The invention relates to an ALD reactor in accordance with the preamble of claim 1 and in particular to an ALD reactor for treating one or more substrates, the ALD reactor comprising at least one reaction chamber including a front plate having gas connections for feeding starting materials, flushing gases and the like gases inside the reaction chamber. The invention also relates to a production line in accordance with the preamble of claim 26 and in particular to a production line which comprises two or more successive process chambers for modifying and/or growing a substrate surface and in which the substrate is carried in horizontal direction through the successive process chambers. The invention further relates to a method in accordance with the preamble of claim 27 and in particular to a method for loading one or more substrates into the reaction chamber of the ALD reactor and removing them therefrom.
In accordance with the prior art, the substrates are loaded into an atomic layer deposition reactor, an ALD reactor, and in particular into its reaction chamber locating inside a low-pressure chamber, and they are removed therefrom through a gate valve, or alternatively, the reaction chamber has an openable cover through which the substrate may be placed in the reaction chamber. In that case each substrate is loaded into the ALD reactor and removed therefrom separately such that the loading/removal consists of a plurality of successive operations or movements, which are performed in a predetermined order.
A problem with the above described arrangement is that complicated and slow solutions for loading a substrate into the reaction chamber make it difficult to utilize the ALD method in connection with production lines. Complicated prior art solutions are slow and require complicated devices for manipulating the substrates when they are loaded into and removed from the reaction chamber by means of several successive movements. In addition, the prior art solutions do not enable a quick and efficient manner of operating the ALD reactor using a flow-through principle such that a substrate may be received from one production stage into the ALD reactor and transferred further to a subsequent production stage after the ALD reactor.
The object of the invention is to provide an ALD reactor, a method for loading the ALD reactor and a production line such that the above problems may be solved. This is achieved by an ALD reactor in accordance with the characterizing part of claim 1, which is characterized in that a front plate is arranged for being placed over the substrate for closing the reaction chamber and at a distance from the substrate for opening the reaction chamber such that the substrate is arranged for being loaded beneath, above or in front of the front plate when the reaction chamber is in an open state, in which the front plate is at a distance from the substrate, and such that the substrate is treatable with the ALD method in the closed state of the reaction chamber, in which the front plate is placed over the substrate. The objects of the invention are further achieved by a production line in accordance with the characterizing part of claim 26. The objects of the invention are still further achieved by a method in accordance with the characterizing part of claim 27, which is characterized in that in the method the substrate is loaded into the reaction chamber for treatment:
by transferring the substrate above, beneath or in front of the front plate of the reaction chamber, the front plate including gas connections for feeding starting materials, flushing gases and the like gases inside the reaction chamber; and
by moving the front plate of the reaction chamber and the substrate with respect to one another in order to place the front plate on the substrate for closing the reaction chamber to a closed state;
and that in the method the substrate is removed from the reaction chamber:
by moving the front plate of the reaction chamber and the substrate with respect to one another in order to place the front plate and the substrate at a distance from one another for opening the reaction chamber to an open state; and
by transferring the substrate away from above, beneath or in front of the front plate of the open-state reaction chamber.
The preferred embodiments of the invention are disclosed in the dependent claims.
The invention is based on the idea that the reaction chamber provided inside a low-pressure chamber of an ALD reactor intended for an atomic layer deposition method (ALD method) is formed to have a structure that a substrate is transferrable in horizontal direction beneath or above a front plate, through which starting materials, flushing gases and other gases are fed, and the substrate and the front plate are movable with respect to one another in order to place the front plate on the substrate surface for closing the reaction chamber. The reaction chamber may thus be set in an open position, in which the front plate is at a distance from the substrate surface above or beneath the substrate. In the open state of the reaction chamber the substrate is trans-ferrable above or beneath the front plate and removable therefrom. In order to close the reaction chamber the front plate and the substrate are moved with respect to one another such that the front plate is placed over the substrate surface to be treated. The relative movement of the substrate and the front plate may be implemented by moving either the front plate or the substrate, or both. When the upper surface of the substrate is treated, the front plate may be lowered from up downwards onto the upper surface of the substrate, or the substrate may be lifted upwards so as to place the front plate onto the substrate surface. Alternatively, the substrate may be lifted upwards and at the same time the front plate may be lowered downwards. When the lower surface of the substrate is treated, the front plate may be lifted upwards to place the front plate on the lower surface of the substrate. The upper face and the lower face of the substrate may be treated both at the same time as described above by providing the reaction chamber with two front plates, which are placed above and beneath the substrate, respectively, whereby the substrate is sandwiched between the front plates. In that case both front plates may be moved in relation to the substrate so as to close the reaction chamber.
Even though it is described in the examples of the present invention that the front and support structures are arranged movable in relation to one another substantially in vertical direction, the front plate and the substrate may also be arranged movable in relation to one another substantially in horizontal direction, for instance. In that case a large glass plate, for instance, which is carried in an upright position, may be transferred in front of the front plate at a distance therefrom such that the front plate and the substrate are movable in horizontal direction with respect to one another to close the reaction chamber, whereby the glass plate is placed in the upright position on the front plate. Correspondingly, the reaction chamber may be opened by means of a relative, horizontal movement of the front plate and the substrate.
An advantage of the method and the system of the invention is that it simplifies the loading of the substrate, in particular a plate-form or planar substrate, into the reaction chamber of the ALD reactor. In accordance with the invention, the opening and the closing of the reaction chamber may be performed by one movement or a relative movement in one direction. Advantageously, in connection with the closing of the reaction chamber it is possible to transfer the substrate into the reaction chamber and enclose it therein, and correspondingly, remove it from the reaction chamber in connection with the opening thereof. Thus, the structure of the reaction chamber is made simple, and correspondingly, the loading of the substrate into the reaction chamber and removal therefrom are made simple and fast, when the closing of the reaction chamber and the loading of the substrate into the reaction chamber are carried out simultaneously by one movement, and correspondingly, the opening of the reaction chamber and the removal of the substrate from the reaction chamber are carried out by one movement, preferably by a movement in one direction. The present invention also has an advantage that the substrate, and optionally also a substrate support, detaches from the conveyor track, whereby no separate movement and force control are needed for upper and lower sealings, the conveyor track is not loaded with closing force, and the conveyor track, such as conveyor belt, may be used for other transfer purposes.
In the following, the invention will be described in greater detail in connection with preferred embodiments, with reference to the attached drawings, in which
With reference to
In this specification, the substrate 2 refers to a substrate alone, or alternatively, both to the actual substrate and the substrate support, to which the substrate is supported or attached during the manufacturing/modifying process. Thus, in the solution of
In the solution of
The reaction chamber in accordance with the present invention is described in greater detail in
The feed and discharge connections are to be provided in the ALD reactor of the invention such that, despite the movement of the front plate 6, the cleanness and tightness of the connections are ensured. A solution for ensuring the tightness of the connections is to mount a completely sealed accordion or bellows pipe of metal between the inner wall of the low-pressure chamber 4 and the movable upper or lower plate. An accordion pipe of this kind is welded to flanges or other corresponding coupling parts that are further attached, by sealing with metal or elastomer, or by welding directly into place to a wall of the low-pressure chamber 4 or to the front plate 6. The connection is thus sealed stationary throughout and it may be provided, if the application or the low pressure zone so requires, completely with metal seals. Alternatively, the accordion pipe may be welded or otherwise tightly attached directly to the wall of the low-pressure chamber and/or to the front plate 6, whereby no separate sealing is needed. When the front plate 6 is moved in a reciprocating manner inside the low-pressure chamber 4, the accordion pipe extends or straightens out and contracts or wrinkles down elastically. In that case inside the low-pressure chamber 4 there will be no sliding, chafing, contacting or other relative movements resulting from lead-ins, which might let or produce impurities inside the low-pressure vessel.
In accordance with the above, a lead-in or connection in the low-pressure vessel implemented by means of an accordion or bellows-type pipe enables a simple and efficient solution, in which the front plate 6 of the reaction chamber is provided movable in relation to the low-pressure chamber 4. The accordion pipe retains tightness during and despite the movement of the movable front plate 6 and/or the support structure 8. By means of the accordion pipe it is possible to introduce gases into the low-pressure vessel and remove them therefrom, and in addition, electricity, thermometers and pressure gauges may be led in via these accordion connections and connected directly to the parts moving inside the low-pressure chamber 4. Inside the accordion pipe there may prevail normal atmospheric pressure, whereby wires and pipes mounted therein as well as other components to be applied inside the low-pressure chamber 4 may be at normal atmospheric pressure and at ambient temperature, and consequently they need not be provided to withstand low pressure or higher temperatures prevailing in the low-pressure vessel. Simultaneously, the accordion connection also enables combination and integration of trace heating of gas connections and lead-ins, when the trace heating is provided in connection with the accordion pipe. Trace heating refers here to the fact that the temperature of connections to be led through a cold wall of the vacuum vessel will be ensured, for instance with separate heaters, so as to avoid possible condensation.
Via the accordion pipe it is also possible to mount in the low-pressure chamber 4 lifting gear, by means of which the front plate 6 and/or the support structure 8 of the reaction chamber may be lifted and lowered. In the solution of
In the embodiment of
The front plate 6 and/or the support structure 8 may be provided with seals, by means of which the reaction chamber can be sealed in the closed state. The seals may be O-rings, for instance. The seals may be placed in the front plate 6 and/or in the support structure 8 such that the seals are between the front plate 6 and the support structure 8 sealing them against one another. In that case the seals may only be provided in one of the front plate 6 and the support structure 8. Alternatively, the seals may be placed in the front plate 6 and/or the support structure 8 such that they rest against the substrate 2 or the substrate support. When high temperatures are used, the sealing of the reaction chamber may be solved without separate seals. In that case the even surfaces of the reaction chamber front plate 6 and/or of the support structure 8 are set against one other such that they come into contact with one another providing the sealing. Also in that case it is possible to seal the reaction chamber by placing at least the edge sections of the front plate 6 and/or the support structure 8 against the substrate 2 or the substrate support so as to provide the sealing.
Further, even though it is set forth above that the ALD reactor 1 or its low-pressure chamber 4 comprises only one reaction chamber, it is also possible to provide the low-pressure chamber 4 of the ALD reactor 1 with two or more reaction chambers. In a preferred solution these reaction chambers are positioned successively in the low-pressure chamber 4 such that a substrate 2 may be introduced into each reaction chamber simultaneously, whereby the capacity of the ALD reactor can be increased. Alternatively, each substrate may be introduced consecutively into these reaction chambers, whereby in each reaction chamber the substrate 2 is treated in a predetermined manner and with predetermined starting materials. In that case in one ALD reactor the substrate 2 may be subjected successively to a variety of surface growing or modifying processes.
In addition, the reaction chamber may be provided with a plasma electrode and/or a spray head or nozzle.
In accordance with
In the embodiment of
The reaction chamber may also be provided such that the support structure 8 is placed below the substrate 2 and the front plate 6 is placed above the substrate 2, between which support structure 8 and front plate 6 the substrate may be placed. In addition, also the support structure 8 and the front plate 6 may be both arranged to move vertically such that the front plate 6 or the support structure 8 locating above the substrate may be lowered downwardly for closing the reaction chamber and lifted upwardly for opening the reaction chamber. In that case if it is only the front plate 6 or the support structure 8 above the substrate 2 that moves, and the front plate 6 or the support structure 8 beneath the substrate is stationary, the front plate 6 or the support structure 8 must be placed beneath the substrate 2 accurately on the same level with the upper surface of the transfer means 18. In an alternative solution both the front plate 6 and the support structure 8 are arranged to move vertically such that the reaction chamber may be closed by moving the front plate 6 and the support structure 8 towards one another and opened by moving them away from one another. This may be implemented in two ways: either the substrate may be lifted, as shown in
In a simpler embodiment of the present invention, the reaction chamber comprises only one front plate 6, which is placed such that the substrate is transferrable above or below it. The front plate 6 placed above the substrate 2 may be lowered on the upper surface of the substrate 2 for closing the reaction chamber and lifted upwardly at a distance from the upper surface of the substrate 2 for opening the reaction chamber. Alternatively, the front plate 6 is placed beneath the substrate 2 and it may be lifted upwardly on the lower surface of the substrate 2 for closing the reaction chamber and it may be lowered downwardly at a distance from the lower surface of the substrate for opening the reaction chamber.
In another embodiment, two planar substrates 2, a first and a second substrate, are superimposed such that their surfaces are against one another. Thus, two substrates may be transferred and treated together. In this embodiment the ALD reactor comprises two front plates 6, a first and a second front plate, which are placed on the side of the first and the second substrates 2, respectively, at a distance from one another. The superimposed first and the second substrates 2 are transferred between the front plates 6 and the front plates 6 are moved onto the substrates so as to form reaction chambers. In that case the first substrate 2 forms the first reaction chamber with the first front plate 6 for treating the surface of the first substrate 2 facing the first front plate 6 and the second substrate 2 forms the second reaction chamber with the second front plate 6 for treating the surface of the second substrate 6 facing the second front plate 6. In this embodiment it is also possible to move the first and the second substrates together towards the first or the second front plate, whereby only the second front plate needs to be moved. This may be implemented, for instance, such that by means of the second front plate the first and the second substrates are moved such that the first stationary front plate will be placed over the first substrate.
In yet another embodiment, two substrates, the first and the second substrates, may be transferred one upon the other or side by side at a distance from one another. The ALD reactor may further comprise one front plate having a first side and a second side. The first and the second substrates are moved simultaneously in front of the first side and the second side of the front plate, respectively, for instance the first substrate in front of or above the first side of the front plate and the second substrate in front of or below the second side of the front plate. For closing the reaction chamber the first and the second substrates are moved such that the first and the second sides of the front plate will be placed over the first and the second substrates, respectively. Alternatively, for closing the reaction chamber it is possible to move the front plate and only one of the substrates. The front plate may be provided such that is forms two separate reaction chambers, one with the first substrate and another with the second substrate. The front plate may also be provided such that it forms only one reaction chamber, whereby the first and the second substrates both constitute a part of the reaction chamber together with the front plate.
With reference to the above, it is possible to implement the reaction chamber by utilizing the described constructional alternatives such that each solution will have an appropriate reaction chamber. In addition, it should be noted that the movement directions of the front plate 6 and the support structure 8 need not be vertical, but they may also move in some other direction, such as horizontal direction. Likewise, the movement direction of the substrate within the process chamber may be some other than the horizontal direction. For instance, the substrate may move vertically and the front plate and/or the support structure may move horizontally. In that case the substrate does not have an upper surface and a lower surface, but a first surface and a second surface, which correspond to the upper surface and the lower surface of the above described embodiments. In that case the substrate is transferred in front of or beside the front plate in the open state of the reaction chamber, in which the front plate is at a distance from the substrate, and the front plate and the substrate are moved with respect to one another for opening and closing the reaction chamber. In a preferred case, however, the plane-like substrate is transferred in the process chamber in the direction parallel to its surface and the front plate and/or the support structure in the direction perpendicular to this substrate surface, whereby the substrate is also lifted and lowered, or moved otherwise when loaded in the reaction chamber, by means of the front plate or the support structure perpendicularly to the substrate surface.
It is apparent to a person skilled in the art that as technology advances the basic idea of the invention may be implemented in a variety of ways. Thus, the invention and the embodiments thereof are not restricted to the above described examples, but they may vary within the scope of the claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 20095126 | Feb 2009 | FI | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/FI2010/050080 | 2/8/2010 | WO | 00 | 7/5/2011 |