Patent Application
20090269932
The invention generally relates to a method of making a semiconductor device, and more particularly, to a method of making semiconductor pillar structures and wiring.
Devices made from semiconductor materials are used to create memory circuits in electrical components and systems. Memory circuits are the backbone of such devices as data and instruction sets are stored therein. Maximizing the number of memory elements per unit area on such circuits minimizes their cost and thus is a primary motivation in the designing of such circuits.
As the dimensions for structures formed on a semiconductor wafer diminish, tools currently available to create these devices reach their limits. By way of example, currently available 193 nanometer immersion tools will fail to create structures with a pitch of less than about 80 nm (i.e., with a half pitch of less than about 40 nm). To fabricate features smaller than this with the currently available tools, one must use more complicated processes. One such process is the technique of double exposure/double patterning. Another is the use of sidewall spacers, formed on a template pattern which is then removed. The sidewall spacers are then used as mask during etching of the underlying film or films.
For simple, one-dimensional, regular line-and-space patterns, both of these techniques have the effect of dividing the photolithographically-produced pitch by two. In this way, the resolution capability of a given photolithography tool can be extended.
However, for a two-dimensional pattern of regularly-spaced pillars, the double-patterning scheme extends the pitch by a factor of the square root of 2. The sidewall spacer method, as-is, cannot be used at all since such a scheme would produce regularly spaced cylindrical annuli, rather than solid pillars.
A method of making a semiconductor device includes forming at least one device layer over a substrate, forming at least two spaced apart features over the at least one device layer, forming sidewall spacers on the at least two features, selectively removing the spaced apart features, filling a space between a first sidewall spacer and a second sidewall spacer with a filler feature, selectively removing the sidewall spacers to leave a plurality of the filler features spaced apart from each other, and etching the at least one device layer using the filler feature as a mask.
The present inventors realized that instead of using sidewall spacers as mask for etching device layers, the sidewall spacers may instead be used as sacrificial spacers when forming the etching mask. Once the etching mask is formed, the sidewall spacers are removed and portions of the device layers located below the former sidewall spacer locations are removed to leave spaced apart devices, such as pillar shaped devices.
For example, one or more device layers are first formed over a substrate. Any suitable substrate may be used, such as a semiconductor wafer (including silicon or compound semiconductor wafers) or a metal, glass, ceramic or plastic substrate. The substrate may be covered by one or more insulating layers and/or one or more devices, such as driver circuits, may be formed on or in the substrate. The device layers may comprise semiconductor layers for semiconductor devices, electrically conductive layer or layers which form electrodes, and/or insulating layers for isolation of the semiconductor or conductive portions of the devices.
At least two spaced apart features are then formed over the device layers. Preferably, a plurality (i.e., more than two) features are formed to form a large device array. The features may be formed directly on or above semiconductor, conductive and/or insulating device layers. The features may have any shape and may be made of any material as long as these features can subsequently function as an etching mask for etching the underlying device layers.
For example, as will be described in more detail below, the features may have a cylindrical shape. However, other shapes, such as rectangular or triangular shape may also be used if rectangular or triangular devices are to be formed. The features may have any desired size, and preferably have the same width as the desired width of the underlying devices. The features should have a sufficient height or thickness to act as an etching mask. The features may comprise an electrically conductive material, such as tungsten, and may optionally be covered by a silicon nitride, titanium nitride or other hard mask material. Other materials may also be used. Alternatively, the features may comprise an insulating material, such as silicon oxide or silicon nitride, or a semiconductor material, such as polysilicon.
Sidewall spacers are then formed on the features. Sidewall spacers may be formed by conventional sidewall spacer formation methods, such as by depositing a film over the features and then anisotropically etching the film to leave sidewall spacers on the features. The spacers may be made of a conductive, insulating or semiconductor material different from that of the upper portions of the features. The sidewall spacer material can be selected i) such that it can be selectively anisotropically etched with dry etch chemistry compared to the material in at least the upper portions of the features; and ii) such that it can be selectively removed (such as isotropically etched) compared to the material in at least the upper portions of the features using a different dry or wet etch chemistry. For example, when the features comprise a hard mask material, such as amorphous carbon (also referred to as an advanced patterning film, or “APF”), tungsten, silicon nitride and/or silicon oxynitride, or other materials, the spacers may be formed from silicon oxide. When the features comprise silicon oxide, the spacers may be formed from a nitride, such as silicon nitride. Other material combinations may also be used.
After the sidewall spacers are formed, the original features are selectively removed. The removal may be performed by selective wet etching for example. The step of selectively removing comprises selectively etching the material of the original features without substantially removing the sidewall spacer material. The removal of the original features leaves the sidewall spacers spaced apart from one another.
Subsequently, the spaces between adjacent spacers are filled with so-called filler features. The filler features may be formed by forming a filler film or layer over and between the sidewall spacers, followed by planarizing the filler film to expose upper portions of the sidewall spacers. The planarization can be carried out by chemical-mechanical polishing (CMP) or etchback. The CMP process can use the upper portions of the spacers as a polish stop. For example, a TiN hard mask on the features may be used as a polish stop. The filler film may comprise the same or different material as the features. The filler film material should be different from the material of the sidewall spacers so that the sidewall spacers can be selectively etched compared to the filler features. For example, the filler film material may comprise tungsten, amorphous carbon, silicon nitride or silicon oxynitride. Alternatively, the filler film material may comprise silicon oxide when the spacers are made of material other than silicon oxide.
After the filler features are formed, the sidewall spacers are selectively removed. The removal may be performed by selective wet etching for example. The step of selectively removing comprises selectively etching the material of the sidewall spacers without substantially removing the filler feature material. The removal of the spacers leaves the filler features spaced apart from each other.
The spaced apart filler features then function as etching mask during the etching of the underlying device layers. The device layers may be etched using isotropic or anisotropic etching using the filler features as a mask. The filler features may be retained in a completed device or removed after etching the device layers. For example, the conductive filler features may be retained as portions of upper electrodes.
Any suitable devices may be formed. The devices may have a substantially cylindrical and/or substantially rectangular pillar shape, depending on the shape of the features and the filler features, as will be described in more detail below. Non-pillar shaped devices may also be formed. The devices may comprise diodes, transistors, resistors, antifuse dielectrics, fuses, resistivity-switching materials, capacitors, etc. Logic, volatile memory or nonvolatile memory devices or arrays may be formed. For example the pillar structures described in U.S. application Ser. No. 12/000,758 filed on Dec. 17, 2007 to Petti et. al., which is hereby incorporated by reference in its entirety, may be formed.
In a preferred non-limiting embodiment, a plurality of pillar shaped devices that comprise a plurality of diodes containing nonvolatile memory cells are formed. Referring to FIG. 1, U.S. Pat. No. 6,952,030, issued to Hemer et al. and entitled “High-Density Three-Dimensional Memory Cell,” hereinafter the “'030 patent” and hereby incorporated by reference in its entirety, discloses an exemplary nonvolatile memory cell which can be formed by the method of the embodiments of the present invention.
The memory cell 20 includes a vertically oriented, cylindrical pillar shaped junction diode. The term junction diode is used herein to refer to a semiconductor device with the property of non-ohmic conduction, having two terminal electrodes, and made of semiconducting material which is p-type at one electrode and n-type at the other. Examples include p-n diodes and n-p diodes, which have a p-type semiconductor material and an n-type semiconductor material in contact, such as Zener diodes, and p-i-n diodes, in which an intrinsic (undoped) semiconductor material is interposed between the p-type semiconductor material and the n-type semiconductor material.
The diode 22 and an optional antifuse dielectric 24 are interposed between top 26 and bottom 28 conductors or electrodes. The vertically oriented junction diode 22 includes a heavily doped semiconductor region 30 of a first conductivity type (such as n-type), an intermediate region 32 which is undoped semiconductor material or lightly doped semiconductor material (which will be referred to as an intrinsic region), and a heavily doped semiconductor region 34 of the second conductivity type (such as p-type) to form a p-i-n diode. If desired, the location of the p and n-type regions may be reversed. The semiconductor material of the junction diode 22 is generally silicon, germanium, or an alloy of silicon and/or germanium. Other semiconductor materials may also be used. The junction diode 22 and the antifuse dielectric 24 are arranged in series between the bottom conductor 28 and the top conductor 26, which may be formed of a metal or any other conductor, such as tungsten and/or TiN. The antifuse dielectric 24 may be located above or below the diode 22.
The memory cell may comprise a one-time programmable (OTP) or re-writable nonvolatile memory cell. For example, each diode 22 may act as a steering element of a memory cell and another material or layer 24 which acts as a resistivity switching material (i.e., which stores the data) is provided in series with the diode between the conductors. Specifically, instead of the antifuse dielectric, the resistivity switching material 24 may comprise a fuse, polysilicon memory effect material, metal oxide (such as nickel oxide, perovskite materials, etc,), carbon nanotubes, phase change materials, switchable complex metal oxides, conductive bridge elements, or switchable polymers. The resistivity of the resistivity switching material 24 may be increased or decreased in response to a forward and/or reverse bias provided between the electrodes or conductors.
Briefly, the cell 20 operates as follows. In the initial state, very little current flows through the junction diode 22 when a read voltage is applied between the top conductor 26 and the bottom conductor 28 because the antifuse dielectric 24 impedes current flow. The application of a programming voltage between the top conductor 26 and bottom conductor 28 causes dielectric breakdown of the antifuse material, permanently forming a conductive path through the antifuse 24. If the diode semiconductor material is initially formed in a high resistivity state, then the semiconductor material of diode 22 may be altered as well, changing it to a lower-resistivity state. After programming, a higher read current flows between the top conductor 26 and the bottom conductor 28 upon application of a read voltage. In this way, a programmed cell can be distinguished from an unprogrammed cell.
In alternative embodiments, the antifuse dielectric 24 may be omitted. Instead, the polycrystalline semiconductor material of diode 22 is formed in a relatively high-resistivity state, which also tends to impede current flow, as described in a U.S. patent application Ser. No. 10/955,549, “Nonvolatile Memory Cell Without a Dielectric Antifuse Having High- and Low-Impedance States,” filed by Herner et al. on Sep. 29, 2004 and hereinafter the “'549 application”; and U.S. patent application Ser. No. 11/148,530, “Nonvolatile Memory Cell Operating by Increasing Order in Polycrystalline Semiconductor Material,” filed by Herner et al. on Jun. 8, 2005 and hereinafter the “'530 application,” both hereby incorporated by reference. The application of a programming voltage lowers the resistivity state of the diode. Thus, the diode acts as a resistivity switching material in this embodiment.
Referring to
The bottom electrodes or conductors 28 can be formed either by subtractive or by Damascene methods. In a subtractive method, a conductive layer or film is patterned into spaced apart electrodes and the gaps between the electrodes are then filled with an insulating material. In a Damascene method, grooves are formed in an insulating material, a conductive layer or film is formed in the grooves and over the insulating layer, and then the conductive layer or film is planarized to leave spaced apart electrodes in the grooves.
One or more semiconductor layers 124, such as silicon or germanium or their alloys are formed over the adhesion layer 122. For example, the semiconductor layers 124 may comprise a lower n-type layer, a middle intrinsic layer and an upper p-type layer. The p-type layer may be formed by ion implantation of p-type dopants into the upper part of the intrinsic layer or by deposition of a p-type doped semiconductor layer on the intrinsic layer. The semiconductor layer 124 may be polycrystalline, amorphous, or single crystalline, and may have a thickness of between about 1000 Å and about 3000 Å, such as between about 1800 Å and 2000 Å. An optional upper adhesion layer 126, such as a TiN layer, is formed over the semiconductor layers 124. Layer 126 may have a thickness of between about 100 Å and about 300 Å, such as between about 150 Å and about 200 Å. A hard mask layer 128, such as a W or amorphous carbon layer, is formed over the adhesion layer 126. Layer 128 may be a lower antireflective layer (such as a DARC layer) that is between about 250 Å and about 750 Å thick, such as between about 400 Å and about 500 Å thick. Finally, an upper layer 130, such as a TiN, silicon nitride, or silicon oxynitride layer is formed on the hard mask layer 128.
Referring to
The features 132 are preferably arranged along a plurality of imaginary diagonal lines 136 in a rhombus or rotated square type pattern, as shown in
Alignment edge features 137 are provided adjacent to the device array boundary, as shown in
The spacers 138 fill the spaces 134 around the features 132 primarily along the plurality of diagonal lines 136, leaving discrete spaces or interstices 140 between adjacent sidewall spacers 138. Due to the annular shape of the sidewall spacers 138, the interstices have a rectangular cross sectional shape with concave sidewalls, as shown in
If desired, an optional cut masking and etching step is performed after the planarization of the filler film to remove the filler film or filler features 142 from the area outside of the device array. A photoresist layer is formed over the plurality of filler features 142. The photoresist layer is exposed such that the edges of the exposed areas intersect all of the edge features 137. Elongating or enlarging the edge features 137 thus allows for an easier alignment of this cut mask. The remaining filler film or filler features remaining in areas outside of the device array boundary that are not covered by the photoresist pattern are etched away. If desired, the cut masking and etching step can be performed prior to the planarization step.
As shown in
The spaces between the pillar devices 112 are filled with a gap fill insulating material, such as silicon oxide, to isolate the devices 112 from each other. The gap fill insulating material may be planarized by CMP or etchback.
The filler features 142 may be either retained in the final device or removed after the formation of the pillar devices 112. For example, the filler features 142 may be retained in contact with the upper part of the devices 112. The upper conductors or electrodes 26 shown in
In the next step shown in
The hard mask structures 204B are then removed by selective etching or ashing, leaving the spacers 206 spaced apart from one another, as shown in
Another alternative embodiment to form conductive electrodes is illustrated in
Formation of a first memory level has been described. Additional memory levels can be formed above this first memory level to form a monolithic three dimensional memory array. In some embodiments, conductors can be shared between memory levels; i.e. top conductor would serve as the bottom conductor of the next memory level. In other embodiments, an interlevel dielectric (not shown) is formed above the first memory level, its surface planarized, and construction of a second memory level begins on this planarized interlevel dielectric, with no shared conductors.
A monolithic three dimensional memory array is one in which multiple memory levels are formed above a single substrate, such as a wafer, with no intervening substrates. The layers forming one memory level are deposited or grown directly over the layers of an existing level or levels. In contrast, stacked memories have been constructed by forming memory levels on separate substrates and adhering the memory levels atop each other, as in Leedy, U.S. Pat. No. 5,915,167, “Three dimensional structure memory.” The substrates may be thinned or removed from the memory levels before bonding, but as the memory levels are initially formed over separate substrates, such memories are not true monolithic three dimensional memory arrays.
A monolithic three dimensional memory array formed above a substrate comprises at least a first memory level formed at a first height above the substrate and a second memory level formed at a second height different from the first height. Three, four, eight, or indeed any number of memory levels can be formed above the substrate in such a multilevel array.
Throughout this description, one layer has been described as being “above” or “below” another. It will be understood that these terms describe the position of layers and elements relative to the substrate upon which they are formed, in most embodiments a monocrystalline silicon wafer substrate; one feature is above another when it is farther from the wafer substrate, and below another when it is closer. Though clearly the wafer, or the die, can be rotated in any direction, the relative orientation of features on the wafer or die will not change. In addition, the drawings are purposefully not shown to scale and are merely representative of layers and processed layers.
The invention has been described in an illustrative manner. It is to be understood that the terminology, which has been used, is intended to be in the nature of words of description rather than of limitation.
Many modifications and variations of the invention are possible in light of the above teachings. Therefore, within the scope of the appended claims, the invention may be practiced other than as specifically described.
