This application is based upon and claims the benefit of priority from Japanese Patent Application No. 2014-052794, filed on Mar. 14, 2014; the entire contents of which are incorporated herein by reference.
Embodiments described herein relate generally to a semiconductor device and a method for manufacturing the same.
The conversion of Si to SiC has been considered for materials in a power MOSFET. The reason for this is that when comparing SiC with Si, the forbidden bandwidth is larger and the breakdown field, the saturated drift velocity, and the thermal conductivity are higher. The one problem in the use of SiC in a MOSFET is that channel resistance is great. For example, while a 4H-SiC crystal in which the Si-face becomes the outermost face is used as the semiconductor substrate, an interface state exists between the SiC substrate and a gate insulating film, and it is thought that interface state reduces the channel mobility (μ) of a MOSFET in which SiC is used. An increase in channel mobility is desired for a MOSFET in which SiC is used.
For example, there is a method for increasing channel mobility by reducing a density of interface state by terminating interface state with nitrogen (N), including nitrogen in a gate insulating film. On the other hand, electric charges injected into the gate insulating film are trapped when an electric potential is applied to the gate insulating film if nitrogen remains excessively in the gate insulating film which is away from the interface state terminated with nitrogen. Thereby, a gate threshold voltage does not become stable when a same electric potential is applied to the gate insulating film.
According to one embodiment, semiconductor device including: a first semiconductor region of a first conductivity type; a second semiconductor region of a second conductivity type provided on the first semiconductor region; a third semiconductor region of a first conductivity type provided on the second semiconductor region, and the third semiconductor region having a higher impurity concentration than an impurity concentration of the first semiconductor region; a gate insulating film being in contact with the third semiconductor region, the second semiconductor region, and the first semiconductor region, and the gate insulating film having a region in which a nitrogen concentration becomes a lower concentration further away from a juncture portion of the third semiconductor region, the second semiconductor region, and the first semiconductor region, or being contact with the third semiconductor region, the second semiconductor region, and the first semiconductor region via a nitrogen-including layer; and a gate electrode provided on the gate insulating film.
Hereinafter, embodiments will be described below with reference to the drawings. In the following description, the same reference numeral is applied to the same member, and for members that have been described once, the description is omitted as appropriate.
The impurity concentration in
A semiconductor device 1 illustrated in
The semiconductor device 1 comprises a drain electrode 10 and a source electrode 11 aligned in the Z direction. An n-type drift region 20 (first semiconductor region) is provided between the drain electrode 10 and the source electrode 11. An n+-type drain region 21 is provided between the drain electrode 10 and the drift region 20.
A p-type base region 30 (second semiconductor region) is provided on the drift region 20. An n+-type source region 40 (third semiconductor region) is provided on the base region 30. The impurity concentration of the source region 40 is higher than the impurity concentration of the drift region 20. A p+-type contact region 35 is provided between the base region 30 and the source electrode 11. The contact region 35 is positioned beside the source region 40. The impurity concentration of the contact region 35 is higher than the impurity concentration of the base region 30. A silicide film 36 is provided between the source electrode 11 and the source region 40 and the contact region 35.
As illustrated in
The gate insulating film 51 includes a region in which the nitrogen concentration decreases further away from a juncture portion 51c that joins the gate insulating film 51 to the source region 40, the base region 30, and the drift region 20. Moreover, a region 30n in which the nitrogen is terminated is present on the surface of the base region 30 facing the gate insulating film 51.
Herein, n+-type and n-type may be referred to as a first conductivity type, and p+-type and p-type may be referred to as a second conductivity type in the embodiments. The order of n+-type and n-type and the order of p+-type and p-type indicate a decrease in the impurity concentration.
The abovementioned “impurity concentration” refers to an effective concentration of impure elements that contribute to conductivity of the semiconductor material. For example, if the semiconductor material includes an impurity element that is a donor and an impurity element that is an acceptor, the concentration excluding the portion canceled out by the donor and the acceptor among the activated impurity elements is considered the impurity concentration.
The main ingredient of the drift region 20, the drain region 21, the base region 30, the source region 40, and the contact region 35 includes silicon carbide (SiC).
Phosphorus (P) or nitrogen (N) and the like, for example, are used as the impurity element in the first conductivity type. Aluminum (Al) or boron (B), for example, are used as the impurity element in the second conductivity type.
The gate electrode 50 includes a polysilicon or a metal introduced by the impurity element. The insulating film in the embodiment includes, for example, a silicon oxide (SiOx) or a silicon nitride (SiNx) and the like.
As illustrated in
Next, as illustrated in
Nitrogen (N) remains in the gate insulating film 51. For example, an example of a nitrogen concentration profile along line A-B is illustrated in the figure on the right in
Next, as illustrated in
That is, after the stacked body 60 and the gate insulating film 51 are heated in the nitrogen- and oxygen-including gas atmosphere in the first embodiment, the surface of the base region 30 facing the gate insulating film 51 is effectively terminated with nitrogen. Moreover, the nitrogen concentration in the gate insulating film 51 is controlled so as to allow a region to be present in which the nitrogen concentration in the gate insulating film 51 decreases further away from the juncture portion 51c of the stacked body 60 and the gate insulating film 51.
Next, a description will be provided of the effects of the first embodiment.
For example, the base region 30 of the semiconductor device 1 includes 4H-SiC crystals and the Si face thereof becomes the outermost surface. The Si face that is the outermost surface is effectively terminated with nitrogen (N).
It can be seen in
However, when nitrogen remains in the gate insulating film 51 as in the nitrogen concentration profile illustrated in
For example, as illustrated in
Accordingly,
Accordingly, a nitrogen-including gas and a nitrogen- and oxygen-including gas are used and the respective heating conditions (temperature, time, atmosphere concentration, etc.) are suitably adjusted in the first embodiment. As a result, the surface of the base region 30 facing the gate insulating film 51 is terminated with nitrogen (N) and a structure in which the nitrogen concentration in the gate insulating film 51 is reduced can be formed. That is, a highly reliable semiconductor device is achieved.
The horizontal axis in
Based on the results in
In this way, while the channel mobility increases when using only the nitrogen-including gas, the threshold potential tends to fluctuate more easily when a negative bias is applied to the gate electrode. Moreover, while the channel mobility when only using the nitrogen- and oxygen-including gas is less than the channel mobility when using only the nitrogen-including gas, fluctuation of the threshold potential is less likely to occur. Accordingly, when using a nitrogen-including gas and a nitrogen- and oxygen-including gas as in the first embodiment, the channel mobility increases and fluctuation of the threshold potential is less likely to occur.
A semiconductor device 2 has, in addition to the structure of the semiconductor device 1, a nitrogen-including layer 31 that is in contact with the source region 40, the base region 30, and the drift region 20. The gate electrode 50 is in contact with the source region 40, the base region 30, and the drift region 20 through the nitrogen-including layer 31 and the gate insulating film 51. The nitrogen-including layer 31 herein is an oxide layer that has been nitrided.
As illustrated in
Next, as illustrated in
Next, in
Because the oxide layer 31a in contact with the base region 30 is nitrided in the second embodiment, the surface of the base region 30 facing the gate insulating film 51 is effectively terminated with nitrogen. Moreover, because the gate insulating film 51 is formed after forming the nitrogen-including layer 31, the gate insulating film 51 does not include nitrogen and the fluctuation of the threshold potential of the gate electrode 50 is suppressed.
The abovementioned nitrogen-including layer 31 is not limited to the second embodiment, and may be formed with the method illustrated below.
As illustrated in
Next, as illustrated in
Before nitriding the surface of the base region 30, acid cleaning may be conducted on the surface of the base region 30 and a natural oxidation film formed on the surface of the base region 30 may be removed.
Next, in
Because of the direct nitridization of the surface layer of the base region 30 in the third embodiment, the surface of the base region 30 facing the gate insulating film 51 is effectively terminated with nitrogen. Moreover, because the gate insulating film 51 is formed after forming the nitrogen-including layer 32, the gate insulating film 51 does not include nitrogen and the fluctuation of the threshold potential of the gate electrode 50 is suppressed.
While a vertical MOSFET in a planar gate structure has been illustrated in the embodiments, the gate electrode 50 may have a trench gate structure so long as the same affects are achieved. Moreover, a p+-type collector region may be interposed between the drain electrode 10 and the drain region 21 as an insulated gate bipolar transistor (IGBT).
While a vertical MOSFET with a planar gate structure which uses 4H-SiC crystals in which the outermost surface is a Si face, that is a (0001) face according to Miller index notation, is illustrated in the embodiments, the crystal face to be the outermost face may be selected and used from any crystal face as the semiconductor substrate. For example, the same effects may be achieved with a MOSFET that uses crystals in which the 4H-SiC crystal face to be the outermost surface is a {0001}, {11-20}, {10-10}, or {03-38} crystal face or an off-cut face thereof.
The term “on” when expressed as “component A is provided on component B” in the above embodiments may be used to signify that component A is provided on component B and is in contact with component B, as well as component A is provided above component B without being in contact with component B. Moreover the phrase “component A is provided on component B” may be applied to a case in which component A and component B are inverted and component A is positioned below component B, or a case where component A and component B are disposed beside each other. This is because even if the semiconductor devices according to the embodiments are rotated, the structure of the semiconductor devices does not change before or after being rotated.
The embodiments have been described above with reference to examples. However, the embodiments are not limited to these examples. More specifically, these examples can be appropriately modified in design by those skilled in the art. Such modifications are also encompassed within the scope of the embodiments as long as they include the features of the embodiments. The components included in the above examples and the layout, material, condition, shape, size and the like thereof are not limited to those illustrated, but can be appropriately modified.
Furthermore, the components included in the above embodiments can be combined as long as technically feasible. Such combinations are also encompassed within the scope of the embodiments as long as they include the features of the embodiments. In addition, those skilled in the art could conceive various modifications and variations within the spirit of the embodiments. It is understood that such modifications and variations are also encompassed within the scope of the embodiments.
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the invention.