Claims
- 1. A positive photo-sensitive resin composition comprising in admixture, 100 parts by weight of a photo-sensitive group-containing polybenzoxazole precursor having a polymerization degree of 2-500, obtained by polymerizing monomers (A), (S) and (C) having groups represented by the following formulas [I], [XV] and [III], respectively, ##STR33## wherein Ar.sub.1 is a divalent aromatic or heterocyclic group, ##STR34## wherein Ar.sub.4 is a tetravalent aromatic or heterocyclic group, l.sub.1 is an integer of 0-2, l.sub.2 is an integer of 1-2, the sum of l.sub.1 and l.sub.2 is 2, and Q is ##STR35## wherein Ar.sub.3 is a divalent aromatic, heterocyclic, alicyclic, silicon-containing or aliphatic group, in such proportions as to satisfy the following formula,
- (A)/[(S)+(C)]=0.9-1.1
- wherein (S) is 2-100 mole % and (C) is 0-98 mole % with the total of (S) and (C) being 100 mole %, and 1-200 parts by weight of at least one organic solvent-soluble polymer having an aromatic group and/or a heterocyclic group or its precursor (E), the polymer being selected from polyimide, polybenzoimidazole, poly-benzothiazole, polytriazole, polyoxadiazole, polythiadiazole, polybenzoxazinone, polyquinazolinedione, polyimidoisoindoloquinazolinedion, polyquinazolone, polyquinacridone, polyanthrazoline, polyindophenazine and polyhydantoin.
- 2. A positive photo-sensitive resin composition comprising in admixture:
- (i) 100 parts by weight of a polybenzoxazole precursor (D) having a polymerization degree of 2-500, obtained by polymerizing monomers (A), (B) and (C) having groups represented by the following formulas [I], [II] and [III], respectively, ##STR36## wherein Ar.sub.1 is a divalent aromatic or heterocyclic group, ##STR37## wherein Ar.sub.2 is a tetravalent aromatic or heterocyclic group,
- --NH--Ar.sub.3 --NH-- [III]
- wherein Ar.sub.3 is a divalent aromatic, heterocyclic, alicyclic, silicon-containing or aliphatic group, in such proportions as to satisfy the following formula,
- (A)/[(B)+(C)]=0.9-1.1
- wherein (B) is 2-100 mole % and (C) is 0-98 mole % with the total of (B) and (C) being 100 mole %,
- (ii) 1-200 parts by weight of at least one organic solvent-soluble polymer having an aromatic group and/or a heterocyclic group or its precursor (E), the polymer being selected from polyimide, polybenzoimidazole, polybenzothiazole, polytriazole, polyoxadiazole, polythiadiazole, polybenzoxazinone, polyquinazolinedione, polyimidoisoindoloquinazolinedione, polyquinazolone, polyquinacridone, polyanthrazoline, polyindophenazine and polyhydantoin, and
- (iii) 10-100 parts by weight of a photo-sensitive agent (H) consisting of a diazoquinone compound (F) and/or a dihydropyridine compound (G).
- 3. A positive photo-sensitive resin composition according to claim 2, wherein the polybenzoxazole precursor (D) is a condensate obtained from a dicarboxylic acid or its chloride or ester and an aromatic dihydroxydiamine compound and/or a heterocyclic dihydroxydiamine compound.
- 4. A positive photo-sensitive resin composition according to claim 3, wherein the dicarboxylic acid is at least one dicarboxylic acid selected from the group consisting of terephthalic acid, isophthalic acid and 4,4'-diphenyl ether dicarboxylic acid.
- 5. A positive photo-sensitive resin composition according to claim 3, wherein the dihydroxydiamine compound is at least one dihydroxydiamine compound selected from the group consisting of hexafluoro-2,2-bis(3-amino-4-hydroxyphenyl)propane, 3,3'-dihydroxybenzidine and 3,3'-dihydroxy-4,4'-diaminodiphenyl ether.
- 6. A positive photo-sensitive resin composition according to claim 1, wherein the organic solvent-soluble polymer having an aromatic group and/or a heterocyclic group or its precursor (E) has bonded thereto a polysiloxane unit represented by the following formula [IV]: ##STR38## wherein R.sub.1 to R.sub.2 are each a divalent aliphatic or aromatic group; R.sub.3 to R.sub.6 are each a monovalent aliphatic or aromatic group; and k is an integer of 1-100.
- 7. A positive photo-sensitive resin composition according to claim 2, wherein the organic solvent-soluble polymer or its precursor (E) is a polyamic acid.
- 8. A positive photo-sensitive resin composition according to claim 7, wherein the polyamic acid is a polyamic acid represented by the following formula [V]: ##STR39## wherein n is an integer of 1-50 and m is an integer of 2-500.
- 9. A positive photo-sensitive resin composition according to claim 2, wherein the diazoquinone compound (F) is represented by any one of the following formulas [VI] to [IX]: ##STR40## wherein Q.sub.1 to Q.sub.6 are each hydrogen atom or 1,2-naphthoquinonediazide-5-sulfonyl group, and at least one of Q.sub.1 to Q.sub.4 and at least one of Q.sub.5 to Q.sub.6 are each 1,2-naphthoquinonediazide-5-sulfonyl group.
- 10. A positive photo-sensitive resin composition according to claim 2, wherein the polybenzoxazole precursor (D) is obtained from (a) dicarboxylic acids consisting of terephthalic acid or terephthalic acid chloride and isophthalic acid or isophthalic acid chloride and (b) hexafluoro-2,2-bis(3-amino-4-hydroxyphenyl)propane, the organic solvent-soluble polymer precursor (E) is a polyamic acid represented by the formula [V], and the diazoquinone compound (F) is represented by the formula [VI].
- 11. A positive photo-sensitive resin composition according to claim 2, wherein the dihydropyridine compound (G) is represented by any one of the following formulas [X] to [XIV]. ##STR41##
Priority Claims (6)
Number |
Date |
Country |
Kind |
2-137111 |
May 1990 |
JPX |
|
2-137112 |
May 1990 |
JPX |
|
2-137113 |
May 1990 |
JPX |
|
2-154049 |
Jun 1990 |
JPX |
|
2-177376 |
Jul 1990 |
JPX |
|
3-104053 |
Feb 1991 |
JPX |
|
Parent Case Info
This application is a continuation of application Ser. No. 07/705,992, filed May 28, 1991, now abandoned.
US Referenced Citations (14)
Foreign Referenced Citations (4)
Number |
Date |
Country |
0264678 |
Apr 1988 |
EPX |
0291779 |
Nov 1988 |
EPX |
0388482 |
Sep 1990 |
EPX |
0402141 |
Dec 1990 |
EPX |
Non-Patent Literature Citations (1)
Entry |
Patent Abstracts of Japan vol. 8, No. 79 (P-267)(1516) 11 Apr. 1984 & JP-A-58 223 147 (Fuji Yakuhin Kogyo K.K.) 24 Dec. 1983 *abstract*. |
Continuations (1)
|
Number |
Date |
Country |
Parent |
705992 |
May 1991 |
|