1. Field of the Invention
The present disclosure generally relates to deposition apparatuses and methods of operating thereof. The present disclosure relates to substrate coating technology solutions involving equipment, processes and materials used in the deposition, patterning, and treatment of substrates and coatings, with representative examples including (but not limited to) applications involving: semiconductor and dielectric materials and devices, silicon-based wafers, flat panel displays (such as TFTs), masks and filters, energy conversion and storage (such as photovoltaic cells, fuel cells, and batteries), solid-state lighting (such as LEDs and OLEDs), magnetic and optical storage, micro-electro-mechanical systems (MEMS) and nano-electro-mechanical systems (NEMS), micro-optic and opto-electro-mechanical systems (OEMS), micro-optic and optoelectronic devices, transparent substrates, architectural and automotive glasses, metallization systems for metal and polymer foils and packaging, and micro- and nano-molding. More specifically, it relates to sputtering apparatuses having a rotatable target and methods of operating thereof.
2. Description of the Related Art
In many applications, it is necessary to deposit thin layers on a substrate. The term “substrate” as used herein shall embrace both inflexible substrates, e.g. a wafer or a glass plate, and flexible substrates such as webs and foils. Known techniques for depositing layers are in particular evaporating and sputtering.
In an evaporation process, the material to be deposited is heated so that it evaporates and condenses on the substrate. Sputtering is a vacuum coating process used to deposit thin films of various materials onto the surface of a substrate. For example, sputtering can be used to deposit a metal layer such as a thin layer of aluminium or ceramics. During the sputtering process, the coating material is transported from a target consisting of that material to the substrate to be coated by bombarding the surface of the target with ions of an inert gas that are accelerated by a high voltage. When the gas ions hit the outer surface of the target, their momentum is transferred to the atoms of the material so that some of them can gain sufficient energy to overcome their bonding energy in order to escape from the target surface and to deposit on the substrate. Thereon, they form a film of the desired material. The thickness of the deposited film is, inter alia, dependent on the duration of exposing the substrate to the sputtering process.
For example, sputtering is used in the production of thin-film solar cells. Generally, a thin-film solar cell comprises a back contact, an absorbing layer, and a transparent and conductive oxide layer (TCO). Typically, the back contact and the TCO layer is produced by sputtering whereas the absorbing layer is typically made in a chemical vapour deposition process. In comparison to an evaporation process such as chemical vapour deposition, sputtering is advantageous in that also materials can be sputtered that cannot be evaporated. Further, the adhesion of the produced layers to the substrate is typically stronger in sputtering processes than in evaporation processes. Further, sputtering is a directional process so that the major part of the material is transferred to the substrate and does therefore not coat the interior of the deposition apparatus (as in evaporation applications).
Notwithstanding the advantages of sputtering, sputtering has also drawbacks. In comparison to evaporation, sputtering a substrate takes longer. Sputtering rates are normally much lower than evaporation rates. It is therefore an ongoing desire to speed up sputtering processes.
On the other hand, despite the better adhesion of sputtered layers to the substrate, it is an ongoing desire to further improve the quality of the deposited layers.
In view of the above, a deposition apparatus and a method for depositing a layer on a substrate are provided.
According to one aspect, a deposition apparatus for sputtering material on a substrate is provided with a substrate holder for holding the substrate, a rotatable target adapted for being sputtered, and a heating system including a back side heating for heating the substrate from the back and a front side heating for heating the substrate from the front. The rotatable target acts as the front side heating and is adapted for heating the substrate to a temperature of at least 100° C.
According to another aspect, a method for depositing a layer of depositing material on a substrate in a deposition apparatus is provided, the method includes holding a substrate, rotating a rotatable target, sputtering material on the substrate, heating the substrate to a temperature of at least 100° C. by the front side heating, and using the rotatable target for heating the substrate from the front.
The description that the front side heating is adapted for heating the substrate to a temperature of 100° C. should be understood in that the front side heating is adapted for causing a temperature rise of the substrate up to a temperature of 100° C.
According to a further aspect, a deposition apparatus for sputtering material on a substrate is provided with a substrate holder for holding the substrate, a rotatable target adapted for being sputtered, and a heating system including a back side heating for heating the substrate from the back and a front side heating for heating the substrate from the front. The rotatable target acts as the front side heating and is adapted for increasing the substrate's temperature by an increment of at least 100° C.
According to another aspect, a method for depositing a layer of depositing material on a substrate in a deposition apparatus is provided, the method includes holding a substrate, rotating a rotatable target, sputtering material on the substrate, increasing the substrate's temperature by an increment of at least 100° C. by the front side heating, and using the rotatable target for heating the substrate from the front.
According to embodiments, the front side heating is adapted for heating the substrate to a temperature of at least 200° C., more typically to a temperature of at least 300° C. According to embodiments, the front side heating is adapted for increasing the substrate's temperature by an increment of at least 200° C., more typically at least 300° C.
Further aspects, details, advantage and features are apparent from the dependent claims, the description and the accompanying drawings.
Embodiments are also directed to apparatuses for carrying out each of the disclosed methods and including apparatus parts for performing each described method steps. These method steps may be performed by way of hardware components, a computer program by appropriate software, by any combination of the two or in any other manner. Furthermore, embodiments are also directed to methods by which the described apparatus operates or by which the described apparatus is manufactured. It includes method steps for carrying out functions of this apparatus or manufacturing parts of the apparatus.
So that the manner in which the above recited features of embodiments can be understood in detail, a more particular description of embodiments of the invention, briefly summarized above, may be had by reference to examples of embodiments. The accompanying drawings relate to embodiments of the invention and are described in the following. Some of the above mentioned embodiments will be described in more detail in the following description of typical embodiments with reference to the following drawings in which:
Within the following description of the drawings, the same reference numbers refer to the same components. Generally, only the differences with respect to the individual embodiments are described.
Reference will now be made in detail to the various embodiments, one ore more examples of which are illustrated in the figures. Each example is provided by way of explanation, and is not meant as a limitation of the invention.
The process of coating a substrate with a material as described herein refers typically to thin-film applications. The term “coating” and the term “depositing” are used synonymously herein.
The deposition apparatus comprises a process source. Generally, this is a rotatable target adapted for being sputtered. As will be discussed in more detail below, the rotatable target can be a bonded rotatable target or a non-bonded rotatable target.
Generally, sputtering can be undertaken as diode sputtering or magnetron sputtering. The magnetron sputtering is particularly advantageous in that its deposition rates are rather high. Typically, a magnet is positioned within the rotatable target. By arranging the magnet or the magnets behind the target, i.e. inside of the target in the case of a rotatable target, in order to trap the free electrons within the generated magnetic field directly below the target surface, these electrons are forced to move within the magnetic field and cannot escape. This enhances the probability of ionizing the gas molecules typically by several orders of magnitude. This, in turn, increases the deposition rate magnificently.
When using the target as a front side heating for the substrate, it is typical that the temperature of the target is controlled such that it is limited by the melting temperature of the target material. Further, in the event of a two or more piece target, such as in the event of a target tube and a target backing tube, it has to be limited in order to take into account the different thermal expansion coefficients of the backing tube and the target. In other words, the heating has to be undertaken such that the two or more piece target does not crack due to the heating. Further, that the magnets are not allowed to exceed a certain temperature is typically the condition that has to be considered.
According to some embodiments, the front side heating is undertaken by a multitude of rotatable targets. That is, the deposition apparatus comprises at least two rotatable targets. The multitude of targets acts as front side heating of the substrate. Further, according to some embodiments, the heat profile of the substrate can be provided in several steps. For instance, one of the multitude of rotatable targets is heated to a lower temperature than the other one.
Typically, the magnets used within the rotatable target are permanent magnets. The permanent magnets typically need cooling because they are positioned within the target tube which is, according to one embodiment, held at a high temperature. In operation, the magnets become rather hot. This is due to the fact that they are surrounded by the rotatable target that is bombarded with ions. Due to the resulting collisions this leads to a heating up of the target.
For that reason, it is usual to provide a cooling of the target and the magnets. This was done in order to keep the magnets at a suitable operating temperature. Further, it has been generally assumed that the optimum deposition temperature is below a certain temperature
Surprisingly, it has been found by the inventors that high temperatures of the target increase the quality of the deposited substrate when compared with the same application at lower temperatures. When talking about quality within the present disclosure, this is to be understood as, for example, the resistivity (which, depending on the application, may have a specific value that can be high or low), the optical parameters such as the absorption spectrum, the thickness, the density, the hardness, the adhesion, the scratch resistance, etc. Depending on the specific application, one or more of these properties of the coated layer have to be set to a desired value. Moreover, this value should vary neither within the same layer nor between several coated substrates.
When examining the effect of the higher target temperature, it has further been found that the process of bombarding the material away from the target, i.e. the sputtering in a strict sense, is not very much influenced by the higher temperature. That is, the sputtering process step of ejecting the material from the target was not found to be influenced by the temperature. Further research revealed that it is the effect of the high temperature target on the substrate that leads to an improved layer deposition. Hence, according to aspects of the present disclosure, it is advantageous to provide a heating from the front side of the substrate in order to heat the substrate up and to provide a heating from the front side as well. In order to do the latter, the rotatable target is used as front side heating.
However, in particular in view of magnetron sputtering, it has to be considered that the magnets must be kept at an operating temperature below a certain threshold value. The typical threshold value for magnet operation is about 80° C. In order to allow the target to become hotter than the threshold temperature of the magnets, it is possible to provide for heat isolation between the outer target and the inside of the target. Such an isolation may be the target material itself (if it is heat isolating). It is also possible to have an additional layer between the outer target that is supposed to be sputtered and the target tube carrying the outer target. For instance, the additional layer may also be a bonding layer for bonding the target material to the target tube.
In addition to the front side heating performed by the target, a back side heating is provided that heats the substrate from the back side. By this combined heating system it can be assured that the substrate is held at a high temperature. According to aspects, the front side heating causes the substrate to reach a temperature of at least 100 degree Celsius. It has been found that the quality of the layers deposited at such a temperature is high when compared to layers deposited at lower temperatures. This effect is further enhanced when the temperature rise caused by the front side heating is to a temperature of at least 200° C., 300° C. or even at least 400° C. Generally, there is no clear-cut correlation between the temperature of the target and the substrate temperature. There might be embodiments where the target is heated to a high temperature such as up to 400° C. and, yet, the substrate is somewhat in the range of the ambient temperature. Hence, according to the present disclosure, it has to be assured that the substrate is at least 100° C. or even hotter by the effect of the target acting as front side heating.
The present disclosure is directed to the coating of several materials. In particular, it is related to the coating of glass. Glass plates have normally a rather high heat storage capacity so that, once they are heated, e.g. prior to entering the deposition chamber, the temperature drop is moderate. Nevertheless, by providing the front side heating, the whole production process becomes more cost-effective because the preheating can be reduced. Moreover, the positive effects of the additional front side heating become effective at lower temperatures if compared to wafer coating. In particular, when coating glass, it is typical that the temperature rise caused by the front side heating is at least 150° C. or 200° C.
The present disclosure is also typically related to wafer coating. The heat storage capacity of the wafers is typically low. Hence, in prior art, if they are preheated prior to entering the deposition chamber, their temperature drop within the deposition chamber is considerable. Hence, by the application of the present disclosure, in particular by providing a front side heating capable of heating the wafer to a temperature of at least 100° C., the temperature within the chamber can be held at a high temperature.
It is typical to heat wafers to high temperatures. Typically, the front side heating heats the wafer to a temperature of at least 250° C., 300° C. or even 400° C. In many embodiments of coating wafers, higher temperatures such as between 350° C. and 500° C. or even 550° C., cause particularly noticeable positive effects of a quality to increase. For instance, this may occur for coating a silicon nitride layer on a wafer.
Typically, the thickness of the deposited layer is smaller than 1 mm, more typically smaller 1 □m, even more typically smaller than 100 nm.
Typically, the rotatable target comprises a target tube. The target tube is denoted by reference number 121 in
In more general terms, the magnetic device is positioned on that side of the target that is closer to the substrate to be coated. The rotatable target is typically of cylindrical shape. According to many embodiments, at least a part of the surface of the magnetic device is—in its cross section—circularly shaped. This is also exemplarily shown in
In
As described herein, it is desired to heat the target up to a high temperature. Typically, at the same time, it is desired to keep the magnetic device below the operation threshold temperature. By reducing the space between the magnetic device and the target, the cooling of this region of the target tube is not effective due to the small interspace through which the flow has to take place. Hence, the target is insignificantly cooled. This effect can be further enhanced by providing the tube with isolating material which will be discussed in more detail below.
Filling the target tube with a cooling medium provides a cooling system that is arranged within the rotatable target. The cooling system serves the cooling of the interior of the target. Most of all, this is the magnetic device. The cooling system according to embodiments described herein has to be adapted for keeping the magnetic device at a temperature of less than the magnetic device operating threshold temperature. On the other hand, it has to be adapted for cooling the rotatable target as less as necessary so that the rotatable target can still act as a front side heating for the substrate. According to typical embodiments, a control feedback loop is provided that controls the cooling element of the rotatable target. Typically, the control feedback loop comprises a target temperature measurement and control means like a metering valve for the supply of cooling fluid. Alternatively or in addition to the temperature measurement of the target, a substrate temperature measurement can be provided. For instance, it is possible that the substrate temperature is constantly controlled to be at or larger than the predetermined minimum temperature. Depending on the temperature measurement result, the cooling fluid temperature is adjusted accordingly, i.e. increased, if the substrate tends to be too cold, or decreased, if the substrate temperature tends to be too high. Typically, water is used as cooling fluid.
Further, the deposition apparatus comprises an outlet 430 for being connected with a vacuum pump. In other embodiments, reference number 430 refers to at least one vacuum pump that is arranged directly on the deposition apparatus. Further, the apparatus comprises an inlet 440 for the sputtering gas. Typically, the sputtering gas is an inert gas that is introduced into the deposition apparatus when in operation. According to a typical embodiment, the sputtering gas is Argon. The sputtering gas is ionized by the electrons and afterwards accelerated towards the target in order to eject target material from the target. Typically, the atmosphere within the deposition apparatus is between 10−2 mbar and 10−4 mbar.
The gas introduced into the deposition apparatus may further comprise an element that binds to the target material. For instance, the production of a silicon nitride layer may be done by providing bulk silicon as target, and by introducing nitrogen gas into the apparatus. Further, in the event that a hydrogen-containing silicon nitride layer is desired, small amounts of ammonia (NH3) or hydrogen (H2) gas are added apart from the nitrogen gas. This benefits the layer quality in terms of passivation properties.
The substrate is then fed to the deposition apparatus that comprises a heating system with a back side heating for heating the back side of the substrate, and a front side heating for heating the front side of the substrate. Therefore, it is possible to keep the temperature of the substrate at a high level. According to the embodiment shown in
As described with respect to
Secondly, the absolute temperature of the substrate is at a high level. According to an aspect, the temperature is at least 100 degree Celsius. According to yet another embodiment, the substrate temperature is kept at at least 200 degree Celsius, more typically at at least 300 degree or even 400 degree Celsius. The high temperature of the substrate improves the layer quality.
As can be seen from these research results, the mass density ρ increases at higher substrate temperatures. Along with the substrate mass density ρ, the overall layer quality improves as well.
Generally, all metals and ceramics having a sufficient conductivity can be sputtered. Depending on the reactive gases, dielectric layers can also be formed. The layers deposited are typically amorphous or monocrystalline. Typically, for metallic processes or dielectric layers from ceramic targets, DC power is used for sputtering. In the event of reactive processes, MF power is normally used.
In general, the target tube is typically made of a metal. Typical materials used for sputtering are silicon (Si), indium (In), indium alloys such as indium tin (InSn), tin (Sn), zinc (Zn), aluminium (Al), silicon nitride (SiN), copper (Cu), aluminium oxide (Al2O3), zinc oxide (ZnO), CuInGa (ClG), or combinations thereof such as ZnO:Al2O3. Typically, the deposited layer such as the silicon layer is a crystalline layer. Generally, all metals and ceramics that are conducting enough can be sputtered. Depending on the reactive gas, dielectric layers can be formed such as e.g. hydrogen-containing silicon nitride (SiN:H). The layers are typically amorphous or microcrystalline.
According to some embodiments, the target tube is bonded to a target backing tube that is denoted by reference number 910 in the embodiment of
According to other embodiments, a non-bonded rotatable target is used for sputtering. In this event, for example, the target tube is either connected in a non-bonded way to a target backing tube such as by mechanical pressure, or the rotatable target is a one-piece tube consisting of the material to be coated only.
According to the embodiments that shall exemplarily be illustrated with respect to
It is further possible that this layer does not completely fill the area between the target backing tube and the target tube. For instance, it can be designed as spacers that are arranged at least at some positions between the target tube and the target backing tube such as at three or four positions. Since the target tube is located in the deposition apparatus vacuum, and therefore the vacuum is present also in between the target backing tube and the target tube, this embodiment will also provide for a good thermal isolation.
Due to the fact that the rotatable target is kept at a high temperature, the deposition apparatus and the environment of it become very hot according to an aspect described herein. Therefore, according to some embodiments, the deposition apparatus is provided with an exterior cooling system. According to some embodiments, the exterior cooling system (not shown in the figures) is attached to the deposition apparatus, for example above the position of the target. The exterior cooling system prevents the deposition apparatus from an overall heating.
The application of present disclosure allows maintaining the substrate temperature at a high level during coating. This is particularly useful for coating thin layers such as silicon wafers. Further, it allows reducing the preheating power and is thus more cost effective. This is particularly useful in coating applications where glass or the like is coated which has a high specific heat capacity.
While the foregoing is directed to embodiments of the invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
This written description uses examples to disclose the invention, including the best mode, and also to enable any person skilled in the art to make and use the invention. While the invention has been described in terms of various specific embodiments, those skilled in the art will recognize that the invention can be practiced with modification within the spirit and scope of the claims. Especially, mutually non-exclusive features of the embodiments described above may be combined with each other. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal languages of the claims.