The present application claims priority from Japanese application JP 2005-333565 filed on Nov. 18, 2005, the content of which is hereby incorporated by reference into this application.
(1) Field of the Invention
The present invention relates to a linewidth calibration sample for electron beam systems used in manufacturing process of semiconductor integrated circuits and, in particular, to a calibration sample for high-precision electron beam metrology systems and a method for calibrating electron beam metrology systems.
(2) Description of Related Art
A stick-on standard sample is widely used for beam calibration of conventional electron beam systems, which is a standard component for calibration (standard sample) 26 having a one-dimensional grating pattern contained in a silicon chip and attached to a holder 27, which is then disposed on a stage 29 near a wafer under measurement, as described in JP-B2-3488745 and shown in
As semiconductor devices are reduced in size, highly precise length measurement on such semiconductor devices is demanded. According to a conventional technique, a standard component is fixed in a position separate from a wafer on a sample stage as shown in
A standard component in which a recess is formed in a wafer consisting of a single silicon layer by machining and a calibration pattern (chip) is embedded in the recess as disclosed in SPIE Microlithography 4689-59, 2002, and a brochure of VLSI Standard Inc. can be taken out from a wafer transfer route without breaking vacuum and thus can be shared among multiple systems. However, the technique of embedding a calibration pattern in a single-silicon-layer wafer has a limitation of machining precision. The height difference precision is currently approximately 10 μm at best. Another problem with the technique is that there is an error in the levelness of the machined surface. If there is a difference in height between a wafer and a calibration pattern embedded in the wafer, that is, the difference in height between a wafer under measurement and a calibration pattern, the focal position of the electron beam system also differs between them, causing an error. If the height error is corrected by using a height sensor for example, degradation in the measurement precision caused by a calibration error of the height sensor cannot be avoided.
In addition, because conventional calibration components consist of a single silicon layer, degradation in calibration precision due to the effect of roughness associated with machining cannot be avoided. The problem of roughness becomes serious as the precision required of length measurement increases.
Furthermore, to perform calibration using a one-dimensional grating pattern, a sufficient secondary electron signal contrast between lines and grooves of the one-dimensional grating pattern is required. For example, if an ArF resist or low-k materials are used, an electron beam system must be calibrated with a current of approximately 5 pA or less. However, with such a low current, the intensity of a secondary electron signal decreases and therefore a sufficient contrast cannot be obtained. As a result the reproducibility of pitch measurement decreases.
An object of the present invention is to provide a standard sample for length measurement calibration and an electron beam system calibration method capable of calibrating an electron beam system with high precision.
To achieve the object as described above, a calibration pattern, preferably a one-dimensional grating pattern, that is arranged at a predetermined pitch is formed on a wafer having approximately the same thickness and diameter as a semiconductor wafer to be measured with an electron beam metrology system, and the calibration wafer (component for length measurement calibration) is placed in the electron beam metrology system to perform beam calibration. Because the calibration wafer has the same diameter as that of the wafer to be measured, the calibration wafer can be loaded on the stage through the same transfer system that is used for loading a wafer to be measured without the need for providing a separate vacuum transport system. Furthermore, because the same sample can be used for calibration of multiple machines, variations in the precision of length measurement can be reduced.
According to the present invention, the substrate used for fabricating a calibration component has a multilayer structure including at least a first material layer that is not tolerant to an etching agent and a second material layer that has a tolerance to the etching agent in order to maintain a certain height and resolution of a pattern. The substrate is preferably an SOI or silicon on insulator (bonding) substrate or a combination of an SOI (bonding) substrate and imprint transfer. With this calibration pattern formation, a uniform height can be produced and a calibration pattern with an ideal profile can be achieved because an oxide layer, which is an insulating material inside the SOI (bonding) substrate, acts as an etch stop layer.
A calibration mark containing a one-dimensional grating pattern is formed in a silicon layer, which is a conductive material layer on the top of an SOI (bonding) substrate, for example, and the substrate is irradiated with laser. As a result of the laser irradiation, the oxide film prevents thermal conduction, and surface melting of the one-dimensional diffraction reduces the surface roughness of the pattern. By grounding the top silicon layer or applying a certain voltage to the top silicon layer, the electric potential contrast between the top silicon layer and the underlying conductive material layer, for example a silicon layer, can be enhanced, a secondary electron image with a high signal-to-noise ratio can be obtained, and a highly precise calibration of an electron beam metrology system can be performed.
According to the present invention, there is provided a standard component for length measurement calibration, comprising a first substrate including at least a first material layer having a tolerance to a first etching process, a second material layer disposed on a surface of the first material layer and is etchable by the first etching process, and a third material layer disposed on the second material layer, having a tolerance to the first etching process, and is etchable by a second etching process, wherein the first substrate has a second substrate disposed thereon, the second substrate having a calibration pattern arranged at a predetermined pitch in a region etched by the first and second etching processes to a position at which the surface of the first material layer is exposed and where the surface of the third material layer is exposed.
According to the present invention, there is provided a method for calibrating an electron beam system having an electron source and scanning or irradiating a sample with an electron beam emitted from the electron source to measure a desired pattern on the sample, comprising: using a standard component for length measurement calibration to scan a correction pattern with the electron beam, the standard component having a correction pattern provided thereon, the correction pattern having grooves arranged at a predetermined pitch on a substrate including at least a first material layer and a second material layer disposed on a surface of the first material layer, the bottom of the grooves being the surface of the first material layer; and comparing a pitch obtained from a signal waveform of the obtained reflection electrons or secondary electrons with a pitch of the one-dimensional grating pattern.
According to the present invention, there is provided a method for calibrating an electron beams system having an electron source and scanning or irradiating a sample with an electron beam emitted from the electron source to measure a desired pattern on the sample, comprising: using a standard component for length measurement calibration to scan a correction pattern with the electron beam, the standard component having an opening on a surface of a first substrate including at least a first material layer and a second material layer disposed on a surface of the first material layer, the bottom of the opening being the surface of the first material layer, the calibration pattern being formed on a second substrate disposed on the bottom of the opening and being arranged at a predetermined pitch; comparing a pitch obtained from a signal waveform of the obtained reflection electrons or secondary electrons with a pitch of the one-dimensional grating pattern.
In the method for calibrating an electron beam system mentioned above, the standard component for length measurement calibration further comprises a third material layer disposed on the surface of the second material layer.
In the method for calibrating an electron beam system mentioned above, the calibration is performed with the third material layer being grounded or supplied with a given voltage.
In the method for calibrating an electron beam system mentioned above, the calibration is performed with the third material layer being insulated from a surrounding conductor.
According to the present invention, there is provided an electron beam system having at least an electron source, a deflection unit which scans a sample with an electron beam emitted from the electron source, and an object lens and measuring a desired pattern on the sample, the electron beam system comprising: a detector which uses a standard component for length measurement to detect reflection electrons or secondary electrons generated by scanning the calibration pattern with the electron beam, the standard component for length measurement calibration having a calibration pattern provided thereon, the calibration pattern having grooves arranged at a predetermined pitch on a substrate including at least a first material layer and a second material layer disposed on a surface of the first material layer, the bottom of the grooves being the surface of the first material layer; a calculation unit which calculates a pitch on the basis of a signal of the detected secondary electrons or reflection electrons; a comparison unit which compares the calculated pitch with a stored pitch of the one-dimensional grating pattern; and a calibration unit which calibrates a measured value on the basis of the result of the comparison.
According to the present invention, there is provided an electron beam system having at least an electron source, a deflection unit which scans a sample with an electron beam emitted from the electron source, and an object lens and measuring a desired pattern on the sample, the electron beam system comprising: a detector which uses a standard component for length measurement calibration to detect reflection electrons or secondary electrons generated by scanning a calibration pattern with the electron beam, the standard component having an opening on a surface of a first substrate including at least a first material layer and a second material layer disposed a surface of on the first material layer, the bottom of the opening being the surface of the first material layer, the calibration pattern being formed on a second substrate disposed on the bottom of the opening and being arranged at a predetermined pitch; a calculation unit which calculates a pitch on the basis of the detected secondary electrons and reflection electrons; a comparison unit which compares the calculated pitch with a stored pitch of the one-dimensional grating pattern; and a calibration unit which calibrates a measured value on the basis of the result of the comparison.
In the electron beam system mentioned above, the system further comprises a memory unit which stores a position at which the calibration is performed and a correction coefficient at the calibration position, and a control unit which controls correction of a measured value on the basis of the stored calibration position and correction coefficient.
In the electron beam system mentioned above, the system further comprises a third material layer disposed on the second material layer of the standard component for length measurement calibration.
In the electron beam system mentioned above, the standard component for length measurement includes the calibration pattern in a plurality of locations; and the memory unit stores a correction coefficient at each of the locations.
Other objects, features and advantages of the invention will become apparent from the following description of the embodiments of the invention taken in conjunction with the accompanying drawings.
Specific examples of the present invention will be described below with reference to the accompanying drawings.
The diameters of semiconductor wafers used in real production recently have been increasing from 200 mm to 300 mm. It is difficult to form patterns on wafers having large diameters such as 300 mm by using electron beam lithography and laser interference lithography systems which form calibration patterns with a pitch of 200 nm or less to form patterns on wafers having large diameters as 300 mm because they can only carry and irradiate samples with limited sizes. Therefore, a calibration mark including a grating pattern is formed on a wafer having a smaller diameter and the pattern is transferred to a wafer having a larger diameter such as 300 mm. With this method, a calibration component having the same diameter as a large-diameter wafer can be fabricated.
First, a bonding substrate with a diameter of 300 mm including a underlying silicon layer 40, an oxide layer 39, and an upper silicon layer 38 with thicknesses of 50 μm, 1 μm, and 725 μm, respectively, is provided as shown in
The calibration pattern may be attached onto the oxide layer without etching the oxide layer. However, in that case, the calibration pattern will be electrically insulated by the oxide layer and therefore can be electrostatically charged. Therefore, preferably a conductive layer is provided under the oxide layer or some means for removing electrostatic charge on the calibration pattern may be provided in the system. Instead of the oxide layer, a second conductive layer tolerant to the etching agent that can etch away silicon may be provided under the upper silicon layer (first conductive material layer) in order to prevent the calibration pattern from being electrostatically charged. Because the upper layer is made of silicon in the example described above, CF gas may be used for etching. A material such as tantalum or tungsten that has a tolerance to CF gas etching may be provided under the upper silicon layer. While an SOI substrate is used as a component on which calibration marks are formed in the example described above, the substrate is not limited to an SOI substrate. Any substrate with a multilayer structure including at least a fist layer of a material not tolerant to a given etching agent and a second layer of a material tolerant to the etching agent may be used. An example may be a structure in which an opening whose bottom is the surface of a first material layer is provided in the surface of a substrate including at least the first material layer and a second material layer provided on the first material layer or a substrate further including a third material layer provided on the second material layer, and a second substrate having a height approximately equal to that of the top surface of the substrate and having a calibration pattern formed in the opening is provided.
A method for calibrating the metrology system shown in
In the case of a standard component placed on the stage in a conventional way, the difference between the height of the wafer 7 under measurement and that of a one-dimensional grating pattern was approximately 10 μm at maximum and accordingly the calibration error was 1 nm or more. Similarly, for a standard component in which a recess is formed in a wafer by machining or etching and a chip is embedded in the recess as described in SPIE Microlithography 4689-59, 2002, and a brochure of VLSI Standard Inc., the difference in height between the wafer and the one-dimensional grating pattern was in the order of 10 μm and a calibration error was 1 nm or more.
In contrast, in the wafer-shaped calibration component of the present invention, the difference between the height of the surface of a wafer under measurement placed and the height of the one-dimensional grating pattern of the wafer-shaped standard component is less than 1 μm and therefore a calibration error of 0.5 nm or less can be achieved. Furthermore, because the standard sample has a diameter approximately equal to that of a wafer under measurement, the standard sample can be loaded in and unloaded from the system through the same transfer route as a wafer under measurement without breaking vacuum, and beam calibration with high precision can be shared among multiple systems. Furthermore, the standard sample according to the present invention is not limited to the system shown in
According to the present example, the height and size of a calibration component can be made approximately equal to those of a wafer to be measured, therefore a highly precise beam calibration can be performed. Moreover, because the calibration mark can be properly placed at a position (including height) on a wafer at which measurement is to be performed, the electron beam system can be precisely calibrated. Furthermore, precise length measurement correction can be performed with high precision among multiple electron beam systems.
Another exemplary configuration of a calibration sample according to another embodiment will be described below.
First, a bonding substrate having an underlying silicon layer 45 with a thickness of 100 nm, an oxide layer 44 with a thickness of 1 μm, and an upper silicon layer 45 with a thickness of 300 mm is provided as shown in
In a conventional silicon layer 33 formed by a conventional dry etching process, the etched bottom is not flat as shown in
In calibration, the stage in
In the conventional profile shown in
Furthermore, when viewed from the upper surface, there are asperities on the one-dimensional grating pattern of the conventional calibration sample due to the influence of roughness associated with machining. Accordingly, the average deviation of variations in an area of approximately 1 nm square was 3 nm. In the present example, calibration samples are irradiated with laser light such as excimer laser in order to reduce the influence of the roughness. The laser irradiation did not cause any changes in the conventional structure because the heat of the irradiation diffused over the silicon substrate. In contrast, in the structure according to the present example as shown in
A third example will be described below.
The calibration component 7 of the first or second example is used in calibration of an electron beam metrology system. First, the calibration component 7 is placed on the stage 9 in
A sufficient secondary electron signal contrast between the lines and grooves in a one-dimensional grating pattern is required during calibration. The depth of the groove of a calibration standard component is uniform and is determined by the thickness of the upper silicon layer. For example, when an electron beam system was calibrated with a low current such as 5 pA or less as in an ArF resist or low-k material, the secondary electron signal intensity decreases and therefore a sufficient contrast was not be able to be achieved. Consequently, the average deviation of the reproducibility of pitch measurement was 10 nm.
Therefore, as shown in
A fourth example will be described below.
A calibration component 7 having multiple one-dimensional grating patterns according to the first or second example is used as a calibration sample for calibration of an electron beam metrology system. The calibration component 7 of the fourth example is held in an electron beam system using an electrostatic chucking. Although the wafer holding using electrostatic chucking equalizes the height of the wafers, it can cause electric field leakage near the edge of the wafer. As a result, an abnormal difference between the value measured in the center of the wafer to be measured and the value measured in the portion near the edge of the wafer under the influence of an electric field of electron beam deflection.
A calibration procedure will be described with reference to the examples in
Then, the pitch of a calibration pattern placed at a different position is obtained using the above described method. This operation is performed for each calibration pattern. The pitches of the one-dimensional grating patterns thus obtained are compared and the calibration positions and correction coefficients at those positions are stored in a memory unit. The calibration positions and correction coefficients may be displayed on a display unit.
When length measurement is performed, the control unit calibrates corrects measurements on the basis of the stored calibration positions and correction coefficients. By providing a calibration pattern in multiple positions on a calibration component, a standard deviation of reproducibility of pitch measurement of less than or equal to 1 nm was obtained at any positions on the wafer to be measured.
According to the fourth example, measurements obtained by an electron beam system can be precisely corrected even if the measurements depend on positions in a wafer which differ from one sample holding method to another, because the calibration mark can be placed at multiple positions on the same wafer. While the fourth example has been described with respect to a holding method using electrostatic chucking, the same effect can be obtained by using other holding methods. For example, in the case of a fixing method using a mechanical pressure, calibration errors due to the influence of warpage of a wafer can be eliminated by disposing calibration patterns near the center of a calibration wafer and concentrically around the center of a wafer.
A fifth example will be described below in which the calibration component described in the above-described example is used for calibrating more than one systems.
When semiconductor devices are manufactured, a number of wafers, for example 10 wafers, as shown in
In a process for manufacturing semiconductor devices, processing is followed by an inspection as shown in
Therefore, multiple electron beam metrology systems A, B are used depending on the number of processed wafers in the fifth example as shown in
If calibration components provided in the metrology systems are individually used to perform calibration, a difference between the calibration samples in the systems may result in a calibration error between the systems. The difference (in height for example) between calibration samples is typically of the order of 10 μm, which can result in a calibration error of approximately 1 nm in terms of measured linewidth error and poses a critical problem in high-precision measurement. A wafer-type standard component such as the one described in SPIE Microlithography 4689-59, 2002, and a brochure of VLSI Standard Inc. may be able to be used in multiple systems. However, because a one-dimensional grating pattern is embedded in the wafer, the method has a limited machining precision and therefore there is a height difference of approximately 10 μm.
Therefore, a wafer-shaped calibration component 106 having one-dimensional grating pattern provided on a multi-layer substrate consisting of a first material that does not have a tolerance to an etching agent and a second material that has a tolerance to that etching agent is used in the fifth example as shown in
Because multiple metrology systems can be calibrated with the same precision in this way, many identical processed wafers can be allocated among the multiple metrology systems and inspected. Thus, efficient production can be achieved.
It should be further understood by those skilled in the art that although the foregoing description has been made on embodiments of the invention, the invention is not limited thereto and various changes and modifications may be made without departing from the spirit of the invention and the scope of the appended claims.
Number | Date | Country | Kind |
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2005-333565 | Nov 2005 | JP | national |