This application claims the benefit of People's Republic of China application Serial No. 201610614946.6, filed Jul. 29, 2016, the subject matter of which is incorporated herein by reference.
The present disclosure relates in general to a semiconductor device and a manufacturing method thereof, and more particularly to a semiconductor device having a resistive random access memory (ReRAM) cell structure and a manufacturing method thereof.
ReRAM devices have advantages of such as simple structures, low operating voltages, and high compatibility with current CMOS manufacturing processes, and therefore are often used in storage devices.
Moreover, in accordance with the current trend where components having deferent functions are to be integrated into a single device, integration of ReRAM components into other devices or the manufacture and improvements of the manufacturing process thereof have become main research topics for industry.
The present disclosure is directed to a semiconductor device and a manufacturing method thereof. According to the embodiments of the semiconductor device and the manufacturing method thereof, the upper metal layer is electrically connected to and directly contacts the top electrode of the ReRAM cell structure; in other words, the manufacturing of the ReRAM cell structure is substantially integrated into the copper manufacturing process of the metal layers, such that the whole size of the semiconductor device can be effectively reduced.
According to an embodiment of the present disclosure, a semiconductor device is disclosed. The semiconductor device includes a substrate, a bottom metal layer, a resistive random access memory (ReRAM) cell structure, and an upper metal layer. The bottom metal layer is located above the substrate. The ReRAM cell structure is formed on the bottom metal layer. The ReRAM cell structure includes a bottom electrode, a memory cell layer, a top electrode, and a spacer. The memory cell layer is formed on the bottom electrode. The top electrode is formed on the memory cell layer. The spacer is formed on two sides of the bottom electrode, the memory cell layer and the top electrode. The upper metal layer is electrically connected to and directly contacting the top electrode.
According to another embodiment of the present disclosure, a semiconductor device is disclosed. The semiconductor device includes a substrate, a bottom metal layer, a plurality of ReRAM cell structures, an upper metal layer, and an air gap. The bottom metal layer is located above the substrate. The ReRAM cell structures are formed on the bottom metal layer. Each of the ReRAM cell structures includes a bottom electrode, a memory cell layer and a top electrode. The memory cell layer is formed on the bottom electrode. The top electrode is formed on the memory cell layer. The upper metal layer is electrically connected to and directly contacting the top electrode. The air gap is formed between the adjacent ReRAM cell structures.
According to a further embodiment of the present disclosure, a manufacturing method of a semiconductor device is disclosed. The manufacturing method of the semiconductor device includes the following steps: providing a substrate; forming a bottom metal layer above the substrate; forming a ReRAM cell structure on the bottom metal layer, comprising: forming a bottom electrode; forming a memory cell layer on the bottom electrode; forming a top electrode on the memory cell layer; and forming a spacer on two sides of the bottom electrode, the memory cell layer and the top electrode; and forming an upper metal layer electrically connected to and directly contacting the top electrode.
The disclosure will become apparent from the following detailed description of the preferred but non-limiting embodiments. The following description is made with reference to the accompanying drawings.
According to the embodiments of the present disclosure, a semiconductor device and a manufacturing method thereof are provided. In the embodiments, the upper metal layer is electrically connected to and directly contacts the top electrode of the ReRAM cell structure; in other words, the manufacturing of the ReRAM cell structure is substantially integrated into the copper manufacturing process of the metal layers, such that the whole size of the semiconductor device can be effectively reduced. The embodiments are described in details with reference to the accompanying drawings. The procedures and details of the manufacturing method and the structure of the embodiments are for exemplification only, not for limiting the scope of protection of the disclosure. Moreover, the identical or similar elements of the embodiments are designated with the same reference numerals. Also, it is also important to point out that the illustrations may not be necessarily be drawn to scale, and that there may be other embodiments of the present disclosure which are not specifically illustrated. Thus, the specification and the drawings are to be regard as an illustrative sense rather than a restrictive sense. It is to be noted that the drawings are simplified for clearly describing the embodiments, and the details of the structures of the embodiments are for exemplification only, not for limiting the scope of protection of the disclosure. Ones having ordinary skills in the art may modify or change the structures according to the embodiments of the present disclosure.
According to the embodiments of the present disclosure, the upper metal layer Mx is electrically connected to and directly contacts the top electrode 230 of the ReRAM cell structure 200; in other words, the manufacturing of the ReRAM cell structure 200 is substantially integrated into the copper manufacturing process of the metal layers, such that the whole size of the semiconductor device can be effectively reduced.
In an embodiment, the semiconductor device 10 is such as a ReRAM device.
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In the embodiment, the inter-metal dielectric 300 has a thickness T1 of such as 2500-3500 Å.
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In the embodiment, the via Vx-1 has a height H1 of such as 1000-1500 Å. For example, in an embodiment, the height H1 of the via Vx-1 is such as 1250 Å.
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In the embodiment, the upper metal layer Mx of the peripheral circuit area P has a height H2 that is for example larger than the height H3 of the upper metal layer Mx of the memory cell area C. For example, in an embodiment, the height H2 of the upper metal layer Mx of the peripheral circuit area P is such as 1600 Å, the height H3 of the upper metal layer Mx of the memory cell area C is such as 1350 Å, and the height H4 of the ReRAM cell structure 200 is such as 1500 Å.
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In some embodiments, the materials of the upper metal layer Mx, the via Vx-1, the bottom metal layer Mx-1, the metal layer Mx-n, and the via Vx-n are such as copper. According to the embodiments of the present disclosure, the manufacturing of the ReRAM cell structure 200 is substantially integrated into the copper manufacturing processes of the above-mentioned metal layers and vias, such that the whole size of the semiconductor device can be effectively reduced.
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In some embodiments, the bottom electrode 210 and the top electrode 230 may respectively include Ti, TiN, Ta, TaN, Pt, W, Al, Cu or any combination thereof.
In some embodiments, the material of the memory cell layer 220 may include HfOx, TaOx, TiOx, ZnOx, WOx, GdOx, IGZO, PCMO, CeOx, BaTiOx, VOx, HfSiOx, Si, BST, HoOx, SrZrOx, AlNx, BaTiOF4, BON, CoOx, GaV4S8, InOx, LaOx, NiN, SmOx, SiOx, NiOx, AlOx, graphene, BiFeO3, NbOx, SrTiOx, SiNx, CuOx, ZrOx, LSMO, ZrTiOx, CuSiOx, LaGdOx, WSiOx, BaSrTiOx, BiTiOx, carbon nanotubes (CNT), GaOx, GeS, LaAlOx, MgOx, silk, TaON, suitable organic material, or any combinations thereof.
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When a current drives the ReRAM cell structure 200 to perform operations, the material of the memory cell layer 220 would release heat. For example, when a memory cell layer 220 of one ReRAM cell structure 200 performs a write operation, and if the material of the memory cell layer 220 releases too much heat, then the diffused heat may easily influence the material of the memory cell layer 220 of an adjacent ReRAM cell structure 200. Such released and diffused heat may possibly transform the material state of the influenced memory cell layer 220 of the adjacent ReRAM cell structure 200, rendering the originally no-to-be-written adjacent memory cell layer 220 to be written, for example, the state may transform from “1” to “0” or from “0” to “1”. On the contrary, according to the embodiments of the present disclosure, the air gap 500 is formed between adjacent ReRAM cell structures 200, and the air in the air gap 500 transmits heat slower than the dielectric material of the inter-metal dielectric 300 does. For example, the thermal conductivity coefficient of air is about 0.02, and the thermal conductivity coefficient of silicon oxide is about 1. As such, the air gap 500 can reduce the heat transmission between adjacent ReRAM cell structures 200, and thus can prevent the operation failures of memory cell devices (semiconductor device 30).
Furthermore, if the heat transmission between adjacent memory cell devices is to be reduced by enlarging the widths of the memory cells, such that the size changes of the memory cells would influence the operation performances of the memory cell devices, and the enlarged widths would cause the size of the memory cell devices to increase as well. On the contrary, according to the embodiments of the present disclosure, the air gap 500 between adjacent ReRAM cell structures 200 is utilized to reduce heat transmission, such that the sizes of the memory cell devices (semiconductor device 300) are not changed, operation failures can be prevented, and the reliability of the memory cell devices (semiconductor device 300) can be further enhanced.
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In the embodiment, the manufacturing process of forming the bottom electrode 210, the memory cell layer 220, and the top electrode 230 may include the following steps. First, a bottom electrode material is formed, then a memory cell material is formed on the bottom electrode material, and then the bottom electrode material, the memory cell material, and the top electrode material are patterned by an etching process for forming the bottom electrode 210, the memory cell layer 220, and the top electrode 230.
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In the embodiment, the manufacturing process of forming the spacer 240 may include such as the following steps. A spacer material is deposited on the bottom electrode 210, the memory cell layer 220, and the top electrode 230, and then the spacer material is etched for forming the spacer 240 on the two sides of the bottom electrode 210, the memory cell layer 220, and the top electrode 230. In the embodiment, the space material may include a silicon oxide material layer and a silicon nitride material layer, and these two layers respectively form a silicon oxide layer 241 and a silicon nitride layer 243 after the etching process.
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In the embodiment, the manufacturing processes of forming the upper metal layer Mx and forming the via Vx-1 may include such as the following steps.
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Specifically speaking, the trench TR1 located above the bottom metal layer Mx-1 of the peripheral circuit area P is filled with a metal material to form the via Vx-1, and the trench TR2 is filled with a metal material to form the upper metal layer Mx. As a result, since the via Vx-1 is only formed in the peripheral circuit area P, such that the manufacturing process of the via does not influence the manufacturing processes and the structures in other areas. The ReRAM cell structure 200 in the memory cell area C does not require the manufacturing of any via and is directly electrically connected to the upper metal layer Mx through the top electrode 230, thereby the whole manufacturing process can be simplified. In addition, a height that could've possibly generated from a via has been omitted, therefore the size of the semiconductor device is reduced along the vertical direction. Furthermore, the via of the present disclosure has a relatively small height, as such the width of the via is relatively small accordingly, as such, the size of the semiconductor device is reduced along the horizontal direction as well.
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In some embodiments, in the manufacturing process of the semiconductor device 30, the dielectric material used for forming the inter-metal dielectric 300 can be preferably a dielectric material of a poorer gap fill capability. In the embodiment, the dielectric material may be for example a low-K material or fluorinated silicon oxide (FSG).
In some embodiments, the aspect ratio (height/width) of the trench between two adjacent ReRAM cell structures 200 may be such as larger than 0.5, preferably may be larger than 1, and preferably may be for example larger than 3.
While the invention has been described by way of example and in terms of the preferred embodiment(s), it is to be understood that the invention is not limited thereto. On the contrary, it is intended to cover various modifications and similar arrangements and procedures, and the scope of the appended claims therefore should be accorded the broadest interpretation so as to encompass all such modifications and similar arrangements and procedures.
Number | Date | Country | Kind |
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201610614946.6 | Jul 2016 | CN | national |