The invention relates to patterned circuit features on a substrate and methods of making patterned circuits.
An etched copper or printed polymer thick film circuit pattern over a polymer film base may be referred to as a flexible circuit or flexible printed wiring board. Flexible circuits generally include a pattern of conductive traces that are supported on a base substrate such as a layer of dielectric material. Originally designed to replace bulky wiring harnesses, flexible circuitry is often the only solution for the miniaturization and movement needed for current, cutting-edge electronic assemblies. Flexible circuits offer attributes such as fine pitch traces, complex circuit designs, and flexibility. Thin, lightweight and ideal for complicated devices, flexible circuit design solutions range from single-sided conductive paths to complex, multilayer three-dimensional packages. Electronic devices, medical devices, hard disk drive suspensions, ink jet printer pens, and touch or finger sensors are common applications for flexible circuits.
Multi-layered interconnect modules are widely used in the semiconductor industry to mechanically support integrated circuit chips and electrically attach the chips to printed wiring boards. Interconnect modules can be configured to support a single chip or multiple chips, and are typically identified by the designation SCM (single chip module) or MCM (multi-chip module).
An interconnect module provides interconnections that serve to electrically couple an integrated circuit chip to signal lines, power lines, and other components carried by a printed wiring board. In particular, the interconnect module provides interconnections that redistribute the densely packed inputs and outputs (I/Os) of the chip to corresponding I/Os on the printed wiring board. In addition to electrical interconnection, an interconnect module typically serves to mechanically couple a chip to a printed wiring board, and may perform other functions such as heat dissipation and environmental protection.
One aspect of the present invention features a process comprising: providing a substrate; preparing a first patterned layer of photoresist on said substrate; depositing conductive material in the pattern formed by the photoresist to a thickness less than the thickness of the photoresist layer; preparing a second patterned layer of photoresist at least partially overlapping said first patterned layer of photoresist such that at least a portion of the conductive material is exposed; depositing additional conductive material in said pattern formed by said first and second layers of photoresist such that the height of the thickest portion of conductive material does not exceed the height of the first layer of photoresist.
Another aspect of the present invention features a process comprising: providing a substrate; applying a layer of uncured photoresist to said substrate; curing a pattern into said photoresist except in at least one portion; removing said uncured photoresist from said at least one portion thereby forming at least one first cavity in said photoresist; depositing conductive material in said first cavity to a thickness less than the thickness of the photoresist layer; applying a second layer of uncured photoresist to said photoresist and conductive material layer; curing a pattern into said photoresist except in at least one second portion, said second portion at least partially overlapping said at least one first cavity; removing said uncured photoresist from said at least one second portion thereby forming at least one second cavity in said photoresist said second cavity at least partially overlapping said at least one first cavity; and depositing conductive material in said at least one second cavity to a desired thickness, wherein the height of the thickest portion of conductive material does not exceed the height of the first layer of photoresist material.
Another aspect of the present invention features a process comprising: providing a dielectric film having a first side and a second metal-coated side; applying a layer of uncured photoresist to said second metal-coated side of said dielectric film; curing a pattern into said photoresist except in at least one portion; removing said uncured photoresist from said at least one portion thereby forming at least one cavity in said photoresist; depositing metal in said first cavity to a thickness less than the thickness of the photoresist layer; applying a second layer of uncured photoresist to said photoresist and metal layer; curing a pattern into said photoresist except in at least one second portion, said second portion partially overlapping said at least one first cavity; removing said uncured photoresist from said at least one second portion thereby forming at least one second cavity in said photoresist, said second cavity at least partially overlapping said at least one first cavity; and depositing metal in said at least one second cavity to a desired thickness, wherein the total height of the thickest portion of the metal does not exceed the height of the first layer of photoresist.
Another aspect of the present invention features a process comprising: providing a substrate; applying a layer of uncured negative photoresist to said substrate; curing a pattern into said photoresist except in at least one portion; removing said uncured photoresist from said at least one portion thereby forming at least one cavity in said photoresist; depositing conductive material in said first cavity to a thickness less than the thickness of the photoresist layer; applying a layer of positive photoresist to said negative photoresist and conductive material layer; forming a pattern of exposed positive photoresist in at least one second portion, said second portion partially overlapping said at least one first cavity, said second cavity at least partially overlapping said at least one first cavity; removing said exposed positive photoresist from said at least one portion thereby forming at least one second cavity in said photoresist; and depositing conductive material in said at least one second cavity to a desired thickness, wherein the total thickness of the highest portion of the conductive material portion of the structure does not exceed the height of the first layer of photoresist material.
Another aspect of the present invention features an article comprising: a substrate; a conductive layer having a trace pattern; and a raised feature on a portion of the trace wherein the width of the raised feature is substantially the same as the width of the portion of the trace on which it is located.
Another aspect of the present invention features an article comprising: a substrate; a conductive layer having a trace pattern; and a raised feature on a portion of the trace, the raised feature comprising at least two layers of the same or different conductive material wherein the X and Y dimensions of the two layers are substantially the same and the two layers are substantially vertically aligned.
An advantage of at least one embodiment of the present invention is that it eliminates the need for precise flexible circuit-to-phototool alignment to when patterning circuit features.
Another advantage of at least one embodiment of the present invention is that it allows circuit feature formation on finer pitch traces.
Another advantage of at least one embodiment of the present invention is that raised circuit features only need to be aligned in a non-critical direction. This allows maximization of the feature widths in the bonding area.
An advantage of at least one embodiment of the present invention is that it can tolerate an image registration error greater than or equal to 50% of the character dimension of a circuit feature.
Other features and advantages of the invention will be apparent from the following drawings, detailed description, and claims.
a to 1i depict steps of an embodiment of the method of the present invention.
a to 2e depict steps of an embodiment of the method of the present invention.
Aspects of the present invention include additive methods for producing thickness-differentiated circuit features for electronic packaging and interconnect applications. The methods use an additive process that includes the buildup of two laminated photoresist layers in conjunction with two separate circuit plating steps. The process is particularly applicable to any circuit construction, including multi-metal layer packages and fine-pitch traces on flexible circuits, for which die-attach bumps or other raised features in a circuit are required in combination with high routing density. At least one embodiment of the invention provides excellent registration of the raised features with other circuit features.
A significant advantage of at least one embodiment of the present invention is that it does not require precise alignment between the substrate and phototool to image aligned circuit features on fine pitch traces. The methods of the present invention use a combination of photoresist-on-photoresist patterning and underfilling to achieve the desired multi-level structure. The negative photoresist type can be wet or dry type. The processes described herein use a negative dry type photoresist and a substrate with only one side having a conductive coating, but is easily extendable to two-metal layer circuits with the benefit of the teachings herein.
Conventional raised circuit feature formation processes form circuit traces on dielectric film with photolithography processes and etching, then forms the raised circuit feature on these traces using a second photolithography process which requires precise alignment between the already formed traces and images of desired circuit feature. This process is limited by the alignment tolerance, and cannot be applied to fine pitch circuit that exceed the alignment capability of the equipment. In addition to this limitation, the photoresist material does not always flow into fine openings in which circuit feature are supposed to be formed.
The manufacture of a number of electronic packaging constructions, including ball grid arrays, flip-chip architectures, and other integrated circuit package (ICP) constrictions, as well as for interconnection to display panels, printed wiring boards, or additional circuit layers require the ability to generate relatively thicker raised circuit features among other relatively thinner features such as wiring traces and via pads.
In a typical additive processing methodology, these raised features are generated by defining and electroplating a relatively large “capture pad” among the other thin circuit features, and then masking all features except the capture pad, upon which a relatively smaller raised contact pad is subsequently electroplated. The capture pad must be relatively large to accommodate registration errors that are incurred during the second expose and plating steps that defines the smaller contact pad. If one assumes a maximum registration error of 8 μm, then a circular capture pad would need to have a diameter D given by
d+2δ
where d is the diameter of the smaller raised contact pad feature, to ensure that the smaller feature would be positioned on the capture pad. The extra space required for the capture pad to account for registration error results in a loss of space in which circuit traces and other features could otherwise be placed.
In the ICP business climate, however, a premium is placed on greater routing densities. At least one aspect of the processing method of the present invention could provide a competitive market advantage possibility because it produces raised circuit features without the necessity of a large capture pad.
In one embodiment of the present invention, a dielectric substrate optionally may be coated with a seed layer of chrome, nickel or alloys thereof using a vacuum sputtering technique. Then a thin layer of nickel, copper, gold, platinum, palladium or alloys thereof is deposited using a vacuum sputtering technique to created a first conductive layer having a thickness of up to about 500 nm. This is followed by a subsequent plating of a conductive material such as tin, nickel, copper, gold, platinum, palladium or alloys thereof to increase the thickness of the first conductive layer to a total of between about 1 μm and about 5 μm thick. This process may be carried out on one or both sides of the dielectric substrate. As an alternative to these steps, a dielectric substrate having a layer of conductive material laminated to one or both surface may be used. A laminated conductive layer will typically have a thickness of about 1 to 5 μm. In either case, the dielectric substrate may be a polymer film such as polyester, polyimide, liquid crystal polymer, polyvinyl chloride, acryl are or polyolefin having a thickness of about 10 μm to about 600 μm. It should be noted that suitable thicknesses are not limited to these exemplary ranges.
A first negative photoresist layer is laminated on at least one side of the dielectric substrate having the conductive coating using standard dry or wet laminating techniques. For example hot roller lamination may be done using dry film, or moisture may be added to the integral surface prior to laminating the dry film. A suitable dry film is available as SF310 from MacDermid, Inc., Waterbury, Mass. The thickness of the photoresist is from about 1 μm to about 50 μm. The photoresist is then exposed to ultraviolet light or other suitable radiation, through a mask or phototool, which crosslinks the exposed portions of the resist. Suitable energy levels are about 50 mJ/cm2 to about 500 mJ/cm2 at a wavelength of about 365 nm. The mask is a negative image of the conductive layer features, e.g., traces. The unexposed portions of the photoresist are then developed with an appropriate solvent. For example, in the case of aqueous resists a dilute aqueous solution, e.g., a 0.5-1.5% sodium or potassium carbonate solution, is applied until the unexposed portion is removed and the desired patterns are obtained. The developing may be accomplished by immersing the substrate in the solution or spraying the solution on the substrate.
Another layer of conductive material is then plated on the exposed portion of the existing conductive layer using standard electroplating or electroless plating methods to a thickness less then the thickness of the photoresist. For example if a 40 μm thick dry film photoresist were used, the additional conductive layer would be plated to a thickness of about 15 μm to about 25 μm thick on top of the 1 to 5 μm first conductive layer.
A second photoresist layer is then laminated on at least one side of the metal-coated dielectric substrate using standard dry or wet laminating techniques. For example hot roller lamination may be done using dry film, or moisture may be added to the integral surface prior to laminating the dry film. The photoresist having sufficient flow characteristics to fill in the previously formed pattern. The photoresist is then exposed to ultraviolet light or other suitable radiation, through a mask or phototool, which crosslinks the exposed portions of the resist. Suitable energy levels are about 50 mJ/cm2 to about 500 mJ/cm2 at a wavelength of about 365 nm. The photoresist layer may be imaged such that only the locations of the raised features (e.g., die attach or interconnection bumps) will not be exposed to the UV light. The unexposed portions of the photoresist are then developed with an appropriate solvent. Typically, the openings in the second photoresist layer for the raised features will be larger than the openings formed in the first photoresist layer for the raised features. The larger opening in the second photoresist layer allows for more registration error in building the raised features. A positive resist may be used instead of a negative photoresist.
Alternatively, the second photoresist layer may be imaged such that a channel is formed in the second resist layer in the region where the raised features will be located. Removal of unexposed photoresist to form the channel will result in the formation of rectangular cavities on the portions of the traces where the raised features are desired. The raised features will be formed by plating up the conductive material in the rectangular cavities. This process requires even less stringent alignment than the alternative described in the previous paragraph because it requires precise alignment of the photoresist layers in only one direction rather than two directions in the plane of the material.
Another electroplating step is used to form the raised features with the maximum height of the raised feature not exceeding the height of the first photoresist layer. Suitable conductive materials for this step include tin, nickel, copper, gold, platinum, palladium or alloys thereof.
If desired, features may be etched in the dielectric film comprising the substrate by placing the circuit into a bath of concentrated base which etches the portions of the dielectric substrate not covered by crosslinked resist. The uncovered portions of the dielectric substrate may be non-metallized portions of the substrate exposed by openings in a photoresist layer or may be on a non-metallized side of the dielectric substrate. This etching step involves contacting unmasked areas of the polymeric film with a concentrated alkaline etching fluid. Useful alkaline etchants include aqueous solutions of alkali metal hydroxides and their mixtures with amines, as described in U.S. Pat. Nos. 5,227,008 and 6,403,211, for introducing holes and related voids into dielectric films. Time requirements for controlled thinning of dielectric film depend upon the type and thickness of the polymeric film. Film etching, using an alkaline etchant heated between 50° C. and 120° C. typically requires a time from about 10 seconds to about 20 minutes.
Typically, all of the photoresist is then stripped off the circuit in a 2-5% solution of an alkaline metal hydroxide at from about 20° C. to about 80° C., preferably from about 20° C. to about 60° C. Subsequently, the exposed portion of the first conductive layer is etched with an etchant such as the peroxide sulfuric etchant available under the trade name PERMA-ETCH from Electrochemicals Inc., Maple Plain, Minn.
One embodiment of the present invention is illustrated by
Another embodiment of the present invention is illustrated by
It should be noted that the defined openings in the photoresist layers are formed without precise alignment of the second photoresist layer to the first photoresist layer. With this method of the present invention, fine pitch features can be designed in an X direction, and coarse pitch features can be designed in a Y direction. The channel defined by the second developed photoresist layer does not require precise alignment to the circuit patterns in the first photoresist layer, which circuit patterns generally extend along the X direction. Precise alignment of the channel image in the Y direction is not needed because the channel image is of a coarse pitch.
Although the previous discussions generally describe the formation of raised features with linear dimensions, e.g., squares and rectangles, the methods of the present invention may also be used to form raised features with curved dimensions, e.g., circles and ovals.
This invention may be illustrated by way of the following example.
To demonstrate this invention, an article with circuit and raised features was prepared. A 38 μm thick polyimide film with 3 μm copper on one side was used as a substrate. A 30 μm thick layer of photoresist was coated on the copper. A 50 μm trace pattern, was created by exposing portions of the photoresist to radiation (which caused it to crosslink) and developing the uncrosslinked portion of the photoresist. Next a 15 μm thick copper layer was plated on the portions of copper exposed between the remaining photoresist. Then a 30 μm thick second photoresist layer was coated on top of the structure. A 100 μm wide channel pattern was created in the second photoresist layer by exposing portions of the photoresist to radiation (which caused it to crosslink) and developing the uncrosslinked portion of the photoresist. Then a second 15 μm thick copper layer was plated on the portions of previously plated copper in the rectangular openings formed by the remaining portions of the first and second photoresist layers. The photoresist was removed to reveal traces having raised features in specific areas. Then 3 μm of copper was etched away to remove the original copper coating on the substrate, thereby isolating the traces.
Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention and it should be understood that this invention is not to be unduly limited to the illustrative embodiments set forth herein.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US04/43606 | 12/27/2004 | WO | 00 | 10/17/2006 |
Number | Date | Country | |
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60608954 | Dec 2003 | US |