Patent Application
20210115560
The present disclosure relates to a film forming method, a film forming system, and a film forming apparatus.
Patent Document 1 proposes a technique for forming a tungsten film as a metal layer on a substrate by a chemical vapor deposition (CVD) method. In Patent Document 1, a method of forming a TiN film as a barrier layer on a silicon layer and forming the tungsten film on the TiN film is used from the viewpoint of adhesion of the substrate to the silicon laver and suppression of reaction between them. Further, in Patent Document 1, prior to main film formation of the tungsten film, a nucleation step is performed so as to make it easy to form the tungsten film uniformly.
Japanese laid-open publication No. 2013-213274
The present disclosure provides some embodiments of a technique capable of reducing the resistance of a metal layer even when it is thinned.
According to one embodiment of the present disclosure, there is provided a film forming method including a step of disposing a substrate on which an insulating film is formed in a processing container and forming a base film by repeatedly supplying a Ti-containing gas, an Al-containing gas, and a reaction gas into the processing container under a decompressed atmosphere, and a step of forming a metal layer made of a metal material on the substrate on which the base film is formed.
According to the present disclosure, it is possible to reduce the resistance of a metal layer even when it is thinned.
Hereinafter, embodiments of a film forming method, a film forming system, and a film forming apparatus disclosed in the present disclosure will be described in detail with reference to the drawings. It should be noted that the present embodiments does not limit the disclosed film forming method, film forming system and film forming apparatus.
By the way, when manufacturing LSIs, metal layers are being widely used for MOSFET gate electrodes, contacts with sources and drains, word lines of memories, and the like.
Therefore, when a tungsten film is formed as a metal layer on a substrate by the technique of Patent Document 1, an initial tungsten film produced by a nucleation step (hereinafter also referred to as a “nucleation film”) has high resistance. Therefore, when the entire tungsten film is thinned, the tungsten film has high resistance due to the influence of the nucleation film portion.
Wiring is miniaturized in LSI, and low resistance of the wiring is required. Therefore, it is expected that the resistance of the metal layer can be reduced even when the film is thinned. For example, in a three-dimensional laminated semiconductor memory such as a 3D NAND flash memory, a tungsten film is formed as a word line, but further reduction in resistance of the tungsten film is required for miniaturization.
In a first embodiment, a case where film formation is performed by a film forming system using a plurality of film forming apparatuses will be described as an example. First, the film forming system according to this embodiment will be described.
As illustrated in
A transfer mechanism is connected to the film forming apparatuses 101 to 104, and a target substrate on which a film is to be filmed is transferred by the transfer mechanism. For example, as illustrated in
Three load lock chambers 302 are connected to the other three wall portions of the vacuum transfer chamber 301 via gate valves G1, respectively. An atmospheric transfer chamber 303 is provided on the opposite side of the vacuum transfer chamber 301 with the load lock chambers 302 interposed therebetween. The three load lock chambers 302 are connected to the atmospheric transfer chamber 303 via gate valves G2, respectively. Each of the load lock chambers 302 controls a pressure between the atmospheric pressure and the vacuum when the wafer W is transferred between the atmospheric transfer chamber 303 and the vacuum transfer chamber 301.
Three carrier mounting ports 305 for mounting carriers (FOUPs, etc.) C for accommodating wafers W are provided on the wall portion of the air transfer chamber 303 opposite to the wall portion on which the load lock chambers 302 are mounted. Further, an alignment chamber 304 for aligning the wafers W is provided on a sidewall of the atmospheric transfer chamber 303. A down-flow of clean air is formed in the atmospheric transfer chamber 303.
A transfer mechanism 306 is provided in the vacuum transfer chamber 301. The transfer mechanism 306 transfers the wafer W to/from the film forming apparatuses 101 to 104 and the load lock chambers 302. The transfer mechanism 306 has two transfer arms 307a and 307b that can move independently.
A transfer mechanism 308 is provided in the atmospheric transfer chamber 303. The transfer mechanism 308 is configured to transfer the wafer W to/from the carriers C, the load lock chambers 302, and the alignment chamber 304.
The film forming system 100 has an overall controller 310. The overall controller 310 is configured as a computer, for example, and includes a main controller such as a CPU, an input device (keyboard, mouse, etc.), an output device (printer, etc.), a display device (display, etc.), and a storage device (storage medium). The main controller controls each component of the film forming apparatuses 101 to 104, an exhaust mechanism, a gas supply mechanism, and the transfer mechanism 306 of the vacuum transfer chamber 301, exhaust mechanisms and gas supply mechanisms of the load lock chambers 302, the transfer mechanism 308 of the atmospheric transfer chamber 303, a drive system of the gate valves G, G1, and G2, and the like. The main controller of the overall controller 310 causes the film forming system 100 to perform a predetermined operation on based on, for example, a processing recipe stored in a storage medium built in the storage device or a storage medium set in the storage device. The overall controller 310 may be a higher-level controller of the controller of each unit such as a controller 6 of the film forming apparatus 101 to be described later.
Next, the operation of the film forming system 100 configured as above will be described. The following processing operation of the film forming system 100 is performed based on the processing recipe stored in the storage medium in the overall controller 310.
First, a wafer W is taken out from a carrier C connected to the atmospheric transfer chamber 303 by the transfer mechanism 308. Further, the wafer W taken out is passed through the alignment chamber 304 and is then loaded into any load lock chamber 302 by opening the gate valve G2 of the load lock chamber 302. Further, after closing the gate valve G2, the interior of the load lock chamber 302 is vacuum-exhausted.
When the load lock chamber 302 reaches a predetermined degree of vacuum, the gate valve G1 is opened, and the wafer W is taken out from the load lock chamber 302 by any of the transfer arms 307a and 307b of the transfer mechanism 306.
Further, the gate valve G of the film forming apparatus 101 is opened, and the wafer W held by any of the transfer arms 307a and 307b of the transfer mechanism 306 is loaded into the film forming apparatus 101. Further, the empty transfer arm is returned to the vacuum transfer chamber 301, the gate valve G is closed, and the film forming apparatus 101 performs a film forming process of a base film.
After the film forming process of the base film is completed, the gate valve G of the film forming apparatus 101 is opened, and the wafer W is loaded out by any of the transfer arms 307a and 307b of the transfer mechanism 306. Further, the film forming apparatus 102 performs a process of forming an initial tungsten film on the wafer W.
After the initial tungsten film forming process is completed, the gate valve G of the film forming apparatus 102 is opened, and the wafer W is loaded out by any of the transfer arms 307a and 307b of the transfer mechanism 306. Further, either of the film forming apparatus 103 or 104 performs a process of forming a main tungsten film on the wafer W. In the following, a case where the film forming apparatus 103 forms the main tungsten film on the wafer W will be described as an example.
For example, the gate valve G of the film forming apparatus 103 is opened, the wafer W held by any of the transfer arms 307a and 307b is loaded into the film forming apparatus 103, the empty transfer arm is returned to the vacuum transfer chamber 301, and then the gate valve G is closed. Further, the film forming apparatus 103 performs the process of forming the main tungsten film on the initial tungsten film formed on the wafer W. After the main tungsten film is formed in this way, the gate valve G of the film forming apparatus 103 is opened, and the wafer W is loaded out by any of the transfer arms 307a and 307b of the transfer mechanism 306. Further, the gate valve G1 of any of the load lock chambers 302 is opened, and the wafer W on the transfer arm is loaded into the load lock chamber 302. Further, the interior of the load lock chamber 302 into which the wafer W is loaded is returned to the atmosphere, the gate valve G2 is opened, and the wafer W in the load lock chamber 302 is returned to the carrier C by the transfer mechanism 308.
The process described as above is performed on a plurality of wafers W simultaneously in parallel to complete a process of forming a tungsten film on a predetermined number of wafers W.
Thus, the film forming system 100 can realize the film formation of the base film and the film formation of the tungsten film with high throughput. The film forming system 100 of this embodiment is shown as a vacuum processing system equipped with four film forming apparatuses, but the number of film forming apparatuses is not limited thereto. The number of film forming apparatuses may be 2, 3, or 4 or more as long as the vacuum processing system can be equipped with a plurality of film forming apparatuses. For example, it may be a vacuum processing system equipped with eight or more film forming apparatuses. Further, the film forming system 100 of this embodiment has been described by taking the case where the vacuum transfer chamber 301 has a heptagonal shape, as an example, but the present disclosure is not limited thereto. The vacuum transfer chamber 301 may have other polygonal shapes such as a pentagon, a hexagon or the like as long as a plurality of film forming apparatuses can be connected to the vacuum transfer chamber 301. Further, the film forming system 100 may be a system in which a plurality of polygonal vacuum transfer chambers is connected.
The film forming apparatus 101 and the film forming apparatuses 102 to 104 according to the first embodiment have substantially the same configurations except for the configuration of the gas supply mechanism for supplying a gas. In the following, the configuration of the film forming apparatus 101 will be mainly described, and different parts of the configurations of the film forming apparatus 102 to 104 will be mainly described.
The configuration of the film forming apparatus 101 according to the first embodiment will be described.
The processing container 1 is made of metal such as aluminum and has substantially a cylindrical shape. The processing container 1 accommodates a wafer W, which is a target substrate. A loading/unloading port 11 for loading or unloading the wafer W is formed on a sidewall of the processing container 1, and the loading/unloading port 11 is opened and closed by a gate valve 12. An annular exhaust duct 13 having a rectangular cross section is provided on a main body of the processing container 1. A slit 13a is formed along the inner peripheral surface of the exhaust duct 13. An exhaust port 13b is formed on an outer wall of the exhaust duct 13. A ceiling wall 14 is provided on the upper surface of the exhaust duct 13 so as to close the upper opening of the processing container 1. A space between the exhaust duct 13 and the ceiling wall 14 are hermetically sealed with a seal ring 15.
The stage 2 horizontally supports the wafer W in the processing container 1, the stage 2 is formed in a disc shape having a size corresponding to the wafer W and is supported by a support member 23. The stage 2 is made of a ceramic material such as aluminum nitride (AlN) or a metal material such as aluminum or a nickel alloy, and a heater 21 for heating the wafer W is embedded in the stage 2. The heater 21 generates heat by being supplied with power from a heater power source (not shown). Further, the wafer W is controlled to a predetermined temperature by controlling the output of the heater 21 by a temperature signal of a thermocouple (not shown) provided in the vicinity of the upper surface of the stage 2. The stage 2 is provided with a cover member 22 formed of ceramics such as alumina so as to cover the outer peripheral region and the side surface of the upper surface of the stage 2.
The support member 23 for supporting the stage 2 is provided on the bottom surface of the stage 2. The support member 23 extends from the center of the bottom surface of the stage 2 to the lower side of the processing container 1 through a hole portion formed in a bottom wall of the processing container 1, and the lower end of the support member 23 is connected to the elevating mechanism 24. The stage 2 is moved up and down, via the support member 23, by the elevating mechanism 24 between a processing position shown in
Three wafer support pins 27 (only two are shown) are provided in the vicinity of the bottom surface of the processing container 1 so as to protrude upward from an elevating plate 27a. The wafer support pins 27 are moved up and down via the elevating plate 27a by an elevating mechanism 28 provided below the processing container 1. The wafer support pins 27 are inserted into through-holes 2a formed in the stage 2 at the transfer position so as to be protrudable from the upper surface of the stage 2. By moving up and down the wafer support pins 27, the wafer W is delivered between the transfer mechanism (not shown) and the stage 2.
The shower head 3 supplies a processing gas into the processing container 1 in the form of a shower. The shower head 3 is made of metal and has substantially the same diameter as the stage 2. The shower head 3 is disposed so as to face the stage 2. The shower head 3 has a main body 31 fixed to the ceiling wall 14 of the processing container 1, and a shower plate 32 connected under the main body 31. A gas diffusion space 33 is formed between the main body 31 and the shower plate 32, and gas introduction holes 36 and 37 are formed in the gas diffusion space 33 so as to penetrate the ceiling wall 14 of the processing container 1 and the center of the main body 31. An annular protrusion 34 protruding downward is formed on the peripheral edge of the shower plate 32. Gas discharge holes 35 are formed on the flat surface inside the annular protrusion 34. When the stage 2 is present at the processing position, a processing space 38 is formed between the stage 2 and the shower plate 32, and the upper surface of the cover member 22 and the annular protrusion 34 are close to each other to form an annular gap 39.
The exhaust part 4 exhausts the interior of the processing container 1. The exhaust part 4 has an exhaust pipe 41 connected to the exhaust port 13b, and an exhaust mechanism 42 having a vacuum pump, a pressure control valve, and the like connected to the exhaust pipe 41. At the time of processing, a gas in the processing container 1 reaches the exhaust duct 13 through the slit 13a and is discharged by the exhaust mechanism 42 from the exhaust duct 13 through the exhaust pipe 41.
The gas supply mechanism 5 is connected to the gas introduction holes 36 and 37 and is capable of supplying various gases used for film formation. For example, the gas supply mechanism 5 has an Al-containing gas supply source 51a, a N2 gas supply source 52a, a N2 gas supply source 53a, a N2 gas supply source 54a, an NH3 gas supply source 55a, a Ti-containing gas supply source 56a, and a N2 gas supply source 57a, as gas supply sources for forming a base film. In the gas supply mechanism 5 shown in
The Al-containing gas supply source 51a supplies an Al-containing gas into the processing container 1 via a gas supply line 51b. Examples of the Al-containing gas may include an AlCl3 gas and a TMA (trimethylaluminum: C6H18Al2) gas. For example, the Al-containing gas supply source 51a supplies the TMA gas as the Al-containing gas. A flow rate controller 51c, a storage tank 51d, and a valve 51e are interposed in the gas supply line 51b from the upstream side. The downstream side of the valve 51e of the gas supply line 51b is connected to the gas introduction hole 36. The Al-containing gas supplied from the Al-containing gas supply source 51a is temporarily stored in the storage tank 51d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 51d. The supply and stop of the Al-containing gas from the storage tank 51d to the processing container 1 is performed by the valve 51e. By temporarily storing the Al-containing gas in the storage tank 51d in this way, the Al-containing gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 52a supplies a N2 gas, which is a purge gas, into the processing container 1 via a gas supply line 52b. A flow rate controller 52c, a storage tank 52d, and a valve 52e are interposed in the gas supply line 52b from the upstream side. The downstream side of the valve 52e of the gas supply line 52b is connected to the gas supply line 51b. The N2 gas supplied from the N2 gas supply source 52a is temporarily stored in the storage tank 52d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 52d. The supply and stop of the N2 gas from the storage tank 52d to the processing container 1 is performed by the valve 52e. By temporarily storing the N2 gas in the storage tank 52d in this way, the N2 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 53a supplies a N2 gas, which is a carrier gas, into the processing container 1 via a gas supply line 53b. A flow rate controller 53c, a valve 53e, and an orifice 53f are interposed in the gas supply line 53b from the upstream side. The downstream side of the orifice 53f of the gas supply line 53b is connected to the gas supply line 51b. The N2 gas supplied from the N2 gas supply source 53a is continuously supplied into the processing container 1 during the film formation of the wafer W. The supply and stop of the N2 gas from the N2 gas supply source 53a to the processing container 1 is performed by the valve 53e. The gases are supplied to the gas supply lines 51b and 52b at a relatively large flow rate by the storage tanks 51d and 52d, respectively, but the gas supplied to the gas supply line 51b is suppressed by the orifice 53f from flowing back to the gas supply line 53b.
The N2 gas supply source 54a supplies a N2 gas, which is a purge gas, into the processing container 1 via a gas supply line 54b. A flow rate controller 54c, a storage tank 54d, and a valve 54e are interposed in the gas supply line 54b from the upstream side. The downstream side of the valve 54e of the gas supply line 54b is connected to a gas supply line 55b. The N2 gas supplied from the N2 gas supply source 54a is temporarily stored in the storage tank 54d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 54d. The supply and stop of the N2 gas from the storage tank 54d to the processing container 1 is performed by the valve 54e. By temporarily storing the N2 gas in the storage tank 54d in this way, the N2 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The NH3 gas supply source 55a supplies a reaction gas into the processing container 1 via the gas supply line 55b. Examples of the reaction gas may include a N-containing gas, a rare gas, and an inert gas. Examples of the N-containing gas that can be used as the reaction gas may include an ammonia gas (an NH3 gas) and a hydrazine (N2H4) gas. For example, the NH3 gas supply source 55a supplies the NH3 gas into the processing container 1 as the reaction gas. A flow rate controller 55c, a storage tank 55d, and a valve 55e are interposed in the gas supply line 55b from the upstream side. The downstream side of the valve 55e of the gas supply line 55b is connected to the gas introduction hole 37. The NH3 gas supplied from the NH3 gas supply source 55a is temporarily stored in the storage tank 55d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 55d. The supply and stop of the NH3 gas from the storage tank 55d to the processing container 1 is performed by the valve 55e. By temporarily storing the NH3 gas in the storage tank 55d in this way, the NH3 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The Ti-containing gas supply source 56a supplies a Ti-containing gas into the processing container 1 via a gas supply line 56b. Examples of the Ti-containing gas may include a TiCl4 gas, a TDMAT (tetrakis(dimethylamino)titanium: Ti[N(CH3)2]4) gas, and a TMEAT (tetrakis(methylethylamino)titanium: C12H32N4Ti) gas. For example, the Ti-containing gas supply source 56a supplies the TiCl4 gas as the Ti-containing gas. A flow rate controller 56c, a storage tank 56d, and a valve 56e are interposed in the gas supply line 56b from the upstream side. The downstream side of the valve 56e of the gas supply line 56b is connected to the gas supply line 55b. The Ti-containing gas supplied from the Ti-containing gas supply source 56a is temporarily stored in the storage tank 56d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 56d. The supply and stop of the Ti-containing gas from the storage tank 56d to the processing container 1 is performed by the valve 56e. By temporarily storing the Ti-containing gas in the storage tank 56d in this way, the Ti-containing gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 57a supplies a N2 gas, which is a carrier gas, into the processing container 1 via a gas supply line 57b. A flow rate controller 57c, a valve 57e, and an orifice 57f are interposed in the gas supply line 57b from the upstream side. The downstream side of the orifice 57f of the gas supply line 57b is connected to the gas supply line 55b. The N2 gas supplied from the N2 gas supply source 57a is continuously supplied into the processing container 1 during the film formation of the wafer W. The supply and stop of the N2 gas from the N2 gas supply source 57a to the processing container 1 is performed by the valve 57e. The gases are supplied to the gas supply lines 55b and 56b at a relatively large flow rate by the storage tanks 55d and 56d, respectively, but the gas supplied to the gas supply line 55b is suppressed by the orifice 57f from flowing back to the gas supply line 57b.
The operation of the film forming apparatus 101 configured as above is collectively controlled by the controller 6. The controller 6 is, for example, a computer and includes a CPU (Central Processing Unit), a RAM (Random Access Memory), a ROM (Read Only Memory), an auxiliary storage device, and the like. The CPU operates based on a program stored in the ROM or the auxiliary storage device and controls the overall operation of the apparatus. The controller 6 may be provided inside the film forming apparatus 101, or may be provided externally. When the controller 6 is provided externally, the controller 6 can control the film forming apparatus 101 by a wired or wireless communication means.
Next, the configuration of the film forming apparatus 102 according to the first embodiment will be described.
The film forming apparatus 102 has the same configuration as the film forming apparatus 101 illustrated in
The gas supply mechanism 5 is connected to the gas introduction holes 36 and 37 and is capable of supplying various gases used for film formation. For example, the gas supply mechanism 5 has a WF6 gas supply source 61a, a N2 gas supply source 62a, a N2 gas supply source 63a, a B2H6 gas supply source 65a, a N2 gas supply source 66a, and a N2 gas supply source 67a, as gas supply sources for forming an initial tungsten film. In the gas supply mechanism 5 shown in
The WF6 gas supply source 61a supplies a WF6 gas into the processing container 1 via a gas supply line 61b. A flow rate controller 61c, a storage tank 61d, and a valve 61e are interposed in the gas supply line 61b from the upstream side. The downstream side of the valve 61e of the gas supply line 61b is connected to the gas introduction hole 36. The WF6 gas supplied from the WF6 gas supply source 61a is temporarily stored in the storage tank 61d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 61d. The supply and stop of the WF6 gas from the storage tank 61d to the processing container 1 is performed by the valve 61e. By temporarily storing the WF6 gas in the storage tank 61d in this way, the WF6 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 62a supplies a N2 gas, which is a purge gas, into the processing container 1 via a gas supply line 62b. A flow rate controller 62c, a storage tank 62d, and a valve 62e are interposed in the gas supply line 62b from the upstream side. The downstream side of the valve 62e of the gas supply line 62b is connected to the gas supply line 61b. The N2 gas supplied from the N2 gas supply source 62a is temporarily stored in the storage tank 62d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 62d. The supply and stop of the N2 gas from the storage tank 62d to the processing container 1 is performed by the valve 62e. By temporarily storing the N2 gas in the storage tank 62d in this way, the N2 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 63a supplies a N2 gas, which is a carrier gas, into the processing container 1 via a gas supply line 63b. A flow rate controller 63c, a valve 63e, and an orifice 63f are interposed in the gas supply line 63b from the upstream side. The downstream side of the orifice 63f of the gas supply line 63b is connected to the gas supply line 61b. The N2 gas supplied from the N2 gas supply source 63a is continuously supplied into the processing container 1 during the film formation of the wafer W. The supply and stop of the N2 gas from the N2 gas supply source 63a to the processing container 1 is performed by the valve 63e. The gases are supplied to the gas supply lines 61b and 62b at a relatively large flow rate by the storage tanks 61d and 62d, respectively, but the gas supplied to the gas supply lines 61b and 62b is suppressed by the orifice 63f from flowing back to the gas supply line 63b.
The B2H6 gas supply source 65a supplies a B2H6 gas, which is a reducing gas, into the processing container 1 via a gas supply line 65b. A flow rate controller 65c, a storage tank 65d, and a valve 65e are interposed in the gas supply line 65b from the upstream side. The downstream side of the valve 65e of the gas supply line 65b is connected to a gas supply line 64b. The downstream side of the gas supply line 64b is connected to the gas introduction hole 37. The B2H6 gas supplied from the B2H6 gas supply source 65a is temporarily stored in the storage tank 65d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 65d. The supply and stop of the B2H6 gas from the storage tank 65d to the processing container 1 is performed by the valve 65e. By temporarily storing the B2H6 gas in the storage tank 65d in this way, the B2H6 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 66a supplies a N2 gas, which is a purge gas, into the processing container 1 via a gas supply line 66b. A flow rate controller 66c, a storage tank 66d, and a valve 66e are interposed in the gas supply line 66b from the upstream side. The downstream side of the valve 66e of the gas supply line 66b is connected to the gas supply line 64b. The N2 gas supplied from the N2 gas supply source 66a is temporarily stored in the storage tank 66d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 66d. The supply and stop of the N2 gas from the storage tank 66d to the processing container 1 is performed by the valve 66e. By temporarily storing the N2 gas in the storage tank 66d in this way, the N2 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 67a supplies a N2 gas, which is a carrier gas, into the processing container 1 via a gas supply line 67b. A flow rate controller 67c, a valve 67e, and an orifice 67f are interposed in the gas supply line 67b from the upstream side. The downstream side of the orifice 67f of the gas supply line 67b is connected to the gas supply line 64b. The N2 gas supplied from the N2 gas supply source 67a is continuously supplied into the processing container 1 during the film formation of the wafer W. The supply and stop of the N2 gas from the N2 gas supply source 67a to the processing container 1 is performed by the valve 67e. The gases are supplied to the gas supply lines 65b and 66b at a relatively large flow rate by the storage tanks 65d and 66d, respectively, but the gas supplied to the gas supply lines 65b and 66b is suppressed by the orifice 67f from flowing back to the gas supply line 67b.
Next, the configurations of the film forming apparatuses 103 and 104 according to the first embodiment will be described. Since the film forming apparatuses 103 and 104 according to the first embodiment have substantially the same configuration, the configuration of the film forming apparatus 103 will be described as a representative.
The gas supply mechanism 5 is connected to the gas introduction holes 36 and 37 and is capable of supplying various gases used for film formation. For example, the gas supply mechanism 5 uses a WF6 gas supply source 61a, a N2 gas supply source 62a, a N2 gas supply source 63a, a H2 gas supply source 64a, and a N2 gas supply source 66a, a N2 gas supply source 67a, and a H2 gas supply source 68a, as gas supply sources for forming a tungsten film. In the gas supply mechanism 5 shown in
The WF6 gas supply source 61a supplies a WF6 gas into the processing container 1 via the gas supply line 61b. A flow rate controller 61c, a storage tank 61d, and a valve 61e are interposed in the gas supply line 61b from the upstream side. The downstream side of the valve 61e of the gas supply line 61b is connected to the gas introduction hole 36. The WF6 gas supplied from the WF6 gas supply source 61a is temporarily stored in the storage tank 61d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 61d. The supply and stop of the WF6 gas from the storage tank 61d to the processing container 1 is performed by the valve 61e. By temporarily storing the WF6 gas in the storage tank 61d in this way, the WF6 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 62a supplies a N2 gas, which is a purge gas, into the processing container 1 via the gas supply line 62b. A flow rate controller 62c, a storage tank 62d, and a valve 62e are interposed in the gas supply line 62b from the upstream side. The downstream side of the valve 62e of the gas supply line 62b is connected to the gas supply line 61b. The N2 gas supplied from the N2 gas supply source 62a is temporarily stored in the storage tank 62d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 62d. The supply and stop of the N2 gas from the storage tank 62d to the processing container 1 is performed by the valve 62e. By temporarily storing the N2 gas in the storage tank 62d in this way, the N2 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 63a supplies a N2 gas, which is a carrier gas, into the processing container 1 via the gas supply line 63b. A flow rate controller 63c, a valve 63e, and an orifice 63f are interposed in the gas supply line 63b from the upstream side. The downstream side of the orifice 63f of the gas supply line 63b is connected to the gas supply line 61b. The N2 gas supplied from the N2 gas supply source 63a is continuously supplied into the processing container 1 during the film formation of the wafer W. The supply and stop of the N2 gas from the N2 gas supply source 63a to the processing container 1 is performed by the valve 63e. The gases are supplied to the gas supply lines 61b and 62b at a relatively large flow rate by the storage tanks 61d and 62d, respectively, but the gas supplied to the gas supply lines 61b and 62b is suppressed by the orifice 63f from flowing back to the gas supply line 63b.
The H2 gas supply source 64a supplies a H2 gas, which is a reducing gas, into the processing container 1 via the gas supply line 64b. A flow rate controller 64c, a valve 64e, and an orifice 64f are interposed in the gas supply line 64b from the upstream side. The downstream side of the orifice 64f of the gas supply line 64b is connected to the gas introduction hole 37. The H2 gas supplied from the H2 gas supply source 64a is continuously supplied into the processing container 1 during the film formation of the wafer W. The supply and stop of the H2 gas from the H2 gas supply source 64a to the processing container 1 is performed by the valve 64e. The gases are supplied to the gas supply lines 66b and 68b at a relatively large flow rate by the storage tanks 66d and 68d to be described later, respectively, but the gas supplied to the gas supply lines 66b and 68b is suppressed by the orifice 64f from flowing back to the gas supply line 64b.
The H2 gas supply source 68a supplies a H2 gas, which is a reducing gas, into the processing container 1 via the gas supply line 68b. A flow rate controller 68c, a storage tank 68d, and a valve 68e are interposed in the gas supply line 68b from the upstream side. The downstream side of the valve 68e of the gas supply line 68b is connected to the gas supply line 64b. The H2 gas supplied from the H2 gas supply source 68a is temporarily stored in the storage tank 68d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 68d. The supply and stop of the H2 gas from the storage tank 68d to the processing container 1 is performed by the valve 68e. By temporarily storing the H2 gas in the storage tank 68d in this way, the H2 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 66a supplies a N2 gas, which is a purge gas, into the processing container 1 via the gas supply line 66b. A flow rate controller 66c, a storage tank 66d, and a valve 66e are interposed in the gas supply line 66b from the upstream side. The downstream side of the valve 66e of the gas supply line 66b is connected to the gas supply line 64b. The N2 gas supplied from the N2 gas supply source 66a is temporarily stored in the storage tank 66d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 66d. The supply and stop of the N2 gas from the storage tank 66d to the processing container 1 is performed by the valve 66e. By temporarily storing the N2 gas in the storage tank 66d in this way, the N2 gas can be stably supplied into the processing container 1 at a relatively large flow rate.
The N2 gas supply source 67a supplies a N2 gas, which is a carrier gas, into the processing container 1 via the gas supply line 67b. A flow rate controller 67c, a valve 67e, and an orifice 67f are interposed in the gas supply line 67b from the upstream side. The downstream side of the orifice 67f of the gas supply line 67b is connected to the gas supply line 64b. The N2 gas supplied from the N2 gas supply source 67a is continuously supplied into the processing container 1 during the film formation of the wafer W. The supply and stop of the N2 gas from the N2 gas supply source 67a to the processing container 1 is performed by the valve 67e. The gases are supplied to the gas supply lines 66b and 68b at a relatively large flow rate by the storage tanks 66d and 68d, respectively, but the gas supplied to the gas supply lines 66b and 68b is suppressed by the orifice 67f from flowing back to the gas supply line 67b.
Next, a method for forming a tungsten film, which is performed using the film forming system 100 configured as above, will be described.
In the film forming method according to the present embodiment, first, a wafer W (
The film forming apparatus 101 forms a base film on the wafer W by an ALD (Atomic Layer Deposition) method (step S1 in
The film forming apparatus 102 alternately supplies a WF6 gas and a B2H6 gas into the processing container 1 with a supply of a N2 gas, which is a purge gas, interposed between the supplies of WF6 gas and the B2H6 gas to form a nucleation film as an initial tungsten film for generating tungsten nuclei on the surface of the wafer W (step S2 in
The film forming apparatus 103 forms a tungsten film on the wafer W (step S3 in
As described above, the film forming system 100 performs each step of the film forming method shown in steps S1 to S3 to form the base film and the metal layer (the nucleation film, the tungsten film) on the wafer W on which the insulating film is formed, in order. Hereinafter, the details of the film forming method of each step of steps S1 to S3 will be described.
Next, a flow in which the film forming apparatus 101 forms a base film will be described. The film forming apparatus 101 repeatedly supplies a Ti-containing gas, an Al-containing gas, and a reaction gas into the processing container 1 to form the base film. For example, the film forming apparatus 101 forms the base film by repeating, at least once, a step of forming a first base film by repeating, at least once, the alternating supply of Ti-containing gas and reaction gas with a purge step interposed therebetween and a step of forming a second base film by repeating, at least once, the alternating supply of Al-containing gas and reaction gas with a purge step interposed therebetween. In the present embodiment, an AlTiN film obtained by laminating a TiN film as the first base film and an AlN film as the second base film is formed as the base film.
The controller 6 opens the valves 53e and 57e to supply a predetermined flow rate of carrier gas (N2 gas) from the N2 gas supply sources 53a and 57a to the gas supply lines 53b and 57b, respectively. Further, the controller 6 supplies a N2 gas, an NH3 gas, and a Ti-containing gas from the N2 gas supply sources 52a and 54a, the NH3 gas supply source 55a, and the Ti-containing gas supply source 56a to the gas supply lines 52b, 54b, 55b, and 56b, respectively. At this time, since the valves 52e, 54e, 55e, and 56e are closed, the N2 gas, the NH3 gas, and the Ti-containing gas are stored in the storage tanks 52d, 54d, 55d, and 56d, respectively, and the internal pressures of the storage tanks 51d, 55d, and 56d are increased.
The controller 6 opens the valve 56e to supply the Ti-containing gas stored in the storage tank 56d into the processing container 1 and adsorb a film by the Ti-containing gas on the surface of the wafer W (step S11). For example, when a TiCl4 gas is used as the Ti-containing gas, TiN is adsorbed on the surface of the wafer W by reaction of TiCl4+NH3→TiN+HCl↑. Further, for example, when a TDMAT gas is used as the Ti-containing gas, TiN is adsorbed on the surface of the wafer W by reaction of (Ti[N(CH3)2]4)+NH3→TiN+CxHy↑. Further, for example, when a TMEAT gas is used as the Ti-containing gas, TiN is adsorbed on the surface of the wafer W by reaction of C12H32N4Ti+NH3→TiN+CxHy↑.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 56e, the controller 6 closes the valve 56e to stop the supply of the Ti-containing gas into the processing container 1. Further, the controller 6 opens the valves 52e and 54e to supply the N2 gas stored in the storage tanks 52d and 54d into the processing container 1, as a purge gas (step S12). At this time, since the N2 gas is supplied from the storage tanks 52d and 54d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the Ti-containing gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas atmosphere from the Ti-containing gas atmosphere in a short time. Further, since the valve 56e is closed, the Ti-containing gas supplied from the Ti-containing gas supply source 56a to the gas supply line 56b is stored in the storage tank 56d, and the internal pressure of the storage tank 56d is increased. Further, since the valve 56e is closed, the carrier gas (N2) supplied from the gas supply line 53b and the gas supply line 57b also functions as a purge gas to be able to discharge the excess Ti-containing gas.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valves 52e and 54e, the controller 6 closes the valves 52e and 54e to stop the supply of the purge gas into the processing container 1. Further, the controller 6 opens the valve 55e to supply the NH3 gas stored in the storage tank 55d into the processing container 1 to reduce the Ti-containing gas adsorbed on the surface of the wafer W (step S13).
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 55e, the controller 6 closes the valve 55e to stop the supply of the NH3 gas into the processing container 1. Further, the controller 6 opens the valves 52e and 54e to supply the N2 gas stored in the storage tanks 52d and 54d into the processing container 1, as a purge gas (step S14). At this time, since the N2 gas is supplied from the storage tanks 52d and 54d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the NH3 gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas atmosphere from the NH3 gas atmosphere in a short time. Further, since the valve 55e is closed, the NH3 gas supplied from the NH3 gas supply source 55a to the gas supply line 55b is stored in the storage tank 55d, and the internal pressure of the storage tank 55d is increased. Further, since the valve 55e is closed, the carrier gas (N2) supplied from the gas supply line 53b and the gas supply line 57b also functions as a purge gas to be able to discharge the excess NH3 gas.
An A cycle of steps S11 to S14 corresponds to the step of forming the first base film.
The controller 6 opens the valves 53e and 57e to supply a predetermined flow rate of carrier gas (N2 gas) from the N2 gas supply sources 53a and 57a to the gas supply lines 53b and 57b, respectively. Further, the controller 6 stops the supply of the Ti-containing gas from the Ti-containing gas supply source 56a. Further, the controller 6 supplies an Al-containing gas, a N2 gas, and an NH3 gas from the Al-containing gas supply source 51a, the N2 gas supply sources 52a and 54a, and the NH3 gas supply source 55a to the gas supply lines 51b, 52b, 54b, and 55b, respectively. At this time, since the valves 51e, 52e, 54e, and 55e are closed, the Al-containing gas, the N2 gas, and the NH3 gas are stored in the storage tanks 51d, 52d, 54d, and 55d, respectively, and the internal pressures of the storage tanks 51d, 55d, 54d, and 56d are increased.
The controller 6 opens the valve 51e to supply the Al-containing gas stored in the storage tank 51d into the processing container 1 and adsorb a film by the Al-containing gas on the surface of the wafer W (step S15). For example, when an AlCl3 gas is used as the Al-containing gas, AlN is adsorbed on the surface of the wafer W by reaction of AlCl3+NH3→AlN+HCl↑. Further, for example, when a TMA gas is used as the Al-containing gas, AlN is adsorbed on the surface of the wafer W by reaction of C6H18Al2+NH→AlN+CxHy↑.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 51e, the controller 6 closes the valve 51e to stop the supply of the Al-containing gas into the processing container 1. Further, the controller 6 opens the valves 52e and 54e to supply the N2 gas stored in the storage tanks 52d and 54d into the processing container 1, as a purge gas (step S16). At this time, since the N2 gas is supplied from the storage tanks 52d and 54d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the Al-containing gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas atmosphere from the Al-containing gas atmosphere in a short time. Further, since the valve 51e is closed, the Al-containing gas supplied from the Al-containing gas supply source 51a to the gas supply line 51b is stored in the storage tank 51d, and the internal pressure of the storage tank 51d is increased. Further, since the valve 51e is closed, the carrier gas (N2) supplied from the gas supply line 53b and the gas supply line 57b also functions as a purge gas to be able to discharge the excess Al-containing gas.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valves 52e and 54e, the controller 6 closes the valves 52e and 54e to stop the supply of the purge gas into the processing container 1. Further, the controller 6 opens the valve 55e to supply the NH3 gas stored in the storage tank 55d into the processing container 1 to reduce the Al-containing gas adsorbed on the surface of the wafer W (step S17).
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 55e, the controller 6 closes the valve 55e to stop the supply of the NH3 gas into the processing container 1. Further, the controller 6 opens the valves 52e and 54e to supply the N2 gas stored in the storage tanks 52d and 54e into the processing container 1, as a purge gas (step S18). At this time, since the N2 gas is supplied from the storage tanks 52d and 54d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the NH3 gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas atmosphere from the NH3 gas atmosphere in a short time. Further, since the valve 55e is closed, the NH3 gas supplied from the NH3 gas supply source 55a to the gas supply line 55b is stored in the storage tank 55d, and the internal pressure of the storage tank 55d is increased. Further, since the valve 55e is closed, the carrier gas (N2) supplied from the gas supply line 53b and the gas supply line 57b also functions as a purge gas to be able to discharge the excess NH3 gas.
A B cycle of steps S15 to S18 corresponds to the step of forming the second base film.
The controller 6 forms an AlTiN film having a desired film thickness as a base film by repeating a cycle of steps S11 to S18a plurality of times.
Note that the gas supply sequence and process gas conditions for forming the base film shown in
Here, in the gas supply sequence shown in
It is preferable that the base film has the high Ti content rate in the lower portion on the AlO layer from the viewpoint of adhesion and reaction suppression. Further, it is preferable that the base film has the high Al content rate in the upper portion on the AlO layer from the viewpoint of easy formation and orientation of a metal layer. Therefore, it is preferable that the AlTiN film has the high Ti content rate in the lower portion and the high Al content rate in the upper portion.
Therefore, when forming the base film, the controller 6 controls the number of executions of the step of forming the first base film and the step of forming the second base film to adjust the film formation ratio of the first base film and the second base film. This makes it possible to make a gradation of element concentration for the base film. Further, for example, when forming the lower portion of the base film, the controller 6 performs the step of forming the first base film more than the step of forming the second base film. Further, when forming the upper portion of the base film, the controller 6 performs the step of forming the second base film more than the step of forming the first base film. For example, the controller 6 sets the cycle of steps S11 to S18 as one set and repeats the set Z times to form the AlTiN film. In the lower portion film formation of the AlTiN film, the controller 6 performs the number of A cycles per set more than the number of B cycles per set. Further, in the upper portion film formation of the AlTiN film, the controller 6 performs the number of B cycles per set more than the number of A cycles per set. Further, for example, the controller 6 controls to perform the A cycle more times in the initial set of film formation of the base film and perform the B cycle more times in the final set of film formation of the base film. As an example, in the lower portion film formation of the base film, the controller 6 performs the A cycle twice and then the B cycle once. In the center film formation of the base film, the controller 6 performs the A cycle once and then the B cycle once. In the upper portion film formation of the base film, the controller 6 performs the A cycle once and then the B cycle twice. The number of times of performance of the A cycle and the B cycle is an example, and is not limited thereto. From the viewpoint of adhesion to the AlO layer, it is preferable that the base film is first subjected to the A cycle. Further, from the viewpoint of easy formation and orientation of a metal layer, it is preferable that the base film is subjected to the B cycle at the end.
The controller 6 adjusts the film formation ratio of the first base film and the second base film so that the composition ratio of Ti and Al of the base film is 20 to 95%: 5 to 80%.
Next, the flow of forming a metal layer will be described. In the present embodiment, the film forming apparatus 102 forms an initial tungsten film as a metal layer, and the film forming apparatus 103 forms a main tungsten film as a metal layer.
The controller 6 of the film forming apparatus 102 controls the heater 21 of the stage 2 to heat the wafer W to a predetermined temperature (for example, 250 to 550 degrees C.). Further, the controller 6 controls the pressure control valve of the exhaust mechanism 42 to adjust the interior of the processing container 1 to a predetermined pressure (for example, 0.1 to 10 Torr).
The controller 6 opens the valves 63e and 67e to supply a predetermined flow rate of carrier gas (N2 gas) from the N2 gas supply sources 63a and 67a to the gas supply lines 63b and 67b, respectively. Further, the controller 6 supplies a WF6 gas and a B2H6 gas to the gas supply lines 61b and 65b, respectively, from the WF6 gas supply source 61a and the B2H6 gas supply source 65a, respectively. At this time, since the valves 61e and 65e are closed, the WF6 gas and the B2H6 gas are stored in the storage tanks 61d and 65d, respectively, and the internal pressures of the storage tanks 61d and 65d are increased.
Next, the controller 6 opens the valve 61e to supply the WF6 gas stored in the storage tank 61d into the processing container 1 and adsorb the WF6 gas on the surface of the wafer W (step S21). Further, the controller 6 supplies a purge gas (N2 gas) from the N2 gas supply sources 62a and 66a to the gas supply lines 62b and 66b, respectively, in parallel with the supply of the WF6 gas into the processing container 1. At this time, since the valves 62e and 66e are closed, the purge gas is stored in the storage tanks 62d and 66d, and the internal pressures of the storage tanks 62d and 66d are increased.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 61e, the controller 6 closes the valve 61e to stop the supply of the WF6 gas into the processing container 1. Further, the controller 6 opens the valves 62e and 66e to supply the purge gas stored in the storage tanks 62d and 66d into the processing container 1 (step S22). At this time, since the purge gas is supplied from the storage tanks 62d and 66d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the WF6 gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, and the interior of the processing container 1 is replaced with the N2 gas-containing atmosphere from the WF6 gas atmosphere in a short time. On the other hand, since the valve 61e is closed, the WF6 gas supplied from the WF6 gas supply source 61a to the gas supply line 61b is stored in the storage tank 61d, and the internal pressure of the storage tank 61d is increased.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valves 62e and 66e, the controller 6 closes the valves 62e and 66e to stop the supply of the purge gas into the processing container 1. Further, the controller 6 opens the valve 65e to supply the B2H6 gas stored in the storage tank 65d into the processing container 1 to reduce the WF6 gas adsorbed on the surface of the wafer W (step S23). At this time, since the valves 62e and 66e are closed, the purge gas supplied from the N2 gas supply sources 62a and 66a to the gas supply lines 62b and 66b is stored in the storage tanks 62d and 66d, and the internal pressures of the storage tanks 62d and 66d are increased.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 65e, the controller 6 closes the valve 65e to stop the supply of the B2H6 gas into the processing container 1. Further, the controller 6 opens the valves 62e and 66e to supply the purge gas stored in the storage tanks 62d and 66d into the processing container 1 (step S24). At this time, since the purge gas is supplied from the storage tanks 62d and 66d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the B2H6 gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas-containing atmosphere from the B2H6 gas atmosphere in a short time. On the other hand, since the valve 65e is closed, the B2H6 gas supplied from the B2H6 gas supply source 65a to the gas supply line 65b is stored in the storage tank 65d, and the internal pressure of the storage tank 65d is increased.
The controller 6 forms the initial tungsten film having a desired film thickness by repeating a cycle of steps S21 to S24 a plurality of times (for example, 1 to 50 cycles).
Note that the gas supply sequence and process gas conditions for forming the initial tungsten film shown in
The controller 6 opens the valves 63e and 67e to supply a predetermined flow rate of carrier gas (N2 gas) from the N2 gas supply sources 63a and 67a to the gas supply lines 63b and 67b, respectively. Further, the controller 6 opens the valve 64e to supply a predetermined flow rate of H2 gas from the H2 gas supply source 64a to the gas supply line 64b. Further, the controller 6 supplies a WF6 gas and a H2 gas from the WF6 gas supply source 61a and the H2 gas supply source 68a to the gas supply lines 61b and 68b, respectively. At this time, since the valves 61e and 68e are closed, the WF6 gas and the H2 gas are stored in the storage tanks 61d and 68d, respectively, and the internal pressures of the storage tanks 61d and 68d are increased.
Next, the controller 6 opens the valve 61e to supply the WF6 gas stored in the storage tank 61d into the processing container 1 and adsorb the WF6 gas on the surface of the wafer W (step S21). Further, the controller 6 supplies a purge gas (N2 gas) from the N2 gas supply sources 62a and 66a to the gas supply lines 62b and 66b, respectively, in parallel with the supply of the WF6 gas into the processing container 1. At this time, since the valves 62e and 66e are closed, the purge gas is stored in the storage tanks 62d and 66d, and the internal pressures of the storage tanks 62d and 66d are increased.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 61e, the controller 6 closes the valve 61e to stop the supply of the WF6 gas into the processing container 1. Further, the controller 6 opens the valves 62e and 66e to supply the purge gas stored in the storage tanks 62d and 66d into the processing container 1 (step S22). At this time, since the purge gas is supplied from the storage tanks 62d and 66d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the WF6 gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, and the interior of the processing container 1 is replaced with the atmosphere containing the H2 gas and the N2 gas from the WF6 gas atmosphere in a short time. On the other hand, since the valve 61e is closed, the WF6 gas supplied from the WF6 gas supply source 61a to the gas supply line 61b is stored in the storage tank 61d, and the internal pressure of the storage tank 61d is increased.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valves 62e and 66e, the controller 6 closes the valves 62e and 66e to stop the supply of the purge gas into the processing container 1. Further, the controller 6 opens the valve 68e to supply the H2 gas stored in the storage tank 68d into the processing container 1 to reduce the WF6 gas adsorbed on the surface of the wafer W (step S23). At this time, since the valves 62e and 66e are closed, the purge gas supplied from the N2 gas supply sources 62a and 66a to the gas supply lines 62b and 66b is stored in the storage tanks 62d and 66d, and the internal pressures of the storage tanks 62d and 66d are increased.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 68e, the controller 6 closes the valve 68e to stop the supply of the H2 gas into the processing container 1. Further, the controller 6 opens the valves 62e and 66e to supply the purge gas stored in the storage tanks 62d and 66d into the processing container 1 (step S24). At this time, since the purge gas is supplied from the storage tanks 62d and 66d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the H2 gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the atmosphere containing H2 gas and N2 gas from the H2 gas atmosphere in a short time. On the other hand, since the valve 68e is closed, the H2 gas supplied from the H2 gas supply source 68a to the gas supply line 68b is stored in the storage tank 68d, and the internal pressure of the storage tank 68d is increased.
The controller 6 forms a tungsten film having a desired film thickness by repeating a cycle of steps S21 to S24 a plurality of times (for example, 50 to 3,000 cycles).
Note that the gas supply sequence and process gas conditions for forming the main tungsten film shown in
Next, the operation and effects of the film forming method according to the present embodiment will be described.
Here, an example of the process conditions of the film forming method according to the embodiment is collectively described below.
AlTiN Film
Temperature: 250 to 550 degrees C.
Pressure: 0.1 to 10 Torr
Ti-containing gas: 10 to 500 sccm
Al-containing gas: 10 to 500 sccm
Carrier gas (N2): 3,000 to 30,000 sccm
Purge gas (N2): 0 to 20.00 sccm
NH3 gas: 1,000 to 20,000 sccm
Time:
Ti-containing gas: 0.05 to 5 seconds
Al-containing gas: 0.05 to 5 seconds
Purge: 0.05 to 5 seconds
NH3 gas: 0.05 to 5 seconds
Purge: 0.05 to 5 seconds
Nucleation Film:
Temperature: 250 to 550 degrees C.
Pressure: 0.1 to 10 Torr
W-containing gas: 10 to 500 sccm
Carrier gas (N2): 3,000 to 30,000 sccm
Purge gas (N2): 1,000 to 10,000 sccm
H2 gas: 1,000 to 10,000 sccm
SiH4 gas, B2H6 gas: 10 to 1,000 sccm
Time:
W-containing gas: 0.05 to 5 seconds
Purge: 0.05 to 5 seconds
SiH4 gas, B2H6 gas: 0.05 to 5 seconds
Purge: 0.05 to 5 seconds
W Film:
Temperature: 250 to 550 degrees C.
Pressure: 0.1 to 10 Torr
W-containing gas: 100 to 500 sccm
Carrier gas (N2): 3.000 to 30,000 sccm
Purge gas (N2): 1,000 to 10,000 sccm
H2 gas: 1,000 to 10,000 sccm
Time:
W-containing gas: 0.05 to 15 seconds
Purge: 0.05 to 15 seconds
H2 gas: 0.05 to 15 seconds
Purge: 0.05 to 15 seconds
The wafer W can obtain adhesion by forming the AlTiN film having the high Ti content rate in the lower portion on the AlO layer, thereby suppressing the reaction of the AlO layer. The thickness of the AlTiN film is preferably 3.5 nm or less, and if the thickness is about 1 nm, the adhesion to the AlO layer can be obtained, thereby suppressing the reaction of the AlO layer. Further, by increasing the Ti content rate in the lower portion of the AlTiN film, the adhesion to the AlO layer can be further enhanced. Further, by increasing the Al content rate in the upper portion of the AlTiN film, the orientation of TiN can be canceled. As a result, in the wafer W, the grains of tungsten to be formed can be grown larger, thereby reducing the resistance of the tungsten film.
Further, in the wafer W, the adhesion of the tungsten to be formed can be improved by forming the nucleation film. Further, in the wafer W, the uniformity of the tungsten to be formed can be improved by forming the nucleation film. The nucleation film preferably has a thickness of about 0.5 to 5 nm.
Here, the effects will be explained using a comparative example.
An example of the process conditions for forming each film of the comparative example is described below.
Nucleation Film:
Temperature: 250 to 550 degrees C.
Pressure: 0.1 to 10 Torr
W-containing gas: 10 to 500 sccm
Carrier gas (N2): 3,000 to 30,000 sccm
Purge gas (N2): 1,000 to 10,000 sccm
H2 gas: 1,000 to 20,000 sccm
SiH4 gas, B2H6 gas: 10 to 1,000 sccm
Time:
W-containing gas: 0.05 to 5 seconds
Purge: 0.05 to 5 seconds
SiH4 gas, B2H6 gas: 0.05 to 5 seconds
Purge: 0.05 to 5 seconds
W Film:
Temperature: 250 to 550 degrees C.
Pressure: 0.1 to 20 Torr
W-containing gas: 100 to 500 sccm
Carrier gas (N2): 1,000 to 10,000 sccm
Purge gas (N2): 0 to 10,000 sccm
H2 gas: 500 to 20,000 sccm
Time:
W-containing gas: 0.05 to 15 seconds
Purge: 0.05 to 15 seconds
H2 gas: 0.05 to 15 seconds
Purge: 0.05 to 15 seconds
Here, as described above, the wring of LSI is miniaturized and thus it is required to reduce the resistance of the wiring. For example, in a three-dimensional laminated semiconductor memory such as a 3D NAND flash memory, a tungsten film is formed as a word line, but further reduction in the resistance of the tungsten film is required for miniaturization.
In contrast, the layer configuration of the present embodiment can reduce the resistance of the tungsten film even when it is thinned.
Further, in the layer configuration of the comparative example shown in
Further, in the layer configuration of the comparative example shown in
Further, the wafer W on which the metal layer is formed is further subjected to various substrate processing such as etching.
As illustrated in
Further, in the method of the comparative example, since the reaction of AlN+ClF3→AlF occurs and AlF becomes a particle source because of its low volatility, it is difficult to perform dry cleaning in a chamber by, for example, ClF3 or the like. On the other hand, in the method of the present embodiment, when dry cleaning is performed with, for example, ClF3 or the like, the reaction of AlTiN+ClF3→AlTiF occurs and AlTiF may be removed by the dry cleaning. Therefore, it is possible to perform the dry cleaning of the chamber.
Further, in the film forming method according to the present embodiment, the Ti and Al content rates of the AlTiN film formed as the base film can be controlled. The higher the Al ratio of the base film, the better the barrier property of fluorine (F).
Further, in the layer configuration of the present embodiment as illustrated in
Further, the crystallinity of the AlTiN film formed as the base film changes depending on the Al ratio due to the influence of TiN. Since the TiN film is a film having the crystallinity, a peak occurs in intensity at a specific diffraction angle when an X-ray analysis (X-ray diffraction: XRD) is performed.
As described above, the film forming method according to the present embodiment has the step in which the wafer W on which the insulating film (AlO layer) is formed is disposed in the processing container 1 and the Ti-containing gas, the Al-containing gas, and the reaction gas are repeatedly supplied into the processing container 1 under the decompressed atmosphere to form the base film and the step in which the metal layer made of a metal material is formed on the wafer W on which the base film is formed. As a result, the film forming method according to the present embodiment can reduce the resistance of the tungsten film even when the film is thinned.
Further, in the film forming method according to the present embodiment, the step of forming the base film includes repeating at least once the step of forming the first base film by repeating at least once the alternating supply of the Ti-containing gas and the reaction gas with the purge step interposed therebetween (the A cycle) and the step of forming the second base film by repeating at least once the alternating supply of the Al-containing gas and the reaction gas with the purge step interposed therebetween (the B cycle). As a result, the film forming method according to the present embodiment can make gradations of element concentrations of Ti and Al for the base film.
Further, in the film forming method according to the present embodiment, in the case of forming the lower portion of the base film, the step of forming the base film performs the step of forming the first base film more than the step of forming the second base film. In the case of forming the upper portion of the base film, the step of forming the base film performs the step of forming the second base film more than the step of forming the first base film. As a result, the film forming method according to the present embodiment can form a film having the high Ti content rate in the lower portion of the base film and the high Al content rate in the upper portion of the base film.
Further, in the film forming method according to the present embodiment, the step of forming the base film performs first the step of forming the first base film. As a result, the film forming method according to the present embodiment can improve the adhesion between the insulating film and the base film.
Further, in the film forming method according to the present embodiment, the step of forming the base film performs finally the step of forming the second base film. As a result, the film forming method according to the present embodiment can form a metal layer with good uniformity.
Next, a second embodiment will be described. A film forming system 100 and film forming apparatuses 101 to 104 according to the second embodiment are the same configurations of the film forming system 100 and the film forming apparatuses 101 to 104 according to the first embodiment illustrated in
A flow in which the film forming apparatus 101 forms a base film will be described. The film forming apparatus 101 repeatedly supplies a Ti-containing gas, an Al-containing gas, and a reaction gas into the processing container 1 to form a base film.
The controller 6 opens the valve 56e to supply the Ti-containing gas stored in the storage tank 56d into the processing container 1 and adsorb a film by the Ti-containing gas on the surface of the wafer W (step S51).
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 56e, the controller 6 closes the valve 56e to stop the supply of the Ti-containing gas into the processing container 1. Further, the controller 6 opens the valves 52e and 54e to supply the N2 gas stored in the storage tanks 52d and 54d into the processing container 1, as a purge gas (step S52). At this time, since the N2 gas is supplied from the storage tanks 52d and 54d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the Ti-containing gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas atmosphere from the Ti-containing gas atmosphere in a short time. Further, since the valve 56e is closed, the Ti-containing gas supplied from the Ti-containing gas supply source 56a to the gas supply line 56b is stored in the storage tank 56d, and the internal pressure of the storage tank 56d is increased. Further, since the valve 56e is closed, the carrier gas (N2) supplied from the gas supply line 53b and the gas supply line 57b also functions as a purge gas to be able to discharge the excess Ti-containing gas.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valves 52e and 54e, the controller 6 closes the valves 52e and 54e to stop the supply of the purge gas into the processing container 1. Further, the controller 6 opens the valve 51e to supply the Al-containing gas stored in the storage tank 51d into the processing container 1 and adsorb a film by the Al-containing gas on the surface of the wafer W (step S53).
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 51e, the controller 6 closes the valve 51e to stop the supply of the Al-containing gas into the processing container 1. Further, the controller 6 opens the valves 52e and 54e to supply the N2 gas stored in the storage tanks 52d and 54d into the processing container 1, as a purge gas (step S54). At this time, since the N2 gas is supplied from the storage tanks 52d and 54d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the Al-containing gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas atmosphere from the Al-containing gas atmosphere in a short time. Further, since the valve 51e is closed, the Al-containing gas supplied from the Al-containing gas supply source 51a to the gas supply line 51b is stored in the storage tank 51d, and the internal pressure of the storage tank 51d is increased. Further, since the valve 51e is closed, the carrier gas (N2) supplied from the gas supply line 53b and the gas supply line 57b also functions as a purge gas to be able to discharge the excess Al-containing gas.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valves 52e and 54e, the controller 6 closes the valves 52e and 54e to stop the supply of the purge gas into the processing container 1. Further, the controller 6 opens the valve 55e to supply the NH3 gas stored in the storage tank 55d into the processing container 1 to reduce the Al-containing gas and the Ti-containing gas adsorbed on the surface of the wafer W (step S55).
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 55e, the controller 6 closes the valve 55e to stop the supply of the NH3 gas into the processing container 1. Further, the controller 6 opens the valves 52e and 54e to supply the N2 gas stored in the storage tank 52d into the processing container 1, as a purge gas (step S56). At this time, since the N2 gas is supplied from the storage tanks 52d and 54d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the NH3 gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas atmosphere from the NH3 gas atmosphere in a short time. Since the valve 55e is closed, the NH3 gas supplied from the NH3 gas supply source 55a to the gas supply line 55b is stored in the storage tank 55d, and the internal pressure of the storage tank 55d is increased. Further, since the valve 55e is closed, the carrier gas (N2) supplied from the gas supply line 53b and the gas supply line 57b also functions as a purge gas to be able to discharge the excess NH3 gas.
The controller 6 repeats an X cycle of steps S51 to S55 a plurality of times (for example, 2 to 1,000 cycles) to form an AlTiN film having a desired film thickness as the base film.
Here, in the gas supply sequence shown in
It is preferable that the base film has the high Ti content rate in the lower portion on the AlO layer from the viewpoint of adhesion and reaction suppression. Further, it is preferable that the base film has the high Al content rate in the upper portion on the AlO layer from the viewpoint of easy formation and orientation of a metal layer. For example, it is preferable that the AlTiN film has the high Ti content rate in the lower portion and the high Al content rate in the upper portion.
Therefore, when forming the base film, the controller 6 adjusts the ratio of the supply amount of the Ti-containing gas and the supply amount of the Al-containing gas. This makes it possible to make gradations of element concentrations of Ti and Al for the base film. For example, the controller 6 controls so that the supply amount of Ti-containing gas is larger than the supply amount of Al-containing gas when forming the lower portion of the base film, and controls so that the supply amount of Ti-containing gas is smaller than the supply amount of Al-containing gas when forming the upper portion of the base film. For example, when forming the lower portion of the base film, the controller 6 performs one or both of a control for lengthening the supply time of Ti-containing gas and a control for shortening the supply time of Al-containing gas so that the supply amount of Ti-containing gas is larger than the supply amount of Al-containing gas. Further, when forming the upper portion of the base film, the controller 6 performs one or both of a control for shortening the supply time of Ti-containing gas and a control for lengthening the supply time of Al-containing gas so that the supply amount of Ti-containing gas is smaller than the supply amount of Al-containing gas. As a result, as illustrated in
Note that the gas supply sequence and process gas conditions for forming the base film shown in
As described above, in the film forming method according to the present embodiment, the base film is formed by setting the supply amount of Ti-containing gas to be larger than the supply amount of Al-containing gas when forming the lower portion of the base film, and the supply amount of Ti-containing gas to be smaller than the supply amount of Al-containing gas when forming the upper portion of the base film, and repeatedly supplying the Ti-containing gas, the Al-containing gas, and the reaction gas in order into the processing container 1 with the purge step interposed therebetween. As a result, in the film forming method according to the present embodiment, the base film can be formed with the high Ti content rate in the lower portion and the high Al content rate in the upper portion.
Next, a third embodiment will be described. In the third embodiment, the film forming apparatus 101 is provided with the function of the film forming apparatus 102, and the film forming apparatus 102 can have the same configuration as the film forming apparatuses 103 and 104. A film forming system 100 according to the third embodiment is the same as those of the first and second embodiments and therefore, explanation thereof will not be repeated.
The configuration of the film forming apparatus 101 according to the third embodiment will be described.
The gas supply mechanism 5 further has a nucleation gas supply source 58a as a gas supply source for forming a base film. In the gas supply mechanism 5 shown in
The nucleation gas supply source 58a supplies a nucleation gas for generating nuclei of a metal layer to be formed later into the processing container 1 via a gas supply line 58b. The nucleation gas is a gas that forms nuclei so that a metal layer can be easily formed uniformly on the wafer W. When the metal layer is a tungsten film, the nucleation gas may be a B2H6 gas, a BCl3 gas, a SiH4 gas, a Si2H6 gas, or a SiH2Cl2 gas. For example, the nucleation gas supply source 58a supplies the B2H6 gas as the nucleation gas. A flow rate controller 58c, a storage tank 58d, and a valve 58e are interposed in the gas supply line 58b from the upstream side. The downstream side of the valve 58e of the gas supply line 58b is connected to the gas supply line 55b. The nucleation gas supplied from the nucleation gas supply source 58a is temporarily stored in the storage tank 58d before being supplied into the processing container 1, and is supplied into the processing container 1 after being boosted to a predetermined pressure in the storage tank 58d. The supply and stop of the nucleation gas from the storage tank 58d to the processing container 1 is performed by the valve 58e. By temporarily storing the nucleation gas in the storage tank 58d in this way, the nucleation gas can be stably supplied into the processing container 1 at a relatively large flow rate.
Next, a flow in which the film forming apparatus 101 according to the third embodiment forms the base film will be described. The film forming apparatus 101 repeatedly supplies a Ti-containing gas, an Al-containing gas, and a nucleation gas into the processing container 1 to form the base film. For example, the film forming apparatus 101 forms the base film by at least once repeating a step of forming a first base film by repeating the alternating supply of Ti-containing gas and reaction gas at least once with a purge step interposed therebetween, a step of forming a second base film by repeating the alternating supply of Al-containing gas and reaction gas at least once with a purge step interposed therebetween, and a step of forming a third base film by repeating the supply of nucleation gas at least once with a purge step interposed therebetween. In the present embodiment, an AlTiBN film formed by thinly and alternately laminating a TiN film as the first base film, an AlN film as the second base film, and a B-containing film by the B2H6 gas as the third base film is formed as the base film.
The controller 6 opens the valves 53e and 57e to supply a predetermined flow rate of carrier gas (N2 gas) from the N2 gas supply sources 53a and 57a to the gas supply lines 53b and 57b, respectively. Further, the controller 6 stops the supply of the Ti-containing gas, the Al-containing gas, and the NH3 gas from the Ti-containing gas supply source 56a, the Al-containing gas supply source 51a, and the NH3 gas supply source 55a. Further, the controller 6 supplies the N2 gas and the nucleation gas from the N2 gas supply sources 52a and 54a and the nucleation gas supply source 58a to the gas supply lines 52b, 54b, and 58b, respectively. At this time, since the valves 52e, 54e, and 58e are closed, the N2 gas and the nucleation gas are stored in the storage tanks 52d, 54d, and 58d, respectively, and the internal pressures of the storage tanks 52d, 54d, and 58d are increased.
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valves 52e and 54e, the controller 6 closes the valves 52e and 54e to stop the supply of the purge gas into the processing container 1. Further, the controller 6 opens the valve 58e to supply the nucleation gas stored in the storage tank 58d into the processing container 1 to generate nuclei on the surface of the wafer W (step S9).
With the lapse of a predetermined time (for example, 0.05 to 5 seconds) from the open of the valve 58e, the controller 6 closes the valve 58e to stop the supply of the nucleation gas into the processing container 1. Further, the controller 6 opens the valves 52e and 54e to supply the N2 gas stored in the storage tanks 52d and 54d into the processing container 1, as a purge gas (step S20). At this time, since the N2 gas is supplied from the storage tanks 52d and 54d in a state where the pressure is increased, the purge gas is supplied into the processing container 1 at a relatively large flow rate, for example, a flow rate larger than the flow rate of the carrier gas. Therefore, the nucleation gas remaining in the processing container 1 is quickly discharged to the exhaust pipe 41, so that the interior of the processing container 1 is replaced with the N2 gas atmosphere from the nucleation gas atmosphere in a short time. Since the valve 58e is closed, the nucleation gas supplied from the nucleation gas supply source 58a to the gas supply line 58b is stored in the storage tank 58d, and the internal pressure of the storage tank 58d is increased. Further, since the valve 58e is closed, the carrier gas (N2) supplied from the gas supply line 53b and the gas supply line 57b also functions as a purge gas to be able to discharge the excess nucleation gas.
A C cycle of steps S19 and S20 corresponds to the step of forming the third base film.
The controller 6 forms an AlTiBN film having a desired film thickness as a base film by repeating a cycle of steps S11 to S20 a plurality of times.
Note that the gas supply sequence and process gas conditions for forming the base film shown in
Here, in the gas supply sequence shown in
It is preferable that the base film has the high Ti content rate in the lower portion on the AlO layer from the viewpoint of adhesion and reaction suppression. Further, it is preferable that the base film has the high Al content rate in the middle portion on the AlO layer from the viewpoint of easy formation and orientation of a metal layer. Further, it is preferable that the base film has the high B content rate in the upper portion from the viewpoint of formation of a tungsten film. Therefore, it is preferable that the AlTiBN film has the high Ti content rate in the lower portion, the high Al content rate in the middle portion, and the high B content rate in the upper portion.
Therefore, when forming the base film, the controller 6 controls the number of executions of the step of forming the first base film, the step of forming the second base film, and the step of forming the third base film to adjust the film formation ratio of the first base film, the second base film, and the third base film. This makes it possible to make a gradation of element concentration for the base film. For example, when forming the lower portion of the base film, the controller 6 performs the step of forming the first base film more than the step of forming the second base film and the step of forming the third base film. Further, when forming the middle portion of the base film, the controller 6 performs the step of forming the second base film more than the step of forming the first base film and the step of forming the third base film. Further, when forming the upper portion of the base film, the controller 6 performs the step of forming the third base film more than the step of forming the first base film and the step of forming the second base film. From the viewpoint of adhesion to the AlO layer, it is preferable that the base film is first subjected to the A cycle. Further, from the viewpoint of easy formation, uniformity, and orientation of a metal layer, it is preferable that the base film is subjected to the C cycle at the end.
In the film forming system 100 according to the third embodiment, the wafer W on which the AlTiBN film is formed is transferred to any of the film forming apparatuses 102 to 104 and a process of forming a tungsten film is performed on the wafer W by any of the film forming apparatuses 102 to 104.
In the layer configuration of the present embodiment, since the AlTiBN film also functions as a nucleation film, it is not necessary to forma nucleation film. As a result, in the layer configuration of the present embodiment, the tungsten film can be formed thicker by the thickness of the nucleation film, so that the resistance of the tungsten film can be reduced even when the film is thinned.
As described above, in the film forming method according to the present embodiment, in the step of forming the base film, the nucleation gas is further repeatedly supplied into the processing container 1 to form the base film. As a result, the film forming method according to the present embodiment does not require the formation of a nucleation film, so that the resistance of the tungsten film can be reduced even when the film is thinned.
Further, in the film forming method according to the present embodiment, the step of forming the base film includes at least once repeating the step of forming the first base film by repeating the alternating supply of Ti-containing gas and reaction gas at least once with the purge step interposed therebetween, the step of forming the second base film by repeating the alternating supply of Al-containing gas and reaction gas at least once with the purge step interposed therebetween, and the step of forming the third base film by repeating the supply of nucleation gas at least once with the purge step interposed therebetween. As a result, in the film forming method according to the present embodiment, the first base film, the second base film, and the third base film can be thinly and alternately laminated to form the base film, and the gradation of element concentration can be made by changing the ratio of the first base film, the second base film, and the third base film.
Although the embodiments have been described above, it should be considered that the embodiments disclosed this time are examples in all respects and are not restrictive. Indeed, the above embodiments can be embodied in a variety of forms. Moreover, the above embodiments may be omitted, replaced, or changed in various forms without departing from the claims and the gist thereof.
For example, the film forming system 100 according to the embodiments has been described as an example in which the formation of the base film and the formation of the metal layer are performed by different film forming apparatuses, but the present disclosure is not limited thereto. For example, the formation of the base film and the formation of the metal layer may be performed by the same film forming apparatus. For example, in the film forming system 100, the film forming apparatuses 101 to 104 may perform the formation of the base film and the formation of the metal layer, respectively. In this case, the film forming apparatuses 101 to 104 may together have the configuration of the gas supply mechanism 5 shown in
Further, the film forming system 100 according to the embodiments has been described as an example in which the NH3 gas is used as the reaction gas that reacts with the Ti-containing gas or the Al-containing gas when the AlTiN film or the AlTiBN film is formed, but the present disclosure is not limited thereto. For example, a hydrazine gas may be used as the reaction gas. Moreover, the NH3 gas and the hydrazine gas may be used. For example, the Ti-containing gas may be reacted with the hydrazine gas to adsorb TiN on the surface of the wafer W, and the Al-containing gas may be reacted with the NH3 gas to adsorb AlN on the surface of the wafer W. Further, the Ti-containing gas may be reacted with the NH3 gas to adsorb TiN on the surface of the wafer W, and the Al-containing gas may be reacted with the hydrazine gas to adsorb AlN on the surface of the wafer W.
Further, the film forming system 100 according to the embodiments has been described as an example in which the H2 gas is used as the reducing gas for forming the main tungsten film but the reducing gas may be any reducing gas containing hydrogen, such as a SiH4 gas, a B2H6 gas, an NH3 gas, or the like in addition to the H2 gas. As the reducing gas for forming the main tungsten film, two or more of the H2 gas, the SiH4 gas, the B2H6 gas, and the NH3 gas may be supplied. Further, other reducing gases other than these, such as a PH3 gas and a SiH2Cl2 gas, may be used. From the viewpoint of further reducing impurities in the film to obtain a low resistance value, it is preferable to use the H2 gas. Further, as the purge gas and the carrier gas, another inert gas such as an Ar gas can be used instead of the N2 gas.
Further, although the semiconductor wafer has been described as an example of the substrate, the semiconductor wafer may be silicon or a compound semiconductor such as GaAs, SiC, GaN, or the like. The present disclosure is not limited to the semiconductor wafer, but may also be applied to a glass substrate, a ceramic substrate, and the like used for flat panel displays (FPDs) such as liquid crystal display devices and the like.
1: processing container, 5: gas supply mechanism, 6: controller, 100: film forming system, 101 to 104: film forming apparatus, W: wafer
| Number | Date | Country | Kind |
|---|---|---|---|
| 2018-123688 | Jun 2018 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2019/019770 | 5/17/2019 | WO | 00 |
