Extremely stretchable electronics

Abstract
In embodiments, the present invention may attach at least two isolated electronic components to an elastomeric substrate, and arrange an electrical interconnection between the components in a boustrophedonic pattern interconnecting the two isolated electronic components with the electrical interconnection. The elastomeric substrate may then be stretched such that the components separate relative to one another, where the electrical interconnection maintains substantially identical electrical performance characteristics during stretching, and where the stretching may extend the separation distance between the electrical components to many times that of the un-stretched distance.
Description
FIELD OF THE INVENTION

The present invention relates to systems, apparatuses, and methods utilizing expandable or stretchable integrated circuitry, and more particularly to extremely stretchable integrated circuitry.


BACKGROUND OF THE INVENTION

The field of stretchable electronics continues to grow due to the demand of high performance and mechanically unconstrained applications of the future. However, stretchable electronics have been thus far limited in stretchability. This has limited the ability of stretchable electronics to accommodate applications that require more extreme stretchability. Therefore a need exists for extremely stretchable electronics.


SUMMARY OF THE INVENTION

This invention is for extremely stretchable electrical interconnects and methods of making the same. In embodiments, the invention comprises a method of making stretchable electronics, which in some embodiments can be out of high quality single crystal semiconductor materials or other semiconductor materials, that are typically rigid. For example, single crystal semiconductor materials are brittle and cannot typically withstand strains of greater than about +/−2%. This invention describes a method of electronics that are capable of stretching and compressing while withstanding high translational strains, such as in the range of −100,000% to +100,000%, and/or high rotational strains, such as to an extent greater than 180°, while maintaining electrical performance found in their unstrained state.


In embodiments, the stretching and compressing may be accomplished by fabricating integrated circuits (ICs) out of thin membrane single crystal semiconductors, which are formed into “islands” that are mechanically and electrically connected by “interconnects,” and transferring said ICs onto an elastomeric substrate capable of stretching and compressing. The islands are regions of non-stretchable/compressible ICs, while the interconnects are regions of material formed in a way to be highly stretchable/compressible. The underlying elastomeric substrate is much more compliant than the islands, so that minimal strain is transferred into the islands while the majority of the strain is transferred to the interconnects, which only contain electrical connections and not ICs. Each interconnect attaches one island to another island, and is capable of accommodating strain between the two aforementioned islands, including translation, rotation, or a combination of translation with rotation of one island relative to another. Even though the interconnects may be made of a rigid material, they act like weak springs rather than rigid plates or beams. This configuration thereby allows for the making of extremely stretchable electronics.


These and other systems, methods, objects, features, and advantages of the present invention will be apparent to those skilled in the art from the following detailed description of the preferred embodiment and the drawings. All documents mentioned herein are hereby incorporated in their entirety by reference.





BRIEF DESCRIPTION OF THE DRAWINGS

The invention and the following detailed description of certain embodiments thereof may be understood by reference to the following figures:



FIG. 1 depicts an overhead view of an embodiment of the present invention showing two device islands connected edge-to-edge by a monolithically formed extremely stretchable interconnect, prior to being stretched.



FIG. 2 depicts an overhead view of an embodiment of the present invention showing two device islands connected edge-to-edge by two extremely stretchable interconnects.



FIG. 3 depicts an overhead view of an embodiment of the present invention showing two device islands connected edge-to-edge by three extremely stretchable interconnects; in this case, the long bars of the interconnects are rotated by 90° which allows them to be longer than if they were not rotated.



FIG. 4 depicts four device islands arranged in a square matrix in an embodiment of the present invention, with each edge connected by an extremely stretchable interconnect to its nearest neighbors island edge, and the interconnects are formed so as to maximize the amount of chip area that is used for either an island or interconnect.



FIG. 5 depicts the case of FIG. 1, with the short bars widened for extra mechanical strength at those locations.



FIGS. 6A and 6B depict embodiments of the present invention, where FIG. 6A is a side view of device islands and extremely stretchable interconnects transferred onto an elastomeric substrate. In this case, the substrate has been molded to have posts that are of the same area as the device islands (note that in embodiments these could be smaller or larger than the device islands). The height “h” of the molded post regions may range from, but is not limited to, about 1-1000 μm. The interconnects are located in between these regions as shown, FIG. 6B Side view as before, with a similarly shaped elastomeric superstrate to serve as an encapsulation layer protecting the devices from direct mechanical contact.



FIG. 7 depicts a side view of a two-layer PDMS substrate in an embodiment of the present invention comprising silicon device islands adhered to top layer, free-standing interconnects, and square wave ripples in the lower layer PDMS to promote increased stretching through the substrate.



FIG. 8 depicts an embodiment of the present invention with a side view of two layers of cured jDhotoresist (SU-8 50 and SU-8 2002) used to make the two-layer PDMS substrate described in FIG. 7.



FIG. 9 depicts an embodiment of the present invention with a side view of a two-layer PDMS substrate consisting of sinusoidal waves in the lower layer of PDMS to promote increased stretching through the substrate.





While the invention has been described in connection with certain preferred embodiments, other embodiments would be understood by one of ordinary skill in the art and are encompassed herein.


All documents referenced herein are hereby incorporated by reference.


DETAILED DESCRIPTION OF THE INVENTION

The present invention accomplishes extremely stretchable electronics by forming the electronics on discrete islands 102 of silicon.


With reference to the present invention, the term “stretchable”, and roots and derivations thereof, when used to modify circuitry or components thereof is meant to encompass circuitry that comprises components having soft or elastic properties capable of being made longer or wider without tearing or breaking, and it is also meant to encompass circuitry having components (whether or not the components themselves are individually stretchable as stated above) that are configured in such a way so as to accommodate and remain functional when applied to a stretchable, inflatable, or otherwise expandable surface. The term “expandable”, and roots and derivations thereof, when used to modify circuitry or components thereof is also meant to have the meaning ascribed above. Thus, “stretch” and “expand”, and all derivations thereof, may be used interchangeably when referring to the present invention.


In embodiments, the discrete islands mention above are discrete operative (in embodiments, arranged in a “device island” arrangement) and are themselves capable of performing the functionality described herein, or portions thereof. In embodiments, such functionality of the operative devices can include integrated circuits, physical sensors (e.g. temperature, pH, light, radiation etc), biological and/or chemical sensors, amplifiers, A/D and D/A converters, optical collectors, electromechanical transducers, piezo-electric actuators, light emitting electronics which include LEDs, and combinations thereof. The purpose and advantage of using standard ICs (in embodiments, CMOS, on single crystal silicon) is to have and use high quality, high performance, and high functioning circuit components that are also already commonly mass-produced with well known processes, and which provide a range of functionality and generation of data far superior to that produced by a passive means.


In an example, the discrete islands 102 may range from about, but not limited to, 10-100 μm in size measured on an edge or by diameter, and connecting said islands 102A-B with one or more extremely stretchable interconnects 104. The novel geometry of the interconnects 104 is what makes them extremely compliant. Each interconnect 104 is patterned and etched so that its structural form has width and thickness dimensions that may be of comparable size (such as their ratio or inverse ratio not exceeding about a factor of 10); and may be preferably equal in size. In embodiments, the dimensions may not be greater than about Sum (e.g. where both dimensions are about 1 μm or less). The interconnect 104 may be formed in a boustrophedonic style such that it effectively comprises long bars 108 and short bars 110 as shown in FIG. 1. This unique geometry minimizes the stresses that are produced in the interconnect 104 when subsequently stretched because it has the effective form of a wire, and behaves very differently than interconnect form factors having one dimension greatly exceeding the other two (for example plates). Plate type structures primarily relieve stress only about a single axis via buckling, and withstand only a slight amount of shear stress before cracking. This invention may relieve stress about all three axes, including shears and any other stress.


In addition, because the interconnect 104 may be formed out of rigid materials, after being stretched it may have a restorative force which helps prevent its wire-like form from getting tangled or knotted when re-compressing to the unstretched state. Another advantage of the boustrophedonic geometry is that it minimizes the initial separation distance between the islands 102A-B. This is illustrated in FIG. 1. One or more interconnects 104 may be formed in various ways, as shown in FIGS. 2-4. The parts of the interconnect 104 where the majority of stresses build up during stretching may be the short linking bars. To minimize cracking here, the short linking bars 110A may be made several micrometers wider than the longer bars 108, as shown in FIG. 5.


In embodiments, the connection point of the interconnect 104 to the device island 102 may be anywhere along the device island edge, or may be at a point on the surface of the device island 102 (in which case the interconnect may be located just above the plane of the device island).


In embodiments, device islands 102 may be made on any suitable material substrate, provided that a top membrane layer of said substrate that contains the ICs can be freed from the bulk of the substrate and transfer printed onto an elastomeric substrate.


In the present invention, the interconnects 104 (as described herein) may be formed either monolithically (i.e., out of the same semiconductor material as the device islands) or may be formed out of another material. In one non-limiting example embodiment, the stretchable electronics arc fabricated on a silicon-on-insulator (SOI) wafer, having a 1 μm thick top silicon layer and a 1 μm thick buried oxide layer. Devices arc formed on the top silicon wafer, and arranged into a square pattern of islands 102A-D and interconnects 104 of the general form shown in FIG. 4, in which the islands 102 are 100 μm on an edge, and the interconnects 104 are 1 μm wide, and the space between each long bar is 1 μm, and the interconnects 104 comprise 10 long bars 108, all about 100 jam long. The islands 102 and interconnects 104 are formed in an etching step which removes the excess silicon. The islands 102 and interconnects 104 are coated with a 1 μm layer of polyimide that is patterned to only cover the islands 102 and interconnects 104. Next, the islands 102 and interconnects 104 are released in an HF etch which undercuts the underlying buried oxide. After drying, the islands 102 and interconnects 104 are transfer printed with a Polydimethylsiloxane (PDMS) stamp onto an elastomeric substrate 602. After being picked up by the transfer stamp, and prior to being placed onto the elastomeric substrate 602, the backsides of the islands 102 may be coated with a layer of polyimide (patterned to only cover the islands 102 and interconnects 104), and an additional layer of evaporated 3 nm chromium and 30 nm silicon dioxide selectively over the island regions to improve adhesion to the elastomeric substrate 602 at those locations, and not along the interconnects 102. The elastomeric substrate 602 may be PDMS or another highly compliant material. The elastomeric substrate 602 may additionally be molded or etched into the shape shown in FIG. 6A-B, to further increase selective adhesion in the device island region but not the interconnect region, and to reduce the amount of material strain in the elastomeric substrate 602 that is transferred to the device islands 102. In this example, the interconnects may accommodate stretching the device islands apart by approximately up to 800 μm. In addition, the interconnects 104 of this example may be capable of accommodating lateral shear displacements of about 800 μm. In general, they may be capable of accommodating any relative displacement of the two islands such that they remain approximately within 800 μm of each other. In addition, the interconnects 104 may accommodate corkscrew type rotations of one island relative to another about any of the three axes of rotation. This feature may be limited only by the interconnects becoming entangled within each other. In any practical application, the completed stretchable device may not be so severely rotated, and the interconnect may easily accommodate rotations of up to 180°. It is noted that by increasing the number of long bars 108 used in the interconnect 104, or by increasing the length of the long bars 108, the interconnect may be able to accommodate even larger displacement strains. In embodiments, there may be no practical upper limit to the amount of displacement enabled through the present invention.


In another embodiment the elastomeric substrate 602 may comprise two layers separated by a height. The top “contact” layer contacts the device island 102 as in the embodiment illustrated in FIG. 6. In addition, FIG. 7 shows the bottom layer 702 may be a “wavy” layer containing ripples or square waves molded into the substrate 602 during elastomer fabrication. These square waves enable additional stretching, whose extent depends on the amplitude and wavelength of the waves pattern-molded in the elastomer 602. FIG. 7 shows one non-limiting layout and topology of an elastomeric substrate 602 relative to the position of the interconnects 104 and device islands 102A-B. In an example, a two layer molded substrate can be fabricated using two step process consisting of two types of negative photoresist (SU-8 50 and SU-8 2002; Microchem Corporation). The negative resists can be spin-coated on a transfer silicon wafer with spin speeds of 3000 rpm. The SU-8 50 layer can be spun on the wafer, and subsequently cured with UV radiation. Once the SU-8 50 layer has hardened, the SU-8 2002 can be spun and cured with a photo-mask and an alignment tool. In this example, the thickness of the SU-8 50 and SU-8 2002 are 40-50 μm 708 and 2-10 μm 704, respectively. The 40-50 μm thick regions of SU-8 50 contain ripples 702 of SU-8 2002 (in this instance in the form of square waves) on their surfaces. Upon curing of the SU-8 2002 layer, liquid PDMS can be poured over the SU-8 patterns to form a substrate in the shape of the SU-8 molds 802, as shown in FIG. 8. The amplitude of the ripples in the SU-8 mold 802 can be varied by changing the spin speed used for spinning the thin layer of SU-8 2002. In this configuration, the interconnects 104 are free-standing. The entire substrate-device configuration can be immersed in non-cured elastomer (fluid layer) layer followed by a cured layer of PDMS to encapsulate the fluid and devices.


In another embodiment, the PDMS in the lower layer may be designed with periodic sinusoidal ripples 702B. In embodiments, this ripple configuration may be achieved by bonding Si nanoribbons on the surface of pre-strained PDMS in a uniform parallel pattern. The release of the prestrain in the PDMS substrate generates sinusoidal waves along the thin Si-nanoribbons (caused by buckling) and the surface of the PDMS substrate. The amplitude and wavelength of these waves 702B may depend on the extent of uniaxial pre-strain exerted on the PDMS and on the mechanical properties of the Si-nanoribbons. The wavy surface on the PDMS may be used as a transfer mold. Two-part liquid plastic solution can be poured over the wavy PDMS substrate and cured at room temperature over time (−2 hrs). Once the plastic hardens, the plastic substrate can be peeled away from the PDMS. This new plastic transfer substrate with wavy surface features can be used to produce more PDMS substrates containing wave features. The wavy PDMS may serve as the lower layer of PDMS as in the previous embodiment. To produce a two layer PDMS structure, a top layer of PDMS can be plasma bonded to this lower layer of PDMS using oxygen plasma surface activation to produce the substrate illustrated in FIG. 9.


In another embodiment, the PDMS transfer stamp is stretched after the islands 102A-B and interconnects 104 are picked up. A subsequent transfer to another elastomeric substrate 602 may place these pre-stretched devices in a configuration, which allows the new elastomeric substrate to undergo compression. The devices may be able to accommodate that compression because the interconnects are pre-stretched.


In another embodiment, the interconnects 104 are not made out of the same material as the device islands 102. In this case, the islands 102A-B are completely isolated from each other by etching, with no interconnects in between. In an example, a layer of polyimide may then be deposited, contact vias etched to various locations on the surface of the device island 102, and then metal interconnects 104 deposited and patterned into a boustrophedonic pattern, followed by another layer of polyimide. Both layers of polyimide may now be patterned and etched to leave a small border around the interconnects 104 (thereby fully encapsulating the interconnects). These interconnects may have the advantage that they arc already fully encapsulated in polyimide and will not adhere as well to the elastomeric substrate as the device islands will. The other advantage is that these interconnects may not be limited to only connecting along the edge of an island. The contact via may be etched anywhere on the surface of the island 102, including near the center. This may allow for easier connections to devices, more connections than possible only along an edge, increased strain compliance, decreased strain at the contact vias, and multiple layers of interconnects made with polymer passivation layers in between, allowing even more interconnects, or allowing one device island 102A to connect to a non-neighboring device island 102B.


In another embodiment of the invention, the device islands 102 are fabricated and transfer printed onto the elastomeric substrate 602, or substrate comprising a polymeric release layer and polymeric non-release layer. After transfer printing, the interconnects 104 are formed as described above, which may be possible because they do not require any high temperature processing, and then in the latter case, the release layer is etched and the devices that are on the non-release layer, are transfer printed onto another elastomeric substrate 602. In the former case, the islands 102 may be transferred onto the elastomeric substrate using pick and place technology so that islands 102 that are initially fabricated very close to each other are spread apart when they are transfer printed. This allows the interconnects 104 to be fabricated in a pattern that resembles their stretched configuration (if desired), to allow compression.


In embodiments, the present invention may comprise a stretchable electrical interconnect 104, including an electrical interconnect 104 for connecting two electrical contacts 102A-B (e.g. device islands 102A-B), where the electrical interconnect 104 may be arranged boustrophedonicially to define rungs 108 (i.e. long bars 108) between the contacts 102A-B, and where the rungs 108 may be substantially parallel with one another and where a plurality of rungs 108 may have substantially the same length and displacement therebetween. In addition, the ratio of the length of the plurality of rungs 108 and the displacement between the plurality of rungs 108 may be large, such as at least 10:1, 100:1, 1000:1, and the like. The electrical integrity of the electrical interconnect 104 may be maintained as stretched, such as to displacements that are increased to 1000%, 10000%, 100000%, and the like during stretching. In embodiments, the rungs 108 may be substantially perpendicular to the contacts 102A-B, the interconnection 104 may have a trace width and/or inter-rung spacing ranging between 0.1-10 microns. In embodiments, the two electrical contacts 102A-B may be located on an elastomeric substrate 602, the electrical contacts 102A-B may be bonded to the substrate 602 and the interconnection 104 not bonded to the substrate 602, the electrical contacts 102A-B may be semiconductor circuits, metal contacts, and the like.


In embodiments, the present invention may comprise a stretchable electrical interconnect 104, including an electrical interconnect 104 for connecting two electrical contacts 102A-B, where the electrical interconnect 104 is arranged boustrophedonicially to define rungs 108 between the contacts 102A-B, and where the interconnect 104 maintains electrical conductivity and electrical integrity when a displacement between the contacts 102A-B is increased, such as by 1000%, 10000%, 100000%, and the like.


In embodiments, the present invention may electrically interconnect two electrical contacts 102A-B with a stretchable interconnection 104 that has the ability to twist between the two electrical contacts 102A-B by up to approximately 180 degrees while maintaining electrical integrity of the stretchable interconnection 104.


In embodiments, the present invention may be a device including a body having a stretchable surface (e.g. an elastomeric substrate 602), and a stretchable electronic circuit including (i) a first discrete operative device 102A, (ii) a second discrete operative device 102B, and (iii) a stretchable interconnect 104 connecting the first discrete operative device 102A to the second discrete operative device 102B, where the interconnect 104 may have a substantially boustrophedonic pattern and be able to maintain electrical conductivity when stretched, such as up to 1000%, 10000%, 100000%, and the like. The stretchable electronic circuit may be affixed to the stretchable surface of the body. In embodiments, the connection may be to a metal contact, to a semiconductor device, and the like. The first discrete operative device 102A, the second discrete operative device 102B, and the stretchable interconnect 104 may all be made from the same material, and that material may be a semiconductor material.


In embodiments, the present invention may attach at least two isolated electronic components (which in embodiments may be discrete operative devices) 102A-B to an elastomeric substrate 602, and arrange an electrical interconnection 104 between the components 102A-B in a boustrophedonic pattern interconnecting the two isolated electronic components 102A-B with the electrical interconnection 104. The elastomeric substrate 602 may then be stretched such that components 102A-B separate relative to one another, where the electrical interconnection 104 maintains substantially identical electrical performance characteristics that the electrical interconnection 104 had in a pre-stretched form. In embodiments, the stretching may be a translational stretching, where the separation between the isolated electronic components 102A-B increases by a percent as a result of the stretching, such as 10%, 100%, 1000%, 10000%, 100000%, and the like. The stretching may be a rotational stretching, where the rotation may be greater than a certain rotation angle, such as 90°, 180°, 270°, 360°, and the like, where the stretching may be in all three axes. In embodiments, the electrical interconnection 104 may be made from semiconductive material. The electrical interconnection 104 may be made from the same semiconductor material as the isolated electronic components 102A-B, fabricated at the same time as the isolated electronic components 102A-B, and the like. The semiconductor material may be a single crystal semiconductor material. The electrical interconnection 104 may made of a different material than the isolated electronic components 102A-B, such as a metal. In embodiments, the interconnect material 104 may be loosely bound to the elastomeric substrate 602, not connected at all, raised above the surface of the elastomeric substrate 602, and the like. In embodiments, the at least two isolated semiconductor circuits may be fabricated on an upper surface 604 of the elastomeric substrate 602 separated by a lower surface 608 of the elastomeric substrate 602, and the electrical interconnection 104 may be fabricated at the level of the upper surface 604 of the elastomeric substrate 602. In this way, the electrical interconnection 104 may have no direct contact with the lower level 608, and thereby be substantially free from adhesion to the lower level 608 during stretching. In addition, the lower surface 608 of the elastomeric substrate 602 may include a wavy form 702, where the wavy form 704 may allow the elastomeric substrate 602 to expand during stretching.


While the invention has been described in connection with certain preferred embodiments, other embodiments would be understood by one of ordinary skill in the art and are encompassed herein.


All documents referenced herein are hereby incorporated by reference.

Claims
  • 1. A stretchable integrated circuit (IC) system comprising: a flexible substrate;a first device island mounted to the flexible substrate and comprising a first integrated circuit (IC) device fabricated from a rigid single-crystal semiconductor;a second device island mounted to the flexible substrate and comprising a second integrated circuit (IC) device fabricated from a rigid single-crystal semiconductor; anda flexible electrical interconnect electrically coupling the first IC device to the second IC device, wherein the flexible interconnect includes a polymer passivation layer and maintains electrical connectivity under translational and rotational strains.
  • 2. The stretchable IC system of claim 1, wherein each of the IC devices comprises a thin-membrane single-crystal semiconductor with a width or diameter of about 10-100 micrometers (μm).
  • 3. The stretchable IC system of claim 2, wherein the flexible electrical interconnect electrically and mechanically coupling the first IC device to the second IC device, the flexible electrical interconnect maintains electrical conductivity and integrity under high translational and rotational strains.
  • 4. The stretchable IC system of claim 1, wherein the polymer passivation layer is pattered to only cover the flexible interconnect.
  • 5. The stretchable IC system of claim 1, wherein the polymer passivation layer is patterned to leave a border around the flexible interconnect.
  • 6. The stretchable IC system of claim 1, wherein the polymer passivation layer includes polyimide.
  • 7. The stretchable IC system of claim 6, wherein the polyimide polymer passivation layer covers at least a portion of the first device island and the second device island.
  • 8. The stretchable IC system of claim 1, wherein the first and second IC devices each comprises one or more physical sensors, one or more chemical sensors, one or more packaged light emitting diodes (LED), or any combination thereof.
  • 9. The stretchable IC system of claim 8, wherein the first IC device comprises at least one of the physical sensors, the at least one physical sensor selected from a group consisting of: temperature sensors, pH sensors, light sensors, and radiation sensors.
  • 10. The stretchable IC system of claim 1, wherein the first IC device comprises a high performance microprocessor and the second IC device comprises a physical sensor, a chemical sensor, an LED, or any combination thereof.
  • 11. The stretchable IC system of claim 1, wherein the first and second IC devices each comprises at least one high performance biological sensor, the at least one high performance biological sensor selected from a group consisting of: electrophysiological sensors, skin temperature sensors, and skin pH sensors.
  • 12. The stretchable IC system of claim 1, wherein the first and second device islands include a thin polymeric layer between each device island and the flexible elastomeric substrate.
  • 13. The stretchable IC system of claim 1, wherein the first and second device islands and the flexible electrical interconnect are encased within the flexible elastomeric substrate.
  • 14. The stretchable IC system of claim 1, wherein the first and second device islands are adhered to the flexible elastomeric substrate, and wherein the flexible electrical interconnect lacks adhesion to the elastomeric substrate.
  • 15. The stretchable IC system of claim 1, wherein the flexible electrical interconnect includes rectilinear rungs connected by rectilinear short bars.
  • 16. The stretchable IC system of claim 15, wherein a plurality of the rungs are parallel or substantially parallel with one another, and a plurality of the short bars are parallel or substantially parallel with one another.
  • 17. The stretchable IC system of claim 16, wherein the plurality of the rungs have substantially the same length and have substantially the same displacement therebetween.
  • 18. The stretchable IC system of claim 15, wherein a ratio of the length of the plurality of the rungs and the displacement between the plurality of the rungs is at least about 10:1.
  • 19. The stretchable IC system of claim 18, wherein each of the rungs has a respective width of about 0.1-10 microns.
  • 20. The stretchable IC system of claim 1, wherein the flexible electrical interconnect includes two interconnect layers separated by a polymer passivation layer.
  • 21. The stretchable IC system of claim 1, wherein the flexible electrical interconnect is configured to maintain electrical integrity and conductivity when a distance between the first and second IC devices is increased by 1000%.
  • 22. The stretchable IC system of claim 1, wherein the flexible electrical interconnect is configured to maintain electrical integrity and conductivity when the first and second IC devices are twisted up to approximately 180 degrees.
  • 23. The stretchable IC system of claim 1, wherein the flexible electrical interconnect includes a metal material.
  • 24. The stretchable IC system of claim 1, wherein the flexible electrical interconnect includes a semiconductor material.
  • 25. The stretchable IC system of claim 24, wherein the semiconductor material of the flexible electrical interconnect is the same or substantially the same as the single-crystal semiconductor material.
  • 26. A method of making a stretchable integrated circuit (IC) system, the method comprising: mounting a first device island comprising a first integrated circuit (IC) device fabricated from a rigid single-crystal semiconductor to a polymer layer;mounting a second device island comprising a second integrated circuit (IC) device fabricated from a rigid single-crystal semiconductor to the polymer layer;electrically connecting the first device island to the second device island by a flexible electrical interconnect formed on the polymer layer; andadhering the first device island and the second device island to a flexible elastomeric substrate.
  • 27. The method according to claim 26, wherein the polymer layer includes polyimide.
  • 28. The method according to claim 26, wherein the polymer layer is patterned to only cover the device islands and flexible electrical interconnect.
  • 29. The method according to claim 28, wherein the polymer layer is patterned to leave a border around the flexible electrical interconnect.
  • 30. The method according to claim 26, wherein the flexible electrical interconnect is encapsulated in the polymer layer.
  • 31. The method according to claim 26, wherein the first device island, the second device island and the flexible electrical interconnect are encapsulated in the flexible elastomeric substrate.
  • 32. The method according to claim 26, wherein the flexible electrical interconnect includes a metal material.
  • 33. The method according to claim 26, wherein the flexible electrical interconnect includes a semiconductor material.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of U.S. Provisional Application No. 61/113,622 entitled “Extremely Stretchable Interconnects” filed on Nov. 12, 2008, the entirety of which is incorporated herein by reference. Also, this application is a continuation-in-part of, and claims the benefit of U.S. Non-Provisional application Ser. No. 12/575,008, entitled “Catheter Balloon Having Stretchable Integrated Circuitry and Sensor Array” filed on Oct. 7, 2009, the entirety of which is incorporated herein by reference. Application Ser. No. 12/575,008 claimed the priority of U.S. Provisional Application Nos. 61/103,361, filed Oct. 7, 2008 and 61/113,007, filed Nov. 10, 2008 the entirety of each of which is incorporated herein by reference.

US Referenced Citations (519)
Number Name Date Kind
3716861 Root Feb 1973 A
3805427 Epstein Apr 1974 A
3949410 Bassous Apr 1976 A
4058418 Lindmayer Nov 1977 A
4304235 Kaufman Dec 1981 A
4392451 Mickelsen et al. Jul 1983 A
4416288 Freeman Nov 1983 A
4471003 Cann Sep 1984 A
4487162 Cann Dec 1984 A
4658153 Brosh Apr 1987 A
4663828 Hanak May 1987 A
4761335 Aurichio et al. Aug 1988 A
4763275 Carlin Aug 1988 A
4766670 Gazdik et al. Aug 1988 A
4784720 Douglas Nov 1988 A
4855017 Douglas Aug 1989 A
5041973 Lebron et al. Aug 1991 A
5086785 Gentile et al. Feb 1992 A
5118400 Wollam Jun 1992 A
5147519 Legge Sep 1992 A
5178957 Kolpe et al. Jan 1993 A
5204144 Cann et al. Apr 1993 A
5306917 Black Apr 1994 A
5313094 Beyer et al. May 1994 A
5331966 Bennett et al. Jul 1994 A
5360987 Shibib Nov 1994 A
5403700 Heller et al. Apr 1995 A
5427096 Bogusiewicz et al. Jun 1995 A
5434751 Cole, Jr. et al. Jul 1995 A
5455178 Fattnger Oct 1995 A
5469845 DeLonzor et al. Nov 1995 A
5501893 Laermer et al. Mar 1996 A
5525815 Einset Jun 1996 A
5539935 Rush, III Jul 1996 A
5545291 Smith et al. Aug 1996 A
5549108 Edwards et al. Aug 1996 A
5560974 Langley Oct 1996 A
5567975 Walsh Oct 1996 A
5625471 Smith Apr 1997 A
5648148 Simpson Jul 1997 A
5687737 Branham et al. Nov 1997 A
5691245 Bakhit et al. Nov 1997 A
5746207 McLaughlin May 1998 A
5753529 Chang et al. May 1998 A
5757081 Chang et al. May 1998 A
5767578 Chang et al. Jun 1998 A
5772905 Chou Jun 1998 A
5783856 Smith et al. Jul 1998 A
5790151 Mills Aug 1998 A
5811790 Endo Sep 1998 A
5817008 Rafert et al. Oct 1998 A
5817242 Biebuyck et al. Oct 1998 A
5824186 Smith et al. Oct 1998 A
5860974 Abele Jan 1999 A
5871443 Edwards et al. Feb 1999 A
5904545 Smith et al. May 1999 A
5907189 Mertol May 1999 A
5907477 Tuttle et al. May 1999 A
5915180 Hara et al. Jun 1999 A
5917534 Rajeswaran Jun 1999 A
5919155 Lattin et al. Jul 1999 A
5928001 Gillette et al. Jul 1999 A
5955781 Joshi et al. Sep 1999 A
5976683 Liehrr et al. Nov 1999 A
5978972 Stewart Nov 1999 A
5998291 Bakhit et al. Dec 1999 A
6024702 Iversen Feb 2000 A
6057212 Chan et al. May 2000 A
6063046 Allum May 2000 A
6080608 Nowak Jun 2000 A
6097984 Douglas Aug 2000 A
6121110 Hong Sep 2000 A
6165391 Vedamuttu Dec 2000 A
6165885 Gaynes et al. Dec 2000 A
6171730 Kuroda et al. Jan 2001 B1
6181551 Herman et al. Jan 2001 B1
6225149 Gan et al. May 2001 B1
6236883 Ciaccio et al. May 2001 B1
6265326 Ueno Jul 2001 B1
6274508 Jacobsen et al. Aug 2001 B1
6276775 Schulte Aug 2001 B1
6277712 Kang et al. Aug 2001 B1
6281038 Jacobsen et al. Aug 2001 B1
6284418 Trantolo Sep 2001 B1
6291896 Smith Sep 2001 B1
6301500 Van Herk Oct 2001 B1
6316278 Jacobsen et al. Nov 2001 B1
6316283 Saurer Nov 2001 B1
6317175 Salerno et al. Nov 2001 B1
6322895 Canham Nov 2001 B1
6334960 Willson et al. Jan 2002 B1
6344616 Yokokawa Feb 2002 B1
6360615 Smela Mar 2002 B1
6380729 Smith Apr 2002 B1
6403397 Katz Jun 2002 B1
6413790 Duthaler et al. Jul 2002 B1
6414783 Zavracky et al. Jul 2002 B2
6417025 Gengel Jul 2002 B1
6420266 Smith et al. Jul 2002 B1
6421016 Phillips Jul 2002 B1
6433401 Clark et al. Aug 2002 B1
6451191 Bentsen et al. Sep 2002 B1
6459418 Comiskey et al. Oct 2002 B1
6468638 Jacobsen et al. Oct 2002 B2
6479395 Smith et al. Nov 2002 B1
6504105 Acocella et al. Jan 2003 B1
6517995 Jacobson et al. Feb 2003 B1
6527964 Smith et al. Mar 2003 B1
6555408 Jacobsen et al. Apr 2003 B1
6566744 Gengel May 2003 B2
6567158 Falcial May 2003 B1
6580151 Vandeputte et al. Jun 2003 B2
6586338 Smith et al. Jul 2003 B2
6590346 Hadley et al. Jul 2003 B1
6606079 Smith Aug 2003 B1
6606247 Credelle et al. Aug 2003 B2
6608370 Chen et al. Aug 2003 B1
6613979 Miller et al. Sep 2003 B1
6623579 Smith et al. Sep 2003 B1
6639578 Comiskey et al. Oct 2003 B1
6655286 Rogers Dec 2003 B2
6657289 Craig et al. Dec 2003 B1
6661037 Pan et al. Dec 2003 B2
6665044 Jacobsen et al. Dec 2003 B1
6666821 Keimel Dec 2003 B2
6667548 O'Connor et al. Dec 2003 B2
6683663 Hadley et al. Jan 2004 B1
6693384 Vicentini et al. Feb 2004 B1
6706402 Rueckes et al. Mar 2004 B2
6720469 Curtis et al. Apr 2004 B1
6723576 Nozawa et al. Apr 2004 B2
6730990 Kondo et al. May 2004 B2
6731353 Credelle et al. May 2004 B1
6743982 Biegelsen et al. Jun 2004 B2
6762510 Fock et al. Jul 2004 B2
6775906 Silverbrook Aug 2004 B1
6780696 Schatz Aug 2004 B1
6784450 Pan et al. Aug 2004 B2
6784844 Boakes et al. Aug 2004 B1
6787052 Vaganov Sep 2004 B1
6814898 Deeman et al. Nov 2004 B1
6816380 Credelle et al. Nov 2004 B2
6826509 Crisco, III et al. Nov 2004 B2
6836744 Asphahani et al. Dec 2004 B1
6844673 Bernkopf Jan 2005 B1
6848162 Arneson et al. Feb 2005 B2
6850312 Jacobsen et al. Feb 2005 B2
6856830 He Feb 2005 B2
6863219 Jacobsen et al. Mar 2005 B1
6864435 Hermanns et al. Mar 2005 B2
6864570 Smith Mar 2005 B2
6872645 Duan et al. Mar 2005 B2
6878871 Scher et al. Apr 2005 B2
6881979 Starikov et al. Apr 2005 B2
6885030 Onozuka et al. Apr 2005 B2
6887450 Chen et al. May 2005 B2
6900094 Hammond et al. May 2005 B2
6917061 Pan et al. Jul 2005 B2
6936181 Bulthaup et al. Aug 2005 B2
6949199 Gauzner et al. Sep 2005 B1
6949206 Whitford et al. Sep 2005 B2
6950220 Abramson et al. Sep 2005 B2
6965160 Cobbley Nov 2005 B2
6967362 Nam et al. Nov 2005 B2
6984934 Moller et al. Jan 2006 B2
6987314 Yoshida Jan 2006 B1
6989285 Ball Jan 2006 B2
7029951 Chen et al. Apr 2006 B2
7033961 Smart et al. Apr 2006 B1
7054784 Flentov et al. May 2006 B2
7067903 Tachibana et al. Jun 2006 B2
7081642 Onozuka et al. Jul 2006 B2
7116318 Amundson et al. Oct 2006 B2
7132313 O'Connor et al. Nov 2006 B2
7148512 Leu et al. Dec 2006 B2
7158277 Berggren et al. Jan 2007 B2
7169546 Suzuki et al. Jan 2007 B2
7169669 Blakers et al. Jan 2007 B2
7170164 Chen et al. Jan 2007 B2
7186624 Weiser et al. Mar 2007 B2
7190051 Mech et al. Mar 2007 B2
7195733 Rogers et al. Mar 2007 B2
7223609 Anvar et al. May 2007 B2
7223632 Onozuka et al. May 2007 B2
7252664 Nasab et al. Aug 2007 B2
7253442 Huang et al. Aug 2007 B2
7255919 Sakata et al. Aug 2007 B2
7265298 Maghribi et al. Sep 2007 B2
7291146 Steinke et al. Nov 2007 B2
7291540 Mech et al. Nov 2007 B2
7293353 Matsuda Nov 2007 B2
7302751 Hamburgen Dec 2007 B2
7337012 Maghribi et al. Feb 2008 B2
7374968 Kornilovich et al. May 2008 B2
7425523 Ikemizu et al. Sep 2008 B2
7487587 Vanfleteren et al. Feb 2009 B2
7491892 Wagner et al. Feb 2009 B2
7509835 Beck Mar 2009 B2
7521292 Rogers et al. Apr 2009 B2
7526389 Greenwald et al. Apr 2009 B2
7557367 Rogers et al. Jul 2009 B2
7593086 Jeong et al. Sep 2009 B2
7618260 Daniel et al. Nov 2009 B2
7622367 Nuzzo et al. Nov 2009 B1
7629691 Roush et al. Dec 2009 B2
7633761 Kim Dec 2009 B2
7635755 Kaplan et al. Dec 2009 B2
7674882 Kaplan et al. Mar 2010 B2
7700402 Wild et al. Apr 2010 B2
7704684 Rogers et al. Apr 2010 B2
7705280 Nuzzo et al. Apr 2010 B2
7709961 Greenberg et al. May 2010 B2
7727199 Fernandes et al. Jun 2010 B2
7727575 Kaplan et al. Jun 2010 B2
7742795 Stone et al. Jun 2010 B2
7759167 Vanfleteren et al. Jul 2010 B2
7799699 Nuzzo et al. Sep 2010 B2
7842780 Kaplan et al. Nov 2010 B2
7857781 Noda et al. Dec 2010 B2
7871661 Maghribi et al. Jan 2011 B2
7884540 Sung et al. Feb 2011 B2
7932123 Rogers et al. Apr 2011 B2
7935056 Zdeblick May 2011 B2
7943491 Nuzzo et al. May 2011 B2
7960246 Flamand et al. Jun 2011 B2
7972875 Rogers et al. Jul 2011 B2
7982296 Nuzzo et al. Jul 2011 B2
8039847 Nuzzo et al. Oct 2011 B2
8107248 Shin et al. Jan 2012 B2
8198621 Rogers et al. Jun 2012 B2
8207473 Axisa et al. Jun 2012 B2
8217381 Rogers Jul 2012 B2
8431828 Vanfleteren Apr 2013 B2
8440546 Nuzzo May 2013 B2
8552299 Rogers Oct 2013 B2
8664699 Nuzzo Mar 2014 B2
8679888 Rogers Mar 2014 B2
8729524 Rogers May 2014 B2
8754396 Rogers Jun 2014 B2
8865489 Rogers Oct 2014 B2
8905772 Rogers Dec 2014 B2
20010003043 Metspalu et al. Jun 2001 A1
20010012918 Swanson Aug 2001 A1
20010021867 Kordis Sep 2001 A1
20020021445 Boxhevolnyi et al. Feb 2002 A1
20020026127 Balbierz Feb 2002 A1
20020082515 Campbell et al. Jun 2002 A1
20020094701 Biegelsen et al. Jul 2002 A1
20020110766 Tsai et al. Aug 2002 A1
20020113739 Howard Aug 2002 A1
20020128700 Cross, Jr. Sep 2002 A1
20020151934 Levine Oct 2002 A1
20030006527 Rabolt et al. Jan 2003 A1
20030017848 Engstrom et al. Jan 2003 A1
20030032892 Erlach et al. Feb 2003 A1
20030045025 Coyle Mar 2003 A1
20030082889 Maruyama et al. May 2003 A1
20030087476 Oohata et al. May 2003 A1
20030097165 Krulevitch May 2003 A1
20030138704 Mei et al. Jul 2003 A1
20030149456 Rottenberg et al. Aug 2003 A1
20030162507 Vatt Aug 2003 A1
20030171691 Casscells et al. Sep 2003 A1
20030178316 Jacobs et al. Sep 2003 A1
20030214408 Grajales Nov 2003 A1
20030222282 Fjelstad et al. Dec 2003 A1
20030227116 Halik et al. Dec 2003 A1
20030236455 Swanson Dec 2003 A1
20040005723 Empedocles et al. Jan 2004 A1
20040006264 Mojarradi et al. Jan 2004 A1
20040026684 Empedocles et al. Feb 2004 A1
20040061543 Nam et al. Apr 2004 A1
20040079464 Kumakura Apr 2004 A1
20040081384 Datesman et al. Apr 2004 A1
20040092806 Sagon May 2004 A1
20040095658 Buretea et al. May 2004 A1
20040106334 Suzuki Jun 2004 A1
20040112964 Empedocles et al. Jun 2004 A1
20040135094 Niigaki Jul 2004 A1
20040136866 Pontis et al. Jul 2004 A1
20040138558 Dunki-Jacobs Jul 2004 A1
20040146560 Whiteford et al. Jul 2004 A1
20040149921 Smyk Aug 2004 A1
20040155290 Mech et al. Aug 2004 A1
20040171969 Socci Sep 2004 A1
20040178390 Whiteford Sep 2004 A1
20040178466 Merrill Sep 2004 A1
20040192062 Mikelson Sep 2004 A1
20040192082 Wagner et al. Sep 2004 A1
20040200734 Co et al. Oct 2004 A1
20040203486 Shepherd Oct 2004 A1
20040206448 Dubrow Oct 2004 A1
20040211458 Gui et al. Oct 2004 A1
20040211459 Suenaga et al. Oct 2004 A1
20040221370 Hannula et al. Nov 2004 A1
20040229830 Tachibana et al. Nov 2004 A1
20040243204 Maghribi Dec 2004 A1
20040250950 Dubrow Dec 2004 A1
20040252559 Gupta Dec 2004 A1
20050020094 Forbes et al. Jan 2005 A1
20050021103 DiLorenzo Jan 2005 A1
20050038498 Dubrow et al. Feb 2005 A1
20050067293 Naito Mar 2005 A1
20050082526 Bedell et al. Apr 2005 A1
20050096513 Ozguz May 2005 A1
20050113744 Donoghue May 2005 A1
20050124712 Anderson et al. Jun 2005 A1
20050133954 Homola Jun 2005 A1
20050139683 Yi Jun 2005 A1
20050171524 Stern et al. Aug 2005 A1
20050177335 Crisco Aug 2005 A1
20050203366 Donoghue Sep 2005 A1
20050214962 Daniels et al. Sep 2005 A1
20050227389 Bhattacharya et al. Oct 2005 A1
20050233546 Oohata et al. Oct 2005 A1
20050238967 Rogers et al. Oct 2005 A1
20050255686 Yamano et al. Nov 2005 A1
20050260706 Kaplan et al. Nov 2005 A1
20050261561 Jones et al. Nov 2005 A1
20060003709 Wood Jan 2006 A1
20060038182 Rogers et al. Feb 2006 A1
20060049485 Pan et al. Mar 2006 A1
20060056161 Shin et al. Mar 2006 A1
20060071349 Tokushige Apr 2006 A1
20060076561 Hicki et al. Apr 2006 A1
20060084012 Nuzzo et al. Apr 2006 A1
20060084394 Engstrom et al. Apr 2006 A1
20060085976 Eldridge et al. Apr 2006 A1
20060102525 Volkel et al. May 2006 A1
20060106321 Lewinsky et al. May 2006 A1
20060119853 Baumberg et al. Jun 2006 A1
20060127817 Ramanujan et al. Jun 2006 A1
20060128346 Yasui Jun 2006 A1
20060129056 Leuthardt et al. Jun 2006 A1
20060132025 Gao et al. Jun 2006 A1
20060134893 Savage et al. Jun 2006 A1
20060154398 Qing Jul 2006 A1
20060159837 Kaplan et al. Jul 2006 A1
20060160560 Josenhans Jul 2006 A1
20060169989 Bhattacharya et al. Aug 2006 A1
20060173364 Clancy et al. Aug 2006 A1
20060177479 Giachelli et al. Aug 2006 A1
20060178655 Santini et al. Aug 2006 A1
20060244105 Forbes et al. Nov 2006 A1
20060255341 Pinnington et al. Nov 2006 A1
20060264767 Shennib Nov 2006 A1
20060273279 Kaplan et al. Dec 2006 A1
20060279191 Geohegan et al. Dec 2006 A1
20060286488 Rogers et al. Dec 2006 A1
20060286785 Rogers et al. Dec 2006 A1
20070009968 Cunningham et al. Jan 2007 A1
20070027514 Gerber Feb 2007 A1
20070031607 Dubson et al. Feb 2007 A1
20070032089 Nuzzo et al. Feb 2007 A1
20070043416 Callas et al. Feb 2007 A1
20070058254 Kim Mar 2007 A1
20070073130 Finch et al. Mar 2007 A1
20070108389 Makela May 2007 A1
20070123756 Kitajima et al. May 2007 A1
20070187862 Kaplan et al. Aug 2007 A1
20070212730 Vepari et al. Sep 2007 A1
20070213616 Anderson et al. Sep 2007 A1
20070227586 Zapalac Oct 2007 A1
20070233208 Kurtz et al. Oct 2007 A1
20080000871 Suh et al. Jan 2008 A1
20080008626 Lin et al. Jan 2008 A1
20080038236 Gimble et al. Feb 2008 A1
20080041617 Chen et al. Feb 2008 A1
20080046080 Bulcke et al. Feb 2008 A1
20080054875 Saito Mar 2008 A1
20080055581 Rogers et al. Mar 2008 A1
20080074383 Dean Mar 2008 A1
20080077225 Carlin et al. Mar 2008 A1
20080085272 Kaplan et al. Apr 2008 A1
20080090322 Mech et al. Apr 2008 A1
20080096620 Lee Apr 2008 A1
20080102096 Molin et al. May 2008 A1
20080108171 Rogers et al. May 2008 A1
20080108942 Brister et al. May 2008 A1
20080139894 Szydlo-Moore et al. Jun 2008 A1
20080140152 Imran Jun 2008 A1
20080152281 Lundquist et al. Jun 2008 A1
20080157234 Hong Jul 2008 A1
20080157235 Rogers et al. Jul 2008 A1
20080183076 Witte et al. Jul 2008 A1
20080188912 Stone et al. Aug 2008 A1
20080193749 Thompson Aug 2008 A1
20080203268 Hobbs et al. Aug 2008 A1
20080203431 Garcia et al. Aug 2008 A1
20080204021 Leussler et al. Aug 2008 A1
20080208268 Bartic Aug 2008 A1
20080211087 Mueller-Hipper Sep 2008 A1
20080212102 Nuzzo et al. Sep 2008 A1
20080237840 Alcoe Oct 2008 A1
20080239755 Parker et al. Oct 2008 A1
20080257586 Chen et al. Oct 2008 A1
20080259576 Johnson et al. Oct 2008 A1
20080280360 Kaplan et al. Nov 2008 A1
20080287167 Caine Nov 2008 A1
20080288037 Neysmith et al. Nov 2008 A1
20080293919 Kaplan et al. Nov 2008 A1
20080313552 Buehler et al. Dec 2008 A1
20090000377 Shipps et al. Jan 2009 A1
20090004737 Borenstein et al. Jan 2009 A1
20090015560 Robinson et al. Jan 2009 A1
20090017884 Rotschild Jan 2009 A1
20090028910 DeSimone et al. Jan 2009 A1
20090048556 Durand Feb 2009 A1
20090054742 Kaminska et al. Feb 2009 A1
20090088750 Hushka Apr 2009 A1
20090107704 Vanfleteren et al. Apr 2009 A1
20090149930 Schenck Jun 2009 A1
20090154736 Lee Jun 2009 A1
20090184254 Miura Jul 2009 A1
20090198293 Cauller et al. Aug 2009 A1
20090199960 Nuzzo et al. Aug 2009 A1
20090202614 Kaplan et al. Aug 2009 A1
20090208555 Kuttler et al. Aug 2009 A1
20090215385 Waters Aug 2009 A1
20090221896 Rickert et al. Sep 2009 A1
20090225751 Koenck Sep 2009 A1
20090232963 Kaplan et al. Sep 2009 A1
20090234026 Kaplan et al. Sep 2009 A1
20090247909 Mukumoto Oct 2009 A1
20090261828 Nordmeyer-Massner Oct 2009 A1
20090273909 Shin Nov 2009 A1
20090289246 Schneider et al. Nov 2009 A1
20090294803 Nuzzo et al. Dec 2009 A1
20090317639 Axisa et al. Dec 2009 A1
20090322480 Benedict et al. Dec 2009 A1
20100002402 Rogers et al. Jan 2010 A1
20100028451 Kaplan et al. Feb 2010 A1
20100046902 Kaplan et al. Feb 2010 A1
20100052112 Rogers et al. Mar 2010 A1
20100055438 Kaplan et al. Mar 2010 A1
20100059863 Rogers et al. Mar 2010 A1
20100063404 Kaplan et al. Mar 2010 A1
20100065784 Kaplan et al. Mar 2010 A1
20100068740 Kaplan et al. Mar 2010 A1
20100070068 Kaplan et al. Mar 2010 A1
20100072577 Nuzzo et al. Mar 2010 A1
20100073669 Colvin Mar 2010 A1
20100090781 Yamamoto Apr 2010 A1
20100090824 Rowell et al. Apr 2010 A1
20100096763 Kaplan et al. Apr 2010 A1
20100117660 Douglas May 2010 A1
20100120116 Kaplan et al. May 2010 A1
20100121420 Fiset et al. May 2010 A1
20100152619 Kalpaxis et al. Jun 2010 A1
20100176705 Van Herpen et al. Jul 2010 A1
20100178304 Wang et al. Jul 2010 A1
20100191328 Kaplan et al. Jul 2010 A1
20100196447 Kaplan et al. Aug 2010 A1
20100200752 Lee et al. Aug 2010 A1
20100203226 Kaplan et al. Aug 2010 A1
20100245011 Chatzopoulos et al. Sep 2010 A1
20100252840 Ibbetson et al. Oct 2010 A1
20100279112 Kaplan et al. Nov 2010 A1
20100283069 Rogers et al. Nov 2010 A1
20100289124 Nuzzo et al. Nov 2010 A1
20100298895 Ghaffari et al. Nov 2010 A1
20100317132 Rogers et al. Dec 2010 A1
20100321161 Isabell Dec 2010 A1
20100324455 Rangel et al. Dec 2010 A1
20100327387 Kasai Dec 2010 A1
20110011179 Gustafsson Jan 2011 A1
20110034912 De Graff et al. Feb 2011 A1
20110051384 Kriechbaum Mar 2011 A1
20110054583 Litt et al. Mar 2011 A1
20110068672 Hasnain Mar 2011 A1
20110101789 Salter et al. May 2011 A1
20110121822 Parsche May 2011 A1
20110140897 Purks et al. Jun 2011 A1
20110147715 Rogers et al. Jun 2011 A1
20110170225 Rogers et al. Jul 2011 A1
20110171813 Rogers et al. Jul 2011 A1
20110175735 Forster Jul 2011 A1
20110184320 Shipps Jul 2011 A1
20110187798 Rogers et al. Aug 2011 A1
20110220890 Nuzzo et al. Sep 2011 A1
20110230747 Rogers et al. Sep 2011 A1
20110266561 Rogers et al. Nov 2011 A1
20110277813 Rogers et al. Nov 2011 A1
20110316120 Rogers et al. Dec 2011 A1
20120016258 Webster et al. Jan 2012 A1
20120051005 Vanfleteren et al. Mar 2012 A1
20120052268 Axisa et al. Mar 2012 A1
20120065937 de Graff Mar 2012 A1
20120074546 Chong Mar 2012 A1
20120087216 Keung et al. Apr 2012 A1
20120091594 Landesberger Apr 2012 A1
20120092178 Callsen Apr 2012 A1
20120092222 Kato et al. Apr 2012 A1
20120105528 Alleyne May 2012 A1
20120108012 Yasuda May 2012 A1
20120157804 Rogers et al. Jun 2012 A1
20120157986 Stone et al. Jun 2012 A1
20120157987 Steinke et al. Jun 2012 A1
20120157988 Stone et al. Jun 2012 A1
20120157989 Stone et al. Jun 2012 A1
20120158101 Stone et al. Jun 2012 A1
20120165759 Rogers et al. Jun 2012 A1
20120172697 Urman Jul 2012 A1
20120256308 Helin Oct 2012 A1
20120261551 Rogers Oct 2012 A1
20120316455 Rahman et al. Dec 2012 A1
20120327608 Rogers Dec 2012 A1
20130041235 Rogers et al. Feb 2013 A1
20130100618 Rogers Apr 2013 A1
20130211761 Brandsma et al. Aug 2013 A1
20130245388 Rafferty et al. Sep 2013 A1
20130316442 Meurville et al. Nov 2013 A1
20130320503 Nuzzo Dec 2013 A1
20130321373 Yoshizumi Dec 2013 A1
20140140020 Rogers May 2014 A1
20140191236 Nuzzo Jul 2014 A1
20140216524 Rogers Aug 2014 A1
20140374872 Rogers Dec 2014 A1
20150001462 Rogers Jan 2015 A1
Foreign Referenced Citations (19)
Number Date Country
0585670 Mar 1994 EP
05-087511 Apr 1993 JP
2009-170173 Jul 2009 JP
WO 9938211 Jul 1999 WO
WO 03021679 Mar 2003 WO
WO 2005122285 Dec 2005 WO
WO 2007003019 Jan 2007 WO
WO 2007116344 Oct 2007 WO
WO 2007136726 Nov 2007 WO
WO 2008030960 Mar 2008 WO
WO 2009111641 Sep 2009 WO
WO 2009114689 Sep 2009 WO
WO 2010036807 Apr 2010 WO
WO 2010046883 Apr 2010 WO
WO 2010132552 Nov 2010 WO
WO 2011003181 Jan 2011 WO
WO 2011084450 Jul 2011 WO
WO 2013034987 Mar 2013 WO
WO 2013170032 Nov 2013 WO
Non-Patent Literature Citations (16)
Entry
Demura et al., “Immobilization of Glucose Oxidase with Bombyx mori Silk Fibroin by Only Stretching Treatment and its Application to Glucose Sensor,” Biotechnology and Bioengineering, vol. 33, 598-603 (6 pages) (1989).
Halsted, “Ligature and Suture Material,” Journal of the American Medical Association, vol. LX, No. 15, 1119-1126, (8 pages) (Apr. 12, 1913).
Kim et al., “Complementary Metal Oxide Silicon Integrated Circuits Incorporating Monolithically Integrated Stretchable Wavy Interconnects,” Applied Physics Letters, vol. 93, 044102-044102.3 (3 pages) (Jul. 31, 2008).
Kim et al., “Dissolvable Films of Silk Fibroin for Ultrathin Conformal Bio-Integrated Electronics,” Nature, 1-8 (8 pages) (Apr. 18, 2010).
Kim et al., “Materials and Noncoplanar Mesh Designs for Integrated Circuits with Linear Elastic Responses to Extreme Mechanical Deformations,” PNAS, vol. 105, No. 48, 18675-18680 (6 pages) (Dec. 2, 2008).
Kim et al., “Stretchable and Foldable Silicon Integrated Circuits,” Science, vol. 320, 507-511 (5 pages) (Apr. 25, 2008).
Ko et al., “A Hemispherical Electronic Eye Camera Based on Compressible Silicon Optoelectronics,” Nature, vol. 454, 748-753 (6 pages) (Aug. 7, 2008).
Lawrence et al., “Bioactive Silk Protein Biomaterial Systems for Optical Devices,” Biomacromolecules, vol. 9, 1214-1220 (7 pages) (Nov. 4, 2008).
Meitl et al., “Transfer Printing by Kinetic Control of Adhesion to an Elastomeric Stamp,” Nature, vol. 5, 33-38 (6 pages) (Jan. 2006).
Omenetto et al., “A New Route for Silk,” Nature Photonics, vol. 2, 641-643 (3 pages) (Nov. 2008).
Omenetto et al., “New Opportunities for an Ancient Material,” Science, vol. 329, 528-531 (5 pages) (Jul. 30, 2010).
Tsukada et al., “Structural Changes of Silk Fibroin Membranes Induced by Immersion in Methanol Aqueous Solutions,” Journal of Polymer Science, vol. 32, 961-968 (8 pages) (1994).
Wang et al., “Controlled Release From Multilayer Silk Biomaterial Coatings to Modulate Vascular Cell Responses” Biomaterials, 29, 894-903 (10 pages) (Nov. 28, 2008).
Canadian Office Action corresponding to co-pending Canadian Patent Application Serial No. CA 2,780,747, Canadian Patent Office, dated Jan. 11, 2016; (7 pages).
European Search Report corresponding to co-pending European Patent Application Serial No. EP 15157473.8, European Patent Office, dated Sep. 15, 2015; (7 pages).
European Search Report corresponding to co-pending European Patent Application Serial No. EP 15157469.6, European Patent Office, dated Sep. 15, 2015; (6 pages).
Related Publications (1)
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20150069617 A1 Mar 2015 US
Provisional Applications (3)
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61113622 Nov 2008 US
61103361 Oct 2008 US
61113007 Nov 2008 US
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Parent 13767262 Feb 2013 US
Child 14488544 US
Parent 12616922 Nov 2009 US
Child 13767262 US
Continuation in Parts (1)
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Parent 12575008 Oct 2009 US
Child 12616922 US