The invention relates to the manufacture of dielectric substrates with holes using controlled chemical etching techniques.
With the market trend moving towards developing smaller, more compact and increased functionality devices, the amount of space within the enclosures of such devices for the placement of internal components such as power source, flexible circuit, among others, is reduced.
Flexible circuits are circuits that are formed on flexible dielectric substrates. The circuits may have one or more conductive layers as well as circuitry on one or both of the major surfaces. The circuits often include additional functional layers, insulating layers, adhesive layers, encapsulating layers, stiffening layers, among others. Flexible circuits are typically useful for electronic packages where flexibility, weight control and the like are important. In many high volume situations, flexible circuits also provide cost advantages associated with efficiency of the manufacturing process employed.
To maximise the use of space within each device enclosure, much effort is put into the design of the device including the layout and placement of the internal components within the enclosure. This creates a need for the flexible circuit to be able to be easily folded at pre-defined locations and for the flexible circuit to be able to retain its folded position by itself without the use of additional devices. It is important that the substrate folds only at pre-defined locations so as to prevent unnecessary creases on the flexible circuit when the internal components are positioned as the device is assembled which may then cause the flexible circuit to fail prematurely.
In the absence of a heat sink 20, an improperly folded flexible circuit 10, which is less likely to retain its folded position and has a high tendency to warp, may also prematurely fail due to vibration, abrasion, static discharge, or other forces when it comes into contact with other internal components within the enclosure or the enclosure casing itself. The other components within the casing or the casing may serve as the source of the vibration, abrasion, static discharge, or other forces.
One way of increasing the ease of folding of a flexible circuit at a pre-defined location is to reduce the amount of substrate at that location.
Japanese Patent Application No. 91450 describes a film carrier having the thickness of its insulating base material at the bending location reduced by irradiation with an excimer laser to cleave the bonds between the molecules of the base material by means of photochemical ablation process.
There are at least three problems associated with the method described in the Japanese patent application. First, the use of a laser beam device to reduce the thickness of the substrate at the bending location is an additional process step in the manufacture of the flexible circuit. Second, slits created using laser beams tend to have very sharp corners at the trough. These corners are high pressure points that generate high stress which then may cause the substrate to crack at the corners when the substrate is bent. One way of reducing the stress at the corners, thereby reducing the likelihood of cracks developing at the corners, is to widen the breadth of the slits resulting in the creation of slots. As the stress generated is distributed across the breadth, there is a lesser tendency for the substrate to crack. However, this excavation of slots adds considerable time to the manufacturing process resulting in a loss of productivity. Third, the substrate fragments may spatter during the laser etching process thereby contaminating the surface of the substrate which necessitates an additional cleaning step in the flexible circuit manufacturing process. The use of a laser to reduce the substrate thickness and the addition of the cleaning step in the manufacturing process to remove substrate fragments are expensive and add costs to the manufacturing process.
Japanese Patent No. 3327252 describes the formation of a grid of zigzag-like mesh holes in the bending location by a punching press-work using a metallic mould. In this case, a grid of holes is punched through the substrate to form the bending location prior to the flexible circuit manufacturing process.
The manufacturing process for flexible circuits involves many steps and for some steps, such as flexible circuit inspection, it is necessary to have completely etched through holes on the substrate. These through holes are also needed after the flexible circuits are manufactured and when the flexible circuits are adopted for use on the devices for which they are made. The through holes serve as sprocket holes or tooling holes depending on when they are used and the purpose for which they are used.
In broad terms in one aspect the invention comprises a method of forming holes in a dielectric substrate comprising the steps of applying a layer of photoresist to a dielectric substrate, exposing portions of the photoresist to actinic radiation through a photomask to form a pattern in the photoresist for an array of holes to be etched in the substrate, developing the photoresist, etching the dielectric substrate to form an array of holes, each hole extending at least partially through the dielectric substrate, and removing the excess photoresist.
In broad terms in another embodiment the invention comprises a method of forming holes in a dielectric substrate comprising the steps of: applying a layer of photoresist to a dielectric substrate, exposing portions of the photoresist to actinic radiation through a photomask to form a pattern in the photoresist for a plurality of holes comprising at least one array of holes to be etched in the substrate, developing the photoresist, etching the dielectric substrate to form an array of holes extending partially through the dielectric substrate and at least one hole extending completely through the dielectric substrate, and removing the excess photoresist.
In at least one embodiment the method further includes the steps of providing a photomask comprising an array of distinct dots, exposing portions of the photoresist to actinic radiation through the photomask, etching the dielectric substrate to form an array of holes, wherein the size and/or the pitch of the dots on the photomask are selected so that at least two of the holes formed in the dielectric substrate after etching are connected.
In broad terms in another embodiment the invention comprises a dielectric substrate comprising at least one array of holes partially etched into the dielectric substrate, wiring formed on the dielectric substrate, and solder resist layered over the wiring to protect the wiring.
In broad terms in another embodiment the invention comprises a dielectric substrate comprising at least one array of holes partially etched into the dielectric substrate, at least one hole etched completely through the dielectric substrate, wiring formed on the dielectric substrate, and solder resist layered over the wiring to protect the wiring.
In at least one embodiment the dielectric substrate is flexible.
In at least one embodiment at least two holes in the array of holes are connected after being etched.
In at least one embodiment the array of holes is arranged to form a fold guide in the dielectric substrate.
In at least one embodiment the thickness of the etched portion of the fold guide substrate is about 80% of the unetched dielectric substrate thickness.
In at least one embodiment the dielectric substrate is formed from polyimide.
In at least one embodiment the dielectric substrate may further comprise at least one integrated circuit.
The invention will be further described by way of example only and without intending to be limiting with reference to the following drawings, wherein:
Circuits may be made by a number of suitable methods such as subtractive, additive-subtractive, and semi-additive.
In a typical subtractive circuit-making process, a substrate usually having a thickness of about 10 microns to about 150 microns is first provided.
The substrate serves to insulate the conductors from each other and provides much of the mechanical strength of the circuit. Other attributes of the substrate include flexibility, thinness, high temperature performance, etchability, size reduction, weight reduction, among others.
Many different materials may be used as substrates for flexible circuit manufacture. The substrate choice is dependent on a combination of factors including economics, end-product application and assembly technology to be used for components on the finished product.
The substrate may be any suitable polyimide including, but not limited to, those available under the trade name APICAL, including APICAL NPI from Kaneka High-Tech Materials, Inc., Pasadena, Tex. (USA); and those available under the trade names KAPTON, including KAPTON E, KAPTON EN, KAPTON H, and KAPTON V from DuPont High Performance Materials, Circleville, Ohio (USA).
Other polymers such as liquid crystal polymer (LCP), available from Kuraray High Performance Materials Division, Osaka (Japan); poly(ethylene terephthalate) (PET) and poly(ethylene naphthalate) (PEN), available under trade names of MYLAR and TEONEX respectively from DuPont Tiejin Films, Hopewell, Va. (USA); and polycarbonate available under trade name of LEXAN from General Electric Plastics, Pittsfield, Mass. (USA), among others, may be used.
Preferably the substrate is a polyimide. Desirably the dielectric substrate is flexible.
The substrate may first be coated with a tie layer. After a tie layer is deposited, a conductive layer may be deposited by known methods such as vapour deposition or sputtering. Optionally, the deposited conductive layer(s) can be plated up further to a desired thickness by known electroplating or electroless plating processes.
The conductive layer can be patterned using a number of well-known methods including photolithography. If photolithography is used, photoresists, which may be aqueous or solvent based, and may be negative or positive photoresists, are then laminated or coated on at least the metal-coated side of the substrate using standard laminating techniques with hot rollers or any number of coating techniques (e.g. knife coating, die coating, gravure roll coating, etc.). The thickness of the photoresist ranges from about 1 micron to about 100 microns. The photoresist is then exposed to actinic radiation, for example ultraviolet light or the like, through a photomask or phototool. For a negative photoresist, the exposed portions are crosslinked and the unexposed portions of the photoresist are then developed with an appropriate solvent.
The exposed portions of the conductive layer are etched away using an appropriate etchant. Then the exposed portions of the tie layer are etched away using a suitable etchant. The remaining (unexposed) conductive metal layer preferably has a final thickness ranging from about 5 microns to about 70 microns. The crosslinked resist is then stripped off the laminate in a suitable solution. The conductive layer may form wiring on the substrate. The wiring may be plated with solder resist to protect the wiring.
If desired, the substrate may be etched to form features in the substrate. Subsequent processing steps, such as application of a covercoat or solder resist and additional plating may then be carried out. Integrated circuits can also be provided on the substrate.
Another possible method of forming the circuit portion would utilize semi-additive plating and the following typical step sequence:
A substrate may be coated with a tie layer. A thin first conductive layer may then be deposited using a vacuum sputtering or an evaporation technique. The materials and thicknesses of the substrate and conductive layer may be the same as those described in the previous paragraphs.
The conductive layer can be patterned in the same manner as described above in the subtractive circuit-making process. The first exposed portions of the conductive layer(s) may then be further plated using standard electroplating or electroless plating methods until the desired circuit thickness in the range of about 5 microns to about 70 microns is achieved.
The cross-linked exposed portions of the resist are then stripped off. Subsequently, the exposed portions of the thin first conductive layer(s) is/are etched with an etchant that does not harm the substrate. If the tie layer is to be removed where exposed, it can be removed with appropriate etchants. The remaining conductive layer may form wiring on the substrate.
If desired the substrate may be etched to form features in the substrate. Subsequent processing steps, such as application of a covercoat or solder resist, and additional plating may then be carried out. The substrate may further be provided with one or more integrated circuits.
Another possible method of forming the circuit portion would utilise a combination of subtractive and additive plating, referred to as a subtractive-additive method, and the following typical step sequence:
A substrate may be coated with a tie layer. A thin first conductive layer may then be deposited using a vacuum sputtering or evaporation technique. The materials and thicknesses for the dielectric substrate and conductive layer may be as described in the previous paragraphs.
The conductive layer can be patterned by a number of well-known methods including photolithography, as described above. When the photoresist forms a positive pattern of the desired pattern for the conductive layer, the exposed conductive material is typically etched away using a suitable etchant. The tie layer is then etched with a suitable etchant. The exposed (crosslinked) portion of the resist is then stripped. The desired conductive layer thickness can then be achieved with additional plating to a final thickness of about 5 microns to 70 microns.
If desired the substrate may be etched to form features in the substrate. Subsequent processing steps, such as application of a covercoat or solder resist and additional plating may then be carried out.
It should be noted that the figures in this specification are not drawn to scale. The figures are drawn to explain the concept and/or illustrate the invention and should not be interpreted as scale drawings. It should also be noted that most of the figures represent cross sections of articles that are three dimensional. The cross sections may sometimes be used to illustrate the different layers of a flexible circuit.
The largest circumference holes 138 extend completely through the substrate 100 as shown in
As well as etching holes in the dielectric substrate, circuits can be formed on the major surface of the substrate not etched in the steps described above. Methods and apparatuses for forming metal and circuits on a dielectric substrate are well known. For example wiring can be formed over the substrate and solder resist layered over the wiring to protect the wiring.
Following the step of applying the photoresist 210, the photoresist 210 is exposed to actinic radiation through a photomask 220 as shown in
After exposing the photoresist 210, the photoresist 210 is developed as shown in
The polyimide 200 is then etched using known chemical etching processes. The etching process forms a hole 144 in the polyimide 200 as shown in
It should be noted that while hole 144 in
In a further example the etching can be performed using a strong alkaline solution. In one embodiment potassium hydroxide (KOH) is used as an etching solution for APICAL NPI 3 mil polyimide from Kaneka High-Tech Materials, Inc, Pasadena, Tex. (USA) and the polyimide etching was performed at a temperature of 93° C. using a spray pressure of 800 KPa for an etching period of 350 seconds. In general terms, setting the minimum thickness of the polyimide where the holes are formed at about 63% of the previous polyimide thickness is desirable when the hole pitch is 200 microns. In this example, an etched substrate thickness of about 63% of the unetched substrate thickness will provide a folding area for a fold guide. In this example, the optimum fold guide is formed when the thickness of the etched substrate is about 63% of the unetched substrate thickness. In other examples, different etched substrate thicknesses may be used to form fold guides. If the substrate film in this example is etched for a period of about 220 seconds, the thickness of the polyimide film where the holes are formed is about 90% of the thickness of the unetched polyimide film. In this example, etching the substrate for a shorter duration will produce holes in the substrate where the unetched substrate is a greater thickness than holes produced in longer duration etches. The size and pitch of the dots on the photomask are also related to the amount of etching that will occur during an etch duration.
It should be noted that while the holes shown in the examples are round, holes of any shape can be formed. The holes could be hexagonal for example. Also, the holes may be of the same size or of varying sizes and arranged at the same distance apart or at different distances apart within the same pre-defined location or at different pre-defined locations.
The foregoing describes the invention including preferred forms thereof. Alterations and modifications as will be obvious to those skilled in the art are intended to be incorporated in the scope hereof as defined by the accompanying claims.
Number | Date | Country | Kind |
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200504031-6 | Jun 2005 | SG | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US06/23832 | 6/20/2006 | WO | 00 | 11/16/2009 |