The present invention relates to systems, apparatuses, and methods utilizing expandable or stretchable integrated circuitry, and more particularly to extremely stretchable integrated circuitry.
The field of stretchable electronics continues to grow due to the demand of high performance and mechanically unconstrained applications of the future. However, stretchable electronics have been thus far limited in stretchability. This has limited the ability of stretchable electronics to accommodate applications that require more extreme stretchability. Therefore a need exists for extremely stretchable electronics.
This invention is for extremely stretchable electrical interconnects and methods of making the same. In embodiments, the invention comprises a method of making stretchable electronics, which in some embodiments can be out of high quality single crystal semiconductor materials or other semiconductor materials, that are typically rigid. For example, single crystal semiconductor materials are brittle and cannot typically withstand strains of greater than about +/−2%. This invention describes a method of electronics that are capable of stretching and compressing while withstanding high translational strains, such as in the range of −100,000% to +100,000%, and/or high rotational strains, such as to an extent greater than 180°, while maintaining electrical performance found in their unstrained state.
In embodiments, the stretching and compressing may be accomplished by fabricating integrated circuits (ICs) out of thin membrane single crystal semiconductors, which are formed into “islands” that are mechanically and electrically connected by “interconnects,” and transferring said ICs onto an elastomeric substrate capable of stretching and compressing. The islands are regions of non-stretchable/compressible ICs, while the interconnects are regions of material formed in a way to be highly stretchable/compressible. The underlying elastomeric substrate is much more compliant than the islands, so that minimal strain is transferred into the islands while the majority of the strain is transferred to the interconnects, which only contain electrical connections and not ICs. Each interconnect attaches one island to another island, and is capable of accommodating strain between the two aforementioned islands, including translation, rotation, or a combination of translation with rotation of one island relative to another. Even though the interconnects may be made of a rigid material, they act like weak springs rather than rigid plates or beams. This configuration thereby allows for the making of extremely stretchable electronics.
These and other systems, methods, objects, features, and advantages of the present invention will be apparent to those skilled in the art from the following detailed description of the preferred embodiment and the drawings. All documents mentioned herein are hereby incorporated in their entirety by reference.
The invention and the following detailed description of certain embodiments thereof may be understood by reference to the following figures:
While the invention has been described in connection with certain preferred embodiments, other embodiments would be understood by one of ordinary skill in the art and are encompassed herein.
All documents referenced herein are hereby incorporated by reference.
The present invention accomplishes extremely stretchable electronics by forming the electronics on discrete islands 102 of silicon.
With reference to the present invention, the term “stretchable”, and roots and derivations thereof, when used to modify circuitry or components thereof is meant to encompass circuitry that comprises components having soft or elastic properties capable of being made longer or wider without tearing or breaking, and it is also meant to encompass circuitry having components (whether or not the components themselves are individually stretchable as stated above) that are configured in such a way so as to accommodate and remain functional when applied to a stretchable, inflatable, or otherwise expandable surface. The term “expandable”, and roots and derivations thereof, when used to modify circuitry or components thereof is also meant to have the meaning ascribed above. Thus, “stretch” and “expand”, and all derivations thereof, may be used interchangeably when referring to the present invention.
In embodiments, the discrete islands mention above are discrete operative (in embodiments, arranged in a “device island” arrangement) and are themselves capable of performing the functionality described herein, or portions thereof. In embodiments, such functionality of the operative devices can include integrated circuits, physical sensors (e.g. temperature, pH, light, radiation etc), biological and/or chemical sensors, amplifiers, A/D and D/A converters, optical collectors, electromechanical transducers, piezo-electric actuators, light emitting electronics which include LEDs, and combinations thereof. The purpose and advantage of using standard ICs (in embodiments, CMOS, on single crystal silicon) is to have and use high quality, high performance, and high functioning circuit components that are also already commonly mass-produced with well known processes, and which provide a range of functionality and generation of data far superior to that produced by a passive means.
In an example, the discrete islands 102 may range from about, but not limited to, 10-100 μm in size measured on an edge or by diameter, and connecting said islands 102A-B with one or more extremely stretchable interconnects 104. The novel geometry of the interconnects 104 is what makes them extremely compliant. Each interconnect 104 is patterned and etched so that its structural form has width and thickness dimensions that may be of comparable size (such as their ratio or inverse ratio not exceeding about a factor of 10); and may be preferably equal in size. In embodiments, the dimensions may not be greater than about Sum (e.g. where both dimensions are about 1 μm or less). The interconnect 104 may be formed in a boustrophedonic style such that it effectively comprises long bars 108 and short bars 110 as shown in
In addition, because the interconnect 104 may be formed out of rigid materials, after being stretched it may have a restorative force which helps prevent its wire-like form from getting tangled or knotted when re-compressing to the unstretched state. Another advantage of the boustrophedonic geometry is that it minimizes the initial separation distance between the islands 102A-B. This is illustrated in
In embodiments, the connection point of the interconnect 104 to the device island 102 may be anywhere along the device island edge, or may be at a point on the surface of the device island 102 (in which case the interconnect may be located just above the plane of the device island).
In embodiments, device islands 102 may be made on any suitable material substrate, provided that a top membrane layer of said substrate that contains the ICs can be freed from the bulk of the substrate and transfer printed onto an elastomeric substrate.
In the present invention, the interconnects 104 (as described herein) may be formed either monolithically (i.e., out of the same semiconductor material as the device islands) or may be formed out of another material. In one non-limiting example embodiment, the stretchable electronics arc fabricated on a silicon-on-insulator (SOI) wafer, having a 1 μm thick top silicon layer and a 1 μm thick buried oxide layer. Devices arc formed on the top silicon wafer, and arranged into a square pattern of islands 102A-D and interconnects 104 of the general form shown in
In another embodiment the elastomeric substrate 602 may comprise two layers separated by a height. The top “contact” layer contacts the device island 102 as in the embodiment illustrated in
In another embodiment, the PDMS in the lower layer may be designed with periodic sinusoidal ripples 702B. In embodiments, this ripple configuration may be achieved by bonding Si nanoribbons on the surface of pre-strained PDMS in a uniform parallel pattern. The release of the prestrain in the PDMS substrate generates sinusoidal waves along the thin Si-nanoribbons (caused by buckling) and the surface of the PDMS substrate. The amplitude and wavelength of these waves 702B may depend on the extent of uniaxial pre-strain exerted on the PDMS and on the mechanical properties of the Si-nanoribbons. The wavy surface on the PDMS may be used as a transfer mold. Two-part liquid plastic solution can be poured over the wavy PDMS substrate and cured at room temperature over time (−2 hrs). Once the plastic hardens, the plastic substrate can be peeled away from the PDMS. This new plastic transfer substrate with wavy surface features can be used to produce more PDMS substrates containing wave features. The wavy PDMS may serve as the lower layer of PDMS as in the previous embodiment. To produce a two layer PDMS structure, a top layer of PDMS can be plasma bonded to this lower layer of PDMS using oxygen plasma surface activation to produce the substrate illustrated in
In another embodiment, the PDMS transfer stamp is stretched after the islands 102A-B and interconnects 104 are picked up. A subsequent transfer to another elastomeric substrate 602 may place these pre-stretched devices in a configuration, which allows the new elastomeric substrate to undergo compression. The devices may be able to accommodate that compression because the interconnects are pre-stretched.
In another embodiment, the interconnects 104 are not made out of the same material as the device islands 102. In this case, the islands 102A-B are completely isolated from each other by etching, with no interconnects in between. In an example, a layer of polyimide may then be deposited, contact vias etched to various locations on the surface of the device island 102, and then metal interconnects 104 deposited and patterned into a boustrophedonic pattern, followed by another layer of polyimide. Both layers of polyimide may now be patterned and etched to leave a small border around the interconnects 104 (thereby fully encapsulating the interconnects). These interconnects may have the advantage that they arc already fully encapsulated in polyimide and will not adhere as well to the elastomeric substrate as the device islands will. The other advantage is that these interconnects may not be limited to only connecting along the edge of an island. The contact via may be etched anywhere on the surface of the island 102, including near the center. This may allow for easier connections to devices, more connections than possible only along an edge, increased strain compliance, decreased strain at the contact vias, and multiple layers of interconnects made with polymer passivation layers in between, allowing even more interconnects, or allowing one device island 102A to connect to a non-neighboring device island 102B.
In another embodiment of the invention, the device islands 102 are fabricated and transfer printed onto the elastomeric substrate 602, or substrate comprising a polymeric release layer and polymeric non-release layer. After transfer printing, the interconnects 104 are formed as described above, which may be possible because they do not require any high temperature processing, and then in the latter case, the release layer is etched and the devices that are on the non-release layer, are transfer printed onto another elastomeric substrate 602. In the former case, the islands 102 may be transferred onto the elastomeric substrate using pick and place technology so that islands 102 that are initially fabricated very close to each other are spread apart when they are transfer printed. This allows the interconnects 104 to be fabricated in a pattern that resembles their stretched configuration (if desired), to allow compression.
In embodiments, the present invention may comprise a stretchable electrical interconnect 104, including an electrical interconnect 104 for connecting two electrical contacts 102A-B (e.g. device islands 102A-B), where the electrical interconnect 104 may be arranged boustrophedonicially to define rungs 108 (i.e. long bars 108) between the contacts 102A-B, and where the rungs 108 may be substantially parallel with one another and where a plurality of rungs 108 may have substantially the same length and displacement therebetween. In addition, the ratio of the length of the plurality of rungs 108 and the displacement between the plurality of rungs 108 may be large, such as at least 10:1, 100:1, 1000:1, and the like. The electrical integrity of the electrical interconnect 104 may be maintained as stretched, such as to displacements that are increased to 1000%, 10000%, 100000%, and the like during stretching. In embodiments, the rungs 108 may be substantially perpendicular to the contacts 102A-B, the interconnection 104 may have a trace width and/or inter-rung spacing ranging between 0.1-10 microns. In embodiments, the two electrical contacts 102A-B may be located on an elastomeric substrate 602, the electrical contacts 102A-B may be bonded to the substrate 602 and the interconnection 104 not bonded to the substrate 602, the electrical contacts 102A-B may be semiconductor circuits, metal contacts, and the like.
In embodiments, the present invention may comprise a stretchable electrical interconnect 104, including an electrical interconnect 104 for connecting two electrical contacts 102A-B, where the electrical interconnect 104 is arranged boustrophedonicially to define rungs 108 between the contacts 102A-B, and where the interconnect 104 maintains electrical conductivity and electrical integrity when a displacement between the contacts 102A-B is increased, such as by 1000%, 10000%, 100000%, and the like.
In embodiments, the present invention may electrically interconnect two electrical contacts 102A-B with a stretchable interconnection 104 that has the ability to twist between the two electrical contacts 102A-B by up to approximately 180 degrees while maintaining electrical integrity of the stretchable interconnection 104.
In embodiments, the present invention may be a device including a body having a stretchable surface (e.g. an elastomeric substrate 602), and a stretchable electronic circuit including (i) a first discrete operative device 102A, (ii) a second discrete operative device 102B, and (iii) a stretchable interconnect 104 connecting the first discrete operative device 102A to the second discrete operative device 102B, where the interconnect 104 may have a substantially boustrophedonic pattern and be able to maintain electrical conductivity when stretched, such as up to 1000%, 10000%, 100000%, and the like. The stretchable electronic circuit may be affixed to the stretchable surface of the body. In embodiments, the connection may be to a metal contact, to a semiconductor device, and the like. The first discrete operative device 102A, the second discrete operative device 102B, and the stretchable interconnect 104 may all be made from the same material, and that material may be a semiconductor material.
In embodiments, the present invention may attach at least two isolated electronic components (which in embodiments may be discrete operative devices) 102A-B to an elastomeric substrate 602, and arrange an electrical interconnection 104 between the components 102A-B in a boustrophedonic pattern interconnecting the two isolated electronic components 102A-B with the electrical interconnection 104. The elastomeric substrate 602 may then be stretched such that components 102A-B separate relative to one another, where the electrical interconnection 104 maintains substantially identical electrical performance characteristics that the electrical interconnection 104 had in a pre-stretched form. In embodiments, the stretching may be a translational stretching, where the separation between the isolated electronic components 102A-B increases by a percent as a result of the stretching, such as 10%, 100%, 1000%, 10000%, 100000%, and the like. The stretching may be a rotational stretching, where the rotation may be greater than a certain rotation angle, such as 90°, 180°, 270°, 360°, and the like, where the stretching may be in all three axes. In embodiments, the electrical interconnection 104 may be made from semiconductive material. The electrical interconnection 104 may be made from the same semiconductor material as the isolated electronic components 102A-B, fabricated at the same time as the isolated electronic components 102A-B, and the like. The semiconductor material may be a single crystal semiconductor material. The electrical interconnection 104 may made of a different material than the isolated electronic components 102A-B, such as a metal. In embodiments, the interconnect material 104 may be loosely bound to the elastomeric substrate 602, not connected at all, raised above the surface of the elastomeric substrate 602, and the like. In embodiments, the at least two isolated semiconductor circuits may be fabricated on an upper surface 604 of the elastomeric substrate 602 separated by a lower surface 608 of the elastomeric substrate 602, and the electrical interconnection 104 may be fabricated at the level of the upper surface 604 of the elastomeric substrate 602. In this way, the electrical interconnection 104 may have no direct contact with the lower level 608, and thereby be substantially free from adhesion to the lower level 608 during stretching. In addition, the lower surface 608 of the elastomeric substrate 602 may include a wavy form 702, where the wavy form 704 may allow the elastomeric substrate 602 to expand during stretching.
While the invention has been described in connection with certain preferred embodiments, other embodiments would be understood by one of ordinary skill in the art and are encompassed herein.
All documents referenced herein are hereby incorporated by reference.
This application claims the benefit of U.S. Provisional Application No. 61/113,622 entitled “Extremely Stretchable Interconnects” filed on Nov. 12, 2008, the entirety of which is incorporated herein by reference. Also, this application is a continuation-in-part of, and claims the benefit of U.S. Non-Provisional application Ser. No. 12/575,008, entitled “Catheter Balloon Having Stretchable Integrated Circuitry and Sensor Array” filed on Oct. 7, 2009, the entirety of which is incorporated herein by reference. Application Ser. No. 12/575,008 claimed the priority of U.S. Provisional Application Nos. 61/103,361, filed Oct. 7, 2008 and 61/113,007, filed Nov. 10, 2008 the entirety of each of which is incorporated herein by reference.
| Number | Name | Date | Kind |
|---|---|---|---|
| 3716861 | Root | Feb 1973 | A |
| 3805427 | Epstein | Apr 1974 | A |
| 3949410 | Bassous | Apr 1976 | A |
| 4058418 | Lindmayer | Nov 1977 | A |
| 4304235 | Kaufman | Dec 1981 | A |
| 4392451 | Mickelsen et al. | Jul 1983 | A |
| 4416288 | Freeman | Nov 1983 | A |
| 4471003 | Cann | Sep 1984 | A |
| 4487162 | Cann | Dec 1984 | A |
| 4658153 | Brosh | Apr 1987 | A |
| 4663828 | Hanak | May 1987 | A |
| 4761335 | Aurichio et al. | Aug 1988 | A |
| 4763275 | Carlin | Aug 1988 | A |
| 4766670 | Gazdik et al. | Aug 1988 | A |
| 4784720 | Douglas | Nov 1988 | A |
| 4855017 | Douglas | Aug 1989 | A |
| 5041973 | Lebron et al. | Aug 1991 | A |
| 5086785 | Gentile et al. | Feb 1992 | A |
| 5118400 | Wollam | Jun 1992 | A |
| 5147519 | Legge | Sep 1992 | A |
| 5178957 | Kolpe et al. | Jan 1993 | A |
| 5204144 | Cann et al. | Apr 1993 | A |
| 5306917 | Black | Apr 1994 | A |
| 5313094 | Beyer et al. | May 1994 | A |
| 5331966 | Bennett et al. | Jul 1994 | A |
| 5360987 | Shibib | Nov 1994 | A |
| 5403700 | Heller et al. | Apr 1995 | A |
| 5427096 | Bogusiewicz et al. | Jun 1995 | A |
| 5434751 | Cole, Jr. et al. | Jul 1995 | A |
| 5455178 | Fattnger | Oct 1995 | A |
| 5469845 | DeLonzor et al. | Nov 1995 | A |
| 5501893 | Laermer et al. | Mar 1996 | A |
| 5525815 | Einset | Jun 1996 | A |
| 5539935 | Rush, III | Jul 1996 | A |
| 5545291 | Smith et al. | Aug 1996 | A |
| 5549108 | Edwards et al. | Aug 1996 | A |
| 5560974 | Langley | Oct 1996 | A |
| 5567975 | Walsh | Oct 1996 | A |
| 5625471 | Smith | Apr 1997 | A |
| 5648148 | Simpson | Jul 1997 | A |
| 5687737 | Branham et al. | Nov 1997 | A |
| 5691245 | Bakhit et al. | Nov 1997 | A |
| 5746207 | McLaughlin | May 1998 | A |
| 5753529 | Chang et al. | May 1998 | A |
| 5757081 | Chang et al. | May 1998 | A |
| 5767578 | Chang et al. | Jun 1998 | A |
| 5772905 | Chou | Jun 1998 | A |
| 5783856 | Smith et al. | Jul 1998 | A |
| 5790151 | Mills | Aug 1998 | A |
| 5811790 | Endo | Sep 1998 | A |
| 5817008 | Rafert et al. | Oct 1998 | A |
| 5817242 | Biebuyck et al. | Oct 1998 | A |
| 5824186 | Smith et al. | Oct 1998 | A |
| 5860974 | Abele | Jan 1999 | A |
| 5871443 | Edwards et al. | Feb 1999 | A |
| 5904545 | Smith et al. | May 1999 | A |
| 5907189 | Mertol | May 1999 | A |
| 5907477 | Tuttle et al. | May 1999 | A |
| 5915180 | Hara et al. | Jun 1999 | A |
| 5917534 | Rajeswaran | Jun 1999 | A |
| 5919155 | Lattin et al. | Jul 1999 | A |
| 5928001 | Gillette et al. | Jul 1999 | A |
| 5955781 | Joshi et al. | Sep 1999 | A |
| 5976683 | Liehrr et al. | Nov 1999 | A |
| 5978972 | Stewart | Nov 1999 | A |
| 5998291 | Bakhit et al. | Dec 1999 | A |
| 6024702 | Iversen | Feb 2000 | A |
| 6057212 | Chan et al. | May 2000 | A |
| 6063046 | Allum | May 2000 | A |
| 6080608 | Nowak | Jun 2000 | A |
| 6097984 | Douglas | Aug 2000 | A |
| 6121110 | Hong | Sep 2000 | A |
| 6165391 | Vedamuttu | Dec 2000 | A |
| 6165885 | Gaynes et al. | Dec 2000 | A |
| 6171730 | Kuroda et al. | Jan 2001 | B1 |
| 6181551 | Herman et al. | Jan 2001 | B1 |
| 6225149 | Gan et al. | May 2001 | B1 |
| 6236883 | Ciaccio et al. | May 2001 | B1 |
| 6265326 | Ueno | Jul 2001 | B1 |
| 6274508 | Jacobsen et al. | Aug 2001 | B1 |
| 6276775 | Schulte | Aug 2001 | B1 |
| 6277712 | Kang et al. | Aug 2001 | B1 |
| 6281038 | Jacobsen et al. | Aug 2001 | B1 |
| 6284418 | Trantolo | Sep 2001 | B1 |
| 6291896 | Smith | Sep 2001 | B1 |
| 6301500 | Van Herk | Oct 2001 | B1 |
| 6316278 | Jacobsen et al. | Nov 2001 | B1 |
| 6316283 | Saurer | Nov 2001 | B1 |
| 6317175 | Salerno et al. | Nov 2001 | B1 |
| 6322895 | Canham | Nov 2001 | B1 |
| 6334960 | Willson et al. | Jan 2002 | B1 |
| 6344616 | Yokokawa | Feb 2002 | B1 |
| 6360615 | Smela | Mar 2002 | B1 |
| 6380729 | Smith | Apr 2002 | B1 |
| 6403397 | Katz | Jun 2002 | B1 |
| 6413790 | Duthaler et al. | Jul 2002 | B1 |
| 6414783 | Zavracky et al. | Jul 2002 | B2 |
| 6417025 | Gengel | Jul 2002 | B1 |
| 6420266 | Smith et al. | Jul 2002 | B1 |
| 6421016 | Phillips | Jul 2002 | B1 |
| 6433401 | Clark et al. | Aug 2002 | B1 |
| 6451191 | Bentsen et al. | Sep 2002 | B1 |
| 6459418 | Comiskey et al. | Oct 2002 | B1 |
| 6468638 | Jacobsen et al. | Oct 2002 | B2 |
| 6479395 | Smith et al. | Nov 2002 | B1 |
| 6504105 | Acocella et al. | Jan 2003 | B1 |
| 6517995 | Jacobson et al. | Feb 2003 | B1 |
| 6527964 | Smith et al. | Mar 2003 | B1 |
| 6555408 | Jacobsen et al. | Apr 2003 | B1 |
| 6566744 | Gengel | May 2003 | B2 |
| 6567158 | Falcial | May 2003 | B1 |
| 6580151 | Vandeputte et al. | Jun 2003 | B2 |
| 6586338 | Smith et al. | Jul 2003 | B2 |
| 6590346 | Hadley et al. | Jul 2003 | B1 |
| 6606079 | Smith | Aug 2003 | B1 |
| 6606247 | Credelle et al. | Aug 2003 | B2 |
| 6608370 | Chen et al. | Aug 2003 | B1 |
| 6613979 | Miller et al. | Sep 2003 | B1 |
| 6623579 | Smith et al. | Sep 2003 | B1 |
| 6639578 | Comiskey et al. | Oct 2003 | B1 |
| 6655286 | Rogers | Dec 2003 | B2 |
| 6657289 | Craig et al. | Dec 2003 | B1 |
| 6661037 | Pan et al. | Dec 2003 | B2 |
| 6665044 | Jacobsen et al. | Dec 2003 | B1 |
| 6666821 | Keimel | Dec 2003 | B2 |
| 6667548 | O'Connor et al. | Dec 2003 | B2 |
| 6683663 | Hadley et al. | Jan 2004 | B1 |
| 6693384 | Vicentini et al. | Feb 2004 | B1 |
| 6706402 | Rueckes et al. | Mar 2004 | B2 |
| 6720469 | Curtis et al. | Apr 2004 | B1 |
| 6723576 | Nozawa et al. | Apr 2004 | B2 |
| 6730990 | Kondo et al. | May 2004 | B2 |
| 6731353 | Credelle et al. | May 2004 | B1 |
| 6743982 | Biegelsen et al. | Jun 2004 | B2 |
| 6762510 | Fock et al. | Jul 2004 | B2 |
| 6775906 | Silverbrook | Aug 2004 | B1 |
| 6780696 | Schatz | Aug 2004 | B1 |
| 6784450 | Pan et al. | Aug 2004 | B2 |
| 6784844 | Boakes et al. | Aug 2004 | B1 |
| 6787052 | Vaganov | Sep 2004 | B1 |
| 6814898 | Deeman et al. | Nov 2004 | B1 |
| 6816380 | Credelle et al. | Nov 2004 | B2 |
| 6826509 | Crisco, III et al. | Nov 2004 | B2 |
| 6836744 | Asphahani et al. | Dec 2004 | B1 |
| 6844673 | Bernkopf | Jan 2005 | B1 |
| 6848162 | Arneson et al. | Feb 2005 | B2 |
| 6850312 | Jacobsen et al. | Feb 2005 | B2 |
| 6856830 | He | Feb 2005 | B2 |
| 6863219 | Jacobsen et al. | Mar 2005 | B1 |
| 6864435 | Hermanns et al. | Mar 2005 | B2 |
| 6864570 | Smith | Mar 2005 | B2 |
| 6872645 | Duan et al. | Mar 2005 | B2 |
| 6878871 | Scher et al. | Apr 2005 | B2 |
| 6881979 | Starikov et al. | Apr 2005 | B2 |
| 6885030 | Onozuka et al. | Apr 2005 | B2 |
| 6887450 | Chen et al. | May 2005 | B2 |
| 6900094 | Hammond et al. | May 2005 | B2 |
| 6917061 | Pan et al. | Jul 2005 | B2 |
| 6936181 | Bulthaup et al. | Aug 2005 | B2 |
| 6949199 | Gauzner et al. | Sep 2005 | B1 |
| 6949206 | Whitford et al. | Sep 2005 | B2 |
| 6950220 | Abramson et al. | Sep 2005 | B2 |
| 6965160 | Cobbley | Nov 2005 | B2 |
| 6967362 | Nam et al. | Nov 2005 | B2 |
| 6984934 | Moller et al. | Jan 2006 | B2 |
| 6987314 | Yoshida | Jan 2006 | B1 |
| 6989285 | Ball | Jan 2006 | B2 |
| 7029951 | Chen et al. | Apr 2006 | B2 |
| 7033961 | Smart et al. | Apr 2006 | B1 |
| 7054784 | Flentov et al. | May 2006 | B2 |
| 7067903 | Tachibana et al. | Jun 2006 | B2 |
| 7081642 | Onozuka et al. | Jul 2006 | B2 |
| 7116318 | Amundson et al. | Oct 2006 | B2 |
| 7132313 | O'Connor et al. | Nov 2006 | B2 |
| 7148512 | Leu et al. | Dec 2006 | B2 |
| 7158277 | Berggren et al. | Jan 2007 | B2 |
| 7169546 | Suzuki et al. | Jan 2007 | B2 |
| 7169669 | Blakers et al. | Jan 2007 | B2 |
| 7170164 | Chen et al. | Jan 2007 | B2 |
| 7186624 | Weiser et al. | Mar 2007 | B2 |
| 7190051 | Mech et al. | Mar 2007 | B2 |
| 7195733 | Rogers et al. | Mar 2007 | B2 |
| 7223609 | Anvar et al. | May 2007 | B2 |
| 7223632 | Onozuka et al. | May 2007 | B2 |
| 7252664 | Nasab et al. | Aug 2007 | B2 |
| 7253442 | Huang et al. | Aug 2007 | B2 |
| 7255919 | Sakata et al. | Aug 2007 | B2 |
| 7265298 | Maghribi et al. | Sep 2007 | B2 |
| 7291146 | Steinke et al. | Nov 2007 | B2 |
| 7291540 | Mech et al. | Nov 2007 | B2 |
| 7293353 | Matsuda | Nov 2007 | B2 |
| 7302751 | Hamburgen | Dec 2007 | B2 |
| 7337012 | Maghribi et al. | Feb 2008 | B2 |
| 7374968 | Kornilovich et al. | May 2008 | B2 |
| 7425523 | Ikemizu et al. | Sep 2008 | B2 |
| 7487587 | Vanfleteren et al. | Feb 2009 | B2 |
| 7491892 | Wagner et al. | Feb 2009 | B2 |
| 7509835 | Beck | Mar 2009 | B2 |
| 7521292 | Rogers et al. | Apr 2009 | B2 |
| 7526389 | Greenwald et al. | Apr 2009 | B2 |
| 7557367 | Rogers et al. | Jul 2009 | B2 |
| 7593086 | Jeong et al. | Sep 2009 | B2 |
| 7618260 | Daniel et al. | Nov 2009 | B2 |
| 7622367 | Nuzzo et al. | Nov 2009 | B1 |
| 7629691 | Roush et al. | Dec 2009 | B2 |
| 7633761 | Kim | Dec 2009 | B2 |
| 7635755 | Kaplan et al. | Dec 2009 | B2 |
| 7674882 | Kaplan et al. | Mar 2010 | B2 |
| 7700402 | Wild et al. | Apr 2010 | B2 |
| 7704684 | Rogers et al. | Apr 2010 | B2 |
| 7705280 | Nuzzo et al. | Apr 2010 | B2 |
| 7709961 | Greenberg et al. | May 2010 | B2 |
| 7727199 | Fernandes et al. | Jun 2010 | B2 |
| 7727575 | Kaplan et al. | Jun 2010 | B2 |
| 7742795 | Stone et al. | Jun 2010 | B2 |
| 7759167 | Vanfleteren et al. | Jul 2010 | B2 |
| 7799699 | Nuzzo et al. | Sep 2010 | B2 |
| 7842780 | Kaplan et al. | Nov 2010 | B2 |
| 7857781 | Noda et al. | Dec 2010 | B2 |
| 7871661 | Maghribi et al. | Jan 2011 | B2 |
| 7884540 | Sung et al. | Feb 2011 | B2 |
| 7932123 | Rogers et al. | Apr 2011 | B2 |
| 7935056 | Zdeblick | May 2011 | B2 |
| 7943491 | Nuzzo et al. | May 2011 | B2 |
| 7960246 | Flamand et al. | Jun 2011 | B2 |
| 7972875 | Rogers et al. | Jul 2011 | B2 |
| 7982296 | Nuzzo et al. | Jul 2011 | B2 |
| 8039847 | Nuzzo et al. | Oct 2011 | B2 |
| 8107248 | Shin et al. | Jan 2012 | B2 |
| 8198621 | Rogers et al. | Jun 2012 | B2 |
| 8207473 | Axisa et al. | Jun 2012 | B2 |
| 8217381 | Rogers | Jul 2012 | B2 |
| 8431828 | Vanfleteren | Apr 2013 | B2 |
| 8440546 | Nuzzo | May 2013 | B2 |
| 8552299 | Rogers | Oct 2013 | B2 |
| 8664699 | Nuzzo | Mar 2014 | B2 |
| 8679888 | Rogers | Mar 2014 | B2 |
| 8729524 | Rogers | May 2014 | B2 |
| 8754396 | Rogers | Jun 2014 | B2 |
| 8865489 | Rogers | Oct 2014 | B2 |
| 8905772 | Rogers | Dec 2014 | B2 |
| 20010003043 | Metspalu et al. | Jun 2001 | A1 |
| 20010012918 | Swanson | Aug 2001 | A1 |
| 20010021867 | Kordis | Sep 2001 | A1 |
| 20020021445 | Boxhevolnyi et al. | Feb 2002 | A1 |
| 20020026127 | Balbierz | Feb 2002 | A1 |
| 20020082515 | Campbell et al. | Jun 2002 | A1 |
| 20020094701 | Biegelsen et al. | Jul 2002 | A1 |
| 20020110766 | Tsai et al. | Aug 2002 | A1 |
| 20020113739 | Howard | Aug 2002 | A1 |
| 20020128700 | Cross, Jr. | Sep 2002 | A1 |
| 20020151934 | Levine | Oct 2002 | A1 |
| 20030006527 | Rabolt et al. | Jan 2003 | A1 |
| 20030017848 | Engstrom et al. | Jan 2003 | A1 |
| 20030032892 | Erlach et al. | Feb 2003 | A1 |
| 20030045025 | Coyle | Mar 2003 | A1 |
| 20030082889 | Maruyama et al. | May 2003 | A1 |
| 20030087476 | Oohata et al. | May 2003 | A1 |
| 20030097165 | Krulevitch | May 2003 | A1 |
| 20030138704 | Mei et al. | Jul 2003 | A1 |
| 20030149456 | Rottenberg et al. | Aug 2003 | A1 |
| 20030162507 | Vatt | Aug 2003 | A1 |
| 20030171691 | Casscells et al. | Sep 2003 | A1 |
| 20030178316 | Jacobs et al. | Sep 2003 | A1 |
| 20030214408 | Grajales | Nov 2003 | A1 |
| 20030222282 | Fjelstad et al. | Dec 2003 | A1 |
| 20030227116 | Halik et al. | Dec 2003 | A1 |
| 20030236455 | Swanson | Dec 2003 | A1 |
| 20040005723 | Empedocles et al. | Jan 2004 | A1 |
| 20040006264 | Mojarradi et al. | Jan 2004 | A1 |
| 20040026684 | Empedocles et al. | Feb 2004 | A1 |
| 20040061543 | Nam et al. | Apr 2004 | A1 |
| 20040079464 | Kumakura | Apr 2004 | A1 |
| 20040081384 | Datesman et al. | Apr 2004 | A1 |
| 20040092806 | Sagon | May 2004 | A1 |
| 20040095658 | Buretea et al. | May 2004 | A1 |
| 20040106334 | Suzuki | Jun 2004 | A1 |
| 20040112964 | Empedocles et al. | Jun 2004 | A1 |
| 20040135094 | Niigaki | Jul 2004 | A1 |
| 20040136866 | Pontis et al. | Jul 2004 | A1 |
| 20040138558 | Dunki-Jacobs | Jul 2004 | A1 |
| 20040146560 | Whiteford et al. | Jul 2004 | A1 |
| 20040149921 | Smyk | Aug 2004 | A1 |
| 20040155290 | Mech et al. | Aug 2004 | A1 |
| 20040171969 | Socci | Sep 2004 | A1 |
| 20040178390 | Whiteford | Sep 2004 | A1 |
| 20040178466 | Merrill | Sep 2004 | A1 |
| 20040192062 | Mikelson | Sep 2004 | A1 |
| 20040192082 | Wagner et al. | Sep 2004 | A1 |
| 20040200734 | Co et al. | Oct 2004 | A1 |
| 20040203486 | Shepherd | Oct 2004 | A1 |
| 20040206448 | Dubrow | Oct 2004 | A1 |
| 20040211458 | Gui et al. | Oct 2004 | A1 |
| 20040211459 | Suenaga et al. | Oct 2004 | A1 |
| 20040221370 | Hannula et al. | Nov 2004 | A1 |
| 20040229830 | Tachibana et al. | Nov 2004 | A1 |
| 20040243204 | Maghribi | Dec 2004 | A1 |
| 20040250950 | Dubrow | Dec 2004 | A1 |
| 20040252559 | Gupta | Dec 2004 | A1 |
| 20050020094 | Forbes et al. | Jan 2005 | A1 |
| 20050021103 | DiLorenzo | Jan 2005 | A1 |
| 20050038498 | Dubrow et al. | Feb 2005 | A1 |
| 20050067293 | Naito | Mar 2005 | A1 |
| 20050082526 | Bedell et al. | Apr 2005 | A1 |
| 20050096513 | Ozguz | May 2005 | A1 |
| 20050113744 | Donoghue | May 2005 | A1 |
| 20050124712 | Anderson et al. | Jun 2005 | A1 |
| 20050133954 | Homola | Jun 2005 | A1 |
| 20050139683 | Yi | Jun 2005 | A1 |
| 20050171524 | Stern et al. | Aug 2005 | A1 |
| 20050177335 | Crisco | Aug 2005 | A1 |
| 20050203366 | Donoghue | Sep 2005 | A1 |
| 20050214962 | Daniels et al. | Sep 2005 | A1 |
| 20050227389 | Bhattacharya et al. | Oct 2005 | A1 |
| 20050233546 | Oohata et al. | Oct 2005 | A1 |
| 20050238967 | Rogers et al. | Oct 2005 | A1 |
| 20050255686 | Yamano et al. | Nov 2005 | A1 |
| 20050260706 | Kaplan et al. | Nov 2005 | A1 |
| 20050261561 | Jones et al. | Nov 2005 | A1 |
| 20060003709 | Wood | Jan 2006 | A1 |
| 20060038182 | Rogers et al. | Feb 2006 | A1 |
| 20060049485 | Pan et al. | Mar 2006 | A1 |
| 20060056161 | Shin et al. | Mar 2006 | A1 |
| 20060071349 | Tokushige | Apr 2006 | A1 |
| 20060076561 | Hicki et al. | Apr 2006 | A1 |
| 20060084012 | Nuzzo et al. | Apr 2006 | A1 |
| 20060084394 | Engstrom et al. | Apr 2006 | A1 |
| 20060085976 | Eldridge et al. | Apr 2006 | A1 |
| 20060102525 | Volkel et al. | May 2006 | A1 |
| 20060106321 | Lewinsky et al. | May 2006 | A1 |
| 20060119853 | Baumberg et al. | Jun 2006 | A1 |
| 20060127817 | Ramanujan et al. | Jun 2006 | A1 |
| 20060128346 | Yasui | Jun 2006 | A1 |
| 20060129056 | Leuthardt et al. | Jun 2006 | A1 |
| 20060132025 | Gao et al. | Jun 2006 | A1 |
| 20060134893 | Savage et al. | Jun 2006 | A1 |
| 20060154398 | Qing | Jul 2006 | A1 |
| 20060159837 | Kaplan et al. | Jul 2006 | A1 |
| 20060160560 | Josenhans | Jul 2006 | A1 |
| 20060169989 | Bhattacharya et al. | Aug 2006 | A1 |
| 20060173364 | Clancy et al. | Aug 2006 | A1 |
| 20060177479 | Giachelli et al. | Aug 2006 | A1 |
| 20060178655 | Santini et al. | Aug 2006 | A1 |
| 20060244105 | Forbes et al. | Nov 2006 | A1 |
| 20060255341 | Pinnington et al. | Nov 2006 | A1 |
| 20060264767 | Shennib | Nov 2006 | A1 |
| 20060273279 | Kaplan et al. | Dec 2006 | A1 |
| 20060279191 | Geohegan et al. | Dec 2006 | A1 |
| 20060286488 | Rogers et al. | Dec 2006 | A1 |
| 20060286785 | Rogers et al. | Dec 2006 | A1 |
| 20070009968 | Cunningham et al. | Jan 2007 | A1 |
| 20070027514 | Gerber | Feb 2007 | A1 |
| 20070031607 | Dubson et al. | Feb 2007 | A1 |
| 20070032089 | Nuzzo et al. | Feb 2007 | A1 |
| 20070043416 | Callas et al. | Feb 2007 | A1 |
| 20070058254 | Kim | Mar 2007 | A1 |
| 20070073130 | Finch et al. | Mar 2007 | A1 |
| 20070108389 | Makela | May 2007 | A1 |
| 20070123756 | Kitajima et al. | May 2007 | A1 |
| 20070187862 | Kaplan et al. | Aug 2007 | A1 |
| 20070212730 | Vepari et al. | Sep 2007 | A1 |
| 20070213616 | Anderson et al. | Sep 2007 | A1 |
| 20070227586 | Zapalac | Oct 2007 | A1 |
| 20070233208 | Kurtz et al. | Oct 2007 | A1 |
| 20080000871 | Suh et al. | Jan 2008 | A1 |
| 20080008626 | Lin et al. | Jan 2008 | A1 |
| 20080038236 | Gimble et al. | Feb 2008 | A1 |
| 20080041617 | Chen et al. | Feb 2008 | A1 |
| 20080046080 | Bulcke et al. | Feb 2008 | A1 |
| 20080054875 | Saito | Mar 2008 | A1 |
| 20080055581 | Rogers et al. | Mar 2008 | A1 |
| 20080074383 | Dean | Mar 2008 | A1 |
| 20080077225 | Carlin et al. | Mar 2008 | A1 |
| 20080085272 | Kaplan et al. | Apr 2008 | A1 |
| 20080090322 | Mech et al. | Apr 2008 | A1 |
| 20080096620 | Lee | Apr 2008 | A1 |
| 20080102096 | Molin et al. | May 2008 | A1 |
| 20080108171 | Rogers et al. | May 2008 | A1 |
| 20080108942 | Brister et al. | May 2008 | A1 |
| 20080139894 | Szydlo-Moore et al. | Jun 2008 | A1 |
| 20080140152 | Imran | Jun 2008 | A1 |
| 20080152281 | Lundquist et al. | Jun 2008 | A1 |
| 20080157234 | Hong | Jul 2008 | A1 |
| 20080157235 | Rogers et al. | Jul 2008 | A1 |
| 20080183076 | Witte et al. | Jul 2008 | A1 |
| 20080188912 | Stone et al. | Aug 2008 | A1 |
| 20080193749 | Thompson | Aug 2008 | A1 |
| 20080203268 | Hobbs et al. | Aug 2008 | A1 |
| 20080203431 | Garcia et al. | Aug 2008 | A1 |
| 20080204021 | Leussler et al. | Aug 2008 | A1 |
| 20080208268 | Bartic | Aug 2008 | A1 |
| 20080211087 | Mueller-Hipper | Sep 2008 | A1 |
| 20080212102 | Nuzzo et al. | Sep 2008 | A1 |
| 20080237840 | Alcoe | Oct 2008 | A1 |
| 20080239755 | Parker et al. | Oct 2008 | A1 |
| 20080257586 | Chen et al. | Oct 2008 | A1 |
| 20080259576 | Johnson et al. | Oct 2008 | A1 |
| 20080280360 | Kaplan et al. | Nov 2008 | A1 |
| 20080287167 | Caine | Nov 2008 | A1 |
| 20080288037 | Neysmith et al. | Nov 2008 | A1 |
| 20080293919 | Kaplan et al. | Nov 2008 | A1 |
| 20080313552 | Buehler et al. | Dec 2008 | A1 |
| 20090000377 | Shipps et al. | Jan 2009 | A1 |
| 20090004737 | Borenstein et al. | Jan 2009 | A1 |
| 20090015560 | Robinson et al. | Jan 2009 | A1 |
| 20090017884 | Rotschild | Jan 2009 | A1 |
| 20090028910 | DeSimone et al. | Jan 2009 | A1 |
| 20090048556 | Durand | Feb 2009 | A1 |
| 20090054742 | Kaminska et al. | Feb 2009 | A1 |
| 20090088750 | Hushka | Apr 2009 | A1 |
| 20090107704 | Vanfleteren et al. | Apr 2009 | A1 |
| 20090149930 | Schenck | Jun 2009 | A1 |
| 20090154736 | Lee | Jun 2009 | A1 |
| 20090184254 | Miura | Jul 2009 | A1 |
| 20090198293 | Cauller et al. | Aug 2009 | A1 |
| 20090199960 | Nuzzo et al. | Aug 2009 | A1 |
| 20090202614 | Kaplan et al. | Aug 2009 | A1 |
| 20090208555 | Kuttler et al. | Aug 2009 | A1 |
| 20090215385 | Waters | Aug 2009 | A1 |
| 20090221896 | Rickert et al. | Sep 2009 | A1 |
| 20090225751 | Koenck | Sep 2009 | A1 |
| 20090232963 | Kaplan et al. | Sep 2009 | A1 |
| 20090234026 | Kaplan et al. | Sep 2009 | A1 |
| 20090247909 | Mukumoto | Oct 2009 | A1 |
| 20090261828 | Nordmeyer-Massner | Oct 2009 | A1 |
| 20090273909 | Shin | Nov 2009 | A1 |
| 20090289246 | Schneider et al. | Nov 2009 | A1 |
| 20090294803 | Nuzzo et al. | Dec 2009 | A1 |
| 20090317639 | Axisa et al. | Dec 2009 | A1 |
| 20090322480 | Benedict et al. | Dec 2009 | A1 |
| 20100002402 | Rogers et al. | Jan 2010 | A1 |
| 20100028451 | Kaplan et al. | Feb 2010 | A1 |
| 20100046902 | Kaplan et al. | Feb 2010 | A1 |
| 20100052112 | Rogers et al. | Mar 2010 | A1 |
| 20100055438 | Kaplan et al. | Mar 2010 | A1 |
| 20100059863 | Rogers et al. | Mar 2010 | A1 |
| 20100063404 | Kaplan et al. | Mar 2010 | A1 |
| 20100065784 | Kaplan et al. | Mar 2010 | A1 |
| 20100068740 | Kaplan et al. | Mar 2010 | A1 |
| 20100070068 | Kaplan et al. | Mar 2010 | A1 |
| 20100072577 | Nuzzo et al. | Mar 2010 | A1 |
| 20100073669 | Colvin | Mar 2010 | A1 |
| 20100090781 | Yamamoto | Apr 2010 | A1 |
| 20100090824 | Rowell et al. | Apr 2010 | A1 |
| 20100096763 | Kaplan et al. | Apr 2010 | A1 |
| 20100117660 | Douglas | May 2010 | A1 |
| 20100120116 | Kaplan et al. | May 2010 | A1 |
| 20100121420 | Fiset et al. | May 2010 | A1 |
| 20100152619 | Kalpaxis et al. | Jun 2010 | A1 |
| 20100176705 | Van Herpen et al. | Jul 2010 | A1 |
| 20100178304 | Wang et al. | Jul 2010 | A1 |
| 20100191328 | Kaplan et al. | Jul 2010 | A1 |
| 20100196447 | Kaplan et al. | Aug 2010 | A1 |
| 20100200752 | Lee et al. | Aug 2010 | A1 |
| 20100203226 | Kaplan et al. | Aug 2010 | A1 |
| 20100245011 | Chatzopoulos et al. | Sep 2010 | A1 |
| 20100252840 | Ibbetson et al. | Oct 2010 | A1 |
| 20100279112 | Kaplan et al. | Nov 2010 | A1 |
| 20100283069 | Rogers et al. | Nov 2010 | A1 |
| 20100289124 | Nuzzo et al. | Nov 2010 | A1 |
| 20100298895 | Ghaffari et al. | Nov 2010 | A1 |
| 20100317132 | Rogers et al. | Dec 2010 | A1 |
| 20100321161 | Isabell | Dec 2010 | A1 |
| 20100324455 | Rangel et al. | Dec 2010 | A1 |
| 20100327387 | Kasai | Dec 2010 | A1 |
| 20110011179 | Gustafsson | Jan 2011 | A1 |
| 20110034912 | De Graff et al. | Feb 2011 | A1 |
| 20110051384 | Kriechbaum | Mar 2011 | A1 |
| 20110054583 | Litt et al. | Mar 2011 | A1 |
| 20110068672 | Hasnain | Mar 2011 | A1 |
| 20110101789 | Salter et al. | May 2011 | A1 |
| 20110121822 | Parsche | May 2011 | A1 |
| 20110140897 | Purks et al. | Jun 2011 | A1 |
| 20110147715 | Rogers et al. | Jun 2011 | A1 |
| 20110170225 | Rogers et al. | Jul 2011 | A1 |
| 20110171813 | Rogers et al. | Jul 2011 | A1 |
| 20110175735 | Forster | Jul 2011 | A1 |
| 20110184320 | Shipps | Jul 2011 | A1 |
| 20110187798 | Rogers et al. | Aug 2011 | A1 |
| 20110220890 | Nuzzo et al. | Sep 2011 | A1 |
| 20110230747 | Rogers et al. | Sep 2011 | A1 |
| 20110266561 | Rogers et al. | Nov 2011 | A1 |
| 20110277813 | Rogers et al. | Nov 2011 | A1 |
| 20110316120 | Rogers et al. | Dec 2011 | A1 |
| 20120016258 | Webster et al. | Jan 2012 | A1 |
| 20120051005 | Vanfleteren et al. | Mar 2012 | A1 |
| 20120052268 | Axisa et al. | Mar 2012 | A1 |
| 20120065937 | de Graff | Mar 2012 | A1 |
| 20120074546 | Chong | Mar 2012 | A1 |
| 20120087216 | Keung et al. | Apr 2012 | A1 |
| 20120091594 | Landesberger | Apr 2012 | A1 |
| 20120092178 | Callsen | Apr 2012 | A1 |
| 20120092222 | Kato et al. | Apr 2012 | A1 |
| 20120105528 | Alleyne | May 2012 | A1 |
| 20120108012 | Yasuda | May 2012 | A1 |
| 20120157804 | Rogers et al. | Jun 2012 | A1 |
| 20120157986 | Stone et al. | Jun 2012 | A1 |
| 20120157987 | Steinke et al. | Jun 2012 | A1 |
| 20120157988 | Stone et al. | Jun 2012 | A1 |
| 20120157989 | Stone et al. | Jun 2012 | A1 |
| 20120158101 | Stone et al. | Jun 2012 | A1 |
| 20120165759 | Rogers et al. | Jun 2012 | A1 |
| 20120172697 | Urman | Jul 2012 | A1 |
| 20120256308 | Helin | Oct 2012 | A1 |
| 20120261551 | Rogers | Oct 2012 | A1 |
| 20120316455 | Rahman et al. | Dec 2012 | A1 |
| 20120327608 | Rogers | Dec 2012 | A1 |
| 20130041235 | Rogers et al. | Feb 2013 | A1 |
| 20130100618 | Rogers | Apr 2013 | A1 |
| 20130211761 | Brandsma et al. | Aug 2013 | A1 |
| 20130245388 | Rafferty et al. | Sep 2013 | A1 |
| 20130316442 | Meurville et al. | Nov 2013 | A1 |
| 20130320503 | Nuzzo | Dec 2013 | A1 |
| 20130321373 | Yoshizumi | Dec 2013 | A1 |
| 20140140020 | Rogers | May 2014 | A1 |
| 20140191236 | Nuzzo | Jul 2014 | A1 |
| 20140216524 | Rogers | Aug 2014 | A1 |
| 20140374872 | Rogers | Dec 2014 | A1 |
| 20150001462 | Rogers | Jan 2015 | A1 |
| Number | Date | Country |
|---|---|---|
| 0585670 | Mar 1994 | EP |
| 05-087511 | Apr 1993 | JP |
| 2009-170173 | Jul 2009 | JP |
| WO 9938211 | Jul 1999 | WO |
| WO 03021679 | Mar 2003 | WO |
| WO 2005122285 | Dec 2005 | WO |
| WO 2007003019 | Jan 2007 | WO |
| WO 2007116344 | Oct 2007 | WO |
| WO 2007136726 | Nov 2007 | WO |
| WO 2008030960 | Mar 2008 | WO |
| WO 2009111641 | Sep 2009 | WO |
| WO 2009114689 | Sep 2009 | WO |
| WO 2010036807 | Apr 2010 | WO |
| WO 2010046883 | Apr 2010 | WO |
| WO 2010132552 | Nov 2010 | WO |
| WO 2011003181 | Jan 2011 | WO |
| WO 2011084450 | Jul 2011 | WO |
| WO 2013034987 | Mar 2013 | WO |
| WO 2013170032 | Nov 2013 | WO |
| Entry |
|---|
| Demura et al., “Immobilization of Glucose Oxidase with Bombyx mori Silk Fibroin by Only Stretching Treatment and its Application to Glucose Sensor,” Biotechnology and Bioengineering, vol. 33, 598-603 (6 pages) (1989). |
| Halsted, “Ligature and Suture Material,” Journal of the American Medical Association, vol. LX, No. 15, 1119-1126, (8 pages) (Apr. 12, 1913). |
| Kim et al., “Complementary Metal Oxide Silicon Integrated Circuits Incorporating Monolithically Integrated Stretchable Wavy Interconnects,” Applied Physics Letters, vol. 93, 044102-044102.3 (3 pages) (Jul. 31, 2008). |
| Kim et al., “Dissolvable Films of Silk Fibroin for Ultrathin Conformal Bio-Integrated Electronics,” Nature, 1-8 (8 pages) (Apr. 18, 2010). |
| Kim et al., “Materials and Noncoplanar Mesh Designs for Integrated Circuits with Linear Elastic Responses to Extreme Mechanical Deformations,” PNAS, vol. 105, No. 48, 18675-18680 (6 pages) (Dec. 2, 2008). |
| Kim et al., “Stretchable and Foldable Silicon Integrated Circuits,” Science, vol. 320, 507-511 (5 pages) (Apr. 25, 2008). |
| Ko et al., “A Hemispherical Electronic Eye Camera Based on Compressible Silicon Optoelectronics,” Nature, vol. 454, 748-753 (6 pages) (Aug. 7, 2008). |
| Lawrence et al., “Bioactive Silk Protein Biomaterial Systems for Optical Devices,” Biomacromolecules, vol. 9, 1214-1220 (7 pages) (Nov. 4, 2008). |
| Meitl et al., “Transfer Printing by Kinetic Control of Adhesion to an Elastomeric Stamp,” Nature, vol. 5, 33-38 (6 pages) (Jan. 2006). |
| Omenetto et al., “A New Route for Silk,” Nature Photonics, vol. 2, 641-643 (3 pages) (Nov. 2008). |
| Omenetto et al., “New Opportunities for an Ancient Material,” Science, vol. 329, 528-531 (5 pages) (Jul. 30, 2010). |
| Tsukada et al., “Structural Changes of Silk Fibroin Membranes Induced by Immersion in Methanol Aqueous Solutions,” Journal of Polymer Science, vol. 32, 961-968 (8 pages) (1994). |
| Wang et al., “Controlled Release From Multilayer Silk Biomaterial Coatings to Modulate Vascular Cell Responses” Biomaterials, 29, 894-903 (10 pages) (Nov. 28, 2008). |
| Canadian Office Action corresponding to co-pending Canadian Patent Application Serial No. CA 2,780,747, Canadian Patent Office, dated Jan. 11, 2016; (7 pages). |
| European Search Report corresponding to co-pending European Patent Application Serial No. EP 15157473.8, European Patent Office, dated Sep. 15, 2015; (7 pages). |
| European Search Report corresponding to co-pending European Patent Application Serial No. EP 15157469.6, European Patent Office, dated Sep. 15, 2015; (6 pages). |
| Number | Date | Country | |
|---|---|---|---|
| 20150069617 A1 | Mar 2015 | US |
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|---|---|---|---|
| 61113622 | Nov 2008 | US | |
| 61103361 | Oct 2008 | US | |
| 61113007 | Nov 2008 | US |
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