This Utility Patent Application claims priority to German Patent Application No. DE 10 2007 001 130.1 filed on Jan. 4, 2007, which is incorporated herein by reference.
Integrated circuits having semiconductors with via holes, i.e. electrical contacts between two layer surfaces, are used in various technological areas. In the area of three-dimensional integration of memory devices, for example, via holes are used in order to connect the individual memory chips to each other. In the fabrication of via holes increased demands exist due to a large aspect ratio of the via holes which are passivated and filled up with an electrically conductive material. Furthermore, the electrical via holes may fulfill a plurality of technical parameters, e.g., the electrical resistance, the electrical capacity and electrical inductivity may be small.
For these and other reasons, there is a need for the present invention.
The accompanying drawings are included to provide a further understanding of the present invention and are incorporated in and constitute a part of this specification. The drawings illustrate the embodiments of the present invention and together with the description serve to explain the principles of the invention. Other embodiments of the present invention and many of the intended advantages of the present invention will be readily appreciated as they become better understood by reference to the following detailed description. The elements of the drawings are not necessarily to scale relative to each other. Like reference numerals designate corresponding similar parts.
In the following Detailed Description, reference is made to the accompanying drawings, which form a part hereof, and in which is illustrated by way of illustration specific embodiments in which the invention may be practiced. In this regard, directional terminology, such as “top,” “bottom,” “front,” “back,” “leading,” “trailing,” etc., is used with reference to the orientation of the Figure(s) being described. Because components of embodiments of the present invention can be positioned in a number of different orientations, the directional terminology is used for purposes of illustration and is in no way limiting. It is to be understood that other embodiments may be utilized and structural or logical changes may be made without departing from the scope of the present invention. The following detailed description, therefore, is not to be taken in a limiting sense, and the scope of the present invention is defined by the appended claims.
Embodiments of the present invention provide an integrated circuit and method of making an integrated circuit having a via. One embodiment may in a first process produce the electrical contact. Then the electrical contact is isolated and the layer is subsequently configured. In this manner, electrical contacts may be produced having high aspect ratios, i.e. having a high ratio considering the length of the contact with regard to its diameter.
In a further embodiment, the contact is made of carbon.
In a further embodiment, the contact is made of carbon fibers, for example of carbon tubes. The formation of carbon fibers allows for producing contacts with high Ohmic resistance and a high aspect ratio.
In a further embodiment, the layer consists of a semiconductor material, e.g., of silicon. The forming of the layer of a semiconductor material may be carried out by using a technologically simple process. The use of silicon for forming the layer allows for further integration of mechanical and/or electrical components and circuits, such as memory chips or logic chips in the layer.
In a further embodiment, the silicon may be epitaxially grown on the substrate.
In a further embodiment, a contact may be produced in the shape of a carbon fiber bundle. In this manner, contacts with good electrical properties may be produced using a process technology.
In one embodiment, a silicon oxide layer is deposited on the substrate. A silicon layer is deposited on the silicon oxide layer. A recess with a predetermined area intended for the contact is introduced into the silicon layer, whereby the recess reaches the buried silicon oxide layer. A catalyst material may be introduced into the recess. Subsequently, a carbon is deposited on the catalyst material and the contact is produced. This allows for a well-defined forming of the contact. In a further embodiment, a catalyst material may be used for forming the carbon contact. Suitable catalyst materials may be e.g., nickel, iron or cobalt or combinations thereof.
In a further embodiment of the method, an insulating layer is deposited on the substrate and on the contact in order to insulate the contact. Subsequently, the insulating layer is removed from the substrate surface to a shell surface surrounding the contact. Thereafter, the layer is deposited on the uncovered substrate and on the shell surface.
The carbon may be produced by pyrolysis of carbon-containing gases. Carbon tubes may e.g., be grown by using ethylene and water vapor.
The contact may have a height of 1 to 500 μm and a diameter of 10 nm to 100 μm.
When forming the contact from carbon, in another embodiment the carbon tubes are covered with pyrolytically deposited carbon. Thereby, the spaces between the carbon tubes are filled with carbon. This improves the electric properties of the contact. Furthermore, the carbon tubes are mechanically stabilized. In a further embodiment, the carbon tube contact is doped with charge carriers, thus improving the conductivity of the via holes. In a further embodiment, the pyrolytically deposited carbon is doped with charge carriers. This also improves the electrical properties of the via holes.
In a further embodiment, an electrically conductive layer is formed on the substrate, consisting of a carbon tube felt. The carbon tubes are subsequently infiltrated with a pyrolytically deposited carbon, e.g., by using a carbon layer. The electrically conductive layer is subsequently structured into individual contact bundles, whereby the electrically conductive layer is removed down to the contact bundles. The contact bundles are surrounded by an insulating layer and the semiconductor surface is freed from the insulating layer and cleaned. The spaces between the contact bundles are filled with a semiconductor layer. In this manner, contacts can be produced easily and with an individual geometry.
In a further embodiment of the inventive method, a layer is provided in the form of an insulating layer with at least one contact recess. The insulating layer is applied onto the substrate, whereby the contact is inserted into the contact recess. The space between the contact and the insulating layer is filled by a material. In this manner, a layer including a via hole is produced. The described method offers the advantage that the layer including the contact recess may be fabricated regardless of the substrate including the contact. Thus, various processes may be used for forming the contacts and the layer.
In an embodiment of the method, the space between the contact and the contact recess is filled with a polymer.
In a further embodiment, the carbon fibers are at least partly covered by a pyrolytically deposited carbon.
An embodiment of the present invention relates to a method in which exposed contacts are formed on a substrate and in which at least the shell surfaces of the contacts are subsequently covered by an insulating layer. Then the space between the contacts is filled with a material, such as a semiconductor material. Afterwards, electrical circuits are introduced into the material and the via hole is connected to the electrical circuit in an electrically conductive manner. Subsequently, the substrate may be removed in a further process. By using this procedure, thin material layers, such as semiconductor material including via holes, may be obtained, which may e.g., be electrically contacted in a further process from both sides of the layer. Due to the new procedure, the via holes may have high aspect ratios, since contrary to conventional methods the via holes are not fabricated by producing a via hole and by filling the via hole. In this procedure, at first the contacts for the via holes are fabricated and subsequently the layer in which the via holes are arranged is produced. In this manner, via holes with higher aspect ratios may be produced. During production, various electrically conductive materials may be used. In one embodiment, the contacts are fabricated from carbon, e.g., from carbon tubes. Carbon nano tubes may also be used for this purpose. Contrary to metals, the materials and methods used allow for high temperature further processing, as generally used in semiconductor technology.
Instead of the described method, use may also be made of other methods in which a contact 4 is formed in the shape of a carbon fiber bundle, in particular carbon tubes. The contacts 4 may also be produced by using other materials which are electrically conductive and may be produced by deposition processes.
After forming the contacts 4, at least the contacts 4 are covered by a second insulating layer, as illustrated in
In a further method process, the result of which is illustrated in
Eventually, the layer 6 including the via holes in the shape of the contacts 4, as illustrated in
In one embodiment, as illustrated in
In a further process, the substrate 1 and the insulating layer 2 may be removed as illustrated in
The insulating layer 2 may have a thickness of 10 to 100 nm. Likewise, the further layer 8 may have a thickness of 10 to 200 nm. The catalyst layers 10 may e.g., have a thickness of 0.5 nm and include nickel, iron or cobalt.
In a further process, bundles of carbon tubes are grown on the catalyst layers 10. The height of the bundles may be between 1 and 500 μm, e.g., between 1 and 100 μm. In order to deposit the carbon tubes, various methods may be used, whereby the carbon is deposited e.g., by using ethylene as a carbon source and water vapor, as described in
In a further process, the surface of the contacts 4 and the surface of the further layer 8 is covered by a second insulating layer 5. The second insulating layer 5 may for example be formed of silicon nitride and/or silicon oxide. The deposited second insulating layer 5 is removed down to the shell surface 5, thereby exposing a part of the surface of the further layer 8. For example, the entire surface of the second layer 8 is exposed down to the basic area of the shell surfaces 5. The second insulating layer 5 may be removed e.g., by back etching. The further layer 8 may also be formed of a crystalline silicon layer.
Subsequently, a layer 6 is formed between the contacts 4, i.e. between the shell surfaces 5. In one embodiment example, the layer 6 is formed as an epitaxially deposited silicon layer, whereby a silicon growth of 150 to 300 nm/min can be achieved. The silicon is e.g., deposited in a low temperature epitaxial process, selectively depositing silicon in an ultra-high vacuum by using a thermo-chemical gas deposition. In this process, disilane (Si2H6), hydrogen gas and chlorine gas may be employed at a temperature of 800° C. for deposition in a CVD reactor. Thereby, epitaxially grown silicon layers are generated, whereby layer growth may reach up to 150 nm/min at a temperature of 800° C. and a pressure of about 24 mTorr. In this process, 10% silane and hydrogen and chlorine are used having a minimal silicon:chlorine ratio of 1. Better selectivity with regard to silicon oxide and silicon nitride can be achieved by the described deposition technique, whereby low partial chlorine pressures are sufficient for ensuring selectivity. In this manner, in one embodiment the layer 6 may be formed as an epitaxial silicon layer. Subsequently, electrical circuits 7 are introduced on and/or into the layer 6. This stage of the process is illustrated in
In a further process, the substrate 1 and the insulating layer 2 are removed e.g., by an etching process. In this way, a component layer 13 may be obtained. Several component layers 13 may be arranged on top of each other, thus obtaining a stack 14 of component layers 13, as illustrated in
Eventually, a contact 4 consisting of carbon fibers, particularly carbon tubes, is disposed on the catalyst layers 10. The contact 4 may be in form of a bundle consisting of a plurality of carbon fibers or carbon tubes. The carbon fibers or the carbon tubes, respectively, are produced according to a method as already explained in conjunction with
Subsequently, in a further process carbon may be pyrolytically disposed on the contacts 4 in the form of a carbon layer 15. Thereby, the carbon fibers or the carbon tubes, respectively, are covered with carbon. As a result, for example, free spaces between the carbon fibers or carbon tubes may be at least partly or completely filled.
In a further embodiment, the carbon layer 15 may additionally be doped by using charge carriers. The doping may take place during the pyrolytic deposition of the carbon or be carried out after depositing the carbon layer 15. For doping, use can be made of nitrogen, phosphorus, arsenic or boron.
After depositing the carbon layer 15, a second insulating layer 5 is applied. The second insulating layer 5 may consist of silicon nitride or silicon oxide. This process stage is illustrated in
In a further embodiment, the carbon layer 15 is removed from the surface of the further layer 8 and the second insulating layer 5 is disposed only subsequently. The second insulating layer 5 is removed from the surface of the further layer 8 to a ring area of surrounding the contacts 4. Eventually, a layer 6 consisting of a material, e.g., silicon, is disposed between the contacts 4. The silicon may e.g., be disposed by a selective, epitaxial deposition method. After this, electrical circuits 7 are disposed in or on the layer 6, respectively. The electrical circuits 7 may be connected to the contacts 4 in an electrically conductive manner via contact lines 23, which are disposed in or on the layer 6. This process stage is illustrated in
In a further process, the substrate 1 and the insulating layer 2 are removed. In this way, a second component layer 16 is obtained. This process stage is illustrated in
By using the above-described method, a carbon layer 17 consisting of carbon tubes 20 is grown on the catalyst layer 10. The carbon layer 17 may be a felt of carbon tubes 20. Instead of the carbon tubes 20, carbon fibers may be provided as well. Thereby, the carbon tubes 20 are grown on the catalyst layer 10 and include a length of up to 100 μm. The carbon tubes 20 are arranged essentially perpendicular to the surface of the catalyst layer 10. This process stage is illustrated in
In a further process, the carbon layer 17 consisting of carbon tubes 20 and the pyrolytic carbon 15 is structured to result in electrical contacts 4, as illustrated in
Depending on the selected embodiment, the coating with the pyrolytic carbon 15 may also be carried out after structuring of the carbon layer 17 into bundles of carbon tubes 20.
The contacts 4 which are configured as bundles of carbon tubes 20 are subsequently covered by a second insulating layer 5. The insulating layer 5 and the native oxide layer on the silicon layer 10 are entirely removed from between the contacts 4 of the silicon layer 10 by etching techniques. Thereby, a spacer etching of the insulating layer is employed together with a wet etch clean using diluted hydrofluoric acid. After this, the layer 6 is formed between the contacts 4. Thereby, e.g., silicon may be formed as epitaxial silicon layer according to the method already described above. Subsequently, electrical circuits 7 are disposed in and/or on the layer 6. The electrical circuits 6 may be connected to the contacts 4 in an electrically conductive manner by using the contact lines 23. This process stage is illustrated in
In a further process, the substrate 1 and the insulating layer 2 are removed. This process stage is illustrated in
From the fourth component layer 24 illustrated in
In a following process, a carbon layer 17 consisting of carbon tubes 20 is grown on the catalyst layer 10, as already described in
Afterwards, the carbon layer 17 consisting of carbon tubes 20 may be structured to result in individual contacts 4 which are in the shape of carbon tubes 20. For this purpose, e.g., etch masks and anisotropic etching processes are used. Depending on the selected embodiment, the pyrolytic carbon layer 15 may not be deposited on the contacts 4 until the contacts 4 are formed, whereby an ion implant as well as other doping techniques may be carried out. This process stage is illustrated in
This process is illustrated in
In a further process, the substrate 1 is removed and an arrangement according to
The contacts 4 may be connected in a reflow soldering process by using the solder of the conductive layer 20. In this way, the electrical contact between the conductive layers 20 and the contacts 4 is improved.
By using the method described in conjunction with
The layer 6 already includes electric circuits 7. In this manner, a layer 6 including electric circuits 7 and second contact recesses 22 is obtained.
In a further process, the second contact recesses 22 are filled with an electrical material, such as copper by electro-plating. In this manner, a layer 6 with contacts 4 is obtained, as illustrated in
Depending on the selected embodiment, several layers may be arranged on top of each other in the form of a stack. This embodiment is illustrated in
Although specific embodiments have been illustrated and described herein, it will be appreciated by those of ordinary skill in the art that a variety of alternate and/or equivalent implementations may be substituted for the specific embodiments illustrated and described without departing from the scope of the present invention. This application is intended to cover any adaptations or variations of the specific embodiments discussed herein. Therefore, it is intended that this invention be limited only by the claims and the equivalents thereof.
Number | Date | Country | Kind |
---|---|---|---|
10 2007 001 130.1 | Jan 2007 | DE | national |