1. Technical Field
The present disclosure relates to a method for manufacturing electronic components on a semiconductor substrate. It relates in particular to photolithography processes implementing successive steps of patterning in a layer called “hard mask” deposited onto a target layer.
2. Description of the Related Art
Photolithography processes consist in etching patterns using a layer in a photosensitive material, such as a photoresist deposited onto a target layer formed on a substrate. A layer called “hard mask” may be deposited onto the target layer before depositing the photoresist layer. The pattern to be transferred to the target layer is then transferred to the photoresist layer by photolithography, then by etching to the hard mask layer and target layer. A transfer of patterns to the photoresist layer generally consists in exposing the layer in a photolithography machine to a beam of particles through a mask having the patterns to be transferred, then removing the exposed parts (in the case of a positive photoresist) or the not exposed parts (in the case of a negative photoresist) using a developing solvent. The minimum size for the patterns susceptible of being transferred to a photosensitive layer is called “critical dimension” (CD) and corresponds for example to the width of a pattern line. The critical dimension depends on features of the photolithography exposition machine and in particular the optical projection device, and on features of the exposition, development and the photosensitive material used.
To reduce even more the critical dimensions of patterns susceptible of being etched into a target layer without replacing the photolithography machine, several methods of multiple patterning have been developed. Some of these methods include successively transferring several patterns to a hard mask layer formed on the target layer, by depositing a new photoresist layer onto the hard mask layer between each transfer. According to a multiple patterning method described in the patent U.S. Pat. No. 6,787,469, line patterns of a first mask, have parallel lines having the critical dimension of the photolithography process. Cutting patterns of a second mask, have shapes that remove a part of the line patterns, and in particular cut some lines formed by the line patterns. This method is used in particular to form gates of CMOS transistors in polysilicon, which may currently reach a minimum width of around 30 nm.
Such a photolithography process using multiple patterning is shown by
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In practice, all the processes between the etching of the lines and the final etching of the hard mask layer have an effect of reducing the critical dimensions of the patterns formed in this layer and therefore in the target layer. Each etching process is therefore followed by a meteorology step during which different parameters including the critical dimensions are measured. The photolithography process forming the line patterns in the layer PR may be adapted if the critical dimensions measured varies from those to be reached. Likewise, the measures obtained after the first etching of the hard mask layer HM (
All the processing steps affect the critical dimensions except for the photolithography step of the layer PR′. This step may therefore be performed with a photolithography machine less precise and therefore less expensive than that which are used for the other photolithography steps. However, a change of photolithography machine during a multiple patterning process at critical dimension raises several sensitive issues and in particular issues regarding the alignment of the two mask patterns to be transferred onto the semiconductor wafer. During the process of the structures at critical dimension, the measures obtained during the first hard mask etching process are used to adjust the second hard mask etching process. If a machine change occurs between these two hard mask etching processes, these measures must be saved and introduced into the machine performing the second hard mask etching process.
It is therefore desirable to simplify such a multiple patterning method. It is also desirable to reduce the utilization time of an expensive photolithography machine, in particular by making it possible to use a less expensive photolithography machine for the processes not involved at critical dimension.
Embodiments relate to a method for etching a target layer, comprising: depositing a hard mask layer on a target layer and on the hard mask layer, a first layer in a photosensitive material, exposing the first photosensitive layer to a beam of particles through a first mask (MSK1) to transfer first patterns, forming the first patterns in the photosensitive layer, transferring the first patterns into the hard mask layer by etching this layer through the first photosensitive layer, depositing onto the hard mask layer etched a second layer in a photosensitive material, exposing the second photosensitive layer to a beam of particles through a second mask to transfer second patterns, forming the second patterns in the second photosensitive layer, transferring the second patterns into the hard mask layer by etching this layer through the second photosensitive layer, and transferring the first and second patterns into the target layer by etching this layer through the hard mask layer, wherein the second patterns form lines in the hard mask layer, and the first patterns form trenches cutting the lines in the hard mask layer.
According to an embodiment, between the steps of second etching of the hard mask layer and etching of the target layer, the method comprises: depositing onto the hard mask layer etched a third layer in a photosensitive material, exposing the third photosensitive layer to a beam of particles through a third mask to transfer third patterns, forming the third patterns in the third photosensitive layer, and transferring the third patterns into the hard mask layer by etching this layer through the third photosensitive layer, the target layer being etched by receiving the first, second and third patterns formed in the hard mask layer, the third patterns forming lines cut by the first patterns.
According to an embodiment, one or each of the photosensitive layers is directly deposited onto the hard mask layer, previously etched or not, the photosensitive layer having a reflection coefficient of the beam of particles lower than 1%, and a plane upper face, and covers the hard mask layer without trapping gas bubbles.
According to an embodiment, the upper surface of one or each of the photosensitive layers has a height variation lower than 20%, and preferably, lower than 15%.
According to an embodiment, an additional layer is directly deposited onto the hard mask layer, previously etched or not, one or each of the photosensitive layers being deposited onto the additional layer, the method comprising etching the additional layer to transfer the patterns formed in the photosensitive layer to the additional layer.
According to an embodiment, the additional layer has a reflection coefficient of the beam of particles lower than 1%, and a plane upper face, and covers the hard mask layer without trapping gas bubbles.
According to an embodiment, the upper surface of one or each of the photosensitive layers has a height variation lower than 20%, and preferably, lower than 15%.
According to an embodiment, one or each of the photosensitive layers is deposited onto a second hard mask layer, the second hard mask layer being deposited onto the additional layer, the method comprising etching the second hard mask layer to transfer the patterns formed in the photosensitive layer to the hard mask layer.
According to an embodiment, the target layer is a layer provided to form gates of CMOS transistors.
Embodiments of the disclosure will be described hereinafter, in relation with, but not limited to the appended figures wherein:
At step S1, a hard mask layer HM and a layer of a photosensitive material PR are successively deposited onto the target layer TL.
At step S2, the layer PR is subjected to a beam of particles (photons, electrons, . . . ) through a mask MSK1. Step S3 is a development step during which the parts exposed (or not exposed) by the photolithography machine through the mask MSK1 are removed.
The following step S4 is a meteorology step allowing the quality of the transfer from the mask MSK1 to the layer PR to be controlled. If, on a batch of wafers, the patterns R1, R2 have dimensions higher or lower than desired dimensions, the photolithography process performed at steps S2, S3 may be readjusted for a following batch of wafers. This readjustment according to measures forms a regulation loop (here of Run to Run type) which allows the global quality of the batches of wafers thus produced to be improved. The measures obtained at step S4 on a given batch of wafers, may also be used to adjust on this same batch of wafers, the etching parameters of the hard mask layer at the following step S5. This readjustment performed at a following step (usually called “Feed Forward”), based on measures obtained at a previous step, is also important for the control of fabrication processes.
The shapes and dimensions of the patterns R1, R2 thus transferred are not decisive for the quality of the final result of the process of the target layer TL. At step S5, the layer HM is etched through the layer PR, so as to transfer the patterns formed in the layer PR to the layer HM, and the layer PR is removed.
At step S7, a new photoresist layer PR′ is deposited onto the layer HM which has been etched at step S5.
Step S9 is a development step during which the parts exposed (or not exposed) by the photolithography machine through the mask MSK2 are removed.
The following step S10 is a meteorology step allowing the dimensions of the patterns transferred to the layer PR′ to be controlled. If at step S10, the dimensions of the patterns transferred into the layer PR′ are superior or inferior to desired dimensions, the photolithography process performed at steps S8, S9 may be readjusted for a following batch of wafers. At step S11, the layer HM is etched at the shape of the patterns transferred into the layer PR′ and the layer PR′ is removed. If at step S10, the dimensions of the patterns transferred into the layer PR′ are superior or inferior to desired dimensions, the etching process of the layer HM may be extended. The target layer TL is then etched at the shape of the patterns R1, R2, L1, L2, L3 transferred to the layer HM.
The etching processes of the hard mask layer have an effect of reducing the critical dimensions of the patterns formed in this layer and therefore in the target layer. Thus, in one embodiment, the patterns L1, L2, L3 transferred into the layer PR′ have a critical dimension of 52 nm, and when they are transferred to the target layer TL, they may reach a dimension of 34 nm. The meteorology steps are for example performed using a scanning electron microscope SEM, or by scatterometry. The patterns thus formed in the target layer TL allow for example gates of CMOS transistors to be made, the layer TL then being polysilicon, but the target layer could be of other materials, such a metal or single-crystal semiconductor. The width D2 of the lines L1, L2, L3 corresponds to the length of the gates of the transistors thus formed. These lines therefore have a dimension (their width) which is decisive for the electrical performances of these transistors. On the contrary, no dimension of the patterns R1, R2 is decisive for the electrical performances of these transistors. The presence of the trenches R1, R2 separates the gates of the transistors collectively formed by the lines L1, L2, L3.
It is observed that the formation of patterns L1, L2, L3 in the hard mask layer HM is not affected by the presence of the trenches R1, R2 previously formed in the layer HM. Indeed, so that a photosensitive layer is properly exposed, the surface to be exposed should be very planar. Depositing a photosensitive layer on the slightest relief is therefore to be avoided in particular when the structures to be formed are very critical regarding their dimensions. In the current case, depositing the photosensitive layer PR′ directly onto the trenches R1, R2 formed in the layer HM was therefore to be avoided. Depositing onto the hard mask layer HM a layer having planarizing and antireflective properties should be sufficient to avoid the presence of relief (trenches R1, R2) in the layer HM. Thus, the photoresist used to form the layer PR′ may be chosen so as to cover the layer HM by penetrating into the trenches R1, R2 formed at step S5 without trapping gas bubbles, and to have an upper face planar and antireflective enough, at the end of its deposit onto the layer HM not to affect the following processes of photolithography and etching of the hard mask layer HM. In practice, it is desirable that the layer deposited onto the hard mask layer HM be planar enough for its upper surface to have, in particular on each side of the edge of a trench pattern R1, R2, a variation of its height lower than 20%, and preferably, lower than 15%, this variation being expressed in percentage of the depth of field of the photolithography process used. For example, for a photolithography process having a depth of field of 120 nm and a hard mask 30 nm thick, the local height variations resulting from the presence of the trenches would represent 25% of the depth of field. In the absence of layer having sufficient planarizing properties, the upper surface of the photoresist PR′ would have local variations too, representing 25% of the depth of field, which is unacceptable in practice for a critical photolithography step. On the other hand, a photoresist layer making it possible to reduce to less than 20 nm at its upper surface, the height variations of 30 nm at its lower surface resulting from the trenches, allows the local height variations of the upper surface of the photoresist to be reduced to less than 17% of the depth of field, which is acceptable.
The method which has been described has the advantage of successively performing the critical photolithography and etching processes (steps S7, S8, S9 and S11), i.e., decisive for the electrical performances of the electronic components made. In prior art, the photolithography and etching processes of the trenches were performed between the final photolithography and etching processes of the electrically critical structures. This advantage offers the possibility of performing the critical photolithography and etching processes without changing of etching machine. This also makes it possible to optimally implement regulation loops of feed forward type. This method also has the advantage of having to perform only two critical dimensional controls instead of three like in the method of prior art. Indeed, the dimensional control performed at step S4 does not concern critical patterns regarding the formation of the electronic components.
In practice, to reach a line width D2 of around 30 nm, the photoresists used have planarizing and antireflective properties. The planarizing and antireflective properties of the photoresists are generally not sufficient to reach critical dimensions lower than 100 nm. The antireflective property is characterized by a reflection coefficient of the beam of particles emitted by the photolithography machine lower than 1%, or 0.5%. This property may be obtained using a Bottom Anti-Reflective Coating BARC formed under the photoresist layer PR′ and possibly under the layer PR. The coating BARC may be made by coating an antireflective photoresist, or by depositing (CVD—Chemical Vapor Deposition, PECVD—Plasma-Enhanced Chemical Vapor Deposition, . . . ) an organic layer (for example in amorphous carbon) and/or a dielectric layer (for example in silicon oxide SiO2, silicon nitride Si3N4, . . . ).
Another solution is to associate the layers PR and PR′ with a hard mask layer and a layer in a planarizing and antireflective material, not necessarily photosensitive.
To increase the density of the structures transferred to the layer HM, steps S7 to S10 may be repeated with masks forming complementary patterns such that the combination of masks allows high density structures to be formed. These high density structures are generally cut after being formed in the hard mask layer and before their final transfer to the layer to be etched. According to one embodiment, the steps of forming areas to be suppressed (trenches) in the hard mask layer are performed before the multiple steps of forming high density structures (lines).
In
The method which has just been described (implementing three mask projections) thus allows a line spacing to be reached, which is twice smaller than that obtained by the method previously used, implementing two mask projections (
It will be clear to those skilled in the art that the present disclosure is susceptible of various embodiments and applications. In particular, the disclosure is not limited to etching a layer of polysilicon to form gates of transistors, but may be applied to etching hard mask layers to perform doping of areas of the substrate or a layer in a semiconductor material, or etching various layers formed on a wafer in a semiconductor material.
The various layers shown in
The present disclosure is not limited either to patterns of rectangular shapes for line and cutting patterns. Other more complex polygonal pattern shapes may admittedly be transferred to the hard mask layer and the target layer.
The various embodiments described above can be combined to provide further embodiments. These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.
Number | Date | Country | Kind |
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1100662 | Mar 2011 | FR | national |