The present invention relates to a stage for holding a silicon wafer substrate that includes a lamp heater below the stage and has the capability of measuring the temperature of the silicon wafer substrate in a noncontacting manner.
A stage according to the present invention holds a silicon wafer substrate without contacting the silicon wafer substrate, thereby enabling continuous measurement of the temperature at least one point on the silicon wafer substrate.
There have been contact measurement methods using a thermocouple and contactless measurement methods using a radiation thermometer as techniques for measuring the temperature of silicon wafer substrates.
A typical temperature measuring method using a thermocouple is described in Patent Document 3 and therefore description thereof will be omitted herein. Patent Document 1 particularly discloses a method of disposing a thermocouple on a stage.
Patent Document 1 describes a method for providing a temperature-programmed desorption analyzer that makes the controlled temperature of the surface of a sample equal to that of a thermocouple in which at least the top of a sample stage is made from a highly thermal conductive material and a thermocouple and the surface of the sample are brought into contact with the sample stage to heat the sample stage through heat conduction to reduce the difference in temperature between the sample stage and the thermocouple. An embodiment of the method is described in Patent Document 1 in which the top and bottom of the sample stage are made from quartz and an infrared lamp is used to heat the stage. In another method for directly measuring the temperature of a silicon wafer, a thermocouple is provided on the tip of each of pins of a silicon wafer that pierce the stage in such a manner that they are capable of moving vertically, as described in Patent Document 2.
Another method is to use a dummy wafer on which a thermocouple are provided in contact with the wafer (Patent Documents 4 and 5). However, this method is impractical because it is difficult to correct the difference in temperature between a wafer to be processed and the dummy wafer.
None of these contact measuring methods using thermocouples according to the conventional techniques has been capable of readily moving a measurement point.
The contacted measuring methods using a radiation thermometer also have a problem. Conventional radiation thermometers used in a stage equipped with a heater for heating silicon wafer substrates must detect a certain infrared ray because silicon wafer substrates are infrared-transparent. Therefore, an infrared-transparent window made from fluorite is required, which is not only expensive but also causes contamination with Ca produced due to decomposition of the fluorite in an environment in which the fluorite is exposed to highly corrosive vapor.
The method described in Patent Document 1 has a problem that a temperature monitoring thermocouple is heated by transmitted infrared radiation to a temperature higher than that of a sample because the thermocouple senses infrared radiation transmitted through the infrared-transparent quartz.
The method described in Patent Document 2 requires that the thermocouple should be in contact with a silicon wafer all the time in order to measure the temperature of the silicon wafer substrate. Accordingly, there is friction at contacts between the thermocouple and the silicon wafer due to a difference in thermal expansion between them when temperature rises and drops. The friction causes contamination and particles which can decrease yields.
It is extremely difficult to measure an object to be processed that has a high infrared transparency in a lamp-heater-equipped chamber filled with an erosive gas.
First, there is a problem caused by characteristics of lamp heaters. Lamp heaters have the characteristic of irradiating an object to be processed with light emitted from a light source to heat the object. Because of the characteristic of heating with light, heat generated may vary depending on light reception characteristics of objects to be processed. For example, a semiconductor wafer and aluminum plate generate different amount of heat in response to the same amount of light, therefore they have different temperatures. In particular, when a semiconductor wafer to be processed placed in an aluminum chamber is irradiated with light from a heating lamp, the temperature of the semiconductor wafer differs from that of the aluminum chamber. Therefore, measuring the temperature of the aluminum chamber does not mean measuring the temperature of the semiconductor wafer.
Second, there is a problem that it is practically impossible to perform measurement using an infrared thermometer. It may be conceivable that an infrared thermometer can be used to directly measure the temperature of the semiconductor wafer in order to solve the first problem that the temperature of the semiconductor wafer differs from that of the aluminum chamber as described above. However, it was revealed that the temperature of the semiconductor wafer cannot be measured with an infrared thermometer because the semiconductor wafer has high infrared transparency.
Third, there is a problem of the influences of erosive gas. Since an infrared thermometer cannot be used, thermocouples must be used for measurement. However, again, temperatures measured with thermocouples attached to the chamber do not indicate the temperature of the semiconductor wafer because of the first problem described above. On the other hand, measuring the temperature of an object to be processed with a thermocouple directly attached to the object involves attaching and detaching the thermocouples each time processing is performed, which is unfavorable and unrealistic for the field where high processing speeds are required. Furthermore, it is problematic that the thermocouples are exposed to the erosive gas environment in the chamber and therefore are damaged very early. Also, the thermocouples react with the gas to produce particles, which attach to and contaminate an object to be processed.
Fourth, the surface of an object to be measured can change during processing and with this change the surface thermal emissivity of the semiconductor wafer can change, therefore an error can be caused if temperature conversion is performed using a fixed thermal emissivity. The thermal emissivity can drastically vary from approximately 0.2 to 0.8 in an extreme case. As a result, an error of as large as 10% can result at 1,000° C.
[Patent Document 1]: Japanese Patent Application Publication No. 2000-045838
[Patent Document 2]: Japanese Patent Application Publication No. 08-172392
[Patent Document 3]: Japanese Patent No. 3468300
[Patent Document 4]: Japanese Patent No. 3663035 . . . Dummy wafer dotted with recesses
[Patent Document 5]: Japanese Patent No. 2984060 . . . Wafer substrate having inside elongated cavities
An object of the present invention is to propose a temperature measuring method that overcomes drawbacks of conventional contact measuring methods using thermocouples and contacted measuring methods using radiation thermometers.
The present invention proposes a temperature measuring method that effectively uses thermocouples and proposes a stage that implements the measuring method. The stage according to the present invention is as described below.
At least one thermocouple having a piece of silicon attached to its back facing a silicon wafer substrate for sensing temperature is embedded in a stage for holding the silicon wafer substrate attached on the top of a lamp heater in such a manner that the thermocouple is not in contact with the silicon wafer substrate. The temperature of the piece of silicon is measured and the difference in time-varying temperature between the silicon wafer substrate and the piece of silicon due to the difference in thermal mass between the silicon wafer substrate and the piece of silicon is obtained in advance. The obtained difference is used to correct the difference between the silicon wafer substrate and the piece of silicon in time-varying temperature and the temperature of the silicon wafer substrate is measured.
According to the present invention, a silicon wafer substrate stage can be provided that is capable of holding a silicon wafer and has the capability of sensing the temperature of the silicon wafer substrate without being affected by a lamp heater and without contacting the silicon wafer substrate and ozone gas.
By linearly disposing in a cavity multiple thermocouples equipped with a piece of silicon wafer having the same composition as that of a silicon wafer substrate whose temperature is to be measured in an opposite direction to the silicon wafer substrate, information on one-dimensional temperatures of the silicon wafer can be directly and simultaneously obtained. Based on this data, the temperature distribution over the surface of the silicon wafer can be estimated and information about a heater can be excluded to obtain the temperature of a more accurate reaction field at a low cost.
The inventive method can be used for temperature measurement of reaction systems using gasses and chemicals that do not erode quartz and therefore can find wide application.
Using the present invention, temperature can be detected without causing contamination.
Furthermore, a groove is provided in a stage for holding a silicon wafer substrate attached on the top of a lamp heater or an enclosure made from quartz or the like provided on a light-emitting open section side of the lamp heater so that a thermocouple to be embedded is not in contact with an erosive gas. In order to address the first problem described above, an equivalent of an object to be processed is attached to the thermocouple. If the object to be processed is a semiconductor wafer, the thermocouple is attached to a small piece of semiconductor wafer.
A device which has a thermocouple attached to a cutout of an equivalent of an object to be processed is embedded in a lamplight-transparent material such as a stage made from quartz in this way, so that the thermocouple receives the same amount of light that the object to be processed receives and generates a temperature equal to the temperature of the object. Thus, the temperature of the object can be measured through a wire attached to the thermocouple.
In addition, the embedded device structure prevents the device from being affected by an erosive gas or from spattering particles in a process room.
While embodiments of the present invention will be described below, the present invention is not limited to the embodiments.
In order to attach a thermocouple of the present invention, a rectangular parallelepiped cavity (155 mm long×5 mm wide×5 mm high) is provided that extends linearly in parallel to a disc-shaped stage made from quartz of 310 mm in diameter and 8 mm in thickness from one point on a side of the stage. A k-thermocouple K104 from TECH-JAM Co., LTD. is bonded on the front side of a silicon wafer substrate piece that is 3 mm long, 3 mm wide, and 0.76 mm thick and has the same composition and thickness as those of a silicon wafer substrate to be measured by using 0.5 cc of a polyimide adhesive. After the polyimide adhesive is thermoset, the thermocouple is placed in the center of the cavity in such a manner that the thermocouple on the front side of the silicon wafer substrate piece faces the side opposite to a lamp heater. Leads of the thermocouple are connected to predetermined terminals of a 302323 pen recorder from Yokogawa Electric Corporation which is placed in a predetermined place.
The space in the cavity that is not occupied by the thermocouple with the silicon wafer substrate piece is filled with quartz wool. For the purpose of guiding the leads of the thermocouple with the silicon wafer substrate piece, a Teflon (registered trademark) joint is tightly attached to the outlet of the cavity through a fluorocarbon-rubber O-ring. In order to protect the leads of the thermocouple with the silicon wafer substrate piece, a PFA (registered trademark) tube having an inner diameter of 2 mm is inserted in the Teflon (registered trademark) joint. The leads of the thermocouple with the silicon wafer substrate piece are inserted in the PFA (registered trademark) tube and are connected to the predetermined terminal of the 302323 pen recorder from Yokogawa Electric Corporation that is placed in the predetermined place. Thus, the influence of air in the cavity can be reduced, and the leads of the thermocouple with the silicon wafer substrate piece can be protected from external impacts and ambient atmosphere. By connecting the cavity to the ambient air through the PFA (registered trademark) tube, variations in pressure in the cavity during temperature changes can be avoided, improving safety.
If the cavity of the quartz stage has a through structure, multiple such thermocouples with the silicon wafer substrate piece can be disposed in any positions on a silicon wafer substrate so that one-dimensional measurement can be performed.
Embodiments of the present invention will be described with reference to the accompanying drawings.
Five thermocouples 4 for temperature measurement are embedded in an 8-inch silicon wafer 9 and then sealed with a polyimide adhesive 5. A recess is formed for placing the silicon wafer 9 with the thermocouples 4 in contact with the silicon wafer substrate stage 1. After the silicon wafer 9 with the thermocouples 4 is brought into intimate contact with the silicon wafer substrate stage 1, the empty space in the recess is filled with the polyimide adhesive 5 to complete the stage. Two-dimensional temperature information at any number of points can be obtained at a time.
The present invention will be described in further detail with respect to examples.
Number | Date | Country | Kind |
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2004-215957 | Jul 2004 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP05/13559 | 7/25/2005 | WO | 1/5/2007 |