Ion implanters are commonly used in the production of integrated circuits (IC) to create in a semiconductor wafer, usually silicon, regions of different conductivity by p- or n-type doping. In such devices, a plasma source is used to ionize the dopant gas. A beam of positive ions is extracted from the source, accelerated to the desired energy, mass filtered and then directed toward the wafer. As the ions strike the wafer, they penetrate to a certain depth (depending on their kinetic energy and mass) and create regions of different electrical conductivity (depending on the dopant element concentration) into the wafer. The n- or p-doping nature of these regions, along with their geometrical configuration on the wafer, define their functionality, e.g., n-p-n or p-n-p junctions within the transistors. Through interconnection of many such doped regions, the wafers can be transformed into complex integrated circuits.
A block diagram of a representative ion implanter 50 is shown in
Taking into account that the rate of ion extraction from the plasma source is given by
dNextr/dt≅AnvB
where A is the area of the extraction aperture, n the ion density (supposedly equal to electron density), and vB=(kBTe/mi)1/2 the Bohm velocity (with kB, Te and mi the Boltzmann constant, electron temperature and ion mass, respectively) a limited number of plasma sources have proved to have sufficient plasma density to be useful as ion sources. In some embodiments, such as Bernas sources, an arc discharge creates the plasma. Tungsten filaments are used to generate a flux of electrons needed to sustain the high arc plasma density. In other embodiments, such as indirectly heated cathodes (IHC) which are also a form of arc discharge, to prevent the filament from detrimental exposure to the plasma and therefore to extend the lifetime of the source, the necessary electrons are provided by thermionic emission from an indirectly heated cathode. While these quasithermal plasma sources are effective in generating the desired ion densities, they are typically only used to create atomic ions, due to the high temperatures developed within the arc chamber. Because dissociation energies are typically low, the thermal energy in the arc plasma is often high enough to breakdown molecular bonds and to fractionate the feeding gas into smaller molecules or atoms.
It has been found that for shallow implants applications where low ion energy is required, in order to overcome the detrimental space-charge effects and to increase the productivity of the ion implantation process, molecular gases with higher content of the active dopant in the molecule such as C2B10H12, B10H14, and B18H22 can be used. The resulting molecular ions can be accelerated at higher energies, thus preventing the beam from the space-charge detrimental effects. However, due to their heavier mass, shallow implants can be performed.
For such implantation processes that require molecular ions rich in active dopant rather than dopant atomic ions, low temperature plasma sources such as RF inductively coupled discharges are well suited. In these discharges, the plasma is produced by coupling the power from an RF generator through an antenna. One such source is an inductively coupled plasma source (ICP). The high RF currents flowing through the antenna give rise to an oscillatory magnetic field which, according to the Maxwell's 3rd electrodynamics law:
∇×{right arrow over (E)}=−∂{right arrow over (B)}/∂t
produces intense electric fields in a limited spatial region (skin depth) which is a function of the RF excitation frequency and gas pressure. Electrons accelerated by these electric fields gain enough energy to ionize the gas molecules and create a plasma. The created plasma is not in thermal equilibrium since electrons have a temperature (usually ˜2-7 eV) much higher than ion or neutral temperature.
Another potential plasma source for ion implantation purposes is an electron cyclotron resonance (ECR) source. The working principle of ECR source utilizes the electron cyclotron resonance to heat the plasma. Microwaves are injected into a volume, at the frequency corresponding to the electron cyclotron resonance as defined below. The volume may contain a low pressure gas. The microwaves may heat free electrons in the gas which in turn collide with the atoms or molecules of the gas in the volume and cause ionization.
In a cold plasma, a wave propagating along the magnetic field obeys the following dispersion relation
where N is the refraction index, fpe=(nee2/4π2ε0me)1/2 is the plasma frequency (with ne, e, ε0, and me the electron density, elementary charge, dielectric constant of the vacuum, and electron mass, respectively), fce=eB/2πme is the electron cyclotron frequency (B is the induction of the magnetic field), k and k∥ are the total and parallel with the magnetic field wave numbers. The equation that implies “+” sign before the fraction corresponds to the right hand polarized wave and the other (“−” sign) to the left hand polarized wave. Relevant to ECR sources are the right hand polarized (RHP) waves because they may propagate for arbitrarily high plasma densities for magnetic field strengths for which the cutoff is absent. More important, RHP waves have a resonance at the electron cyclotron frequency which means the plasma can efficiently be heated by coupling the power to the electronic component. For the most common microwave frequency (2.45 GHz), the resonance condition is met when the magnetic field strength is B=875 Gauss.
Due to its simple design (helical antennae for ICP sources, ring magnets for ECR sources) cylindrical geometry was adopted for such plasma sources. The drawback for this geometry is that the plasma is radially non-uniform, i.e., the plasma column has a very peaked density profile on the axis of the discharge. This non-uniform plasma density profile along radial direction characteristic limits the application of this geometry for large area plasma processing. Therefore, typically a processing (diffusion or expansion) chamber may be used in conjunction with the source so that the plasma generated in the plasma source expands within the processing chamber and the peaked density profile relaxes. However, although smoother, for some applications, the density profile is unacceptable because it still tracks the plasma density profile in the source, as seen in
Therefore, an ion source that can effectively utilize the relatively high plasma density produced by the ICP and/or ECR plasma sources and create a wide and uniform ribbon ion beam would be beneficial from ion implantation perspective.
The problems of the prior art are addressed by the present disclosure, which describes an ion source, capable of generating a wide ribbon ion beam, which utilizes one or two ICP or ECR plasma sources. In addition to the plasma source(s), the ion source also includes a diffusion chamber. The diffusion chamber, which is a metal cylinder, has an extraction aperture oriented along the central axis of the cylinder. In this way, the peaked radial density profile associated with the cylindrical symmetry of the plasma source is not relevant.
In one embodiment, dual ICP or ECR plasma sources, located on opposing ends of a diffusion chamber are used to create a uniform plasma density along the axial direction in the diffusion chamber and consequently a uniform extracted ribbon ion beam.
In a further embodiment, a multicusp magnetic field surrounding the diffusion chamber is used to further improve the uniformity of the extracted ion beam.
Beam uniformity can also be controlled by means of several independent controls, including gas flow rate, input RF or microwave power, driving frequency, and for ECR sources, the shape of the axial magnetic field profile for each plasma source.
a shows the major components of a conventional ECR plasma source;
b shows the magnetic field profile associated with the ECR source presented in
a shows a side view of an embodiment of the dual ICP plasma source;
b shows a side view of an embodiment of the dual ECR plasma source;
a shows a side view of a first embodiment of the diffusion chamber;
b shows a transversal cross section of the diffusion chamber of
c shows a transversal cross section of the diffusion chamber of
d shows an end view of a first embodiment of the ion source shown in
a shows a side view of the second embodiment of the diffusion chamber;
b shows a longitudinal cross section of the diffusion chamber of
c shows a longitudinal cross section of the diffusion chamber of
d shows an end view of a second embodiment of the ion source shown in
a is a graph showing the distribution of the axial magnetic field induction in the conjugated ECR plasma sources and diffusion chamber
b is a graph showing representative axial plasma densities for various ECR plasma+diffusion chamber configurations;
a shows, in a longitudinal cross-section, the main components of a typical ECR plasma source 150. A cylinder 155 is preferably used to contain the low pressure gas. For proper functioning, the gas pressure within the cylinder 155 made of non-magmetic material is preferably maintained at less than 20 mTorr. To create the electron-cyclotron resonance zone, the necessary magnetic field is provided by a magnet 160, most preferably a solenoid or multiple axially symmetric solenoids, capable of providing an axial magnetic field in excess of 1 kGauss. This will allow running the ECR source at the typical 2.45 GHz microwave frequency. However, running at other RF frequencies is also possible. Higher values of the magnetic field strength can be provided by a stack of Sm—Co or Nd—Fe—B permanent magnets. Thus, the magnet 160 is understood to represent either one or more solenoids or a permanent magnet configuration throughout this disclosure. One end of the ECR source is terminated by a flange 165 that preferably contains the gas inlet 170 through which the desired working gas 151 is introduced into the chamber at a certain flow rate. This end may include a microwave coupler (which are well known in the art) and a dielectric window 168 through which microwaves 157 may enter the cylinder 155. The dielectric window 155 may be made of materials such as quartz, alumina, or sapphire. These microwaves are at a frequency equal to the electron cyclotron resonance, as defined by the magnetic field value at a certain axial position. The opposite end is open and preferably has an elastic coupling 180 for connection of the cylinder 155 to a metallic diffusion chamber. The solenoid(s) 160 is (are) fed by a DC current supply (not shown). The direction of current flow or the orientation of the permanent magnets is chosen so that the magnetic field induction (B) points towards the open end of the cylinder 210 thereby allowing propagation of RHP waves. The {circle around (x)} and {circle around (·)} symbols used in conjunction with the solenoid 160 are used to signify the fact that the current enters and respectively exits the plane of the paper.
The magnetic cylinder's relative axial positions may be precisely tailored so that the desirably electron cyclotron resonance zone will be spatially located at the open end of the source as shown by the hatched zone in
The plasma sources described above typically produce a plasma having a radial density profile that peaks along the central axis of cylinder 110,155. Even when used in conjunction with a diffusion chamber, although more or less flattened, the density profile in the diffusion chamber still exhibits the same non-uniform radial profile as shown in
a illustrates a first embodiment of the ion source 300. Two ICP plasma sources 301, 302 such as those described in conjunction with
b illustrates a second embodiment of the plasma ion source 300. Instead of conjugated ICP sources, two ECR plasma sources 301, 302 such as those described in conjunction with
a shows a side view of a representative diffusion chamber, while
To allow extraction of positive ions, the chamber is electrically biased at positive potential by a high voltage DC power supply (not shown). In one embodiment, shown in
As shown in
By a proper adjustment of these parameters, a strong magnetic field can be created near by the chamber wall whereas the bulk plasma is magnetic field free. In this way, the charged particles (electrons and ions) are trapped by the magnetic field lines 285 and thus resulting in lower losses to the chamber walls 240 and implicitly higher plasma density and uniformity. The strength of the magnetic field may be increased by adding a steel sheet 290 that surrounds the magnets and creates the “yoke” effect. In one embodiment for square cross-section shaped Sm—Co magnets having Δ=⅜″, and d=¾″, a magnetic field strength of 50 G at 1.5″ from the chamber wall was obtained. For the proposed geometry, the resulting overall multicusp magnetic field causes the plasma 260 to shift toward the extraction aperture 230. By having no magnetic field in the extraction aperture region, the charged particles are free to move toward the extraction aperture 230 and therefore a high density ion beam can be extracted. Shown in
In another embodiment shown in
b illustrate two representative configurations used to generate the multicusp magnetic field. For both embodiments, to prevent the beam from undesired magnetic effects, the ion beam extraction region and the bulk plasma is magnetic field free, i.e., the multicusp magnetic field extends over the circumference of the diffusion chamber except the circular sector where the extraction aperture is located. Those skilled in the art will appreciate that other techniques and configurations can be used to achieve this field.
Referring to
b illustrates representative graphs showing the plasma density of various configurations. The lines labeled “PS1” and “PS2” show representative relationships of the plasma density as a function of axial position for the case in which only one plasma source (ICP or ECR) injects plasma into the diffusion chamber. Note that the density decreases as the axial distance from the plasma source 100 increases. The line labeled “PS1+PS2” shows a representative graph of the plasma density for the configuration in which both plasma sources are in operation, i.e., pumping plasma in the common diffusion chamber, but the diffusion chamber has no magnetic multicusp field. Note that the densities from the individual plasma sources add together to create a more uniform plasma density along the axial direction of the diffusion chamber. In this way, the decrease in plasma density experienced within the diffusion chamber 210 as the distance from the first source 301 increases is counteracted by the existence of a second plasma source 302. The line labeled “PS1+PS2+MM” shows a representative profile of the plasma density for the configuration in which both plasma sources are working and the magnetic multicusp field is present. The presence of the magnetic multicusp field extends the longitudinal range of the plasma uniformity.
Note that while the preferred embodiment utilizes two plasma sources (either ICP or ECR), the disclosure also contemplates use of a single plasma source coupled with a diffusion chamber. In this embodiment, the non-uniform beam profile resulting from the decrease in plasma density along the longitudinal axis for deeper and deeper positions into the diffusion chamber can be counteracted through other techniques, such as the use of an extraction slit having variable height (progressively increasing in the direction of plasma density decrease) and/or introducing a magnetic field gradient in the multicusp magnetic field configuration in the diffusion chamber.
Both types of ion sources described above allow the resulting plasma density in the diffusion chamber to be varied in a number of ways. For both embodiments, since each plasma source is independently fed with working gas and the vacuum pumping is accomplished through the extraction aperture on the common diffusion chamber, the rate of gas flow into each of the plasma sources can be varied independently. This will result in a fine adjustment of the plasma density profile along longitudinal direction.
Secondly, the multi-cusp magnetic field within the diffusion chamber can be adjusted to improve the uniformity of the plasma density. This can be achieved by choosing adequate values for the surface magnetic field strength, magnet bars dimensions and separation gaps.
In the case of the ICP sources, the power used to drive the RF antennae can be varied independently for each source, thereby introducing another control parameter. Similarly for ECR sources, the injected microwave power can be varied independently.
In the case of the ECR source, an additional method of adjusting the plasma density axial profile and implicitly the beam uniformity is by shaping the magnetic field in each plasma source, either by varying the DC current (in the scenario where solenoids are used) or adjusting the spatial position (in the scenario where permanent magnets are used).
Fine tuning of each of these control knobs will allow extraction of a high ribbon ion beam current with very good uniformity over extended width. This will allow uniform dose implants for large diameter wafers.
As described above, this device can be used for ion implanters. It is expected that uniform ribbon ion beams of several hundred milliamps, having a width greater than 350 and up to 500 millimeters can be generated using this ion source.
However, its uses are not limited to only classical ion implantation applications. This device can be used for other applications, for instance in doping on-wafer build solar cells as shown in
In a similar fashion, the solar cell foils 400, as shown in
Number | Name | Date | Kind |
---|---|---|---|
6010755 | Suzuki | Jan 2000 | A |
6225745 | Srivastava | May 2001 | B1 |
6332947 | Ichimura et al. | Dec 2001 | B1 |
6863021 | Sneh | Mar 2005 | B2 |
20030015965 | Godyak | Jan 2003 | A1 |
20100055345 | Biloiu et al. | Mar 2010 | A1 |
Number | Date | Country | |
---|---|---|---|
20100264328 A1 | Oct 2010 | US |