Semiconductor device and a method of manufacturing the same.
Microfabrication of NAND flash memory devices is in progress to achieve larger storage capacity. As a result of microfabrication, a NAND flash memory device having a rocket-type cell structure is being manufactured in which the gate electrode of the memory-cell transistor is shaped like a rocket. In a device employing a rocket-type cell structure, processing of the features may become difficult as the aspect ratio increases or a gap fill error may occur during the formation of a control gate electrode. Development of flat-cell NAND flash memory device is expected to address such concerns.
In a flat-cell device, the use of a high-dielectric constant film is being proposed to serve as an interelectrode insulating film disposed between a floating gate electrode and a control gate electrode. In such structure, it is possible to reduce the programming voltage by increasing the capacitive coupling ratio of the floating gate electrode and the control gate electrode through increase in the dielectric constant of the interelectrode insulating film.
However, it is extremely difficult to form an insulating film possessing both high dielectric constant and high insulativity. Thus, increasing the dielectric constant of the interelectrode insulating film may degrade the insulativity of the interelectrode insulating film.
On the other hand, the attempt to maintain the high insulativity of the interelectrode insulating film may inhibit the reduction of the programming voltage due to failure in sufficiently increasing the dielectric constant.
A semiconductor device including a semiconductor substrate having an active region and an element isolation region, the active region isolated by the element isolation region, the element isolation region provided with an element isolation trench; a memory-cell transistor formed above the semiconductor substrate and having a gate electrode formed above the active region via a first insulating film, the gate electrode formed of a stack including a floating gate electrode, a first interelectrode insulating film, and a control gate electrode; an element isolation insulating film filled in the element isolation trench; and a second interelectrode insulating film disposed above the element isolation insulating film so as to form a stack of the second interelectrode insulating film and the control electrode above the element isolation insulating film, and a dielectric constant of the second interelectrode insulating film being higher than a dielectric constant of the first interelectrode insulating film.
Embodiments are described hereinafter with reference to the drawings. In each of the embodiments, elements that are substantially identical are identified with identical reference symbols and are not re-described. However, the drawings are schematic and thus, do not reflect the actual measurements of the features such as the correlation of thickness to planar dimensions and the ratio of thicknesses of each of the layers.
Referring first to
Memory-cell transistors Trm aligned in the X direction (corresponding to word line direction, gate width direction) as viewed in
Further, pairs of select-gate lines SGL1 of the select-gate transistors are formed so as to extend along the X direction as viewed in
Referring to
Referring to
Gate electrode MG of the memory-cell transistor is disposed above tunnel insulating film (first insulating film, gate insulating film) 7 formed above silicon substrate 1 (active region 3 of silicon substrate 1). Tunnel insulating film 7 is formed of for example a silicon oxide (SiO2). Tunnel insulating film 7 is normally insulative, but allows flow of tunnel current when a voltage of a predetermined level within the drive voltage of the NAND flash memory device is applied. Source/drain region (not shown) is formed in the surface layer portion of silicon substrate 1 so as to be located in both sides of gate electrode MG.
Above tunnel insulating film 7, silicon film B is formed which is formed of a polycrystalline silicon. Silicon film 8 serves as floating gate electrode film FG which in turn serves as a charge storing laver. Above silicon film 8, first interelectrode insulating film (IPD film) 9 is formed for example which is formed of a silicate compound (that is, oxides of Hf (hafnium), Zr (zirconium), La ((lanthanum), and Al (aluminum)). The thickness of first interelectrode insulating film 9 is approximately 12 to 30 nm for example. The dielectric constant of first interelectrode insulating film 9 is approximately 6 to 25 for example when represented in relative dielectric constant and exhibits high insulativity. Appropriate compositional ratio is specified for the components of first interelectrode insulating film 9 in order to achieve the above described dielectric constant.
Further, the position of the upper surface of element isolation insulating film 5 in element isolation region 2 is configured to be located substantially in the middle of the thickness-wise direction of the first interelectrode insulating film. Above element isolation insulating film 5, second interelectrode insulating film (IPD film) 10 is formed which is formed of for example a silicate compound (that is, oxides of Hf (hafnium), Zr (zirconium), La (lanthanum), and Al (aluminum)). The dielectric constant of second interelectrode insulating film 10, which is approximately 10 to 30 for example when represented in relative dielectric constant, is higher than the dielectric constant film of first interelectrode insulating film 9 and possesses insulativity. Appropriate compositional ratio is specified for the components of second interelectrode insulating film 10. in order to achieve the above described dielectric constant. It is acceptable for the insulativity of the second interelectrode insulating film 10 to be less than the insulativity of the first interelectrode insulating film 9. In the present embodiment, the insulativity of the first interelectrode insulating film 9 is configured to be higher than the insulativity of second interelectrode insulating film 10.
At both X-direction ends of the upper surface of second interelectrode insulating film 10, projections 10a are formed. Further, the position of portion 10b located between projections 10a at the upper surface of second interelectrode insulating film 10 is formed so as to be lower than the position of the upper surface of the first interelectrode insulating film 9.
Floating gate electrode films FG are formed above silicon substrate 1 and are arranged in a matrix along the X direction and the Y direction. Between the stacks each formed of floating gate electrode film FG and first interelectrode insulating film 9. the upper portion of element isolation insulating film 5 and second interelectrode insulating film 10 are disposed.
Above first interelectrode insulating film 9 and second interelectrode insulating film 10, conductive film 11 formed of tungsten (W) for example is formed. Control gate electrode CG extending in the X direction is formed by conductive film 11.
In the above described structure, gate stack 12 extending in the X direction is formed by the upper portion of element isolation insulating film 5, tunnel insulating film 7, floating gate electrode FG, first interelectrode insulating film 9, and control gate electrode CG. More than one gate stack 12 is provided above silicon substrate 1. An interlayer insulating film (not shown) formed of a silicon oxide for example is formed between and above gate stacks 12. Above the interlayer insulating film, upper layer wirings (not shown) including bit lines are formed.
Next, a description is given on one example of a manufacturing method of the NAND flash memory device of the present embodiment with reference to
First, as shown in
Then, a photoresist (not shown) is coated above CMP stopper film 13 and the resist is patterned by exposure and development. Next, using the patterned resist as a mask, element isolation trenches 4 (refer to
Next, sidewall insulating film 5a (refer to
Then, as illustrated in
Then, as illustrated in
Then, as illustrated in PIG. 10, planarization is carried out using CMP for example until, the upper surface of CMP stopper film 10 is exposed. Thereafter, CMP stopper film 13 is removed by wet etching for example as illustrated in
Thereafter, a line-and-space patterned hard mask (not shown) is formed so as to extend in the X direction. Then, anisotropic etching is performed using the hard mask as a mask to selectively remove conductive film 11, first interelectrode insulating film 9, second interelectrode insulating film 10, silicon film 8, tunnel insulating film 7, and the upper portion of element isolation insulating film 5 (refer to
In the above described structure, silicon film 8 is isolated along the X direction and the Y direction and serve as floating gate electrodes FG aligned in a matrix. Further, first interelectrode insulating film 9 and second interelectrode insulating film 10 serve as the IPD film. Still further, conductive film 11 is shaped into stripes extending in the X direction and serve as control gate electrodes CG.
Next, a silicon oxide film for example is deposited across the entire surface and thereafter planarized to form an interlayer insulating film (not shown) between and above gate stacks 12. Then, upper-laver wirings (riot shown) including hit lines are formed above the interlayer insulating film.
In the present embodiment structured as described above, the dielectric constant of second interelectrode insulating film 10 above STI 2 is configured to be greater than the dielectric constant of first interelectrode insulating film 9 above active region 3 as illustrated in
Further, in the above described embodiment, projections 10a are formed at both X-direction ends of the upper surface of second interelectrode insulating film 10. As a result, it is possible to reduce the programming voltage even more effectively.
More specifically, second interelectrode insulating film 10 is formed above the upper surface of first interelectrode insulating film 9, the side surface of first interelectrode insulating film 9, and the upper surface of element isolation insulating film 5 as illustrated in
In the above described structure, gate stack 12 extending in the X direction is formed by the upper portion of element isolation insulating film 5, tunnel insulating film 7, floating gate electrode FG, first interelectrode insulating film 9, second interelectrode insulating film 10, and control gate electrode CG. More than one gate stack 12 is provided above silicon substrate 1. Between and above gate stacks 12, interlayer insulating film (not shown) is provided which is formed of a silicon oxide for example. Above the interlayer insulating film, upper layer wirings (not shown) including bit lines are formed.
Next, a description will be given one example of a second embodiment of the NAND flash memory device with reference to
The manufacturing process flow up to
Next, CMP stopper film 13 is removed as illustrated in
Then, second interelectrode insulating film 10 is formed above the entire surface (the upper surface of first interelectrode insulating film 9, the side surface of first interelectrode insulating film 9, and the upper surface of element isolation insulating film 5) as illustrated in
Then, conductive film 11 formed of tungsten (b) for example, is formed above second interelectrode insulating film 10 by sputtering for example as illustrated in
Other than those described above, the structures of the second embodiment are the same as the structures of the first embodiment. Thus, it is possible to obtain the operation and effect substantially the same as those of the first embodiment in the second embodiment as well. Especially in the second embodiment, second interelectrode insulating film 10 is configured to remain above the first interelectrode insulating film 9 disposed above active region 3. Thus, it is possible to reduce the number of process steps as compared to the first embodiment.
The following structure maybe employed in addition to the embodiments described above. In each of the above described embodiments, first interelectrode insulating film 9 and second interelectrode insulating film 10 were formed of oxides of Hf, Zr, La, and Al. Apart from such materials, an insulating film may be formed by combining compounds having dielectric constants higher than a silicon oxide to obtain the desired dielectric constant.
For example, an insulating film may be formed by combining one or more of hafnia, hafnium silicate, alumina, hafnium aluminate, lanthanum oxide, lanthanum aluminate, yttrium oxide, yttrium aluminate, titanium oxide, tantalum oxide, silicon nitride, silicon nitride containing oxygen, and the like to obtain the desired dielectric constant.
Further, each of the above described embodiments were described through a NAND flash memory device application, however, other semiconductor devices provided with a flat-cell structure are also applicable.
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
This application is based upon and claims the benefit of priority from U.S. Provisional Patent Application No. 61/952,322, filed on, Mar. 13, 2014 the entire contents of which are incorporated herein by reference.
Number | Date | Country | |
---|---|---|---|
61952322 | Mar 2014 | US |