Patent Application
20070190762
The present invention relates to device manufacturing methods using a lithographic apparatus, and to a computer program product.
A lithographic apparatus is a machine that applies a desired pattern onto a substrate, usually onto a target portion of the substrate. A lithographic apparatus can be used, for example, in the manufacture of integrated circuits (ICs). In that instance, a patterning device, which is alternatively referred to as a mask or a reticle, may be used to generate a circuit pattern to be formed on an individual layer of the IC. This pattern can be transferred onto a target portion (e.g. comprising part of, one, or several dies) on a substrate (e.g. a silicon wafer). Transfer of the pattern is typically via imaging onto a layer of radiation-sensitive material (resist) provided on the substrate. In general, a single substrate will contain a network of adjacent target portions that are successively patterned. Known lithographic apparatus include so-called steppers, in which each target portion is irradiated by exposing an entire pattern onto the target portion at one time, and so-called scanners, in which each target portion is irradiated by scanning the pattern through a radiation beam in a given direction (the “scanning”-direction) while synchronously scanning the substrate parallel or anti-parallel to this direction. It is also possible to transfer the pattern from the patterning device to the substrate by imprinting the pattern onto the substrate.
In order to increase the density of devices on an integrated circuit, the pitch of lines and other features is typically reduced. However, many lithography apparatus operate at or near their resolution limits. Various process techniques have been developed to enable features smaller than the minimum size imagable by a lithography apparatus to be created. For example, United States Patent Application Publication No. US 2003/0203320 discloses the use of conformal organic polymeric films to shrink gaps in a lithography pattern.
As another example, to etch lines narrower than the width of a line in resist, the exposed resist can be treated with an electron beam, causing the remaining resist to liquefy or plasticize and flow to partially close the exposed lines. Then, lines can be etched into the underlying substrate that are narrower than the lines printed in the resist. To expose lines at a pitch smaller than the minimum pitch imagable by the lithographic apparatus, double exposure techniques can be used—a first set of lines is imaged at double the desired pitch, then a second set, complementary to the first set, is imaged again at double the desired pitch but with a positional offset equal to the desired pitch. U.S. Pat. No. 6,589,713 discloses a method using both of these techniques to print features of reduced width and pitch.
A technique not using an e-beam to print spacer gate structures at high densities is disclosed in the article “Edge Defined Lithography for Nano-scale III-N Field Effect Transistors” by J P Long et al. (published in The International Conference on Compound Semiconductor Manufacturing Technology 2005 On-line Digest, available at http://www.gaasmantech.org/Digests/2005/index.htm, no 14.22). In this technique, a sacrificial polysilicon layer is patterned using conventional photolithographic techniques to form mesas and then a thin layer of Si3N4 is conformally deposited over the entire wafer. The Si3N4 layer is then etched using a highly anisotropic Reactive Ion Etching (RIE) process to leave thin Si3N4 walls either side of the polysilicon mesas. The mesas are then removed using a wet KOH etch to leave only the Si3N4 walls, which serve as masks during subsequent etching of SiO2 and polysilicon layers underneath the sacrificial polysilicon layer. The end result is thin polysilicon fins at twice the density of the mesas formed in the sacrificial polysilicon layer.
A similar technique is disclosed in “A Spacer Patterning Technology for Nanoscale CMOS” by Yang-Kyu Choi et al (published in IEEE Transactions on Electron Devices, Vol 49, No 3, March 2002) to make silicon fins for FinFETS.
However, the disclosed techniques have limited application and may sometimes incorrectly image line-ends.
It is therefore desirable to provide an improved method for manufacture of device features at higher densities.
According to an aspect of the invention, there is provided a device manufacturing method using a lithographic apparatus, the method comprising:
printing an array of sacrificial features on a first layer of a substrate, the array of sacrificial features having a first number of features per unit area;
providing a substantially conformal coating to the array of sacrificial features so as to form a first mask defining a first array of holes, the first array of holes being interleaved with the array of sacrificial features and having the first number of features per unit area;
removing the sacrificial features so as to form further holes in the first mask that, with the first array of holes, define a second array of holes having a second number of features per unit area that is double the first number of features per unit area;
providing a second mask that covers a selected part of the second array of holes; and
processing a part of the first layer not covered by the first and second masks.
According to an aspect of the invention, there is provided a device manufacturing method using a lithographic apparatus, the method comprising:
patterning a first sacrificial hardmask of a substrate using the lithographic apparatus to form a first array of projecting features at a first density;
substantially conformally depositing a second sacrificial hardmask onto the first array so that an array of recessed features at the first density is formed, the recessed features being interspersed with the projecting features;
directionally etching the second sacrificial hardmask to reveal the distal surfaces of the projecting features and so that the recessed features become apertures through the second sacrificial hardmask;
selectively etching away the projecting features to leave apertures in the second sacrificial hardmask; and
etching a first hardmask of the substrate through the apertures in the second sacrificial hardmask.
According to an aspect of the invention, there is provided a device manufacturing method using a lithographic apparatus, the method comprising:
patterning a first sacrificial hardmask of a substrate using the lithographic apparatus to form an array of projecting lines at a first pitch;
substantially conformally depositing a second sacrificial hardmask to bury the projecting lines and form a second array of recessed lines interleaved with the buried projecting lines;
directionally etching the second sacrificial hardmask to reveal the distal surfaces of the buried projecting lines and so that the recessed lines become apertures through the second sacrificial hardmask;
selectively etching away the buried projecting lines to leave apertures in the second sacrificial hardmask;
masking at least the ends of one or more of the apertures in the second sacrificial mask; and
etching the substrate through the apertures in the second sacrificial hardmask.
According to an aspect of the invention, there is provided a computer program product comprising program code to control a lithographic cluster including a lithographic apparatus to perform a device manufacturing method comprising:
printing an array of sacrificial features at a first density on a first layer of a substrate;
providing a substantially conformal coating to the array of sacrificial features so as to form a first mask defining a first array of apertures at the first density, the first array of apertures being interleaved with the array of sacrificial features;
removing the sacrificial features so as to form further apertures in the first mask that, with the first array of apertures, define a second array of apertures at a second density that is double the first density; and
processing a part of the first layer not covered by the first mask.
Embodiments of the invention will now be described, by way of example only, with reference to the accompanying schematic drawings in which corresponding reference symbols indicate corresponding parts, and in which:
FIGS. 2 to 8 depict a substrate at various stages in the performance of a first method according to an embodiment of the invention; and
FIGS. 9 to 14 depict a substrate at various stages in performance of a second method according to an embodiment of the invention.
an illumination system (illuminator) IL configured to condition a radiation beam B (e.g. UV radiation or DUV radiation).
a support structure (e.g. a mask table) MT constructed to support a patterning device (e.g. a mask) MA and connected to a first positioner PM configured to accurately position the patterning device in accordance with certain parameters;
a substrate table (e.g. a wafer table) WT constructed to hold a substrate (e.g. a resist-coated wafer) W and connected to a second positioner PW configured to accurately position the substrate in accordance with certain parameters; and
a projection system (e.g. a refractive projection lens system) PS configured to project a pattern imparted to the radiation beam B by patterning device MA onto a target portion C (e.g. comprising one or more dies) of the substrate W.
The illumination system may include various types of optical components, such as refractive, reflective, magnetic, electromagnetic, electrostatic or other types of optical components, or any combination thereof, for directing, shaping, or controlling radiation.
The support structure holds the patterning device in a manner that depends on the orientation of the patterning device, the design of the lithographic apparatus, and other conditions, such as for example whether or not the patterning device is held in a vacuum environment. The support structure can use mechanical, vacuum, electrostatic or other clamping techniques to hold the patterning device. The support structure may be a frame or a table, for example, which may be fixed or movable as required. The support structure may ensure that the patterning device is at a desired position, for example with respect to the projection system. Any use of the terms “reticle” or “mask” herein may be considered synonymous with the more general term “patterning device.”
The term “patterning device” used herein should be broadly interpreted as referring to any device that can be used to impart a radiation beam with a pattern in its cross-section such as to create a pattern in a target portion of the substrate. It should be noted that the pattern imparted to the radiation beam may not exactly correspond to the desired pattern in the target portion of the substrate, for example if the pattern includes phase-shifting features or so called assist features. Generally, the pattern imparted to the radiation beam will correspond to a particular functional layer in a device being created in the target portion, such as an integrated circuit.
The patterning device may be transmissive or reflective. Examples of patterning devices include masks, programmable mirror arrays, and programmable LCD panels. Masks are well known in lithography, and include mask types such as binary, alternating phase-shift, and attenuated phase-shift, as well as various hybrid mask types. An example of a programmable mirror array employs a matrix arrangement of small mirrors, each of which can be individually tilted so as to reflect an incoming radiation beam in different directions. The tilted mirrors impart a pattern in a radiation beam which is reflected by the mirror matrix.
The term “projection system” used herein should be broadly interpreted as encompassing any type of projection system, including refractive, reflective, catadioptric, magnetic, electromagnetic and electrostatic optical systems, or any combination thereof, as appropriate for the exposure radiation being used, or for other factors such as the use of an immersion liquid or the use of a vacuum. Any use of the term “projection lens” herein may be considered as synonymous with the more general term “projection system”.
As here depicted, the apparatus is of a transmissive type (e.g. employing a transmissive mask). Alternatively, the apparatus may be of a reflective type (e.g. employing a programmable mirror array of a type as referred to above, or employing a reflective mask).
The lithographic apparatus may be of a type having two (dual stage) or more substrate tables (and/or two or more support structures). In such “multiple stage” machines the additional tables may be used in parallel, or preparatory steps may be carried out on one or more tables while one or more other tables are being used for exposure.
The lithographic apparatus may also be of a type wherein at least a portion of the substrate may be covered by a liquid having a relatively high refractive index, e.g. water, so as to fill a space between the projection system and the substrate. An immersion liquid may also be applied to other spaces in the lithographic apparatus, for example, between the mask and the projection system. Immersion techniques are well known in the art for increasing the numerical aperture of projection systems. The term “immersion” as used herein does not mean that a structure, such as a substrate, must be submerged in liquid, but rather only means that liquid is located between the projection system and the substrate during exposure.
Referring to
The illuminator IL may comprise an adjuster AD for adjusting the angular intensity distribution of the radiation beam. Generally, at least the outer and/or inner radial extent (commonly referred to as σ-outer and σ-inner, respectively) of the intensity distribution in a pupil plane of the illuminator can be adjusted. In addition, the illuminator IL may comprise various other components, such as an integrator IN and a condenser CO. The illuminator may be used to condition the radiation beam, to have a desired uniformity and intensity distribution in its cross-section.
The radiation beam B is incident on the patterning device (e.g., mask) MA, which is held on the support structure (e.g., mask table) MT, and is patterned by the patterning device. Having traversed the patterning device MA, the radiation beam B passes through the projection system PS, which focuses the beam onto a target portion C of the substrate W. With the aid of the second positioner PW and position sensor IF (e.g. an interferometric device, linear encoder or capacitive sensor), the substrate table WT can be moved accurately, e.g. so as to position different target portions C in the path of the radiation beam B. Similarly, the first positioner PM and another position sensor (which is not explicitly depicted in
The depicted apparatus could be used in at least one of the following modes:
1. In step mode, the support structure MT and the substrate table WT are kept essentially stationary, while an entire pattern imparted to the radiation beam is projected onto a target portion C at one time (i.e. a single static exposure). The substrate table WT is then shifted in the X and/or Y direction so that a different target portion C can be exposed. In step mode, the maximum size of the exposure field limits the size of the target portion C imaged in a single static exposure.
2. In scan mode, the support structure MT and the substrate table WT are scanned synchronously while a pattern imparted to the radiation beam is projected onto a target portion C (i.e. a single dynamic exposure). The velocity and direction of the substrate table WT relative to the support structure MT may be determined by the (de-)magnification and image reversal characteristics of the projection system PS. In scan mode, the maximum size of the exposure field limits the width (in the non-scanning direction) of the target portion in a single dynamic exposure, whereas the length of the scanning motion determines the height (in the scanning direction) of the target portion.
3. In another mode, the support structure MT is kept essentially stationary holding a programmable patterning device, and the substrate table WT is moved or scanned while a pattern imparted to the radiation beam is projected onto a target portion C. In this mode, generally a pulsed radiation source is employed and the programmable patterning device is updated as required after each movement of the substrate table WT or in between successive radiation pulses during a scan. This mode of operation can be readily applied to maskless lithography that utilizes programmable patterning device, such as a programmable mirror array of a type as referred to above.
Combinations and/or variations on the above described modes of use or entirely different modes of use may also be employed.
The lithographic apparatus may be included in a lithocluster, including process apparatus to perform steps such as etching, deposition, ion implantation, etc. or a fabrication plant or fab including such apparatus and systems to automatically transport substrates between apparatus. The cluster or fab may be under computer control.
A first method according to an embodiment of the invention is depicted in FIGS. 2 to 8, which Figures depict the substrate on which the method is performed, at various stages in the method. This method aims to print features in an array at a density higher than would normally be possible with the lithographic apparatus used. In summary, the method comprises printing a first set of sacrificial features at a density half that of ultimately desired and then covering the first set of features with a conformal coating so that a second set of features is defined by recesses interleaved with the first set of features so as to form a combined set of features having a density twice that of the first and second sets of features. Directional etching of the conformal coating to reveal the tops of the first set of sacrificial features and to deepen the second set of features through to the underlying layer, followed by selective etching of the first set of sacrificial features results in an array of apertures at the desired density. This method is described in more detail below by way of an example.
The method of this embodiment of the invention aims to define an array of holes in a dielectric layer 11, which is the uppermost layer of the substrate 10, for example as contact holes. The dielectric layer 11 may lie on top of other device layers previously formed using known methods. As shown in
The studs 13 are set out at a spacing that is twice the spacing of the ultimately desired array and occupying half of the cells of the ultimately desired array. This can be easily understood by thinking of the ultimately desired array as a chessboard—the studs are positioned in the centers of all of the black squares. It should also be appreciated that the array need not be square, i.e. the stud spacing in two orthogonal directions need not be the same. To form an array at the highest possible density, the stud-to-stud distance P is made as small as can be patterned with the lithographic apparatus used for the patterning step in formation of the stud, hence P is substantially equal to the nominal minimum pitch of the apparatus. The distance from a stud to the next immediate stud (e.g., the stud in the horizontal or vertical direction rather than the diagonal direction as shown in
Next, as shown in
After deposition of the conformal coating 14, a controlled directional etch is performed to reach the stage shown in
Next, a selective etch of the studs 13 as against the etched conformal coating 14′ is performed to reach the result as shown in
If it is desired only to provide structures at certain grid positions, a mask 18 can be provided during the etching of the first hardmask layer 12. As shown in
A second method according to an embodiment of the invention is shown in FIGS. 9 to 14, which illustrate a substrate 20 at various stages in the method. By this method, a series of lines at a pitch half that achievable with conventional lithographic techniques can be fabricated, while at the same time ensuring that the line ends are correctly shaped. Certain lines in a series can also be omitted without affecting the adjacent remaining lines. Furthermore, the outermost lines in a block can be made uniform. These advantages can be achieved without the necessity of devoting patterning device space to optical proximity correction features, which are expensive and may increase lead time. Process details and materials that are the same as in the first embodiment and/or well known to the person skilled in the art are omitted below for the sake of brevity.
As a first step, a series of fins or projecting lines 22 are fabricated on the uppermost layer 21 of the substrate, which may be the bare substrate or the last layer deposited, depending on at what stage in the process of manufacturing a device the method of the present invention is employed and which forms a base layer for the present method. As in the first embodiment, the fins 22 are formed of a sacrificial hardmask material and are defined by a lithography step. The pitch P1 of the fins, which at the limit is determined by the capabilities of the lithography apparatus used, determines the pitch of the ultimately produced lines. Note that the fins 22 are formed with a length L1 that is longer than the length of lines that are ultimately desired to be fabricated.
Next, a conformal coating 23, forming a second sacrificial hardmask, is deposited on top of the fins 22. As shown in
After that, a mask 26 may be provided as shown in
The methods of the present invention are particularly useful for the formation of contact holes and vias as well as other devices, such as DRAM, Flash RAM, embedded memory and other memory types, that require structures in regularly repeated arrays. Since the defining lithography step is carried about at half the ultimately obtained pitch or feature density, it may be achieved without OPC features and may still achieve better and more consistent results. In particular, because an array of features can be extended over an area larger than the desired area, which is then cut back in a subsequent undemanding masking step, edge effects, such as differences between edge features and central features, may be avoided.
Although specific reference may be made in this text to the use of the method in the manufacture of ICs using lithographic apparatus, it should be understood that the methods described herein may have other applications, such as the manufacture of integrated optical systems, guidance and detection patterns for magnetic domain memories, flat-panel displays, liquid-crystal displays (LCDs), thin-film magnetic heads, etc. The skilled artisan will appreciate that, in the context of such alternative applications, any use of the terms “wafer” or “die” herein may be considered as synonymous with the more general terms “substrate” or “target portion”, respectively. The substrate referred to herein may be processed, before or after exposure, in for example a track (a tool that typically applies a layer of resist to a substrate and develops the exposed resist), a metrology tool and/or an inspection tool. Where applicable, the disclosure herein may be applied to such and other substrate processing tools. Further, the substrate may be processed more than once, for example in order to create a multi-layer IC, so that the term substrate used herein may also refer to a substrate that already contains multiple processed layers.
Although specific reference may have been made above to the use of embodiments of the invention in the context of optical lithography, it will be appreciated that the invention may be used in other applications, for example imprint lithography, and where the context allows, is not limited to optical lithography. In imprint lithography a topography in a patterning device defines the pattern created on a substrate. The topography of the patterning device may be pressed into a layer of resist supplied to the substrate whereupon the resist is cured by applying electromagnetic radiation, heat, pressure or a combination thereof. The patterning device is moved out of the resist leaving a pattern in it after the resist is cured.
The terms “radiation” and “beam” used herein encompass all types of electromagnetic radiation, including ultraviolet (UV) radiation (e.g. having a wavelength of or about 365, 355, 248, 193, 157 or 126 nm) and extreme ultra-violet (EUV) radiation (e.g. having a wavelength in the range of 5-20 nm), as well as particle beams, such as ion beams or electron beams.
The term “lens”, where the context allows, may refer to any one or combination of various types of optical components, including refractive, reflective, magnetic, electromagnetic and electrostatic optical components.
While specific embodiments of the invention have been described above, it will be appreciated that the invention may be practiced otherwise than as described. For example, the invention may take the form of a computer program containing one or more sequences of machine-readable instructions describing a method as disclosed above, or a data storage medium (e.g. semiconductor memory, magnetic or optical disk) having such a computer program stored therein.
The descriptions above are intended to be illustrative, not limiting. Thus, it will be apparent to one skilled in the art that modifications may be made to the invention as described without departing from the scope of the claims set out below.
