The present patent document relates generally to spin-transfer torque magnetic random access memory and, more particularly, to a magnetic tunnel junction stack having improved performance of the free layer in the magnetic tunnel junction structure.
Magnetoresistive random-access memory (“MRAM”) is a non-volatile memory technology that stores data through magnetic storage elements. These elements are two ferromagnetic plates or electrodes that can hold a magnetic field and are separated by a non-magnetic material, such as a non-magnetic metal or insulator. In general, one of the plates has its magnetization pinned (i.e., a “reference layer”), meaning that this layer has a higher coercivity than the other layer(s) and requires a larger magnetic field or spin-polarized current to change the orientation of its magnetization. The second plate is typically referred to as the free layer and its magnetization direction can be changed by a smaller magnetic field or spin-polarized current relative to the reference layer.
MRAM devices store information by changing the orientation of the magnetization of the free layer. In particular, based on whether the free layer is in a parallel or anti-parallel alignment relative to the reference layer, either a “1” or a “0” can be stored in each MRAM cell. Due to the spin-polarized electron tunneling effect, the electrical resistance of the cell changes due to the orientation of the magnetic fields of the two layers. The cell's resistance will be different for the parallel and anti-parallel states and thus the cell's resistance can be used to distinguish between a “1” and a “0”. One important feature of MRAM devices is that they are non-volatile memory devices, since they maintain the information even when the power is off. The two plates can be sub-micron in lateral size and the magnetization direction can still be stable with respect to thermal fluctuations.
Spin transfer torque or spin transfer switching, uses spin-aligned (“polarized”) electrons to change the magnetization orientation of the free layer in the magnetic tunnel junction (“MTJ”). In general, electrons possess a spin, a quantized number of angular momentum intrinsic to the electron. An electrical current is generally unpolarized, i.e., it consists of 50% spin up and 50% spin down electrons. Passing a current though a magnetic layer polarizes electrons with the spin orientation corresponding to the magnetization direction of the magnetic layer thus produces a spin-polarized current. If a spin-polarized current is passed to the magnetic region of a free layer in the MTJ device, the electrons will transfer a portion of their spin-angular momentum to the magnetization layer to produce a torque on the magnetization of the free layer. Thus, this spin transfer torque can switch the magnetization of the free layer, which, in effect, writes either a “1” or a “0” based on whether the free layer is in the parallel or anti-parallel states relative to the reference layer.
When a current is passed through a magnetic layer (e.g. a polarizer), the spin orientation of the electrons that flow out of the magnetic layer is generally aligned in the direction of the magnetization of the magnetic layer and will exert a spin-transfer torque in that direction (forming a transverse spin current) upon impinging on another magnetic layer. However, due to the conservation of angular moment for the system, the electrons on the opposite side of magnetic layer, those that do not go through the magnetic layer, generally have a spin orientation that is aligned in the direction that is anti-parallel to the magnetization direction of the magnetic layer. The net effect of this process is that the current applied to the magnetic layer undergoes spin filtering, which creates a spin current on one side of the magnetic layer, with spins that are aligned with magnetization direction of the magnetic layer, and a reflected spin current on the other side of the magnetic layer, with spins that are anti-parallel to the magnetization direction of the magnetic layer. This effect occurs upon application of a current to any magnetic layer, including an in-plane polarization layer or an out-of-plane reference magnetic layer. Thus, in a typical MTJ, when switching the magnetization direction of the free layer in one direction (e.g., from the parallel to anti-parallel state) is achieved using spin transfer torque from the transverse spin current, switching the free layer in the other direction (e.g., from the anti-parallel to parallel states) would be achieved using spin transfer torque from the reflected spin current. This is typically accomplished by running electrical current through the MTJ in one direction when switching from the anti-parallel to parallel state and running the electrical current through the MTJ in the other direction when switching from the parallel to anti-parallel state.
The first magnetic layer 114 in the SAF layer 120 is disposed over seed layer 110. SAF layer 120 also has an antiferromagnetic coupling layer 116 disposed over the first magnetic layer 114. Furthermore, a nonmagnetic spacer 140 is disposed on top of MTJ 130 and a polarizer 150 is disposed on top of the nonmagnetic spacer 140. Polarizer 150 is a magnetic layer that has a magnetic direction in its plane, but is perpendicular to the magnetic direction of the reference layer 132 and free layer 136. Polarizer 150 is provided to polarize a current of electrons (“spin-aligned electrons”) applied to MTJ structure 100. Polarizer 150 polarizes the current in a direction perpendicular (orthogonal) to those of the magnetizations of the free magnetic layer 136 and reference magnetic layer 132. Further, one or more capping layers 160 can be provided on top of polarizer 150 to protect the layers below on MTJ stack 100. Finally, a hard mask 170 is deposited over capping layers 160 and is provided to pattern the underlying layers of the MTJ structure 100, using a combination of reactive ion etch (RIE) and ion beam etching (IBE) processes.
Various mechanisms have been proposed to assist the free-layer magnetization switching in MTJ devices. One issue has been that to realize the orthogonal spin transfer effect for in-plane MTJ structures, large spin currents may be required for switching. The need for large switching currents may limit such device's commercial applicability. One way proposed to reduce switching current is to lower the magnetization of the free layer. However, if the effective magnetization of the free layer is lowered significantly, the orthogonal effect has to be limited so that the free-layer does not go into precessional mode that would make the end state of the free-layer magnetization un-deterministic. This defines the operation window for the in-plane OST structures. In an in-plane device, unlike that shown in
In contrast to MTJ structures with an in-plane free layer and perpendicular polarizer perpendicular MTJ structures such as those shown in
In most prior MTJ devices using a polarizer such as polarizer 150, the magnetization direction of polarizer 150 is fixed, which is shown in
The precession of the magnetization vector during switching of the free layer can be assisted by spin transfer torque exerted by the electrons of a spin-polarized current, which is generated in part by the orthogonal polarizer 150. Applying a voltage across the MTJ device 100 produces a charge current through the device. This charge current, in turn, produces a spin-polarized current via spin filtering through the magnetic layers of the device (i.e., the orthogonal polarizer 150 and the reference layer 132). The spin-polarized electrons of the spin-polarized current exerts a spin transfer torque on the magnetic vector 200. This spin transfer torque has an in-plane component of the spin transfer torque 210, which pushes magnetization vector 200′ in the direction of the magnetic vector of polarizer 150 throughout precession of magnetic vector 200′. In addition to the in-plane spin transfer torque 210 from the polarizer, the perpendicular spin transfer torque (not shown), generated by reference layer 132, pulls the magnetic vector 200′ towards the direction antiparallel to its initial direction 200, thereby causing switching of the free layer 136. In devices like those shown in
One solution that has been proposed to overcome this limitation is the use of a precessional spin current (“PSC”) magnetic layer having a magnetization vector that can freely rotate in any magnetic direction, shown in
As seen in on the right-hand side of
However, because of the chirality of perpendicular MTJ structures that utilize a PSC, such as the structure shown in
Thus, in prior devices that utilize in-plane polarization layers having a fixed magnetization direction and having a free magnetic layer 150 that is perpendicular to the plane of the device, once the precession holds, the in-plane spin transfer torque has no net positive effect on the switching mechanism for a full three hundred sixty degree precession. Moreover, in prior devices that utilize a PSC magnetic layer, the in-plane spin transfer torque enhances the switching of the free layer throughout the precession from the first direction to the second direction, but might not enhance the switching of the free layer from the second direction to the first direction.
Therefore, there is a need for a spin torque transfer device that reduces the amount of current needed for switching from both magnetization directions while also switching at high speeds and requiring reduced chip area.
An MRAM device is disclosed that has a magnetic tunnel junction stack having a significantly improved performance of the free layer in the magnetic tunnel junction structure that requires significantly lower switching currents and which significantly reduces switching times for MRAM applications and maintains this characteristic for both switching directions (AP to P and P to AP)
In one embodiment, a magnetic device includes a reference magnetic layer in a first plane. The reference magnetic layer has a magnetization vector that is perpendicular to the first plane and has a fixed magnetization direction. The magnetic device also has a non-magnetic tunnel barrier layer in a second plane and disposed over the reference magnetic layer. The magnetic device also includes a free magnetic layer in a third plane and disposed over the non-magnetic tunnel barrier layer. The free magnetic layer has a magnetization vector that is perpendicular to the third plane and has a magnetization direction that can switch from a first magnetization direction to a second magnetization direction and from the second magnetization direction to the first magnetization direction. The switching process involves precessions of the magnetization vector around an axis perpendicular to the third plane at a precession radius. The magnetization vector of the free magnetic layer has a predetermined precession frequency. The magnetic device also includes a non-magnetic spacer in a fourth plane and disposed over the free magnetic layer. The magnetic device also includes an in-plane polarization magnetic layer in a fifth plane and disposed over the non-magnetic spacer. The in-plane polarization magnetic layer has a magnetization vector that is parallel to the fifth plane. The magnetic device also includes a non-magnetic insulator that is adjacent to the non-magnetic spacer and the in-plane polarization magnetic layer. The magnetic device also includes a metallic terminal coupled to the magnetic tunnel junction. The metallic terminal is adjacent to the non-magnetic insulator and is separated from the non-magnetic spacer and the in-plane polarization magnetic layer by the non-magnetic insulator. The magnetic device also includes a first current source that directs a read current through the metallic terminal and the magnetic tunnel junction. The read current measures the resistance across the magnetic tunnel junction. The magnetic device also includes a second current source that directs a programming current pulse through the magnetic tunnel junction, the non-magnetic spacer, and the in-plane polarization magnetic layer. The programming current pulse comprises a direct current pulse and an alternating perturbation pulse. The alternating perturbation pulse alternates between a maximum current value and a minimum current value at a first frequency. Application of the programming current pulse to the magnetic device produces a spin-polarized current having spin-polarized electrons. The spin-polarized current alternates between a maximum spin-current value and a minimum spin-current value at the first frequency. The spin-polarized electrons exert a spin transfer torque on the magnetization vector of the free magnetic layer, and the spin transfer torque alternates between a maximum magnitude and a minimum magnitude at the first frequency. The first frequency is synchronized with the predetermined precession frequency of the free magnetic layer, thereby causing the spin transfer torque to be at the maximum magnitude when the spin transfer torque increases the precession radius of the magnetization vector of the free magnetic layer, and at the minimum magnitude when the spin transfer torque decreases the precession radius of the magnetization vector of the free magnetic layer. In this way, the switching process of the free magnetic layer is accelerated from the first magnetization direction to the second magnetization direction and from the second magnetization direction to the first magnetization direction.
In another embodiment, a difference in frequency between the first frequency and the predetermined precession frequency of the free magnetic layer is less than twenty percent of the predetermined precession frequency of the free magnetic layer.
In another embodiment, a difference in frequency between the first frequency and the predetermined precession frequency of the free magnetic layer is less than ten percent of the predetermined precession frequency of the free magnetic layer.
In another embodiment, a difference in frequency between the first frequency and the predetermined precession frequency of the free magnetic layer is less than five percent of the predetermined precession frequency of the free magnetic layer.
In another embodiment, a difference in frequency between the first frequency and the predetermined precession frequency of the free magnetic layer is less than two percent of the predetermined precession frequency of the free magnetic layer.
In another embodiment, the direct current pulse has a current value different than zero.
In another embodiment, the direct current pulse has a value that is fixed throughout the duration of the pulse.
In another embodiment, the magnetization vector of the in-plane polarization magnetic layer is fixed.
In another embodiment, the metallic terminal comprises a metal, a metallic nanofiber, or a conductive carbon nanotube.
In another embodiment, the reference magnetic layer comprises CoFeB, the non-magnetic tunnel barrier layer comprises MgO, the free magnetic layer comprises CoFeB, the non-magnetic spacer comprises MgO, and the in-plane polarization magnetic layer comprises CoFeB.
In another embodiment, a magnetic device includes a reference magnetic layer in a first plane. The reference magnetic layer has a magnetization vector that is perpendicular to the first plane and has a fixed magnetization direction. The magnetic device also has a non-magnetic tunnel barrier layer in a second plane and disposed over the reference magnetic layer. The magnetic device also includes a free magnetic layer in a third plane and disposed over the non-magnetic tunnel barrier layer. The free magnetic layer has a magnetization vector that is perpendicular to the third plane and has a magnetization direction that can switch from a first magnetization direction to a second magnetization direction and from the second magnetization direction to the first magnetization direction. The switching process involves precessions of the magnetization vector around an axis perpendicular to the third plane at a precession radius. The magnetization vector of the free magnetic layer has a predetermined precession frequency. The reference magnetic layer, the non-magnetic tunnel barrier layer and the free magnetic layer form a magnetic tunnel junction (MTJ). The magnetic device also includes a non-magnetic spacer in a fourth plane and disposed over the free magnetic layer. The magnetic device also includes an in-plane polarization magnetic layer in a fifth plane and disposed over the non-magnetic spacer. The in-plane polarization magnetic layer has a magnetization vector that is parallel to the fifth plane. The magnetic device also includes a metallic spacer in a sixth plane and disposed over the in-plane polarization magnetic layer. The magnetic device also includes an in-plane spin torque oscillator layer in a seventh plane and disposed over the metallic spacer. The in-plane spin torque oscillator layer has a magnetization vector that precesses around an in-plane anisotropy axis or precesses in the seventh plane upon application of a programming voltage pulse. The magnetic device also includes a non-magnetic spin torque oscillator barrier layer in an eighth plane and disposed over the in-plane spin torque oscillator layer. The magnetic device also includes a perpendicular spin torque oscillator layer in a ninth plane and disposed over the non-magnetic spin torque oscillator barrier layer. The perpendicular spin torque oscillator layer has a magnetization vector that precesses around an out-of-plane anisotropy axis upon application of the programming voltage pulse. The non-magnetic spin torque oscillator barrier layer, the in-plane spin magnetized layer and the perpendicular spin torque oscillator layer form a spin torque nano oscillator (STNO). The magnetic device also includes a non-magnetic insulator that is adjacent to the non-magnetic spacer, the in-plane polarization magnetic layer, the metallic layer, the in-plane spin torque oscillator layer, the non-magnetic spin torque oscillator barrier layer, and the perpendicular spin torque oscillator layer. The magnetic device also includes a metallic terminal that is coupled to the MTJ. The metallic terminal is adjacent to the non-magnetic insulator and is separated from the non-magnetic spacer, the in-plane polarization magnetic layer, the metallic layer, and the STNO by the non-magnetic insulator. The magnetic device also includes a first voltage source that applies a read voltage across the metallic terminal and the MTJ. The read voltage measures the resistance across the MTJ. The magnetic device also includes a second voltage source that applies the programming voltage across the STNO, the metallic layer, the in-plane polarization magnetic layer, the non-magnetic spacer, and the MTJ. Application of the programming voltage pulse to the magnetic device results in a switching voltage across the in-plane polarization magnetic layer, the non-magnetic spacer and the MTJ. The switching voltage alternates between a maximum voltage value and a minimum voltage value at a first frequency. The first frequency is synchronized with the predetermined precession frequency of the free magnetic layer. In this way, the efficiency of the switching process of the free magnetic layer is enhanced during switching from the first magnetization direction to the second magnetization direction and from the second magnetization direction to the first magnetization direction.
In another embodiment, application of the switching voltage across the in-plane polarization magnetic layer, the non-magnetic spacer and the MTJ generates a spin-polarized current having spin-polarized electrons. The spin-polarized current alternates between a maximum spin-current value and a minimum spin-current value at the first frequency. The spin-polarized electrons exert a spin transfer torque on the magnetization vector of the free magnetic layer.
In another embodiment, the spin transfer torque alternates between a maximum magnitude and a minimum magnitude at the first frequency, thereby causing the spin transfer torque to be at the maximum magnitude when the spin transfer torque increases the precession radius of the magnetization vector of the free magnetic layer, and at the minimum magnitude when the spin transfer torque decreases the precession radius of the magnetization vector of the free magnetic layer.
In another embodiment, the metallic spacer comprises Ruthenium or Rhodium.
In another embodiment, the metallic spacer comprises a layer of Ruthenium, the layer of Ruthenium being between 2 and 10 angstroms thick.
In another embodiment, the magnetization vector of the in-plane spin torque oscillator layer and the magnetization vector of the in-plane polarization magnetic layer are magnetically coupled.
In another embodiment, a magnetic device includes a spin torque nano oscillator (STNO) in a first plane. The STNO comprises an in-plane spin torque oscillator layer, a non-magnetic spin torque oscillator barrier layer, and a perpendicular spin torque oscillator layer. The in-plane spin torque oscillator layer and the perpendicular spin torque oscillator layer are separated by the non-magnetic spin torque oscillator barrier layer. The in-plane spin torque oscillator layer has a magnetization vector that precesses around an in-plane anisotropy axis or precesses in the first plane upon application of a programming voltage pulse. The perpendicular spin torque oscillator layer has a magnetization vector that precesses around an out-of-plane anisotropy axis upon application of the programming voltage pulse. The magnetic device also includes a metallic layer in a second plane. The metallic layer separates the spin torque nano oscillator from an in-plane polarization magnetic layer. The magnetic device also includes the in-plane polarization magnetic layer in a third plane. The in-plane polarization magnetic layer has a magnetization vector that is parallel to the third plane. The magnetic device also includes a non-magnetic spacer in a fourth plane. The non-magnetic spacer separates the in-plane polarization magnetic layer from a magnetic tunnel junction (MTJ). The magnetic device also includes the MTJ in a fifth plane. The MTJ comprises a reference magnetic layer, a non-magnetic tunnel barrier layer, and a free magnetic layer. The free magnetic layer and the reference magnetic layer are separated by the non-magnetic tunnel barrier layer. The reference magnetic layer has a magnetization vector that is perpendicular to the fifth plane and has a fixed magnetization direction. The free magnetic layer has a magnetization vector that is perpendicular to the fifth plane and has a magnetization direction that can switch from a first magnetization direction to a second magnetization direction and from the second magnetization direction to the first magnetization direction. The switching process involves precessions of the magnetization vector around an axis perpendicular to the fifth plane at a precession radius. The magnetization vector of the free magnetic layer has a predetermined precession frequency. The magnetic device also includes a non-magnetic insulator that is adjacent to the non-magnetic spacer, the in-plane polarization magnetic layer, the metallic layer, and the STNO. The magnetic device also includes a metallic terminal coupled to the MTJ. The metallic terminal is adjacent to the non-magnetic insulator and the metallic terminal is separated from the non-magnetic spacer, the in-plane polarization magnetic layer, the metallic layer and the STNO by the non-magnetic insulator. The magnetic device also includes first voltage source that applies a read voltage across the metallic terminal and the MTJ, wherein the read voltage measures the resistance across the MTJ. The magnetic device also includes a second voltage source that applies the programming voltage across the STNO, the metallic layer, the in-plane polarization magnetic layer, the non-magnetic spacer, and the MTJ. Application of the programming voltage pulse to the magnetic device results in a switching current pulse that alternates between a maximum current value and a minimum current value at a first frequency. Application of this switching current pulse to the in-plane polarization magnetic layer, the non-magnetic spacer, and the MTJ results in a spin-polarized current having spin-polarized electrons. The spin-polarized current alternating between a maximum spin-current value and a minimum spin-current value at the first frequency. The first frequency is synchronized with the predetermined precession frequency of the free magnetic layer. In this way, the efficiency of the switching process of the free magnetic layer is enhanced during switching from the first magnetization direction to the second magnetization direction and from the second magnetization direction to the first magnetization direction.
In another embodiment, the spin transfer torque alternates between a maximum magnitude and a minimum magnitude at the first frequency, thereby causing the spin transfer torque to be at the maximum magnitude when the spin transfer torque increases the precession radius of the magnetization vector of the free magnetic layer and at the minimum magnitude when the spin transfer torque decreases the precession radius of the magnetization vector of the free magnetic layer.
In another embodiment, the in-plane polarization magnetic layer comprises CoFeB.
In another embodiment, the free magnetic layer comprises CoFeB.
In another embodiment, the non-magnetic tunnel barrier layer comprises MgO.
In another embodiment, the magnetization vector of the in-plane polarization magnetic layer is fixed.
In another embodiment, the in-plane spin torque oscillator layer comprises CoFeB and the perpendicular spin torque oscillator layer comprises CoFeB.
In another embodiment, the programming voltage pulse comprises a direct voltage.
In another embodiment, the magnetization vector of the in-plane polarization magnetic layer is fixed.
In another embodiment, the free magnetic layer comprises CoFeB.
In another embodiment, the non-magnetic tunnel barrier layer comprises MgO.
In another embodiment, the in-plane polarization magnetic layer comprises CoFeB, Fe, FeV, or FeB.
In another embodiment, the in-plane polarization magnetic layer comprises CoFeB.
In another embodiment, the non-magnetic spacer comprises MgO.
The accompanying drawings, which are included as part of the present specification, illustrate the presently preferred embodiments and, together with the general description given above and the detailed description given below, serve to explain and teach the principles of the MTJ devices described herein.
The figures are not necessarily drawn to scale and the elements of similar structures or functions are generally represented by like reference numerals for illustrative purposes throughout the figures. The figures are only intended to facilitate the description of the various embodiments described herein; the figures do not describe every aspect of the teachings disclosed herein and do not limit the scope of the claims.
The following description is presented to enable any person skilled in the art to create and use methods and magnetic devices that utilize a programming current comprising an alternating perturbation current to assist in the switching of a magnetization vector for a magnetic semiconductor device such as an MRAM device. Each of the features and teachings disclosed herein can be utilized separately or in conjunction with other features to implement the disclosed system and method. Representative examples utilizing many of these additional features and teachings, both separately and in combination, are described in further detail with reference to the attached drawings. This detailed description is merely intended to teach a person of skill in the art further details for practicing preferred aspects of the present teachings and is not intended to limit the scope of the claims. Therefore, combinations of features disclosed in the following detailed description may not be necessary to practice the teachings in the broadest sense, and are instead taught merely to describe particularly representative examples of the present teachings.
In the following description, for purposes of explanation only, specific nomenclature is set forth to provide a thorough understanding of the present teachings. However, it will be apparent to one skilled in the art that these specific details are not required to practice the present teachings.
The present patent document discloses a MRAM device that (1) comprises an in-plane polarization layer having a fixed magnetization direction and a perpendicular MTJ; (2) a first current source that directs a read current pulse through the MTJ, bypassing the in-plane polarization layer via a metallic terminal; and (3) a second current source that directs and programming current pulse through the in-plane polarization layer and the MTJ. This device is described with reference to
The present patent document also discloses a MRAM device that (1) comprises a STNO, an in-plane polarization layer having a fixed magnetization direction, and a perpendicular MTJ; (2) a first voltage source that applies a read voltage pulse across the MTJ, bypassing the in-plane polarization layer and the STNO via a metallic terminal; and (3) a second voltage source that directs and programming voltage pulse across the STNO, the in-plane polarization layer and the MTJ. This device is described with reference to
For ease of description, many of the phenomena occurring during the writing process will be described with respect to two-terminal MRAM devices that are analogous to the three-terminal MRAM devices described herein. In particular,
As described above, when a programming current pulse comprising an alternating perturbation current is applied to the in-plane polarization layer 550 and a perpendicular MTJ 530, a spin-polarized current is formed that alternates between a maximum spin-current value and a minimum spin-current value at the first frequency. As the programming current alternates between a maximum current value and a minimum current value, the spin-polarized current also alternates between a maximum spin-current value and a minimum spin-current value at the first frequency. Similarly, when the switching current (generated by application of a programming voltage pulse across device 700) is applied to the in-plane polarization layer 750 and a perpendicular MTJ 730, a spin-polarized current is formed. As the switching current alternates between a maximum current value and a minimum current value, the spin-polarized current also alternates between a maximum spin-current value and a minimum spin-current value at the first frequency.
In addition, the magnitude of the spin-transfer torque exerted on the free layers 536 or 736 is proportional to the spin-current value. Therefore, when the spin current is at the maximum spin-current value, the magnitude of the spin-transfer torque being exerted on the free layer is at the maximum magnitude. When the spin current is at the minimum spin-current value, the magnitude of the spin-transfer torque being exerted on the free layer is at the minimum magnitude. Therefore, in embodiments where the first frequency in synchronized with the predetermined precession frequency of the magnetization vector of the free layer, the magnitude of the spin transfer torque will oscillate between the maximum magnitude and minimum magnitude at a frequency that is synchronized with the precession of the free layer (i.e., the first frequency).
Like the in-plane polarizer 150 previously discussed, the in-plane polarization layer 550 in this embodiment has a magnetic vector with a fixed magnetization direction (top of
The spin-polarized electrons of the spin-polarized current exert a spin transfer torque on the magnetization layer of the free layer. This spin transfer torque has both an in-plane spin torque component 610 and a perpendicular spin torque component (not shown in
The in-plane spin torque 610 also enhances the precessional motion of the magnetization vector of the free layer. As seen on the right-hand side of
Moreover, as shown in
The results of several simulations of a device having the structure described in
For the first series of simulations (switching from the parallel to anti-parallel directions), both the constant non-polarized current (line 8-A with filled squares) and the constant polarized current (line 8-B with filled circles) had a similar effect on the switching of the free layer. The data show that application of an alternating perturbation current causes a reduction in switching Voltage values for the system, with the switching Voltage values decreasing as the perturbation amplitude increases. This effect can be seen by comparing the lines for the currents with 0% perturbation amplitude (line 8-B with filled circles); 10% perturbation amplitude (line 8-C with filled diamonds), 20% perturbation amplitude (line 8-D with filled crosses); and 30% perturbation amplitude (line 8-E with filled pentagons). The lines that correspond to higher values of the perturbation amplitude lie below the lines with lower values of the perturbation amplitude, suggesting that increasing the perturbation amplitudes reduces the WER, i.e., it reduces the probability that a bit is written incorrectly.
Similar results were obtained in the second series of experiments (switching from the anti-parallel to the parallel direction). No significant change in switching voltage was observed between the constant non-polarized current (line 8-F with empty squares) and the constant polarized current (line 8-G with empty circles). However, the switching Voltage values decrease as the perturbation amplitude increases, as can be observed by comparing the lines with 0% perturbation amplitude (line 8-G with empty circles); 10% perturbation amplitude (line 8-H with empty diamonds), 20% perturbation amplitude (line 8-I with empty crosses); and 30% perturbation amplitude (line 8-J with empty pentagons), respectively. The lines that correspond to higher perturbation amplitude lie below the lines with smaller perturbation amplitude.
Thus, the results in
The three-terminal devices disclosed herein offer the additional advantage of bypassing the polarizer during the reading process. As described above, by passing a programming current comprising an alternating perturbation current through the in-plane polarizer and MTJ, efficient switching is obtained. However, during the reading phase, the objective is to measure the resistance across the MTJ without disturbing the free layer. In some embodiments, three-terminal structures such as those described in
In some embodiments, the three-terminal devices disclosed herein utilize a STNO to assist in switching the free layer. For ease of explanation, descriptions of the phenomena involved in switching the free layer of a device comprising an STNO will be made with reference to the two-terminal device depicted in
In one embodiment, the programming voltage pulse is a direct voltage with a fixed voltage value. Upon being subjected to the alternating resistance states of the STNO 570, the resulting current leaving the STNO 770 and (i.e., the switching current) oscillates between a maximum current value and a minimum current value. In one embodiment, the frequency at which the oscillation occurs (i.e., the first frequency) is matched to the predetermined precession frequency of the magnetic vector of the free layer 736 while the precession frequency is near its maximum value. Thus, the switching current will oscillate between the maximum and minimum current values in a manner that is synchronized with the initial precessions of the magnetization vector of the free layer 736 (i.e., the predetermined precession frequency of the free layer 536, which is the frequency at which the magnetization vector of free layer 736 precesses when the vector is nearly perpendicular to the plane). However, later in the switching process, as the precession frequency of the free layer decreases (when the magnetization vector of the free layer 736 precesses near or in the plane), the predetermined precession frequency of the free layer 536 may fall out of phase with the first frequency.
The results of several simulations of a device having the structure described in
For the first series of simulations (switching from the parallel to anti-parallel directions), both the constant non-polarized current (line 13-A with filled squares) and the constant polarized current (line 13-B with filled circles) had a similar effect on the switching of the free layer. The data show that application of an alternating perturbation current causes a reduction in switching Voltage values for the system, with the switching Voltage values decreasing as the perturbation amplitude increases. This effect can be seen by comparing the lines for the currents with 0% perturbation amplitude (line 13-B with filled circles); 10% perturbation amplitude (line 13-C with filled diamonds), 20% perturbation amplitude (line 13-D with filled crosses); and 30% perturbation amplitude (line 13-E with filled pentagons). The lines that correspond to higher values of the perturbation amplitude lie below the lines with lower values of the perturbation amplitude, suggesting that increasing the perturbation amplitudes reduces the WER, i.e., it reduces the probability that a bit is written incorrectly.
Similar results were obtained in the second series of experiments (switching from the anti-parallel to the parallel direction). No significant change in switching voltage was observed between the constant non-polarized current (line 13-F with empty squares) and the constant polarized current (line 13-G with empty circles). However, the switching voltage values decrease as the perturbation amplitude increases, as can be observed by comparing the lines with 0% perturbation amplitude (line 13-G with empty circles); 10% perturbation amplitude (line 13-H with empty diamonds), 20% perturbation amplitude (line 13-I with empty crosses); and 30% perturbation amplitude (line 13-J with empty pentagons), respectively. The lines that correspond to higher perturbation amplitude lie below the lines with smaller perturbation amplitude.
Thus, the results in
The three-terminal devices disclosed herein offer the additional advantage of bypassing the SNTO and the polarizer during the reading process. As described above, by applying a programming voltage across the STNO, the in-plane polarizer and MTJ, efficient switching is obtained. However, during the reading phase, the objective is to measure the resistance across the MTJ without disturbing the free layer. In some embodiments, three-terminal structures such as those described in
A three-terminal memory cell 800 with an in-plane polarization layer 850, an MTJ structure 800, a programming current source 875, a metallic terminal 844, and a reading current source 885 is shown in
Seed layer 810 in the MTJ structure shown in
Nonmagnetic spacer 840 has a number of properties. For example, nonmagnetic spacer 840 physically separates the free layer 836 and the in-plane polarization magnetic layer 850. Nonmagnetic spacer 840 transmits spin current efficiently from the in-plane polarization magnetic layer 850 into the free layer 836 because it preferably has a long spin diffusion length if made metallic. Nonmagnetic spacer 840 also promotes good microstructure and high tunneling magnetoresistance (TMR) and helps keep the damping constant of the free layer 536 low. In one embodiment, nonmagnetic space 840 comprises MgO.
The in-plane polarization magnetic layer 850 is preferably made from CoFeB. It can also be made with Co, Fe, Ni magnetic layers or can be made out of their alloys. The magnetic alloys can also have boron, tantalum, copper or other materials.
Non-magnetic insulator 842 has a number of properties. For example, nonmagnetic insulator 842 physically separates the metallic terminal 844 from the in-plane polarization magnetic layer 850 and the non-magnetic spacer 840. Nonmagnetic insulator 842 does not transfer electrical current or does so with very low efficiency, thereby preventing current from metallic terminal 844 from entering either the in-plane polarization magnetic layer 850 or the non-magnetic spacer 840. Nonmagnetic insulator 842 preferably comprises a nonmagnetic, nonconductive material.
Metallic terminal 844 has a number of properties. Metallic terminal efficiently conducts electrical current from first current source 885 to MTJ structure 830. Metallic terminal 844 preferably comprises a highly-conductive, non-magnetic material. Metallic terminal 844 preferably comprises a metal, a metallic nanofiber, or a conductive carbon nanotube.
Nonmagnetic external insulator 846 has a number of properties. For example, nonmagnetic external insulator 842 physically separates the metallic terminal 844 from anything external to the MTJ stack 800. In addition, nonmagnetic external insulator 846 does not transfer electrical current or does so with very low efficiency. Nonmagnetic external insulator 846 preferably comprises a nonmagnetic, nonconductive material.
Finally capping layer 880 can be any material that provides good interface to the in-plane layer such as Ta, TaN, Ru, MgO, Cu, etc. In some embodiment, first current source 885 generates a direct current. In some embodiments, second current source 875 can generate a programming current pulse that comprises both an alternating perturbation current and a direct current component. In addition, second current source 875 can be configured to produce an alternating perturbation current having an oscillation frequency that is matched to the predetermined precession frequency of the free magnetic layer 836. Current source 875 can also generate programming currents with various ratios of alternating perturbation current and direct current. In some embodiments, current source 875 can provide an alternating perturbation current pulse for a first time interval and a direct current pulse or a switching current pulse for a second time interval. In some embodiments, current source 875 can also generate a programming current comprising an alternating perturbation current and a direct current, and the direct current can be changed from a first direct current value to a second direct current value.
The manner in which a bit is written using a programming current pulse comprising an alternating perturbation current and three-terminal magnetic device 800 will now be described. In particular, an electrical current is supplied, for example, by second current source 875, which passes electrical current through the in-plane polarization magnetic layer 850, the non-magnetic spacer 840, the free magnetic layer 836, the non-magnetic tunneling barrier layer 834, and the reference layer 832. Application of the electrical current (i.e., programming current) to the magnetic device 800 creates a spin polarized current that passes through non-magnetic spacer layer 840, free magnetic layer 836, tunneling barrier layer 834, and reference magnetic layer 832. The spin polarized current exerts a spin transfer torque on free magnetic layer 836, which helps overcome the inherent damping of the magnetic material making up the free layer 836. The spin transfer torque is composed of an in-plane spin transfer torque and a perpendicular spin transfer torque. In one embodiment, when switching the free layer 836 in one direction (e.g., from the parallel direction to the anti-parallel direction), the in-plane spin transfer torque is caused by the transverse spin current generated by the in-plane polarization magnetic layer 850 and the perpendicular spin transfer torque is caused by the reflected spin current generated by the reference magnetic layer 832. This causes the free magnetic layer 836 to precess about its axis, which is shown in
The programming current pulse comprises an alternating perturbation current generated, for example, by current source 875. Therefore, the programming current to alternate between a maximum current value and a minimum current value at a first frequency. As a result, the spin-polarized current, which is generated by application of the programming current to magnetic device 800, alternates between a maximum spin-current value and a minimum spin current value at the same first frequency. The magnitude of the spin transfer torque exerted on the magnetic vector of the free layer 836 is proportional to the spin-current value because at higher spin-current values, there are more spin-polarized electrons flowing through free layer 836. Therefore, the magnitude of the spin transfer torque alternates between a maximum spin torque magnitude and a minimum spin torque magnitude at the same first frequency.
The in-plane spin transfer torque causes the magnetic vector of the free magnetic layer 836 to precess, as depicted in
In particular, the structures and methods described herein utilize an alternating perturbation current that is synchronized with the predetermined precession frequency of the free magnetic layer 836 that provides a net in-plane spin transfer torque throughout the whole precession cycle and therefore significantly enhances the free layer switching process in both switching directions, which will result in faster write times and lower switching threshold currents.
Three-terminal devices such as magnetic device 800 offer additional advantages over the two-terminal devices that are described above (e.g., magnetic device 500). In particular, these three-terminal devices offer all of the advantages of improved switching during the writing process, but allow a significantly reduced read disturb. Benefits from the lower switching threshold currents that are derived from resonant switching currents include reduction in write error rate, reduced damage to the device during each writing process, and an increase in device stability over time. However, lower switching threshold currents can increase the probability of inadvertently writing the bit during the read process. Typically, a weaker current is used during the read process, allowing the resistance across the MTJ to be measured without generating a spin-current that is strong enough to switch the magnetic vector of the free layer. However, as described above, when an in-plane polarizer and an alternating perturbation current resonant with the free layer is used, the strength of the current required to switch the free layer is greatly reduced. Therefore, unless these systems can be bypassed, there will be a substantial probability of inadvertently switching the free layer during the reading process, in spite of the use of a weaker read current. Three-terminal devices such as magnetic device 800 allow a direct current to be used that bypasses the in-plane polarization layer during the read process, thereby reducing the probability of read disturb.
A memory cell with a STNO structure 970, an in-plane polarization layer 950, a MTJ structure 930, a programming current source 975, a metallic terminal 944, and a reading current source 985 is shown in
Seed layer 910 in the MTJ structure shown in
Nonmagnetic spacer 940 has a number of properties. For example, nonmagnetic spacer 940 physically separates the free layer 936 and the in-plane polarization magnetic layer 950. Nonmagnetic spacer 940 transmits spin current efficiently from the in-plane polarization magnetic layer 950 into the free layer 936 because it preferably has a long spin diffusion length if made metallic. Nonmagnetic spacer 940 also promotes good microstructure and high tunneling magnetoresistance (TMR) and helps keep the damping constant of the free layer 936 low. In one embodiment, the nonmagnetic spacer 940 comprises MgO.
The in-plane polarization magnetic layer 950 is preferably made from CoFeB. The in-plane polarization magnetic layer 950 can also be made with CoFeB, Fe, FeV. or FeB. It can also be made with Co, Fe, Ni magnetic layers or can be made out of their alloys. The magnetic alloys can also have boron, tantalum, copper or other materials.
Metallic spacer 960 has a number of properties. For example, metallic spacer 960 physically separates the STNO 970 from the in-plane polarization magnetic layer 950. Preferably, metallic spacer 960 is composed of ruthenium or rhodium. Metallic spacer 960 is preferably made from Ru having thickness in the range of two to ten Angstroms or Rh having thickness in the range of two to ten Angstroms. In one embodiment, when metallic spacer 960 is comprised of a thin layer of Ru (e.g., 7 Angstroms), the in-plane polarization magnetic layer 950 and the in-plane spin torque oscillator layer 972 can be AFM coupled via stray fields, thereby minimizing the stray field that in-plane polarization magnetic layer 550 imparts on free magnetic layer 536. This AFM coupling can be strengthened via electronic oscillatory (RKKY) coupling.
The STNO 970 can be in either of the following configurations: (1) in-plane spin torque oscillator layer 972 disposed over spin torque oscillator barrier layer 974, which is disposed over perpendicular spin torque oscillator layer 976; or (2) perpendicular spin torque oscillator layer 976 disposed over spin torque oscillator barrier layer 974, which is disposed over in-plane spin torque oscillator layer 972. In-plane spin torque oscillator layer 972 can be comprised of a SAF, such as a composite ferromagnetic metal/metallic spacer (Ru or Rd)/ferromagnetic metal structure. The in-plane spin torque oscillator layer 972 can be pinned by a 5-10 nm layer of PtMn exchange bias layer. Preferably, in-plane spin torque oscillator layer 972 comprises CoFeB. Spin torque oscillator barrier layer 974 can be any non-magnetic material such as 2 to 20 Angstroms of ruthenium, 2-20 Angstroms of Ta, 2-20 Angstroms of TaN, 2-20 Angstroms of Cu, 2-20 Angstroms of CuN, or 2-20 Angstroms MgO layer, or or 2-20 Angstroms Al2O3 layer. Spin torque oscillator barrier layer 974 is preferably made from MgO. The perpendicular spin torque oscillator layer 976 can comprise 6-16 Angstoms of Ta/CoFeB. Preferably, the perpendicular spin torque oscillator layer 976 comprises CoFeB.
Nonmagnetic insulator 942 has a number of properties. For example, nonmagnetic insulator 942 physically separates the metallic terminal 944 from the STNO structure 970, the metallic spacer 960, the in-plane polarization magnetic layer 950 and the non-magnetic spacer 940. In addition, nonmagnetic insulator 942 does not transfer electrical current or does so with very low efficiency, thereby preventing current from metallic terminal 944 from entering either the STNO structure 970, the metallic spacer 960, the in-plane polarization magnetic layer 950 and the non-magnetic spacer 940. Nonmagnetic insulator 942 preferably comprises a nonmagnetic, nonconductive material.
Metallic terminal 944 has a number of properties. Metallic terminal efficiently conducts electrical current from first current source 985 to MTJ structure 930. Metallic terminal 944 preferably comprises a highly-conductive, non-magnetic material. Metallic terminal 944 preferably comprises a metal, a metallic nanofiber, or a conductive carbon nanotube.
Nonmagnetic external insulator 946 has a number of properties. For example, nonmagnetic external insulator 946 physically separates the metallic terminal 944 from anything external to the MTJ stack 900. In addition, nonmagnetic external insulator 946 does not transfer electrical current or does so with very low efficiency. Nonmagnetic external insulator 946 preferably comprises a nonmagnetic, nonconductive material. Finally, capping layer 980 can be any material that provides good interface to the perpendicular spin torque oscillator layer such as Ta, TaN, Ru, MgO, Cu, etc.
In some embodiments, first voltage source 985 can generate a direct voltage. In some embodiments, second voltage source 975 can generate a programming voltage pulse that comprises direct voltage pulse. In other embodiments, the strength of the bias produced by voltage source 975 can vary over time.
In one embodiment, during the writing process, magnetic device 900 operates as a voltage divider (when supplied with a constant voltage pulse), with a first voltage across STNO 970 (labeled as V-STNO in
In contrast, during the reading process, the voltage divider of the STNO/MTJ system is bypassed, reading the resistance across only the MTJ. First voltage source 985 generates a voltage across the metallic terminal 944 and MTJ 930. In one embodiment, this voltage (labeled as V-Read in
The manner in which a bit is written using three-terminal magnetic device 900 that comprises STNO 570, in-plane polarization magnetic layer 550, MTJ structure 530, and metallic terminal 944 will now be described. In particular, an electrical voltage is supplied, for example, by voltage source 975, which results in an electrical current through the perpendicular spin torque oscillator layer 976, the non-magnetic spin torque barrier layer 974, the in-plane spin torque oscillator layer 972, the magnetic spacer 960, the in-plane polarization magnetic layer 950, the non-magnetic spacer 940, the free magnetic layer 596, the non-magnetic tunneling barrier layer 934, and the reference layer 932. Application of the programming voltage to STNO 970 causes the magnetization vectors of the perpendicular spin torque oscillator layer 976 and the in-plane spin torque oscillator layer 972 to precess around their respective axes. The precession of the magnetic vectors perpendicular spin torque oscillator layer 976 and the in-plane spin torque oscillator layer 972 causes the resistance across the STNO to oscillate between a maximum resistance value and a minimum resistance value. The net effect is that the current leaving the STNO and passing through the in-plane polarization magnetic layer 950 (i.e., the switching current) alternates between a maximum current value and a minimum current value at a first frequency.
Application of the switching current to the in-plane polarization magnetic layer 950 and MTJ structure 930 creates a spin polarized current that passes through non-magnetic spacer layer 940, free magnetic layer 936, tunneling barrier layer 934, and reference magnetic layer 932. The spin polarized current exerts a spin transfer torque on free magnetic layer 936, which helps overcome the inherent damping of the magnetic material making up the free layer 936. The spin transfer torque is composed of an in-plane spin transfer torque and a perpendicular spin transfer torque. In one embodiment, when switching the free layer 936 in one direction (e.g., from the parallel direction to the anti-parallel direction), the in-plane spin transfer torque is caused by the transverse spin current generated by the in-plane polarization magnetic layer 950 and the perpendicular spin transfer torque is caused by the reflected spin current generated by the reference magnetic layer 932. This causes the free magnetic layer 936 to precess about its axis, which is shown in
The spin-polarized current, which is generated by application of the switching current to in-plane polarization magnetic layer 950 and the MTJ structure 930, alternates between a maximum spin-current value and a minimum spin current value at the same first frequency. The magnitude of the spin transfer torque exerted on the magnetic vector of the free layer 936 is proportional to the spin-current value because at higher spin-current values, there are more spin-polarized electrons flowing through free layer 936. Therefore, the magnitude of the spin transfer torque alternates between a maximum spin torque magnitude and a minimum spin torque magnitude at the same first frequency.
The in-plane spin transfer torque causes the magnetic vector of the free magnetic layer 936 to precess, as depicted in
In particular, the structures described herein utilize a STNO that has been designed to produce oscillations in the current value of the switching current that are synchronized with the predetermined precession frequency of the free magnetic layer 936. As described above, this system provides a net in-plane spin transfer torque throughout the whole precession cycle and therefore significantly enhances the free layer switching process in both switching directions, which will result in faster write times and lower switching threshold currents.
Three-terminal devices such as magnetic device 900 offer additional advantages over the two-terminal devices that are described above (e.g., magnetic device 700). In particular, these three-terminal devices offer all of the advantages of improved switching during the writing process, but allow a significantly reduced read disturb. Benefits from the lower switching threshold currents that are derived from the use of a STNO resonant with the free layer and an in-plane polarizer include reduction in write error rate, reduced damage to the device during each writing process, and an increase in device stability over time. However, lower switching threshold currents can increase the probability of inadvertently writing the bit during the read process. Typically, a weaker current is used during the read process, allowing the resistance across the MTJ to be measured without generating a spin-current that is strong enough to switch the magnetization vector of the free layer. However, as described above, when a STNO resonant with the free layer and an in-plane polarizer are used, the strength of the current required to switch the free layer is greatly reduced. Therefore, unless these systems can be bypassed, there will be a substantial probability of inadvertently switching the free layer during the reading process, in spite of the use of a weaker read current. Three-terminal devices such as magnetic device 900 allow a direct current to be used that bypasses the in-plane polarization layer during the read process, thereby reducing the probability of read disturb. In addition, three terminal device 900 allows the direct read current to bypass the STNO, thereby detecting the resistance across the MTJ without detecting the oscillating resistance values generated by the STNO. Thus, three-terminal devices such as magnetic device 900 offer significant advantages during both the writing and reading processes.
An alternative embodiment is shown in
All of the layers of devices 800, 900 and 1100 illustrated in
It should be appreciated to one skilled in the art that a plurality of MTJ structures 800, 900, and 1100 can be manufactured and provided as respective bit cells of an STT-MRAM device. In other words, each MTJ stack can be implemented as a bit cell for a memory array having a plurality of bit cells.
The above description and drawings are only to be considered illustrative of specific embodiments, which achieve the features and advantages described herein. Modifications and substitutions to specific process conditions can be made. Accordingly, the embodiments in this patent document are not considered as being limited by the foregoing description and drawings.
Number | Name | Date | Kind |
---|---|---|---|
341801 | Fox | May 1886 | A |
5541868 | Prinz | Jul 1996 | A |
5629549 | Johnson | May 1997 | A |
5640343 | Gallagher et al. | Jun 1997 | A |
5654566 | Johnson | Aug 1997 | A |
5691936 | Sakakima et al. | Nov 1997 | A |
5695846 | Lange et al. | Dec 1997 | A |
5695864 | Slonczewski | Dec 1997 | A |
5732016 | Chen et al. | Mar 1998 | A |
5856897 | Mauri | Jan 1999 | A |
5896252 | Kanai | Apr 1999 | A |
5966323 | Chen et al. | Oct 1999 | A |
6016269 | Peterson et al. | Jan 2000 | A |
6055179 | Koganei et al. | Apr 2000 | A |
6097579 | Gill | Aug 2000 | A |
6124711 | Tanaka et al. | Sep 2000 | A |
6134138 | Lu et al. | Oct 2000 | A |
6140838 | Johnson | Oct 2000 | A |
6154349 | Kanai et al. | Nov 2000 | A |
6172902 | Wegrowe et al. | Jan 2001 | B1 |
6233172 | Chen et al. | May 2001 | B1 |
6243288 | Ishikawa et al. | Jun 2001 | B1 |
6252798 | Satoh et al. | Jun 2001 | B1 |
6256223 | Sun | Jul 2001 | B1 |
6292389 | Chen et al. | Sep 2001 | B1 |
6347049 | Childress et al. | Feb 2002 | B1 |
6376260 | Chen et al. | Apr 2002 | B1 |
6385082 | Abraham et al. | May 2002 | B1 |
6436526 | Odagawa et al. | Aug 2002 | B1 |
6458603 | Kersch et al. | Oct 2002 | B1 |
6493197 | Ito et al. | Dec 2002 | B2 |
6522137 | Sun et al. | Feb 2003 | B1 |
6532164 | Redon et al. | Mar 2003 | B2 |
6538918 | Swanson et al. | Mar 2003 | B2 |
6545906 | Savtchenko et al. | Apr 2003 | B1 |
6563681 | Sasaki et al. | May 2003 | B1 |
6566246 | deFelipe et al. | May 2003 | B1 |
6603677 | Redon et al. | Aug 2003 | B2 |
6653153 | Doan et al. | Nov 2003 | B2 |
6654278 | Engel et al. | Nov 2003 | B1 |
6677165 | Lu et al. | Jan 2004 | B1 |
6710984 | Yuasa et al. | Mar 2004 | B1 |
6713195 | Wang et al. | Mar 2004 | B2 |
6714444 | Huai et al. | Mar 2004 | B2 |
6744086 | Daughton et al. | Jun 2004 | B2 |
6750491 | Sharma et al. | Jun 2004 | B2 |
6765824 | Kishi et al. | Jul 2004 | B2 |
6772036 | Eryurek et al. | Aug 2004 | B2 |
6773515 | Li et al. | Aug 2004 | B2 |
6777730 | Daughton et al. | Aug 2004 | B2 |
6785159 | Tuttle | Aug 2004 | B2 |
6812437 | Levy et al. | Nov 2004 | B2 |
6829161 | Huai et al. | Dec 2004 | B2 |
6835423 | Chen et al. | Dec 2004 | B2 |
6838740 | Huai et al. | Jan 2005 | B2 |
6842317 | Sugita et al. | Jan 2005 | B2 |
6847547 | Albert et al. | Jan 2005 | B2 |
6887719 | Lu et al. | May 2005 | B2 |
6888742 | Nguyen et al. | May 2005 | B1 |
6902807 | Argoitia et al. | Jun 2005 | B1 |
6906369 | Ross et al. | Jun 2005 | B2 |
6920063 | Huai et al. | Jul 2005 | B2 |
6933155 | Albert et al. | Aug 2005 | B2 |
6958927 | Nguyen et al. | Oct 2005 | B1 |
6967863 | Huai | Nov 2005 | B2 |
6980469 | Kent et al. | Dec 2005 | B2 |
6985385 | Nguyen et al. | Jan 2006 | B2 |
6992359 | Nguyen et al. | Jan 2006 | B2 |
6995962 | Saito et al. | Feb 2006 | B2 |
7002839 | Kawabata et al. | Feb 2006 | B2 |
7005958 | Wan | Feb 2006 | B2 |
7006375 | Covington | Feb 2006 | B2 |
7009877 | Huai et al. | Mar 2006 | B1 |
7041598 | Sharma | May 2006 | B2 |
7045368 | Hong et al. | May 2006 | B2 |
7149106 | Mancoff et al. | Dec 2006 | B2 |
7170778 | Kent et al. | Jan 2007 | B2 |
7190611 | Nguyen et al. | Mar 2007 | B2 |
7203129 | Lin et al. | Apr 2007 | B2 |
7227773 | Nguyen et al. | Jun 2007 | B1 |
7262941 | Li et al. | Aug 2007 | B2 |
7307876 | Kent et al. | Dec 2007 | B2 |
7324387 | Bergemont et al. | Jan 2008 | B1 |
7335960 | Han et al. | Feb 2008 | B2 |
7351594 | Bae et al. | Apr 2008 | B2 |
7352021 | Bae et al. | Apr 2008 | B2 |
7376006 | Bednorz et al. | May 2008 | B2 |
7378699 | Hayakawa | May 2008 | B2 |
7449345 | Horng et al. | Nov 2008 | B2 |
7476919 | Hong et al. | Jan 2009 | B2 |
7502249 | Ding | Mar 2009 | B1 |
7573737 | Kent et al. | Aug 2009 | B2 |
7598555 | Papworth-Parkin | Oct 2009 | B1 |
7619431 | DeWilde et al. | Nov 2009 | B2 |
7630232 | Guo | Dec 2009 | B2 |
7643332 | Leuschner | Jan 2010 | B2 |
7679155 | Korenivski | Mar 2010 | B2 |
7911832 | Kent et al. | Mar 2011 | B2 |
7936595 | Han et al. | May 2011 | B2 |
7986544 | Kent et al. | Jul 2011 | B2 |
8014193 | Nakayama et al. | Sep 2011 | B2 |
8279663 | Nakayama | Oct 2012 | B2 |
8279666 | Dieny et al. | Oct 2012 | B2 |
8334213 | Mao | Dec 2012 | B2 |
8357982 | Kajiyama | Jan 2013 | B2 |
8363465 | Kent et al. | Jan 2013 | B2 |
8456883 | Liu | Jun 2013 | B1 |
8488375 | Saida et al. | Jul 2013 | B2 |
8492881 | Kuroiwa et al. | Jul 2013 | B2 |
8508979 | Saida et al. | Aug 2013 | B2 |
8535952 | Ranjan et al. | Sep 2013 | B2 |
8574928 | Satoh et al. | Nov 2013 | B2 |
8576616 | Saida et al. | Nov 2013 | B2 |
8582355 | Saida et al. | Nov 2013 | B2 |
8617408 | Balamane | Dec 2013 | B2 |
8716817 | Saida et al. | May 2014 | B2 |
8737122 | Saida et al. | May 2014 | B2 |
8737137 | Choy et al. | May 2014 | B1 |
8779537 | Huai | Jul 2014 | B2 |
8823118 | Horng | Sep 2014 | B2 |
8852760 | Wang et al. | Oct 2014 | B2 |
8860156 | Beach | Oct 2014 | B2 |
8878317 | Daibou et al. | Nov 2014 | B2 |
9025368 | Saida et al. | May 2015 | B2 |
9082888 | Kent et al. | Jul 2015 | B2 |
9117995 | Daibou et al. | Aug 2015 | B2 |
9159342 | Kudo et al. | Oct 2015 | B2 |
9245608 | Chen et al. | Jan 2016 | B2 |
9263667 | Pinarbasi | Feb 2016 | B1 |
9299918 | Daibou et al. | Mar 2016 | B2 |
9337412 | Pinarbasi et al. | Mar 2016 | B2 |
9362486 | Kim et al. | Jun 2016 | B2 |
9379314 | Park | Jun 2016 | B2 |
9406876 | Pinarbasi | Aug 2016 | B2 |
9472748 | Kuo et al. | Oct 2016 | B2 |
9484527 | Han et al. | Nov 2016 | B2 |
9548445 | Lee et al. | Jan 2017 | B2 |
9589616 | Meng | Mar 2017 | B2 |
9728712 | Kardasz et al. | Aug 2017 | B2 |
9741926 | Pinarbasi et al. | Aug 2017 | B1 |
9773540 | Zang et al. | Sep 2017 | B2 |
9773974 | Pinarbasi et al. | Sep 2017 | B2 |
10032978 | Schabes | Jul 2018 | B1 |
20020090533 | Zhang et al. | Jul 2002 | A1 |
20020105823 | Redon et al. | Aug 2002 | A1 |
20020132140 | Igarashi et al. | Sep 2002 | A1 |
20030117840 | Sharma et al. | Jun 2003 | A1 |
20030151944 | Saito | Aug 2003 | A1 |
20030197984 | Inomata et al. | Oct 2003 | A1 |
20030218903 | Luo | Nov 2003 | A1 |
20040012994 | Slaughter et al. | Jan 2004 | A1 |
20040061154 | Huai et al. | Apr 2004 | A1 |
20040094785 | Zhu et al. | May 2004 | A1 |
20040130936 | Nguyen et al. | Jul 2004 | A1 |
20040257717 | Sharma et al. | Dec 2004 | A1 |
20050041342 | Huai et al. | Feb 2005 | A1 |
20050051820 | Stojakovic et al. | Mar 2005 | A1 |
20050063222 | Huai et al. | Mar 2005 | A1 |
20050104101 | Sun et al. | May 2005 | A1 |
20050128842 | Wei | Jun 2005 | A1 |
20050136600 | Huai | Jun 2005 | A1 |
20050158881 | Sharma | Jul 2005 | A1 |
20050174702 | Gill | Aug 2005 | A1 |
20050180202 | Huai et al. | Aug 2005 | A1 |
20050184839 | Nguyen et al. | Aug 2005 | A1 |
20050201023 | Huai et al. | Sep 2005 | A1 |
20050237787 | Huai et al. | Oct 2005 | A1 |
20050280058 | Pakala et al. | Dec 2005 | A1 |
20060018057 | Huai | Jan 2006 | A1 |
20060049472 | Diao et al. | Mar 2006 | A1 |
20060087880 | Mancoff et al. | Apr 2006 | A1 |
20060092696 | Bessho | May 2006 | A1 |
20060132990 | Morise et al. | Jun 2006 | A1 |
20060227465 | Inokuchi et al. | Oct 2006 | A1 |
20070019337 | Apalkov et al. | Jan 2007 | A1 |
20070096229 | Yoshikawa et al. | May 2007 | A1 |
20070242501 | Hung et al. | Oct 2007 | A1 |
20080031035 | Rodmacq et al. | Feb 2008 | A1 |
20080049488 | Rizzo | Feb 2008 | A1 |
20080112094 | Kent et al. | May 2008 | A1 |
20080151442 | Mauri et al. | Jun 2008 | A1 |
20080151614 | Guo | Jun 2008 | A1 |
20080259508 | Kent et al. | Oct 2008 | A2 |
20080297292 | Viala et al. | Dec 2008 | A1 |
20090046501 | Ranjan et al. | Feb 2009 | A1 |
20090072185 | Raksha et al. | Mar 2009 | A1 |
20090091037 | Assefa et al. | Apr 2009 | A1 |
20090098413 | Kanegae | Apr 2009 | A1 |
20090161421 | Cho et al. | Jun 2009 | A1 |
20090209050 | Wang et al. | Aug 2009 | A1 |
20090209102 | Zhong et al. | Aug 2009 | A1 |
20090231909 | Dieny et al. | Sep 2009 | A1 |
20100019333 | Zhao et al. | Jan 2010 | A1 |
20100124091 | Cowburn | May 2010 | A1 |
20100193891 | Wang et al. | Aug 2010 | A1 |
20100232206 | Li | Sep 2010 | A1 |
20100246254 | Prejbeanu et al. | Sep 2010 | A1 |
20100271870 | Zheng et al. | Oct 2010 | A1 |
20100290275 | Park et al. | Nov 2010 | A1 |
20110001108 | Greene et al. | Jan 2011 | A1 |
20110032645 | Noel et al. | Feb 2011 | A1 |
20110058412 | Zheng et al. | Mar 2011 | A1 |
20110089511 | Keshtbod et al. | Apr 2011 | A1 |
20110121417 | Li | May 2011 | A1 |
20110133298 | Chen et al. | Jun 2011 | A1 |
20110216436 | Igarashi et al. | Sep 2011 | A1 |
20120052258 | Op DeBeeck et al. | Mar 2012 | A1 |
20120069649 | Ranjan et al. | Mar 2012 | A1 |
20120120520 | Childress et al. | May 2012 | A1 |
20120155156 | Watts | Jun 2012 | A1 |
20120156390 | Araki | Jun 2012 | A1 |
20120181642 | Prejbeanu et al. | Jul 2012 | A1 |
20120188818 | Ranjan et al. | Jul 2012 | A1 |
20120228728 | Ueki et al. | Sep 2012 | A1 |
20120280336 | Jan | Nov 2012 | A1 |
20120280339 | Zhang et al. | Nov 2012 | A1 |
20120294078 | Kent et al. | Nov 2012 | A1 |
20120299133 | Son et al. | Nov 2012 | A1 |
20130001506 | Sato et al. | Jan 2013 | A1 |
20130001652 | Yoshikawa et al. | Jan 2013 | A1 |
20130021841 | Zhou et al. | Jan 2013 | A1 |
20130062714 | Zhu et al. | Mar 2013 | A1 |
20130075845 | Chen et al. | Mar 2013 | A1 |
20130119495 | Vetro et al. | May 2013 | A1 |
20130157385 | Jung et al. | Jun 2013 | A1 |
20130244344 | Malmhall et al. | Sep 2013 | A1 |
20130267042 | Satoh et al. | Oct 2013 | A1 |
20130270523 | Wang et al. | Oct 2013 | A1 |
20130270661 | Yi et al. | Oct 2013 | A1 |
20130307097 | Yi et al. | Nov 2013 | A1 |
20130341801 | Satoh et al. | Dec 2013 | A1 |
20140009994 | Parkin et al. | Jan 2014 | A1 |
20140036573 | Ishihara et al. | Feb 2014 | A1 |
20140042571 | Gan et al. | Feb 2014 | A1 |
20140048896 | Huang et al. | Feb 2014 | A1 |
20140070341 | Beach et al. | Mar 2014 | A1 |
20140087483 | Ohsawa | Mar 2014 | A1 |
20140093701 | Sahoo et al. | Apr 2014 | A1 |
20140103472 | Kent et al. | Apr 2014 | A1 |
20140169085 | Wang et al. | Jun 2014 | A1 |
20140177316 | Otsuka et al. | Jun 2014 | A1 |
20140217531 | Jan | Aug 2014 | A1 |
20140252439 | Guo | Sep 2014 | A1 |
20140252519 | Kim | Sep 2014 | A1 |
20140264671 | Chepulskyy et al. | Sep 2014 | A1 |
20150008550 | Min et al. | Jan 2015 | A1 |
20150056368 | Wang et al. | Feb 2015 | A1 |
20150171316 | Park et al. | Jun 2015 | A1 |
20150279904 | Pinarbasi | Oct 2015 | A1 |
20150287910 | Lu | Oct 2015 | A1 |
20150357015 | Kent et al. | Dec 2015 | A1 |
20160027999 | Pinarbasi | Jan 2016 | A1 |
20160087193 | Pinarbasi et al. | Mar 2016 | A1 |
20160093798 | Kim et al. | Mar 2016 | A1 |
20160099405 | Zimmer et al. | Apr 2016 | A1 |
20160111634 | Lee et al. | Apr 2016 | A1 |
20160126452 | Kuo et al. | May 2016 | A1 |
20160126453 | Chen et al. | May 2016 | A1 |
20160163965 | Han et al. | Jun 2016 | A1 |
20160163973 | Pinarbasi | Jun 2016 | A1 |
20160181508 | Lee et al. | Jun 2016 | A1 |
20160218278 | Pinarbasi et al. | Jul 2016 | A1 |
20160276006 | Ralph et al. | Sep 2016 | A1 |
20160284762 | Wang et al. | Sep 2016 | A1 |
20160315118 | Kardasz et al. | Oct 2016 | A1 |
20160315259 | Kardasz et al. | Oct 2016 | A1 |
20160372656 | Pinarbasi et al. | Dec 2016 | A1 |
20170025472 | Kim et al. | Jan 2017 | A1 |
20170033156 | Gan et al. | Feb 2017 | A1 |
20170033283 | Pinarbasi et al. | Feb 2017 | A1 |
20170033742 | Akerman | Feb 2017 | A1 |
20170047107 | Berger et al. | Feb 2017 | A1 |
20170084826 | Zhou et al. | Mar 2017 | A1 |
20170222132 | Pinarbasi et al. | Aug 2017 | A1 |
20170324029 | Pinarbasi et al. | Nov 2017 | A1 |
20170331032 | Chen et al. | Nov 2017 | A1 |
20170331033 | Kardasz et al. | Nov 2017 | A1 |
20170346002 | Pinarbasi et al. | Nov 2017 | A1 |
20180047894 | Pinarbasi et al. | Feb 2018 | A1 |
20180076382 | Park et al. | Mar 2018 | A1 |
20180114898 | Lee | Apr 2018 | A1 |
Number | Date | Country |
---|---|---|
2766141 | Jan 2011 | CA |
101036195 | Sep 2008 | CN |
102334207 | Jan 2012 | CN |
102959693 | Mar 2013 | CN |
105706259 | Jun 2016 | CN |
105917480 | Aug 2016 | CN |
106062979 | Oct 2016 | CN |
107750382 | Mar 2018 | CN |
107851712 | Mar 2018 | CN |
1345277 | Sep 2003 | EP |
3298636 | Mar 2018 | EP |
2910716 | Jun 2008 | FI |
2817998 | Jun 2002 | FR |
2832542 | May 2003 | FR |
H10-004012 | Jan 1998 | JP |
H11-120758 | Apr 1999 | JP |
H11-352867 | Dec 1999 | JP |
2001-195878 | Jul 2001 | JP |
2002-261352 | Sep 2002 | JP |
2002-357489 | Dec 2002 | JP |
2003-318461 | Nov 2003 | JP |
2005-044848 | Feb 2005 | JP |
2005-150482 | Jun 2005 | JP |
2005-353111 | Nov 2005 | JP |
406647 | Mar 2006 | JP |
2006-128579 | May 2006 | JP |
2008-524830 | Jul 2006 | JP |
2009-027177 | Feb 2009 | JP |
2013-012546 | Jan 2013 | JP |
2014-039061 | Feb 2014 | JP |
5635666 | Dec 2014 | JP |
2015-002352 | Jan 2015 | JP |
2017-510989 | Apr 2017 | JP |
2017-527097 | Sep 2017 | JP |
2017-532752 | Nov 2017 | JP |
10-2014-0115246 | Sep 2014 | KR |
10-2015-0016162 | Feb 2015 | KR |
WO 2009-080636 | Jul 2009 | WO |
WO 2011-005484 | Jan 2011 | WO |
WO 2014-062681 | Apr 2014 | WO |
WO-2015-153142 | Oct 2015 | WO |
2016011435 | Jan 2016 | WO |
WO-2016-014326 | Jan 2016 | WO |
WO-2016-048603 | Mar 2016 | WO |
WO-2016-171800 | Oct 2016 | WO |
WO-2016-171920 | Oct 2016 | WO |
WO-2016-204835 | Dec 2016 | WO |
WO-2017-019134 | Feb 2017 | WO |
WO-2017-030647 | Feb 2017 | WO |
WO-2017-131894 | Aug 2017 | WO |
Entry |
---|
International Search Report and Written Opinion dated May 10, 2018 in PCT/US2018/014645; 14 pages. |
International Search Report and Written Opinion dated May 30, 2018 in PCT/US2018/014641; 13 pages. |
R.H. Koch, et al., “Thermally Assisted Magnetization Reversal in Submicron-Sized Magnetic Thin Films”; Physical Review Letters; The American Physical Society; vol. 84, No. 23; Jun. 5, 2000, pp. 5419-5422 (4 pages). |
K.J. Lee, et al., “Analytical investigation of spin-transfer dynamics using a perpendicular-to-plane polarizer”; Applied Physics Letters; American Institute of Physics; vol. 86, (2005); pp. 022505-1 to 022505-3 (3 pages). |
Kirsten Martens, et al., “Thermally Induced Magnetic Switching in Thin Ferromagnetic Annuli”; NSF grants PHY-0351964 (DLS); 2005; 11 pages. |
Kirsten Martens, et al., “Magnetic Reversal in Nanoscopic Ferromagnetic Rings”; NSF grants PHY-0351964 (DLS); 2006; 23 pages. |
“Magnetic Technology Sprintronics, Media and Interface”; Data Storage Institute, R&D Highlights; Sep. 2010; 3 pages. |
S. Ikeda, et al., “A perpendicular-anisotropy CoFeB—MgO magnetic tunnel junction”; Nature Materials, vol. 9, Sep. 2010; pp. 721-724; 4 pages. |
Soo-Man Seo, et al.; “Current-induced synchronized switching of magnetization;” Applied Physics Letters 101; 2012 American Institute of Physics; Aug. 7, 2012; 6 pages. |
Kent, et al.; U.S. Appl. No. 61/715,111, filed Oct. 17, 2012, entitled “Inverted Orthogonal Spin Transfer Layer Stack”. |
Pinarbasi, et al.; U.S. Appl. No. 14/341,185, filed Jul. 25, 2014, entitled “Method for Manufacturing MTJ Memory Device”. |
Pinarbasi, et al.; U.S. Appl. No. 14/492,943, filed Sep. 22, 2014, entitled “Magnetic Tunnel Junction Structure for MRAM Device”. |
International Search Report and Written Opinion dated Jul. 10, 2015 in PCT/US2015/021580; 12 pages. |
Pinarbasi, et al.; U.S. Appl. No. 14/814,036, filed Jul. 30, 2015, entitled “Precessional Spin Current Structure for MRAM”. |
Kardasz, et al.; U.S. Appl. No. 14/866,359, filed Sep. 25, 2015, entitled “Spin Transfer Torque Structure for MRAM Devices Having a Spin Current Injection Capping Layer”. |
International Search Report and Written Opinion dated Oct. 30, 2015 in PCT/US2015/040700; 11 pages. |
International Search Report and Written Opinion dated Dec. 14, 2015 in PCT/US2015/047875; 13 pages. |
Pinarbasi, et al.; U.S. Appl. No. 15/041,325, filed Feb. 11, 2016, entitled “Method for Manufacturing MTJ Memory Device”. |
Kardasz, et al.; U.S. Appl. No. 15/091,853, filed Apr. 6, 2016, entitled “High Annealing Temperature Perpendicular Magnetic Anisotropy Structure for Magnetic Random Access Memory”. |
Pinarbasi, et al.; U.S. Appl. No. 15/093,367, filed Apr. 7, 2016, entitled “Magnetic Tunnel Junction Structure for MRAM Device”. |
Pinarbasi, et al.; U.S. Appl. No. 15/097,576, filed Apr. 13, 2016, entitled “Polishing Stop Layer(s) for Processing Arrays of Semiconductor Elements”. |
Pinarbasi, et al.; U.S. Appl. No. 15/157,783, filed May 18, 2016, entitled “Memory Cell Having Magnetic Tunnel Junction and Thermal Stability Enhancement Layer”. |
Berger, et al.; U.S. Appl. No. 15/174,482, filed Jun. 6, 2016, entitled “Method and Apparatus for Bipolar Memory Write-Verify”. |
International Search Report and Written Opinion dated Jun. 17, 2016 in PCT/US2016/021324; 9 pages. |
International Search Report and Written Opinion dated Jun. 17, 2016 in PCT/US2016/021691; 9 pages. |
International Search Report and Written Opinion dated Jul. 15, 2016 in PCT/US2016/026473; 9 pages. |
International Search Report and Written Opinion dated Jul. 21, 2016 in PCT/US2016/027445; 10 pages. |
International Search Report and Written Opinion dated Sep. 26, 2016 in PCT/US2016/037843; 10 pages. |
Pinarbasi, et al.; U.S. Appl. No. 15/445,260, filed Feb. 28, 2017, entitled “Precessional Spin Current Structure for MRAM”. |
Pinarbasi, et al.; U.S. Appl. No. 15/445,362, filed Feb. 28, 2017, entitled “Precessional Spin Current Structure for MRAM”. |
International Search Report and Written Opinion dated Apr. 7, 2017 in PCT/US2016/067444; 13 pages. |
Notice of Allowance dated Apr. 21, 2017 in U.S. Appl. No. 15/157,783; 36 pages. |
Pinarbasi, et al.; U.S. Appl. No. 15/656,398, filed Jul. 21, 2017, entitled “Memory Cell Having Magnetic Tunnel Junction and Thermal Stability Enhancement Layer”. |
Kardasz, et al.; U.S. Appl. No. 15/657,498, filed Jul. 24, 2017, entitled “Spin Transfer Torque Structure for MRAM Devices Having a Spin Current Injection Capping Layer”. |
Notice of Allowance dated Jul. 27, 2017 in U.S. Appl. No. 15/097,576; 22 pages. |
Pinarbasi, et al.; U.S. Appl. No. 15/674,620, filed Aug. 11, 2017, entitled “Polishing Stop Layer(s) for Processing Arrays of Semiconductor Elements”. |
Schabes, et al.; U.S. Appl. No. 15/634,629, filed Jun. 27, 2017, entitled “MRAM with Reduced Stray Magnetic Fields”. |
Notice of Allowance dated Oct. 16, 2017 in U.S. Appl. No. 14/814,036; 16 pages. |
Pinarbasi, et al.; U.S. Appl. No. 15/794,871, filed Oct. 26, 2017, entitled “Precessional Spin Current Structure for MRAM”. |
Tzoufras, et al.; U.S. Appl. No. 15/858,950, filed Dec. 29, 2017, entitled “AC Current Pre-Charge Write-Assist in Orthogonal STT-MRAM”. |
Gajek, et al.; U.S. Appl. No. 15/858,988, filed Dec. 29, 2017, entitled “Self-Generating AC Current Assist in Orthogonal STT MRAM”. |
Ryan, et al.; U.S. Appl. No. 15/859,015, filed Dec. 29, 2017, entitled “Shared Oscillator (STNO) for MRAM Array Write-Assist in Orthogonal STT-MRAM”. |
Tzoufras, et al.; U.S. Appl. No. 15/859,030, filed Dec. 29, 2017, entitled “AC Current Write-Assist in Orthogonal STT-MRAM”. |
Schabes, et al.; U.S. Appl. No. 15/862,788, filed Jan. 5, 2018, entitled “Perpendicular Magnetic Tunnel Junction Device with Skyrmionic Enhancement Layers for the Precessional Spin Current Magnetic Layer”. |
Schabes, et al.; U.S. Appl. No. 15/859,384, filed Dec. 30, 2017, entitled “Perpendicular Magnetic Tunnel Junction Device with Skyrmionic Assist Layers for Free Layer Switching”. |
Schabes, et al.; U.S. Appl. No. 15/859,381, filed Dec. 30, 2017, entitled “Perpendicular Magnetic Tunnel Junction Device with Precessional Spin Current Layer Having a Modulated Moment Density”. |
Schabes, et al.; U.S. Appl. No. 15/859,379, filed Dec. 30, 2017, entitled “Perpendicular Magnetic Tunnel Junction Device with Offset Precessional Spin Current Layer”. |
Schabes, et al.; U.S. Appl. No. 15/859,374, filed Dec. 30, 2017, entitled “Switching and Stability Control for Perpendicular Magnetic Tunnel Junction Device”. |
El Baraji, et al.; U.S. Appl. No. 15/859,514, filed Dec. 30, 2017, entitled “Microwave Write-Assist in Orthogonal STT-MRAM”. |
El Baraji, et al.; U.S. Appl. No. 15/859,517, filed Dec. 30, 2017, entitled “Microwave Write-Assist in Series-Interconnected Orthogonal STT-MRAM Devices”. |