by utilizing the fact that the diffraction angle varies depending on the wavelength of the object light when the object light is applied to the diffraction grating.
The Fourier spectroscopy is spectroscopy utilizing phase-shift interference with a Michelson-type two-beam interference optical system, which is a technology involving formation of an interferogram and mathematical Fourier transform of the interferogram to obtain a spectral characteristic in order to discriminate and identify the substance.
As spectroscopic analysis devices utilizing this Fourier spectroscopy to perform discrimination and identification or the like of the substance, technologies described in Patent Literatures 1 and 2 have been developed.
First, Patent Literature 1 discloses a device that uses micro electro-mechanical systems (MEMS) as actuators to form interfering light to be used for spectroscopic analysis. This device has a mechanism that forms outgoing light, which is interfering light, from incident light, and is configured so that the optical-axis direction of the incident light and the optical-axis direction of the outgoing light are coaxial with each other. For example, Patent Literature 1 discloses, as a mechanism that forms interfering light, a mechanism provided with a splitter 30b including first and second reflection surfaces and third and fourth reflection surfaces symmetrical to the optical axis of the incident light, a movable mirror 50 having orthogonal surfaces facing the first and third reflection surfaces, and a fixed corner reflector 60 having orthogonal surfaces facing the second and fourth reflection surfaces. In addition, Patent Literature 1 discloses that the movable mirror 50 of the mechanism that forms the interfering light moves in a direction of 90° to the optical axis of the incident light.
Since the mechanism that forms the interfering light of Patent Literature 1 has the configuration as described above, when light is made incident on the mechanism that forms interfering light, interfering light is formed as follows.
First, incident light is made incident on the splitter 30b, and then the incident light is reflected at the first and second reflection surfaces of the splitter 30b, respectively, to be divided into two beams of light, and the divided two beams of light are made incident on the movable mirror 50 and the fixed corner reflector 60, respectively. The respective beams of light made incident on the movable mirror 50 and the fixed corner reflector 60 are reflected at the movable mirror 50 and the fixed corner reflector 60, respectively, and made incident on the third and fourth reflection surfaces of the splitter 30b, respectively. The beams of light made incident on the third and fourth reflection surfaces of the splitter 30b are reflected at the third and fourth reflection surfaces of the splitter 30b, respectively, and made incident on the spatial combiner output 70. The beams made incident from the third and fourth reflection surfaces of the splitter 30b become the interfering light through the spatial combiner output 70, and thus the interfering light is made incident on the ditecter 610.
Here, if the movable mirror 50 moves, the two beams of light reflected at the first and second reflection surfaces of the splitter 30b have a difference generated in optical path length (optical path length difference) to where the light is made incident on the spatial combiner output 70. Since this optical path length difference changes depending on the movement amount of the movable mirror 50, detecting the intensity of the interfering light by the ditecter 610 while moving the movable mirror 50 allows an interferogram to be formed on the basis of the intensity of the detected interfering light. That is, in the device of Patent Literature 1, assuming that the incident light incident on the mechanism that forms the interfering light is object light and moving the movable mirror 50 while making the incident light be incident on the mechanism enables formation of the interferogram based on the object light, and it is possible to perform discrimination and identification or the like of the substance that generates the object light on the basis of this interferogram.
Furthermore, the spectroscopic analysis device of Patent Literature 2 includes a dividing optical system that allows multi-wavelength light emitted in various directions from measurement points of an object to be measured to be made incident, an image-forming optical system that directs the multi-wavelength light transmitted through the dividing optical system to almost the same point to form an interference image, a detection part that detects the light intensity of the interference image, an optical path length difference increasing/decreasing means for increasing/decreasing the relative optical path length difference between a part of the multi-wavelength light travelling from the dividing optical system toward the image-forming optical system and the remaining part of the multi-wavelength light, and a processing part that obtains the interferogram of each measurement point of the object to be measured on the basis of the light intensity change detected by the detection part by increasing/decreasing the optical path length difference by the optical path length difference increasing/decreasing means, and performs Fourier transform of the interferogram to acquire a spectrum.
In the spectroscopic analysis device of Patent Literature 2, the dividing optical system has a configuration in which the multi-wavelength light emitted in various directions from measurement points of the object to be measured is divided and directed into a first reflection part and a second reflection part. Furthermore, the optical path length difference increasing/decreasing means is configured to move the first and second reflection parts relative to each other to increase and decrease the optical path length difference between the multi-wavelength light traveling from the dividing optical system via the first reflection part toward the image-forming optical system and the multi-wavelength light traveling from the dividing optical system via the second reflection part toward the image-forming optical system.
Patent Literature 2 further describes that disposing the reflection surfaces of the first and second reflection parts with inclination of 45° with respect to the optical axes of the parallel beams each transmitted through the dividing optical system enables the light reflected at the first and second reflection parts to be directed to the image-forming optical system as it is.
Meanwhile, the Michelson-type two-beam interference optical system described above and the spectroscopic analysis device in Patent Literatures 1 and 2, both of which form the interferogram by forming images of the divided beams at the same position, are characterized as follows.
First, the Michelson-type two-beam interference optical system can precisely align the image-formation positions of the divided beams, but has a problem that even microvibrations affect the interference due to its device configuration. Moreover, there is also a problem that separating the beam into two beams using a beam splitter leads to reduction in the light utilization ratio, making measurement difficult unless the object light has strong intensity.
Compared with the Michelson-type two-beam interference optical system, the spectroscopic analysis device of Patent Literature 1 can reduce the influence of vibration or the like on interference to some extent, but has a problem that, similar to the Michelson-type two-beam interference optical system, dividing the incident light into two beams of light using the splitter 30b results in a low light utilization ratio.
On the other hand, in the spectroscopic analysis device of Patent Literature 2, all of the light rays transmitted through the dividing optical system can be used for analysis, resulting in high light utilization efficiency and enabling measurement even with weak intensity of the object light. However, when the optical path length difference between the beams divided by the dividing optical systems is increased/decreased by the optical path length difference increasing/decreasing means, misalignment occurs in the image-formation positions of the beams. This causes a problem that misalignment occurs in the positions of forming the interference images when the measurement target is measured in two dimensions, resulting in low spatial resolution.
In view of the above circumstances, an object of the present invention is to provide a spectroscopic analysis device and an interfering light formation mechanism that can improve the robustness of the device against disturbance and can increase the light utilization ratio and the spatial resolution.
A spectroscopic analysis device of the present invention includes: a light supply part; an interfering light formation part that forms interfering light from supplied light supplied from the light supply part; and a detection part that detects light intensity of the interfering light formed by the interfering light formation part, in which the interfering light formation part includes a fixed reflection part whose movement is fixed, a movable reflection part provided to be movable along a base plane parallel to an optical axis of the supplied light supplied from the light supply part, and a moving part that moves and fixes the movable reflection part along the base plane, the fixed reflection part includes a first reflection surface that reflects the supplied light supplied from the light supply part and a second reflection surface provided to be plane-symmetrical with the first reflection surface with respect to the base plane and to be orthogonal to the first reflection surface, and the movable reflection part includes a third reflection surface and a fourth reflection surface parallel to the first reflection surface and the second reflection surface of the fixed reflection part, respectively.
According to the present invention, the optical path length is changed by moving the movable reflection part linearly and parallel to the optical-axis direction of the supplied light, which improves the robustness of the device against external disturbance, prevents misalignment of the image-formation positions, and also improves the spatial resolution of measurement. Moreover, since only the reflection of light is used to generate the optical path length difference, it is possible to increase the light utilization efficiency.
The spectroscopic analysis device of the present embodiment is a spectroscopic analysis device that uses Fourier spectroscopy to discriminate and identify a measurement target or a substance contained in the measurement target, and is characterized by a mechanism that forms interfering light.
The measurement target whose substance is to be discriminated and identified by the spectroscopic analysis device of the present embodiment is not particularly limited. The measurement target may be gas, liquid, or solid. Also, the substance to be discriminated and identified is not limited, and may be a substance that allows discrimination and identification of gas, liquid, or solid contained in the measurement target. For example, in the case of gas, it is possible to discriminate and identify carbon-based gases such as methane, carbon dioxide, and the like, natural gases such as ammonia and the like, and industrial gases.
First, description will be made on an interfering light formation mechanism M of the present embodiment (hereinafter sometimes simply referred to as “interfering light formation mechanism M”).
As shown in
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Furthermore, the movable reflection part MR is provided alongside the fixed reflection part FR (see
Note that
Since the interfering light formation mechanism M has the configuration as described above, when supplied light L is made incident on the first reflection surface SR1 and the third reflection surface SR3 of the interfering light formation mechanism M, the supplied light L is reflected in the following manner.
First, it is assumed that the supplied light L is parallel light whose optical axis is parallel to both the base plane BP and the movement direction of the movable reflection part MR, and that the supplied light L is made incident so that the intermediate line of the supplied light L (intermediate line in the up and down direction for
When such supplied light L is made incident on the interfering light formation mechanism M, half of the supplied light L is made incident on the first reflection surface SR1, and the other half of the supplied light L is made incident on the third reflection surface SR3. That is, the supplied light L is made incident on either one of the first reflection surface SR1 and the third reflection surface SR3. Hereinafter, the supplied light L made incident on the first reflection surface SR1 is referred to as “supplied light LA”, and the supplied light L made incident on the third reflection surface SR3 is referred to as “supplied light LB”.
The supplied light LA is reflected toward the second reflection surface SR2 as reflected light RA1 maintaining the state of parallel light at the first reflection surface SR1 (see
When the reflected light RA1 is made incident on the second reflection surface SR2, the reflected light RA1 is reflected as reflected light RA2 maintaining the state of parallel light at the second reflection surface SR2 (see
The reflected light RA2 and the reflected light RB2 have a phase difference (optical path length difference) generated according to the movement amount of the movable reflection part MR in the direction parallel to the base plane BP. Therefore, the movement amount of the movable reflection part MR can be changed to collect the reflected light RA2 and the reflected light RB2 to form the interfering reflected light RF (see
Since the interfering light formation mechanism M of the present invention has the above configuration, the interfering reflected light RF can be formed using entirety of the supplied light L. Therefore, even if the intensity of the supplied light L is weak, the interfering reflected light RF can form an interference image that can form an interferogram with some degree of signal intensity.
Note that the angle θf formed between the first reflection surface SR1 and the second reflection surface SR2 and the angle θm formed between the third reflection surface SR3 and the fourth reflection surface SR4 may not necessarily be right angles. However, forming the angle θf and the angle θm at right angles enables the optical axis of the supplied light LA and the optical axis of the supplied light LB incident on the first reflection surface SR1 and the third reflection surface SR3, respectively, to be parallel with the optical axis of the reflected light RA2 and the optical axis of the reflected light RB2 reflected at the second reflection surface SR2 and the fourth reflection surface SR4, respectively. As a result, the device can be made compact and improved in its robustness.
Next, a spectroscopic analysis device 1 of the present embodiment will be described.
As shown in
Hereinafter, description of configurations will be provided. The configurations provided below are examples, and a configuration other than the following configurations may be adopted as long as exerting similar functions.
Hereinafter, interfering reflected light RFA means the entirety of the supplied light LA, the reflected light RA1, and the reflected light RA2 described above, and interfering reflected light RFB means the entirety of the supplied light LB, the reflected light RB1, and the reflected light RB2. For example, the optical path length of the interfering reflected light RFA means the length totalizing the optical path lengths of the supplied light LA, the reflected light RA1, and the reflected light RA2, and the optical path length of the interfering reflected light RFB means the length totalizing the optical path lengths of the supplied light LB, the reflected light RB1, and the reflected light RB2.
Furthermore, the supplied light L is a concept that includes both the supplied light LA and the supplied light LB. That is, the entirety of light supplied from the light supply part 3 to the interfering light formation part 10 is the supplied light L. Furthermore, the interfering reflected light RF is a concept that includes both the interfering reflected light RFA and the interfering reflected light RFB. That is, the entirety of light supplied from the interfering light formation part 10 to the detection part 5 is the interfering reflected light RF.
The light supply part 3, which supplies the object light BL to the interfering light formation part 10 as the supplied light L, has a supply part 3a and a diffraction grating 4. The supply part 3a supplies the object light to the interfering light formation part 10 as the supplied light L whose optical axis is parallel to the base plane BP of the interfering light formation part 10 and the movement direction of the movable reflection part 20. For example, as the supply part 3a, an optical fiber, a lens, a mirror, a reflective optical unit, or the like can be employed.
Furthermore, the diffraction grating 4 is provided between the supply part 3a and the interfering light formation part 10. The diffraction grating 4 functions as a deflection filter, and has a function of allowing only light of waves in a specific direction to pass through. Between the diffraction grating 4 and the interfering light formation part 10, an incident parallel light formation part 25 is provided.
The detection part 5 has a function of measuring the light intensity of the interfering reflected light RF supplied from the interfering light formation part 10. Specifically, the detection part 5 has a detection surface 5a provided with light-receiving elements, and the detection part 5 is arranged at a position that allows an interference image to be formed on the detection surface 5a. The detection part 5 has a function of measuring the light intensity of interference fringes formed on the detection surface 5a. In addition, the detection part 5 has a function of supplying a signal related to the light intensity detected by the light-receiving elements of the detection surface 5a (light intensity of the interference fringes) to the control part 7.
The detection part 5 is not particularly limited as long as having the functions described above, and a two-dimensional CCD camera, a CMOS camera, or the like may be employed, for example. Like the two-dimensional CCD camera, by using the detection part 5 with the detection surface 5a having a plurality of light-receiving elements arrayed two-dimensionally, it is possible to obtain two-dimensional distribution of the substance in the measurement target. For example, in the measurement target, it also becomes possible to two-dimensionally acquire the presence position of the substance or acquire two-dimensional distribution of concentration or the like.
The control part 7 has an analysis function of analyzing a signal related to the light intensity of the interference image detected by the detection part 5. Specifically, the control part 7 has a function of forming an interferogram on the basis of information related to the optical path length difference between the interfering reflected light RFA and the interfering reflected light RFB and a signal related to the light intensity supplied from the detection part 5, and performing Fourier transform of the interferogram to acquire a spectral characteristic.
Note that the method by which the control part 7 acquires the information related to the optical path length difference between the interfering reflected light RFA and the interfering reflected light RFB is not particularly limited. For example, in the case of manually adjusting the movement amount of the moving part 30 of the interfering light formation part 10 (i.e., the movement amount of the movable reflection part 20), an operator may input the movement amount of the moving part 30 to the control part 7. Furthermore, in the case where the moving part 30 is configured to automatically move the movable reflection part 20, the movement amount of the moving part 30 may be input from the moving part 30 to the control part 7. Furthermore, in the case where the moving part 30 is configured to automatically move the movable reflection part 20, the control part 7 may have a function of controlling operation of the moving part 30 to control the operation amount of the movable reflection part 20. In such case, the control part 7 can set and adjust the optical path length difference between the interfering reflected light RFA and the interfering reflected light RFB.
Furthermore, in the case where the control part 7 has a function of controlling the movement amount of the movable reflection part 20, it is possible to match the movement of the movable reflection part 20, that is, the movement of the third reflection surface 21a and the fourth reflection surface 22a of the movable reflection part 20, with a frame rate of the detection part 5. That is, it becomes also possible for the detection part 5 to acquire the light intensity of the interfering reflected light RF at equal intervals, thus facilitating Fourier transform of the interferogram formed on the basis of the acquired light intensity. As a result, signal processing to acquire the spectral characteristic can be facilitated and data processing time can be shortened.
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As shown in
Note that the configuration for providing the first reflection surface 17a and the second reflection surface 18a on the fixed reflection part 16 is not particularly limited. The body of the fixed reflection part 16 may be processed to form the first reflection surface 17a and the second reflection surface 18a, or the fixed reflection part 16 may be provided with a member having a mirror-finished surface, such as a mirror, and use the mirror-finished surface of this member as the first reflection surface 17a and the second reflection surface 18a.
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Note that the configuration for allowing the movable reflection part 20 to move relative to the fixed reflection part 16 along the movement direction S is not particularly limited. For example, a guide mechanism such as a rail or the like that guides the movable reflection part 20 along the movement direction S may be provided to make the movable reflection part 20 move by being guided by the guide mechanism, or a moving part 30 to be described later may have a mechanism that guides the movement of the movable reflection part 20.
Furthermore, the configuration for providing the third reflection surface 21a and the fourth reflection surface 22a on the movable reflection part 20 is not particularly limited. The body of the movable reflection part 20 may be processed to form the third reflection surface 21a and the fourth reflection surface 22a, or the movable reflection part 20 may be provided with a member having a mirror-finished surface, such as a mirror, and use the mirror-finished surface of this member as the third reflection surface 21a and the fourth reflection surface 22a.
As shown in
Note that the moving part 30 desirably has a function of allowing the movable reflection part 20 to accurately move at constant velocity (for example, 30 μm/s or less) along the movement direction S.
Furthermore, the moving part 30 may be configured to manually or automatically move the movable reflection part 20. Note that, in the case where the moving part 30 is configured to automatically move the movable reflection part 20, it becomes easy to accurately adjust the optical path difference between the interfering reflected light RFA and the interfering reflected light RFB generated when the movable reflection part 20 moves. Furthermore, it is possible to obtain an advantage that the movable reflection part 20 can be moved at constant velocity.
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Furthermore, instead of providing the incident parallel light formation part 25 in the interfering light formation part 10, a mechanism having the equivalent function as the incident parallel light formation part 25 may be provided in the light supply part 3. That is, such a configuration may be adopted in which the interfering light formation part 10 without the incident parallel light formation part 25 is provided and the light supply part 3 has the supply part 3a, the diffraction grating 4, and the collecting lens whose focal point is at the position of the diffraction grating 4. Furthermore, in addition to the light supply part 3 and the interfering light formation part 10, the incident parallel light formation part 25 may be provided between the light supply part 3 and the interfering light formation part 10.
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Furthermore, as shown in
Note that, instead of providing the light collection part 28 in the interfering light formation part 10, a mechanism having the equivalent function as the light collection part 28 may be provided in the detection part 5. That is, such a configuration may be adopted in which the interfering light formation part 10 without the light collection part 28 is provided and the detection part 5 has a camera or the like having the detection surface 5a and the collecting lens whose focal point is at the position of the detection surface 5a. In such case, the detection part 5 may also have the light-traveling direction change member 29, if necessary. Furthermore, in addition to the detection part 5 and the interfering light formation part 10, the light collection part 28 may be provided between the light supply part 3 and the interfering light formation part 10.
Since the spectroscopic analysis device 1 of the present embodiment has the configuration as described above, making the object light supplied from the measurement target through the light supply part 3 incident on the interfering light formation part 10 enables formation of an interference image on the detection surface 5a of the detection part 5. As a result, by analyzing the interference image with the control part 7, it is possible to discriminate and identify the measurement target or a substance contained in the measurement target.
Note that the spectroscopic analysis device 1 of the present embodiment may not necessarily have the control part 7. In such case, the detection part 5 or a device different from the detection part 5 may be provided with a function of storing, as measurement data, a signal related to the light intensity measured on the detection surface 5a of the detection part 5 and a signal related to the optical path length difference between the interfering reflected light RFA and interfering reflected light LFB, and the measurement data stored using this function may be analyzed by another analysis device.
Next, description will be made on an interfering light formation mechanism MA of a second embodiment (hereinafter sometimes simply referred to as “interfering light formation mechanism MA”).
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As shown in
Note that, in the above configuration, in the first reflection part R1, a portion where the incident reflection surface SI described above is provided corresponds to an incident part in claim 6 of CLAIMS, and a portion where the outgoing reflection surface SO described above is provided corresponds to an outgoing part in claim 6 of CLAIMS.
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The first reflection surface SR1 is provided so as to face the incident reflection surface SI of the first reflection part R1. Specifically, the first reflection surface SR1 is provided to allow, when light parallel to the normal of the symmetry plane SP (hereinafter referred to as “supplied light L”) is made incident on the incident reflection surface SI of the first reflection part R1, a part of the reflected light of the incident light (hereinafter referred to as “incident light RL”) (for
The second reflection surface SR2 is provided so as to face the outgoing reflection surface SO of the first reflection part R1. Specifically, the second reflection surface SR2 is provided so that, when the first reflected light L1 made incident from the first reflection surface SR1 is reflected by the second reflection surface SR2, the reflected light (hereinafter referred to as “second reflected light L2”) becomes incident on the outgoing reflection surface SO (specifically, the upper portion of the outgoing reflection surface SO). Moreover, the second reflection surface SR2 is provided so that the angle formed between the optical axis of the second reflected light L2 and the symmetry plane SP becomes the same angle as the angle formed between the optical axis of the incident light LI and the symmetry plane SP. The arrangement as described above leads the entirety of the second reflected light L2 to be reflected toward the outgoing reflection surface SO.
In this situation, since the second reflection surface SR2 is provided plane-symmetrically with the first reflection surface SR1 with respect to the symmetry plane SP, with the above configuration, a reflection angle θo of the outgoing reflection surface SO (angle θo formed between the second reflected light L2 and the light reflected at the outgoing reflection surface SO in
As shown in
The third reflection surface SR3, which is a surface provided in parallel to the first reflection surface SR1, is provided so as to have a positional relationship to the incident reflection surface SI substantially similar to the positional relationship of the first reflection surface SR1. That is, the third reflection surface SR3 is provided so as to allow, when the supplied light L is made incident on the incident reflection surface SI of the first reflection part R1, a part of the incident light RL (for
The fourth reflection surface SR4, which is a surface provided in parallel to the second reflection surface SR2, is provided so as to have a positional relationship to the outgoing reflection surface SO substantially similar to the positional relationship of the second reflection surface SR2. That is, the fourth reflection surface SR4 is provided so that, when the third reflected light L3 made incident from the third reflection surface SR3 is reflected by the fourth reflection surface SR4, the reflected light (hereinafter referred to as “fourth reflected light L4”) becomes incident on the outgoing reflection surface SO (specifically, the lower portion of the outgoing reflection surface SO). Moreover, the fourth reflection surface SR4 is provided so that the angle formed between the optical axis of the fourth reflected light L4 and the symmetry plane SP becomes the same angle as the angle formed between the optical axis of the incident light LI and the symmetry plane SP. That is, the fourth reflection surface SR4 is provided so that a reflection angle θ4 thereof (angle θ4 formed between the third reflected light L3 and the fourth reflected light L4 in
In addition, the movable reflection part MR is provided so that the third reflection surface SR3 and and the fourth reflection surface SR4 can be approximated and separated with respect to the first reflection part R1 with being maintained in the above state. Specifically, the movable reflection part MR is provided so that the third reflection surface SR3 and the fourth reflection surface SR4 can be moved in a direction parallel to the symmetry plane SP (right and left direction for
Moreover, the movable reflection part MR is provided adjacently to the fixed reflection part FR so as to form almost no gap between the end edge of the first reflection surface SR1 on the third reflection surface SR3 side (end edge in the downward direction for
Since the interfering light formation mechanism MA of the second embodiment has the above configuration, it is possible to form an interference image by the interfering reflected light RF using the entirety of the supplied light L. As a result, even if the intensity of the supplied light L is weak, it is possible to form an interference image that can form an interferogram with some degree of signal intensity.
Furthermore, in the interfering light formation mechanism MA of the second embodiment, the entirety of the supplied light L is made incident on one first reflection surface SR1 of the first reflection part R1, and the entirety of the incident light RL reflected at the first reflection surface SR1 can be supplied to the second reflection part R2. Moreover, the incident light RL is reflected at the first to fourth reflection surfaces SR1 to SR4 of the second reflection part R2 with almost no loss and then made incident on the outgoing reflection surface SO as the second reflected light L2 and the fourth reflected light L4. The second reflected light L2 made incident on the outgoing reflection surface SO also produces almost no loss and can be used to form the interference image as the interfering reflected light RF. That is, the interfering light formation mechanism MA of the second embodiment can use the entirety of the supplied light L to form the interference image, which increases the utilization efficiency of the supplied light L.
Furthermore, since the interfering light formation mechanism MA of the second embodiment has the above configuration, all of the reflection angle θi of the incident reflection surface SI, the reflection angles θ1 to θ4 of the first to fourth reflection surfaces SR1 to SR4, and the reflection angle θo of the outgoing reflection surface SO become the same angle, and this relationship does not change even when the movable reflection part MR is moved along the direction parallel to the symmetry plane SP (right and left direction for
Note that the optical axis of the interfering reflected light RF means the optical axis of the beams that include both the interfering reflected light RF1, which is the second reflected light L2 reflected at the outgoing reflection surface SO, and the interfering reflected light RF2, which is the fourth reflected light L4 reflected at the outgoing reflection surface SO.
Next, a spectroscopic analysis device 1A of the second embodiment will be described.
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The spectroscopic analysis device 1A of the second embodiment (hereinafter sometimes simply referred to as “spectroscopic analysis device 1A”) has the light supply part 3 (see
Hereinafter, description of configurations will be provided. The configurations provided below are examples, and another configuration other than the following configurations may be adopted as long as exerting similar functions.
The spectroscopic analysis device 1A includes a frame part 2. The frame part 2 has a base member 2a, a wall member 2b erected on the base member 2a, and a frame body 2c. The base member 2a has a base surface bs (see
Note that the structure of the frame part 2 is not limited to the structure described above or the structure shown in
The light supply part 3 supplies the object light to the interfering light formation part 10 as the supplied light L. Specifically, the light supply part 3 collects the object light and then supplies, as the supplied light L, the collected light to an incident reflection surface 12a of the incident member 12 of the interfering light formation part 10. To be more specific, the light supply part 3 has a function of forming the supplied light L so that the optical axis of the supplied light L is positioned on the optical-axis plane parallel to the base surface bs of the base member 2a (corresponding to the plane V for
Moreover, the light supply part 3 is provided so that the entirety of the supplied light L is made incident on the incident reflection surface 12a of the incident member 12 of the interfering light formation part 10. In this context, the expression “the entirety of the supplied light L is made incident on the incident reflection surface 12a of the incident member 12 of the interfering light formation part 10” means that, of the supplied light L that has passed through the slit 4 to be described later, the entirety of the supplied light L to be used for forming the interfering reflected light RF is made incident on the incident reflection surface 12a of the incident member 12 of the interfering light formation part 10. Furthermore, the expression “the entirety of the supplied light L is made incident on the incident reflection surface 12a of the incident member 12 of the interfering light formation part 10” includes both of the case where the entirety of the supplied light L that has passed through the slit 4 to be described later is made incident on the incident reflection surface 12a of the incident member 12 of the interfering light formation part 10 and the case where a small part of the supplied light L that has passed through the slit 4 to be described later is not made incident on the incident reflection surface 12a of the incident member 12 but the large part of the supplied light L is made incident on the incident reflection surface 12a of the incident member 12 of the interfering light formation part 10.
Note that, for the light supply part 3, it is possible to use a general objective lens, a parabolic mirror, or the like as a member that forms the supplied light L. However, the member is not particularly limited as long as satisfying the functions described above.
The slit 4 is provided between the light supply part 3 and the incident reflection surface 12a of the incident member 12 of the interfering light formation part 10. The slit 4, which functions as, for example, a deflection filter, is provided at the position of the focal point FP described above.
Note that the slit 4 is not necessarily provided. However, providing the slit 4 enables the interference image to be formed only with light of waves in a specific direction, thereby increasing the accuracy of discriminating and identifying the substance. Furthermore, a pinhole may be provided instead of the slit 4.
The interfering light formation part 10 has substantially the same configuration as the interfering light formation mechanism MA described above.
The interfering light formation part 10 has the first reflection part 11, the second reflection part 15, and the moving part 30. The first reflection part 11 and the second reflection part 15 have a function substantially equivalent to that of the first reflection part R1 and the second reflection part R2 of the interfering light formation mechanism MA of the second embodiment described above. In the following, description of portions having the equivalent configuration or equivalent disposition as the interfering light formation mechanism MA of the second embodiment will be omitted as appropriate.
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Furthermore, on the surface s of the wall member 2b, an outgoing member 13 of the first reflection part 11 is provided. The outgoing member 13 has an outgoing reflection surface 13a that allows the reflected light (the second and fourth reflected light L2 and L4 described above) supplied from the second reflection part 15 to be incident thereon, and is arranged so that the outgoing reflection surface 13a becomes plane-symmetrical with the incident reflection surface 12a of the incident member 12 with respect to the symmetry plane SP orthogonal to the optical axis of the supplied light L. The outgoing reflection surface 13a is a parabolic surface, and is provided so as to reflect the reflected light toward the detection part 5 to be described later as the interfering reflected light RF.
Note that, in the above configuration, in the first reflection part 11, the incident member 12 described above corresponds to the incident part in claim 6, and the outgoing member 13 described above corresponds to the outgoing part in claim 6.
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Furthermore, the first mirror 17 is provided so that the reflection angle θ1 of the reflection surface 17a and the reflection angle θi of the incident reflection surface 12a of the incident member 12 of the first reflection part 11 become the same angle and, additionally, the optical axis of the first reflected light L1 becomes parallel to the optical-axis plane (see
On the other hand, the second mirror 18 is provided so that the reflection angle θ2 of the reflection surface 18a and the reflection angle θo of the outgoing reflection surface 13a of the outgoing member 13 of the first reflection part 11 become the same angle and, additionally, the optical axis of the second reflected light L2 becomes parallel to the optical-axis plane (see
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Furthermore, the third mirror 21 is provided so that the reflection angle θ3 of the reflection surface 21a and the reflection angle θi of the incident reflection surface 12a of the incident member 12 of the first reflection part 11 become the same angle and, additionally, the optical axis of the third reflected light L3 becomes parallel to the optical-axis plane (see
On the other hand, the fourth mirror 22 is provided so that the reflection angle θ4 of the reflection surface 22a and the reflection angle θo of the outgoing reflection surface 13a of the outgoing member 13 of the first reflection part 11 become the same angle and, additionally, the optical axis of the fourth reflected light L4 becomes parallel to the optical-axis plane (see
Moreover, the movable reflection part 20 is provided adjacently to the fixed reflection part 16 so as to form almost no gap between the end edge of the first mirror 17 of the fixed reflection part 16 on the third mirror 21 side (end edge in the downward direction for
The moving part 30 is provided on the base surface bs of the base member 2a of the frame part 2 as described above. The moving part 30 has a base part 31, the movable table 32 that is provided to be movable in one direction (right and left direction in
Therefore, when the supplied light L is made incident on the interfering light formation part 10, the supplied light L is reflected at the incident reflection surface 12a of the incident member 12 to become the incident light RL, and the incident light RL is made incident on the first mirror 17 of the fixed reflection part 16 of the second reflection part 15 and the third mirror 21 of the movable reflection part 20. The incident light LI is reflected at the reflection surface 17a of the first mirror 17 and the reflection surface 18a of the second mirror 18 to become the first reflected light L1 and the third reflected light L3, and the first reflected light L1 and the third reflected light L3 are made incident on the second mirror 18 of the fixed reflection part 16 and the fourth mirror 22 of the movable reflection part 20, respectively. The first reflected light L1 and the third reflected light L3 are reflected at the reflection surface 18a of the second mirror 18 and the reflection surface 22a of the third mirror 22, respectively to become the second reflected light L2 and the fourth reflected light L4, and the second reflected light L2 and the fourth reflected light L4 are made incident on the outgoing reflection surface 13a of the outgoing member 13. Then, the second reflected light L2 and the fourth reflected light L4 are reflected at the outgoing reflection surface 13a of the outgoing member 13 and emitted from the interfering light formation part 10 as the interfering reflected light RF, which is a combination of the interfering reflected light RF1 and RF2. At this time, since the optical axis of the suppled light L and the optical axis of the interfering reflected light RF are coaxial, and the optical axes of the first to fourth reflected light L1 to L4 are all parallel to the optical-axis plane, the interfering reflected light RF1 and RF2 form focal points at the same position at a predetermined distance from the outgoing reflection surface 13a of the outgoing member 13. That is, the focal points of the interfering reflected light RF1 and RF2 match each other, and interference images can be formed at this focal point.
Furthermore, when the movable table 32 of the moving part 30 is moved, it is possible to generate an optical path difference between the optical path of a first interfering reflected light beam (beams constituted by the incident light RL, the first reflected light L1, the second reflected light L2, and the interfering reflected light RF1) and the optical path of a second interfering reflected light beam (beams constituted by the incident light RL, the third reflected light L2, the fourth reflected light L4, and the interfering reflected light RF2). Moreover, it is possible to generate a phase difference in substantially-common optical paths (specifically, substantially-common optical paths when viewed from the normal direction of the optical-axis plane), and therefore it is also possible to prevent misalignment of the positions where both beams form an image when the optical path length is changed by moving the movable reflection part 20.
Note that the moving part 30 is not particularly limited as long as having a function of accurately moving the movable table 32 in one direction at constant velocity (for example, 30 μm/s or less). For example, a commercially-available uniaxial stage or the like can be used as the moving part 30.
Furthermore, the movable table 32 may be configured to be manually or automatically moved. Note that, in the case where the movable table 32 is configured to be automatically moved, it becomes easy to accurately adjust the optical path difference. Furthermore, an advantage of being able to move the movable reflection part 20 at constant velocity can be obtained.
The detection part 5 has a function of measuring the light intensity of the interfering reflected light RF supplied from the outgoing reflection surface 13 of the interfering light formation part 10. Specifically, the detection part 5 has the detection surface 5a provided with light-receiving elements, and the detection part 5 is arranged so as to form an interference image on the detection surface 5a. That is, the detection part 5 can have a function of measuring the light intensity of interference fringes formed on the detection surface 5a. In addition, the detection part 5 has a function of supplying a signal related to the light intensity detected by the light-receiving elements of the detection surface 5a (light intensity of the interference fringes) to the control part.
The detection part 5 is not particularly limited as long as having the functions described above, and a two-dimensional CCD camera, a CMOS camera, or the like may be employed. Like the two-dimensional CCD camera, by using the detection part 5 with the detection surface 5a having a plurality of light-receiving elements arrayed two-dimensionally, it is possible to obtain two-dimensional distribution of the substance in the measurement target. For example, in the measurement target, it is also possible to two-dimensionally acquire the presence position of the substance or acquire two-dimensional distribution of concentration or the like.
The control part has an analysis function of analyzing a signal related to the light intensity of the interference image detected by the detection part 5. Specifically, the control part has a function of analyzing the optical path length difference between the interfering reflected light RF1 and RF2 and a signal related to the light intensity supplied from the detection part 5 to form an interferogram, and performing Fourier transform of the interferogram to acquire a spectral characteristic.
Note that, in the case where the moving mechanism of the moving part 30 is configured to automatically move the movable table 32, the control part may have a function of controlling operation of the moving mechanism. With such function, it is possible to match the movement of the movable table 32, i.e., movement of the third mirror 21 and the fourth mirror 22 of the movable reflection part 20 with a frame rate of the camera. That is, since the light intensity can be acquired at equal intervals, Fourier transform of the interferogram formed on the basis of the acquired light intensity is facilitated. As a result, signal processing to acquire the spectral characteristic can be facilitated and data processing time can be shortened.
Since the spectroscopic analysis device 1A of the second embodiment has the configuration as described above, making the object light incident on the interfering light formation part 10 through the light supply part 3 enables formation of an interference image on the detection surface 5a of the detection part 5. As a result, by analyzing the interference image with the control part, it is possible to discriminate and identify the substance contained in the measurement target.
Moreover, since it is possible to use nearly entirety of the object light supplied through the light supply part 3 to form an interference image, the utilization efficiency of the supplied light L can be increased and the accuracy of discriminating and identifying the substance contained in the measurement target can be increased.
Note that the spectroscopic analysis device 1A of the second embodiment is not necessarily provided with the control part. In such case, a function of storing the signals related to the light intensity supplied to the control part and the optical path length difference between the interfering reflected light RF1 and RF2 as measurement data may be provided, and the measurement data may be analyzed by another analysis device.
Regarding the spectroscopic analysis device 1A of the second embodiment, the case has been described as above where the incident reflection surface 12a of the incident member 12 of the incident part of the first reflection part 11 and the outgoing reflection surface 13a of the outgoing member 13 are parabolic surfaces. However, the incident reflection surface 12a of the incident member 12 of the first reflection part 11 and the outgoing reflection surface 13a of the outgoing member 13 may be flat surfaces. That is, as the configuration of the interfering light formation mechanism to be employed in the spectroscopic analysis device 1A of the second embodiment, it is possible to employ an interfering light formation mechanism MB (interfering light formation mechanism MB of a third embodiment) in which the incident reflection surface SI and the outgoing reflection surface SO of the first reflection part R1 are flat surfaces.
Hereinafter, description will be made on the interfering light formation mechanism MB of the third embodiment in which the incident reflection surface SI and the outgoing reflection surface SO of the first reflection part R1 are flat surfaces.
As shown in
As shown in
The first reflection part R1 has a parallel light formation part PP at a position facing the incident reflection surface SI. The parallel light formation part PP is, for example, a collecting lens or the like, and supplies the supplied light L made incident on the incident reflection surface SI as parallel light to the incident reflection surface SI.
Furthermore, the first reflection part R1 includes a light collection part CP at a position facing the outgoing reflection surface SO. The light collection part CP is, for example, a collecting lens or the like, and collects the interfering reflected light RF that is parallel light reflected at the outgoing reflection surface SO.
Note that, in the above configuration, in the first reflection part R1, a portion where the incident reflection surface SI described above is provided and the parallel light formation part PP correspond to the incident part in claim 6 of CLAIMS, and a portion where the outgoing reflection surface SO described above is provided and the light collection part CP correspond to the outgoing part in claim 6 of CLAIMS.
As shown in
As shown in
The first reflection surface SR1 is provided so as to face the incident reflection surface SI of the first reflection part R1. Specifically, the first reflection surface SR1 is provided so as to allow, when light parallel to the normal of the symmetry plane SP (hereinafter referred to as “supplied light L”) is made incident on the incident reflection surface SI of the first reflection part R1, a part of the reflected light of the incident light (hereinafter referred to as “incident light RL”) (for
The second reflection surface SR2 is provided so as to face the outgoing reflection surface SO of the first reflection part R1. Specifically, the second reflection surface SR2 is provided so that, when the first reflected light L1 made incident from the first reflection surface SR1 is reflected by the second reflection surface SR2, the reflected light (hereinafter referred to as “second reflected light L2”) becomes incident on the outgoing reflection surface SO (specifically, the upper portion of the outgoing reflection surface SO). Moreover, the second reflection surface SR2 is provided so that the angle formed between the optical axis of the second reflected light L2 and the symmetry plane SP becomes the same angle as the angle formed between the optical axis of the incident light LI and the symmetry plane SP. The arrangement as described above leads the entirety of the second reflected light L2 to be reflected toward the outgoing reflection surface SO.
In this situation, since the second reflection surface SR2 is provided plane-symmetrically with the first reflection surface SR1 with respect to the symmetry plane SP, with the above configuration, the reflection angle θo of the outgoing reflection surface SO (angle θo formed between the second reflected light L2 and the light reflected at the outgoing reflection surface SO in
As shown in
The third reflection surface SR3, which is a surface provided in parallel to the first reflection surface SR1, is provided so as to have a positional relationship to the incident reflection surface SI substantially similar to the positional relationship of the first reflection surface SR1. That is, the third reflection surface SR3 is provided so as to allow, when the supplied light L is made incident on the incident reflection surface SI of the first reflection part R1, a part of the incident light RL (for
The fourth reflection surface SR4, which is a surface provided in parallel to the second reflection surface SR2, is provided so as to have a positional relationship to the outgoing reflection surface SO substantially similar to the positional relationship of the second reflection surface SR2. That is, the fourth reflection surface SR4 is provided so that, when the third reflected light L3 made incident from the third reflection surface SR3 is reflected by the fourth reflection surface SR4, the reflected light (hereinafter referred to as “fourth reflected light L4”) becomes incident on the outgoing reflection surface SO (specifically, the lower portion of the outgoing reflection surface SO). Moreover, the fourth reflection surface SR4 is provided so that the angle formed between the optical axis of the fourth reflected light L4 and the symmetry plane SP becomes the same angle as the angle formed between the optical axis of the incident light LI and the symmetry plane SP. That is, the fourth reflection surface SR4 is provided so that the reflection angle θ4 thereof (angle θ4 formed between the third reflected light L3 and the fourth reflected light L4 in
In addition, the movable reflection part MR is provided so that the third reflection surface SR3 and and the fourth reflection surface SR4 can be approximated and separated with respect to the first reflection part R1 with being maintained in the above state. Specifically, the movable reflection part MR is provided so that the third reflection surface SR3 and the fourth reflection surface SR4 can be moved in a direction parallel to the symmetry plane SP (right and left direction in
Moreover, the movable reflection part MR is provided adjacently to the fixed reflection part FR so as to form almost no gap between the end edge of the first reflection surface SR1 on the third reflection surface SR3 side (end edge in the downward direction for
Since the interfering light formation mechanism MB of the third embodiment has the above configuration, it is possible to form an interference image by the interfering reflected light RF using the entirety of the supplied light L. As a result, even if the intensity of the supplied light L is weak, it is possible to form an interference image that can form an interferogram with some degree of signal intensity.
Furthermore, since the interfering light formation mechanism MB of the third embodiment has the above configuration, all of the reflection angle θi of the incident reflection surface SI, the reflection angles θ1 to θ4 of the first to fourth reflection surfaces SR1 to SR4, and the reflection angle θo of the outgoing reflection surface SO become the same angle, and this relationship does not change even when the movable reflection part MR is moved (see
Note that the optical axis of the interfering reflected light RF means the optical axis of the beams that include both the interfering reflected light RF1, which is the second reflected light L2 reflected at the outgoing reflection surface SO, and the interfering reflected light RF2, which is the fourth reflected light L4 reflected at the outgoing reflection surface SO.
As described above, regarding the interfering light formation mechanism MB, description has been made on the case where both the incident reflection surface SI and the outgoing reflection surface SO of the first reflection part R1 are flat surfaces. However, also in the case where the incident reflection surface S of the first reflection part R1 is formed as a flat surface, the outgoing reflection surface SO may be formed as a parabolic surface. In such case, need to provide the light collection part CP is eliminated.
Note that, in the case where the outgoing reflection surface SO is formed as a parabolic surface, the incident reflection surface SI of the first reflection part R1 is not plane-symmetrical with the outgoing reflection surface SO. However, if the reflection angle θo of the outgoing reflection surface SO is provided so as to form the same angle as the reflection angle θi of the incident reflection surface SI, it is possible to obtain the interfering reflected light RF whose optical axis is the same as the case where both the incident reflection surface SI and the outgoing reflection surfaces SO of the first reflection part R1 are formed as flat surfaces.
It was confirmed that use of the spectroscopic analysis device having the above-described functions of the present invention enables prevention of misalignment of the image-formation positions of the first interfering reflected light beam and the second interfering reflected light beam even when the optical path length is changed.
In an experiment, a laser beam having a wavelength of 635 nm was made incident from a small laser-beam source (CMP-635-1-D) in the spectroscopic analysis device to change the optical path length, and the interference image formed on the detection part (CMOS camera) was confirmed.
Note that, in the experiment, the spectroscopic analysis device having the structure shown in
Note that the reflection angles θi of the parabolic surfaces of the incident member and the outgoing member (i.e., reflection angles θ1 to θ4 of the first to fourth mirrors (see
The third mirror and the fourth mirror of the movable reflection part were manually moved by a micro gauge provided in the moving part.
Results are shown in
In
It was confirmed that the spectroscopic analysis device having the above-described functions of the present invention can two-dimensionally form an interference image of gas.
For the experiment, the spectroscopic analysis device having the configuration as shown in
In the experiment, a black body (whose temperature is 160° C.) was installed at a position 160 mm distant from the spectroscopic analysis device, to bring a state of photographing the black body by the CMOS camera of the spectroscopic analysis device. In this state, gas was injected into the space between the black body and the spectroscopic analysis device, and the interference image of the object light obtained from the gas was photographed. Then, the photographed interference image was analyzed to form an interferogram at pixels of the CMOS camera, and the interferogram was used to form a visualized image of the gas.
Note that the gas used was dimethyl ether (DME), and the temperature during the experiment was 20° C. Furthermore, the optical path length difference between the interfering reflected light RFA and LFB was changed by moving the manual stage by manually operating the micro gauge.
Results are shown in
As shown in
Furthermore, as shown in
From the above results, it was confirmed that the spectroscopic analysis device of the present invention can form an accurate interferogram at each position within the two-dimensional plane and can form a clear two-dimensional visible image of the gas, because misalignment of the positions of the interference images is not caused even when the optical path length of the interfering reflected light RFA and the optical path length of the interfering reflected light RFB change.
The spectroscopic analysis device of the present invention is suitable for a system that visualizes gas or detects and analyzes gas.
Number | Date | Country | Kind |
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2022-029016 | Feb 2022 | JP | national |
2022-078453 | May 2022 | JP | national |
2023-023684 | Feb 2023 | JP | national |
Number | Date | Country | |
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Parent | PCT/JP2023/006722 | Feb 2023 | WO |
Child | 18586536 | US |