Embodiments of the present invention will be described in detail below with reference to the drawings. In the drawings to be hereinafter described, the same reference numerals designate parts having the same functions, and the repeated description of these parts is omitted.
The semiconductor device of the first embodiment comprises a silicon carbide (SiC) semiconductor base 100, which is configured of an n type silicon carbide substrate 1 and an n type silicon carbide epitaxial layer 2 formed thereon. The semiconductor device comprises a hetero-semiconductor region 3, which is made of, for example, p type single crystal silicon (Si) so as to form a heterojunction 300 with the silicon carbide epitaxial layer 2. Each end of the heterojunction 300 terminates with a field limiting region 4 made of a p type semiconductor layer. The semiconductor device comprises a cathode 7 formed in contact with the silicon carbide substrate 1, and an anode 6 formed in contact with the hetero-semiconductor region 3. Numeral 5 denotes an interlayer insulating film.
In the semiconductor device of the first embodiment, the conduction type of the hetero-semiconductor region 3 is opposite to that of the semiconductor base 100. With this configuration, the semiconductor device can achieve a reduction in leakage current and thus achieve higher breakdown voltage.
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After bonding, heating occurs at 600 degrees in an atmosphere of nitrogen. As shown in
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After the patterning of the hetero-semiconductor region 3, an oxide film is deposited to form an interlayer insulating film 5, as shown in
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As described above, the first embodiment provides the method of manufacturing the semiconductor device. The semiconductor device includes the semiconductor base 100 made of a first semiconductor material (e.g., silicon carbide employed herein); and the hetero-semiconductor region 3 made of a second semiconductor material (e.g., silicon employed herein) having a different band gap from the first semiconductor material and forming the heterojunction 300 with the semiconductor base 100. The formation of the heterojunction 300 is accomplished by bonding together the semiconductor base 100 and the substrate 200 made of the second semiconductor material.
As mentioned above, the single crystal substrate 200, such as silicon, is bonded to the semiconductor base 100, such as silicon carbide, to form the hetero-semiconductor region 3. Thus, the method of the first embodiment can form the hetero-semiconductor region 3 made of high-quality single crystal silicon, without having to use a special process such as laser anneal.
Specifically, the first embodiment has advantageous effects (1) to (4) as given below.
(1) To form a hetero-semiconductor region made of single crystals such as silicon, the earlier technology previously mentioned requires a special process such as laser anneal, which leads to an increase in the costs of manufacturing process. However, the first embodiment facilitates forming the hetero-semiconductor region 3 made of single crystals, thus enabling a reduction in the costs of manufacturing process.
(2) The earlier technology uses polycrystalline silicon in a polycrystalline, that is, unstable state to form a hetero-semiconductor region. In this case, the earlier technology must allow for a considerable margin for the conditions of manufacturing process (mainly, impurity diffusion). Moreover, impurities are prone to diffuse or segregate along grain boundaries between crystal grains. One of essentials for miniaturization is to meet strict conditions of manufacturing process, such as conductance control on minute regions. The earlier technology, however, has difficulty in meeting the strict conditions because of the foregoing problem. The earlier technology is therefore limited in the integration of unit cells and thus has difficulty in reducing on-state resistance. On the other hand, the first embodiment can form the hetero-semiconductor region 3 made of single crystals. Therefore, the first embodiment requires only a narrow range of margin for the conditions of manufacturing process (mainly, impurity diffusion), thus facilitates meeting the conditions of manufacturing process, thus has an advantage in miniaturization, and thus facilitates reducing the on-state resistance.
(3) The resistance of polycrystalline silicon for use in the earlier technology is about two to three times higher than that of single crystal silicon. This leads to high source resistance, which interferes with a reduction in on-state resistance. Since the first embodiment can form the hetero-semiconductor region 3 made of single crystal silicon, the first embodiment can reduce the source resistance and thus easily reduce the on-state resistance.
(4) A large amount of dangling bonds are present on the surfaces of crystal grains of polycrystalline silicon (that is, on the grain boundaries between the crystal grains). The dangling bonds serve as an interface state to thus reduce carrier mobility and decrease a drive current. Since the first embodiment can form the hetero-semiconductor region 3 made of single crystal silicon, the first embodiment can increase the carrier mobility and thus increase the drive current.
There is also provided the method of manufacturing the semiconductor device (specifically the diode). The diode includes the semiconductor base 100 made of the first semiconductor material; the hetero-semiconductor region 3 made of the second semiconductor material having a different band gap from the first semiconductor material and forming the heterojunction 300 with the semiconductor base 100; the cathode 7 formed in contact with the semiconductor base 100; and the anode 6 formed in contact with the hetero-semiconductor region 3. The formation of the heterojunction 300 is accomplished by bonding together the semiconductor base 100 and the substrate 200 made of the second semiconductor material. This method can achieve the same effects as mentioned above.
The method of manufacturing the semiconductor device also includes the act of implanting the hydrogen ions 201 in a predetermined region of the substrate 200; the act of bonding together the substrate 200 and the semiconductor base 100 (see
In the method of the first embodiment, the first semiconductor material is silicon carbide. Although other wide-gap semiconductor materials may be used, silicon carbide is desirable because of having the great merits in manufacturing process, such as the merit of permitting the use of thermal oxidation and the merit of facilitating conductance control on minute regions indicated by the arrows of
In the method of the first embodiment, the second semiconductor material is silicon. Although other semiconductor materials may be used, single crystal silicon is desirable because of having the great merits in manufacturing process, such as the merit of permitting the use of thermal oxidation and the merit of facilitating conductance control on the minute regions indicated by the arrows of
The semiconductor device of the second embodiment includes a p type hetero-semiconductor region 3 (which constitutes part of a single crystal silicon substrate 200); and a silicon carbide semiconductor base 100, which is configured of an n type silicon carbide layer 8 and a higher n type silicon carbide layer 9, which are formed on the hetero-semiconductor region 3. As employed herein, the term “concentration” refers to an impurity concentration. A heterojunction 300 is formed between the silicon carbide layer 8 and the hetero-semiconductor region 3. The semiconductor device includes a cathode 7 formed in contact with the higher concentration n type silicon carbide layer 9, and an anode 6 formed in contact with the hetero-semiconductor region 3 (which constitutes part of the single crystal silicon substrate 200). In
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After bonding, heating occurs at 600 degrees in an atmosphere of nitrogen. As shown in
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The method of manufacturing the semiconductor device according to the second embodiment includes: the act of implanting the hydrogen ions 201 in a predetermined region of the silicon carbide substrate 400; the act of bonding together the silicon carbide substrate 400 and the substrate 200; and the act of separating a part of the silicon carbide substrate 400 along the boundary formed by the predetermined region (specifically the hydrogen ion implanted layer 202) implanted with the hydrogen ions. In the case of the earlier technology previously mentioned, the silicon carbide substrate constitutes almost the entire area of the silicon carbide base. The silicon carbide substrate serves only as a support substrate for the silicon carbide epitaxial layer which ensures breakdown voltage, or serves only as a contact layer for the drain electrode or the cathode. When operating as the semiconductor device, the silicon carbide substrate acts merely as a resistor. Thus, the resistance of the substrate has a direct influence upon on-state resistance and interferes with a reduction in on-state resistance. When the method of manufacturing the semiconductor device according to the second embodiment is used for manufacture, the silicon carbide substrate 400 is almost wholly occupied only by the region which ensures breakdown voltage, and there is no region corresponding to the silicon carbide substrate which has heretofore acted as the resistor. Thus, the method of the second embodiment can achieve a further reduction in on-state resistance. As compared to silicon, the silicon carbide substrate is very costly and leads to an increase in manufacturing costs. In the second embodiment, the silicon carbide substrate 400, after being peeled off (see
The semiconductor device of the third embodiment includes a silicon carbide semiconductor base 100, which is configured of an n type silicon carbide substrate 1 and an n type silicon carbide epitaxial layer 2 formed thereon. A p type field limiting region 4 is formed in a predetermined region of the silicon carbide epitaxial layer 2. The semiconductor device comprises hetero-semiconductor regions 3 and 13, which are made of p type single crystal silicon and n type single crystal silicon, respectively, and are formed on the silicon carbide epitaxial layer 2 to form heterojunctions 300 with the silicon carbide epitaxial layer 2. A trench 14 is formed so as to penetrate in the depth direction through the n type single crystal silicon hetero-semiconductor region 13 and to the silicon carbide epitaxial layer 2. The semiconductor device includes a gate electrode 11 formed within the trench 14 with a gate insulating film 10 in between. The semiconductor device includes a source electrode 12 formed in contact with the hetero-semiconductor regions 3 and 13 made of p type and n type single crystal silicon, respectively; and a drain electrode 15 formed in contact with the silicon carbide substrate 1. A cap oxide film 600 provides electrical isolation between the gate electrode 11 and the p type and n type single crystal silicon hetero-semiconductor regions 3 and 13 and source electrode 12.
In the semiconductor device of the third embodiment, the hetero-semiconductor regions 3 and 13 are electrically connected and are at the same potential. Thus, respective heterojunction diodes formed by the hetero-semiconductor regions 3 and 13 are connected in parallel, thus enabling the passage of a larger current during back-flow operation. Moreover, the conduction type of the hetero-semiconductor region 3 is opposite to that of the semiconductor base 100. Thus, the semiconductor device can achieve a reduction in leakage current and thus achieve higher breakdown voltage. Moreover, a combination of the p type and n type hetero-semiconductor regions 3 and 13 yields both high reverse breakdown voltage and low on-state resistance.
The description will be given below with reference to
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After bonding, heating occurs at 600 degrees in an atmosphere of nitrogen. As shown in
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Then, the gate electrode 11 is partially subjected to thermal oxidation to thereby form a cap oxide film 600. In this step, a region coated with the silicon nitride film 103 is oxidized at an extremely slow rate, so that the cap oxide film 600 is formed only in part of the gate electrode 11, as shown in
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Incidentally, the semiconductor device (specifically the transistor) of the third embodiment may have a planar structure in which the trench 14 is not formed in the silicon carbide epitaxial layer 2 as shown in
As described above, the semiconductor device of the third embodiment is, for example, a heterojunction interface modulation device having an Si—SiC heterojunction interface, based on applications of wafer bonding technique for use in the third embodiment, an SOI (silicon on insulator) wafer, or the like. The third embodiment provides the method of manufacturing the semiconductor device (specifically the transistor). The transistor includes: the semiconductor base 100 made of a first semiconductor material; the hetero-semiconductor regions 3 and 13 having a different band gap from the first semiconductor material and forming the heterojunctions 300 with the semiconductor base 100; the gate electrode 11 disposed adjacent to the heterojunction 300 and in contact with the heterojunction 300 with the gate insulating film 10 in between; the source electrode 12 formed in contact with the hetero-semiconductor regions 3 and 13; and the drain electrode 15 formed in contact with the semiconductor base 100. The formation of the heterojunction 300 is accomplished by bonding together the semiconductor base 100 and the substrate 200 made of the second semiconductor material. The method of the third embodiment can form the hetero-semiconductor regions 3 and 13 made of single crystal silicon, that is, a source region. Thus, the method of the third embodiment can reduce source resistance, as compared to methods of earlier technology in which polycrystalline silicon is used for the hetero-semiconductor region. Therefore, the method of the third embodiment can achieve low on-state resistance. The method of the third embodiment, of course, can achieve cost reduction, because of not having to use a special process such as laser anneal. Moreover, in the third embodiment, no gap (or grain boundary) develops between crystal grains. Thus, the method of the third embodiment can perform conductance control on minute regions (that is, control of a concentration distribution of impurity diffusion) with high accuracy. In other words, the method of the third embodiment facilitates miniaturization. Therefore, the method of the third embodiment can increase the degree of integration of unit cells. Furthermore, the method of the third embodiment can reduce the occurrence of an interface state, thus reduce on-state resistance, and thus increase a drive current of the transistor.
It should be note that the above-described embodiments are for purpose of facilitating the understanding of the invention and are not intended to limit the scope of the invention. The structural components disclosed in connection with the above-mentioned embodiments are therefore intended to cover all such design changes and equivalences as fall within the technical scope of the invention. Although all the embodiments have been described above giving as an example the semiconductor device in which silicon carbide is used as the material for the semiconductor base 100, other semiconductor materials, such as silicon, silicon germanium, gallium nitride or diamond, may be used as the material for the base. In all the embodiments, silicon carbide of polytype 4H, 6H or 3C or other polytypes is available. Although the third embodiment has been described giving as an example a so-called vertical transistor in which the drain electrode 15 and the source electrode 12 are disposed facing each other with a drain region in between so as to pass a drain current in a vertical direction, a so-called lateral transistor, for example, may be used in which the drain electrode 15 and the source electrode 12 are disposed on the same main surface so as to pass a drain current in a lateral direction. Although the third embodiment has been described giving an instance in which polycrystalline silicon is used as the material for the hetero-semiconductor region 3 or 13, any material may be used provided only that it forms a heterojunction with silicon carbide. Although the first and third embodiments have been described giving an instance in which the silicon carbide base 100 configured of the silicon carbide substrate 1 and the silicon carbide epitaxial layer 2 is of the n type, it goes without saying that the base 100 may be of the p type. Although the first and third embodiments have been described giving an instance in which the single crystal silicon substrate 200 and the hetero-semiconductor region 3 are of the p type, the substrate 200 and the region 3 may be of the n type. Although the third embodiment has been described giving an instance in which n type silicon carbide (SiC) and n type polycrystalline silicon are used for the drain region and the hetero-semiconductor region 3 respectively, a combination of either n type SiC and p type polycrystalline silicon, p type SiC and p type polycrystalline silicon, or p type SiC and n type polycrystalline silicon may be used for the drain region and the hetero-semiconductor region 3.
The entire content of a Patent Application No. TOKUGAN 2004-371036 with a filing date of Dec. 22, 2004 in Japan is hereby incorporated by reference.
Although the invention is not limited to the embodiments described above. Modifications and variations of the embodiments described above will occur to those skilled in the art, in light of the teachings. The scope of the invention is defined with reference to the following claims.