Patent Application
20240172765
Wheat flour is a powder made by grinding wheat and used for human consumption. Gluten, the main protein in wheat flour, is a combination of several glutelin proteins, primarily glutenin, and is found in other grains, such as barley and rye, which gives baked goods a characteristic texture, elasticity, and taste. Wheat varieties are called “soft” or “weak” if gluten content is low and “hard” or “strong” if they have high gluten content. Hard flour, or bread flour, is high in gluten, with 12% to 14% gluten content. Its dough has elastic toughness that holds its shape well once baked. Soft flour is comparatively low in gluten and thus results in a loaf with a finer, crumbly texture. In terms of the parts of the grain used in flour—the endosperm or protein/starchy part, the germ or protein/fat/vitamin-rich part, and the bran or fiber part—there are three general types of flour. White flour is made from the endosperm only. Brown flour includes some of the grain's germ and bran, while whole grain or whole meal flour is made from the entire grain, including the bran, endosperm, and germ. Germ flour is made from the endosperm and germ, excluding the bran.
The use of wheat having higher gluten content can cause health problems to many. In addition, it is generally believed that all-purpose white flour is unhealthy because it is very high in carbohydrates that typically have a high glycemic index over 70, low in fat, low in protein, and low in fiber. Often, all-purpose flour is “fortified” to include some vitamins and mineral in an attempt to make the flour “healthier”. However, the imbalance in high carbohydrates is not offset by vitamins and minerals and can cause or exacerbate diabetes, obesity, and other health problems caused by nutritionally imbalanced and high glycemic index foods. With regard to gluten, there are mainly two kinds of harm caused by gluten: celiac disease and non-celiac gluten sensitivity (NCGS) or gluten sensitivity.
Celiac disease, sometimes called celiac sprue or gluten-sensitive enteropathy, is an immune reaction to eating gluten, a protein found in wheat, barley and rye. If a person has celiac disease, eating gluten triggers an immune response in the small intestine. Over time, this reaction damages the small intestine lining and prevents it from absorbing some nutrients (malabsorption). Intestinal damage often causes diarrhea, fatigue, weight loss, bloating, and anemia and can lead to serious complications. In children, malabsorption can also affect growth and development. There is no cure for celiac disease but, for most people, following a strict gluten-free diet can help manage symptoms and promote intestinal healing.
NCGS is a gluten-related disorder that is less serious than celiac disease but has similar symptoms and treatment. There remains much debate in the scientific community as to whether or not NCGS is a distinct clinical disorder. The pathogenesis of NCGS is not well understood but involves the activation of the innate immune system by direct cytotoxic effects of gluten and probably other wheat components. There is evidence that gliadin, a class of proteins which makes up about 70% of the protein in gluten and is the main cytotoxic antigen of gluten, may be the cause. Other proteins, such as amylase/trypsin-inhibitors named (ATIs), which are present in gluten-containing cereals (wheat, rye, barley, and their derivatives) in smaller quantities (about 2-4%) may also play a role in the development of symptoms. ATIs are potent activators of the innate immune system.
NCGS is the most common syndrome of gluten-related disorders, with prevalence rates between 0.5%-13% in the general population. As no biomarker for diagnosing this condition is available, its diagnosis is made by exclusion of other gluten-related disorders, such as celiac disease and wheat allergy. Many people have not been diagnosed following strict criteria, and there may be a fad component underlying the recent rise in popularity of gluten-free diets, leading to debate surrounding the evidence for this condition and its relationship to celiac disease and irritable bowel syndrome. People with NCGS are often unrecognized by specialists and may lack adequate medical care and treatment. They often have a long history of health complaints and unsuccessful consultations with physicians and, thus, many resort to a gluten-free diet and a self-diagnosis of gluten sensitivity.
Other problems with gluten include gluten ataxia and wheat allergy. Gluten ataxia is an autoimmune disorder that affects certain nerve tissues and causes problems with muscle control and voluntary muscle movement. Wheat allergy, like other food allergies, is the result of the immune system mistaking gluten or some other protein found in wheat as a disease-causing agent, such as a virus or bacterium. The immune system creates an antibody to the protein, prompting an immune system response that may result in congestion, breathing difficulties, brain damage, neurological problems affecting motor skills, and other symptoms.
To address gluten-related diseases or allergies, many have turned to gluten-free alternatives to wheat flour, such as gluten-free grain flours including oat flour, rice flour, or corn flour, non-grain flours such as almond flour, coconut flour, and flour blends that contain other substances, such as vegetable proteins in addition to flour. Commercially available gluten-free flours are typically made with different mixtures, that vary widely from brand to brand. They may contain rice flour, teff flour, tapioca flour, sorghum flour, potato starch, garbanzo flour, or buckwheat flour. These flours may also contain nut meals, made from very finely ground almonds or other nuts. Some of these “flours” are also low in carbohydrates.
There are several problems with alternative flours compared to all-purpose white flour, which include not working properly with existing recipes, poor taste, poor flowability, and poor quality of finished baked goods or other food products. This makes those products not only unappealing and more of a “have to eat” instead of a “want to eat” product, making them expensive and non-commercially viable for the general population at large.
Non-grain flours, like coconut flour, are made by grinding dried coconut meat. During manufacture, coconuts are first cracked open and drained of liquid. The coconut meat is then scraped out, rinsed, grated, and strained to separate the solids from the milk. The solids are then baked at a low temperature until dry before being ground into flour. The resulting white powder looks and feels similar to flour made from grains, such as wheat. Its flavor is mild. Compared with wheat flour, coconut flour is higher in fiber, protein, and certain vitamins and minerals, such as potassium and iron. However, coconut flour suffers the same fate as gluten-free flour in not working properly with existing recipes, poor taste, poor flowability, and poor quality of finished baked products or other food products, making them expensive and non-commercially viable for the general population at large.
In an attempt to make healthier flours, flours may be “blended” and include different components. An example of a “blended flour” is coconut flour blended with medium chain triglycerides (MCT) powder, a healthy oil. Because MCTs are liquid at room temperature, they must be processed to form a powder in order to be blended with other powders such as flour. In order to change liquid MCTs into solid powder form, manufacturers mix the oil with a carrier substance (usually a starch), then spray-dry the mixture into a powder form. Carrier powders used in the spray drying process are often low-quality starches that are cheap and easy to work with. MCT powders generally contain 50-80% MCTs and 20-50% starchy powder. This can be a problem for people trying to limit carbohydrates, which can raise insulin levels and cause food sensitivities. A blended flour is generally an attempt to make the resulting flour healthier. However, MCT oil often causes gastrointestinal (GI) distress when taken in even minor doses. In the case of MCT powder blended into regular wheat flour, gluten-free flour, or non-grain flour, blending does not solve the problem of GI distress often associated with the ingestion of MCT. Another problem is the tendency of coconut-MCT blended flour to separate during the mixing process, which then yields incorrect consistencies in baking, resulting in inferior quality baked products.
Other nutritional oils are used in baking, cooking, and for dietary reasons. Some oils, particularly polyunsaturated oils, can have long-term stability problems and may go rancid because of the presence of reactive unsaturated carbon-carbon bonds. Some oils like fish oil have an unpleasant taste. Other oils have temperature stability problems (i.e., low smoke point). Such oils are rarely if ever made into powder form but are added as liquids or consumed in capsules to hide their taste (e.g., fish oil, krill oil, and flaxseed oil).
A major problem with gluten-free flours is their tendency to create poor-tasting and structurally unsound products. Wheat flour and other gluten-containing grain flours typically taste better and yield more durable baked products that hold together using most baked-good recipes already formed around the use of wheat flour. To create products able to bake properly and hold together like gluten-containing flour, gluten-free products may contain substantial quantities of gums, such as carrageenan, which can also cause gastrointestinal GI problems. Gums are naturally derived food additives and include compounds such as carrageenan, xanthan gum, guar gum, and gum Arabic. They are used liberally in gluten-free baking as texture enhancers to replace the superior elastic properties typically provided by gluten. Their ability to thicken and stabilize doughs helps improve the consistency and moisture of notoriously dense and crumbly gluten-free goods. Indeed, food gums are found almost universally in commercial gluten-free baked goods, such as breads, cookies, cakes, and muffins.
Unfortunately, many gums are also fermentable in the gut and may contribute to gas and bloating in susceptible individuals, particularly when intake is high. To be clear, food gums are not considered harmful or unhealthy, and consuming fermentable carbohydrates such as those represented by gums may be healthy for their prebiotic effects. But for people more sensitive to pain associated with intestinal gas, and digestive issues, high intake of food gums may not be tolerable.
Accordingly, there is a long-felt but unsatisfied need to find ways to make wheat and other gluten flours naturally healthier as well as develop healthy alternative flours for baking that can take the place of wheat flour without having to change typical recipes and/or create poor tasting and/or structurally unsound and/or expensive baked products. There is also a long-felt but unsatisfied need to find unique and beneficial ways to deliver effective doses of MCT to a subject without causing GI upset or distress.
Disclosed herein are composite flours having improved nutritional and performance profiles compared to traditional flours and methods of making composite flours. Such composite flours can be used for baking and cooking like traditional flours but with several benefits. These include reducing or eliminating gluten, reducing carbohydrates, and incorporating healthy, energy rich effective doses of medium chain triglyceride (MCT) oil and/or other nutritional oil(s) into the diet that can provide desired nutritional profiles. MCT oil is quickly and easily metabolized into energy as a preferred energy alternative to sugar without raising insulin or glucose levels and without causing GI distress. Other nutritional oil(s) can be included instead of or in addition to MCT oil.
There are three general categories of composite flours disclosed herein: classic wheat or other gluten-containing composite flour with reduced gluten and carbohydrates, gluten-free composite flour with no gluten and reduced carbohydrate, and low carbohydrate composite flour with no gluten and significantly reduced carbohydrates. These categories are not necessarily mutually exclusive but emphasize different aspects. All three categories advantageously contain energy rich, complexed MCT oil and/or other nutritional oil(s). Classic composite flours are made from wheat or other gluten-containing flour. Gluten-free composite flours replace wheat or other gluten-containing flour with plant-based flour made from grains, seeds, nuts, or roots that do not contain gluten. Low carbohydrate composite flours are typically made from seed or nut flours that have naturally low carbohydrate content compared to classic flours and gluten-free flours that have higher carbohydrate content. Each of these flours provides a different and distinct macronutrient profile in which different health characteristics can be identified when used.
Because MCT oil and other nutritional oils are typically liquid at room temperature, the composite flours incorporate micro- and/or nano-sized MCT and/or other nutritional oil droplets or particles encapsulated by and/or complexed with a protein- and/or polysaccharide-based wall structure to form complexed nutritional oil. “MCT oil” includes one or more of C6-C12 triglycerides. In preferred embodiments, the MCT oil comprises one or more of C8 (caprylic acid) triglyceride, C10 (capric acid) triglyceride, mixture of C8 and C10 triglycerides, or C8 and C10 mixed triglyceride.
Other nutritional oils that can be used in place of or in addition to MCT oil include a wide variety of plant- and animal-derived oils. A benefit of encapsulating nutritional oils in wall material is that it can hide or mask the taste and feel of such oils, while providing desired nutritional benefits. Examples of nutritional oils include, but are not limited to, açai oil, almond oil, amaranth oil, animal fats, apricot oil, apple seed oil, argan oil, avocado oil, babassu oil, beech nut oil, ben oil, black seed oil, blackcurrant seed oil, borage seed oil, Borneo tallow nut oil, Brazil nut oil, butterfat, butternut squash seed oil, Camelina sativa oil, camellia oil, canola oil, carob pod oil, castor oil, cocklebur oil, cocoa butter, coriander seed oil, corn oil, cottonseed oil, date seed oil, egusi seed oil, fish oil, evening primrose oil, flaxseed oil, grape seed oil, hazelnut oil, hemp seed oil, kapok seed oil, kenaf seed oil, krill oil, lard, long-chain fatty acids and glycerides thereof, macadamia oil, mafura oil, marula oil, mustard oil, Niger seed oil, nutmeg butter, okra seed oil, olive oil, palm oil, papaya seed oil, peanut oil, peach kernel oil, pecan oil, perilla seed oil, persimmon seed oil, Pequi oil, pili nut oil, pine nut oil, pistachio oil, pomegranate seed oil, poppyseed oil, pracaxi oil, prune kernel oil, pumpkin seed oil, quinoa oil, ramtil oil, rice bran oil, royle oil, sacha inchi oil, safflower oil (e.g., high oleic), salicornia oil, sapote oil, seje oil, sesame oil, shea butter, short-chain fatty acids and glycerides thereof, soybean oil, sunflower oil, taramira oil, thistle oil, tigernut oil, tomato seed oil, walnut oil, watermelon seed oil, and wheat germ oil.
In preferred embodiments, the wall structure of complexed MCT comprises protein (e.g., pea protein), polysaccharide (e.g., starch) from the plant flour (e.g., gluten flour, gluten-free flour, or low carbohydrate flour), emulsifier (e.g., gum Arabic), and optional co-emulsifier (e.g., calcium and/or sodium stearoyl lactylate). In other embodiments, polysaccharide fiber (e.g., acacia fiber) can be used in addition to or in place of the protein to form the wall structure of complexed MCT oil incorporated within composite flours. The complexed MCT oil may optionally be supplemented with or at least partially replaced with one or more other nutritional oils (e.g., that contain unsaturated fatty acids, long-chain fatty acids, and/or short-chain fatty acids).
Forming complexed MCT oil and/or other nutritional oil within composite flour creates the powdered nature of MCT or other nutritional oil and maintains the stability and freshness of the complexed oil(s) and composite flour containing complexed MCT and/or other nutritional oil. Depending on the ratio of wall material to MCT and/or other nutritional oil, there may be an excess of wall material such that a portion of the wall material may form empty micelles, vesicles, or assembled complexes that do not contain and/or are not complexed with MCT and/or other nutritional oil. In some cases, “empty” micelles include a water droplet instead of MCT and/or other nutritional oil. In other cases, assembled complexes may include only wall material. Including an excess of wall material ensures that all or substantially all of the MCT and/or other nutritional oil is encapsulated by and/or complexed with wall material.
The composite flours typically comprise clusters comprised of micro- and/or nanosized particles containing complexed MCT oil and/or other nutritional oil, modified and/or unmodified plant flour particles, and excess wall material, such as nanomicelles, nanovesicles, uncombined protein, and/or uncombined emulsifier, which may form clusters with themselves, complexed MCT oil and/or other nutritional oil, or modified and/or unmodified plant flour particles. In a preferred embodiment, a portion of the wall material used to form the complexed MCT and/or other nutritional oil is provided by plant flour particles, which release starch or other polysaccharide during formation. The release of polysaccharide from plant flour yields modified plant flour particles that include protein but are depleted in polysaccharide. In some embodiments, encapsulated MCT and/or other nutritional oil droplets or particles form nutritional oil cores, and the wall structure forms shells that at least partially encapsulate the nutritional cores.
The various components that make up the composite flour may be considered to involve a physical and/or chemical transformation compared to “blended” native plant flour mixed with traditional forms of MCT oil. Such transformations yield composite flours that store well, flow well, mix well, have increased nutrition, and higher product quality (e.g., improved quality of baked goods). The composite flours have lower bulk density than flours made from the same type of flour, such as native flour and a blend of native flour and MCT powder. They also yield food products with higher volume (i.e., for a given weight or volume of composite flour used to replace traditional flour counterparts in recipes).
The composite flours disclosed herein are markedly different and perform substantially better than blended MCT flour, which is a simple dry blend of native plant (e.g., coconut) flour and typical MCT powder (e.g., MCT oil spray-dried with polysaccharide). Conventional MCT powders typically contain up to 50% polysaccharide. Thus, dry blending MCT powder with native plant flour significantly increases polysaccharide content and reduces protein content of the blended flour. Dry blending MCT powder with native flour does not alter the properties of either the MCT powder or the flour: both behave like they would in the absence of the other). Nor does directly applying MCT oil to native plant flour alter either the MCT oil or the plant flour (i.e., there is no chemical and/or physical change, as occurs when making composite plant-MCT flours as disclosed herein).
For example, consuming MCT oil in either oil form or powder form commonly causes GI problems, such as stomach upset and/or diarrhea. In contrast, the composite flours disclosed herein alter the way the body absorbs MCT oil and reduce or eliminate GI problems commonly associated with taking an effective dose of MCT oil. In addition, some of the starch or other polysaccharide from the plant flour can be incorporated into the wall material that encapsulates and/or is complexed with the MCT oil, which improves the properties and performance of the composite plant-MCT flour. Encapsulating other nutritional oils can beneficially hide and/or improve their taste while providing all the nutritional benefits.
An example embodiment of a method of manufacturing composite flour comprises: (1) forming a wall material slurry comprised of water, native plant flour containing protein and polysaccharide, added protein, and emulsifier(s); (2) combining MCT oil and/or other nutritional oil(s) with the wall material slurry to form a heterogeneous mixture; (3) subjecting the heterogeneous mixture to high speed shearing to form an emulsion comprised of modified plant flour particles depleted in polysaccharide and nutritional oil droplets or particles at least partially encapsulated by and/or complexed with wall material forming composite micelles; (4) subjecting the emulsion to high pressure nanolization to form micro- and/or nano-sized composite micelles comprising wall material that at least partially encapsulates nutritional oil droplets or particles; and (5) spray-drying the nanolized composite micelles with heated air to remove water by evaporation and form dried composite flour particles comprising modified flour particles depleted in polysaccharide and complexed nutritional oil droplets or particles encapsulated by and/or complexed with a wall structure comprised of polysaccharide released from the modified flour particles, protein, and emulsifier(s). In some embodiments, acacia fiber (a polysaccharide fiber) can be used in place of at least a portion of the added protein as wall material.
Another example embodiment of a method of manufacturing composite flour comprises: (1) forming a wall material slurry comprised of water, a first portion of native plant flour containing protein and polysaccharide, added protein, and emulsifier(s); (2) combining MCT oil and/or other nutritional oil(s) with the wall material slurry to form a heterogeneous mixture; (3) subjecting the heterogeneous mixture to high speed shearing to form an emulsion comprised of modified plant flour particles depleted in polysaccharide and nutritional oil droplets or particles at least partially encapsulated by and/or complexed with wall material forming composite micelles; (4) subjecting the emulsion to high pressure nanolization to form micro- and/or nano-sized composite micelles comprising wall material that at least partially encapsulates nutritional oil droplets or particles; (5) spray-drying the nanolized composite micelles with heated air to remove water by evaporation and form partially dried intermediate composite flour particles that are somewhat moist; and (6) mixing the intermediate composite flour particles with a second portion of native plant flour to form a final composite flour, wherein at least some of the second portion of native plant flour particles form agglomerates with intermediate composite flour particles. The final composite flour comprises modified flour particles depleted in polysaccharide, complexed MCT and/or other nutritional oil droplets or particles encapsulated by and/or complexed with a wall structure comprised of polysaccharide released from the modified plant flour particles, protein or polysaccharide fiber, and emulsifier and/or co-emulsifier, and unmodified plant flour particles, at least some of which are agglomerated with composite flour particles. In some embodiments, the first and second portions of native plant flour can be the same flour or different flours. For example, the first portion of native plant flour can have a relatively high quantity of polysaccharide that can form part of the wall structure, and the second first portion of native plant flour can be a low carbohydrate plant flour having a relatively low quantity of polysaccharide.
The use of high-speed shearing to form the emulsion causes at least some of the native flour particles to release polysaccharide (e.g., starch), which results in a physical and/or chemical transformation of native plant flour to form modified plant flour particles. The polysaccharide released from the native plant flour combine with the added protein (or acacia fiber, for example) and emulsifier(s) to form a new type of composite wall material. This composite wall material encapsulates and/or forms a complex with MCT oil droplets or particles to form a new type of composite flour particles having advantageous properties not found in traditional flours or blended MCT flours. The composite flours disclosed herein include composite flour-MCT and/or other nutritional oil particles that have been physically and/or chemically transformed relative to native plant flour and nutritional oil starting materials.
In some embodiments, dried composite flour particles made by the preceding processes can be the final composite flour product. In other embodiments, the dried composite flour particles can be mixed and sieved to produce a refined composite flour product with more uniform particle size. The larger particles removed by sieving can be reground and added back to the refined composite flour product, used as a coarser composite flour product for making food products, and/or recycled back to the wall material slurry and/or heterogeneous mixture used to form the emulsion in the processes above.
In some embodiments, the composite flour can be blended with one or more other materials to form a blended flour product. For example, a first composite flour made using a first native flour (or flour blend) can be blended with a second composite flour made using a different native flour (or flour blend). Alternatively, a composite flour or composite flour mixture can be blended with one or more native flours to form a blended flour product having desired nutritional and/or performance properties.
The composite flours disclosed herein can replace and/or supplement traditional flours to make food products, such as baked goods, fried goods, boiled goods, and non-cooked goods, including but not limited to, breads, biscuits, rolls, buns, cakes, cupcakes, pies, bagels, muffins, flatbread, cakes, brownies, pastries, cookies, crackers, tarts, puff pastries, donuts, tarts, turnovers, crepes, pancakes, waffles, crumpets, cornbread, muffuletta, breaded meats, dumplings, pasta, noodles, tortellini, ravioli, ice cream, yogurt, and the like.
In some cases, the composite flours disclosed herein can increase the volume of products made compared to traditional flours (e.g., all-purpose white flour). The volume increase can be 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45% or 50% compared to an equivalent quantity of all-purpose white flour (on a volume and/or weight basis). The result is a greater quantity (volume) of food product made using the same quantity of composite flour and/or a reduced quantity of composite flour to make a given quantity of food product.
Food products made using the composite flours are reportedly more moist, fluffier, lighter in taste, and sometimes sweeter, even when less sweetener is used, than food products made using traditional flour. The composite flour may allow for a reduction in the amount of oil and/or sugar that would otherwise be required to yield a product of desired taste and quality. Such reduction can yield lower calorie food products. Food products made using composite flours disclosed herein have been found to stay fresher longer, e.g., before becoming stale, developing mold, becoming rancid, and the like. Protein- and/or polysaccharide-complexed MCT oil in the flour reduces or eliminates GI tract issues otherwise caused by consuming MCT oil. The composite flours reduce glycemic spikes because they have lower carbohydrate load, higher protein content, higher fat content, and increased digestive time of the polysaccharides because of how they are incorporated into the wall material. Composite flours may contain one or more optional supplemental oils (e.g., that contain unsaturated fats), which can provide a source of omega-3 and omega-6 polyunsaturated fatty acids, which are essential fatty acids that provide health benefits when not consumed in excess and provided in the correct ratio.
Additional features and advantages will be set forth in part in the description that follows, and in part will be obvious from the description, or may be learned by practice of the embodiments disclosed herein. It is to be understood that both the foregoing brief summary and the following detailed description are exemplary and explanatory only and are not restrictive of the embodiments disclosed herein or as claimed.
To further clarify the above and other advantages and features of the present invention, a more particular description of the invention will be rendered by reference to specific embodiments thereof which are illustrated in the appended drawings. It is appreciated that these drawings depict only typical embodiments of the invention and are therefore not to be considered limiting of its scope. The invention will be described and explained with additional specificity and detail through the use of the accompanying drawings, in which:
Composite flours disclosed herein have improved nutritional and performance profiles compared to traditional plant and blended flours. Composite flours incorporate complexed MCT and/or other nutritional oil(s), which comprise nutritional oil droplets or particles encapsulated by and/or complexed with a wall structure comprised of protein and/or polysaccharide, emulsifier, and optionally co-emulsifier.
Three general categories of composite flours disclosed herein include classic wheat or other gluten-containing composite flour with reduced gluten and carbohydrates, gluten-free composite flour, and low carbohydrate composite flour. Classic composite flours are made from wheat or other gluten-containing flour. Gluten-free composite flours replace wheat or other gluten-containing flour with plant-based flour made from grains, seeds, nuts, or roots that do not contain gluten. Low carbohydrate composite flours are typically made from seed or nut flours that have naturally low carbohydrate content compared to classic flours and gluten-free flours that have higher carbohydrate content.
The composite flours disclosed herein perform substantially better than blended MCT flours, which are simple dry blends of native plant (e.g., coconut) flour and traditional MCT powder (e.g., MCT oil spray-dried with polysaccharide). Dry blending MCT powder with native flour does not alter the properties of either the MCT powder or the flour: both behave like they would in the absence of the other. Nor does directly applying MCT oil to native plant flour alter either the MCT oil or the plant flour (i.e., there is no chemical and/or physical change, as occurs when making the composite plant-MCT flours disclosed herein).
Consuming MCT oil in either oil form or powder form commonly causes GI upset and/or diarrhea. In contrast, the disclosed composite flours alter the way the body absorbs MCT and reduces or eliminates GI problems commonly associated with MCT consumption. Encapsulating and/or complexing MCT oil with wall material comprising protein and carbohydrate beneficially balances fat, protein and carbohydrates, aiding in better digestibility. Composite flours may optionally contain one or more other nutritional oils (e.g., that contain unsaturated fatty acids, long-chain fatty acids, and/or short-chain fatty acids), which can supplement and/or replace at least a portion of the MCT oil. One or more other nutritional oils, when included, can provide a source of omega-3 and omega-6 polyunsaturated fatty acids, which are essential fatty acids that provide health benefits when not consumed in excess and provided in the correct ratio. Long-chain fatty acids provide a source of fat. Short-chain fatty acids can improve gut health.
In addition, incorporating starch or other polysaccharide from the plant flour into the wall material that encapsulates and/or is complexed with MCT and/or other nutritional oil improves nutrition and other properties and performance of the composite flour.
There are three general categories of composite flours: classic wheat or other gluten-containing composite flour with reduced gluten and carbohydrate, gluten-free composite flour, and low carbohydrate composite flour. These categories are not necessarily mutually exclusive but emphasize different aspects. Classic composite flours are made from wheat or other gluten-containing flour. Gluten-free composite flours replace wheat or other gluten-containing flour with plant-based flour made from grains, seeds, nuts, or roots that do not contain gluten. Low carbohydrate composite flours can be made using seed or nut flours that have naturally low carbohydrate content compared to classic flours and gluten-free flours that have high carbohydrate content. Each of these flours provides a different and distinct macronutrient profile in which different health characteristics can be identified when used.
Composite flours disclosed herein comprise protein- and/or polysaccharide-complexed MCT and/or other nutritional oil and plant flour particles homogeneously blended with the complexed nutritional oil. At least a portion of the plant flour particles are depleted in polysaccharide and are therefore modified plant flour particles. The protein- and/or polysaccharide-complexed MCT and/or other nutritional oil comprises nutritional oil droplets or particles encapsulated by and/or complexed with a wall material comprising protein and/or polysaccharide fiber (e.g., acacia fiber), polysaccharide from the plant flour, emulsifier, and optional co-emulsifier. In preferred embodiments, starch or other polysaccharide released from the plant flour particles advantageously forms a portion of the wall structure and makes it more durable. In some embodiments, nutritional oil droplets or particles form nutritional oil cores and protein- and/or polysaccharide-based wall structure forms shells that at least partially encapsulate the nutritional oil cores.
Classic wheat or other gluten-containing composite flours comprise plant flour particles that include and/or are derived from one or more gluten flours, such as one or more of wheat flour, barley flour, rye flour, spelt flour, graham flour, or triticale flour. In some embodiments, composite flours have reduced gluten and carbohydrates per unit and are more nutritionally balanced compared to corresponding plant flour(s). It has been found that composite flours made from wheat flour can be used in place of different types of flour such as all-purpose flour, bread flour, or cake flour without sacrificing performance, and in some cases improving performance, compared to the corresponding plant flour.
Wheat flour can be sub-classified based on gluten content, intended use, and optionally other criteria. Examples include all-purpose flour (bleached or unbleached), bread flour (bleached or unbleached), cake flour (bleached or unbleached), pastry flour (bleached or unbleached), self-rising flour (bleached or unbleached), instant flour, and “00” flour. Whole wheat flour can be bleached or unbleached.
Example gluten-free flours include, but are not limited to, oat flour, corn flour, white rice flour, buckwheat flour, sorghum flour, amaranth flour, teff flour, arrowroot flour, brown rice flour, chickpea flour, tapioca flour, cassava flour, tigernut flour, soy flour, potato flour, millet flour, and quinoa flour.
Example gluten-free and low carbohydrate seed, nut, or vegetable flours, include, but are not limited to, coconut flour, almond flour, peanut flour, sesame flour, sunflower seed flower, hazelnut flour, walnut flour, soy flour, flaxseed (linseed) flour, fava bean flour, pumpkin seed flour, lupine flour, red lentil flour, and white bran flour.
Example wheat flours include white flour, all-purpose flour, and whole wheat flour. Wheat flour is available in many varieties. Categorization can be regional, and the same name may have several different regional meanings. In the United States, for example, flours are typically categorized by gluten/protein content, processing, and use.
“All-purpose flour” (also known as “plain flour”) is a blended wheat flour with a protein content lower than bread flour, ranging from 9% to 12%. Depending on brand or the region where it is purchased, all-purpose flour may be composed of hard or soft wheats, but is typically a blend of both, and can range from low to moderately high protein content. All-purpose flour is marketed as an inexpensive alternative to bakers' flour and is acceptable for most baking needs.
“Bread flour” or “strong flour” is made from hard wheat, usually hard spring wheat. It has a relatively high protein content, between 10% and 13%, making it excellent for yeast bread baking. It can be white or whole wheat or in between.
“Cake flour” is a finely milled white flour made from soft wheat. It has relatively low protein content, between 8% and 10%, making it suitable for soft-textured cakes and cookies. The higher protein content of other flours would make the cakes tough. Related to cake flour are masa harina (from maize), maida flour (from wheat or tapioca), and pure starches.
“Durum flour” is made from Durum wheat and is suited for pasta making, traditional pizza, and flatbread for doner kebab.
“Graham flour” is a special type of whole wheat flour. The endosperm is finely ground, as in white flour, while the bran and germ are coarsely ground. Graham flour is uncommon outside of the United States (except for see atta flour, a similar product). Graham flour is the basis of true graham crackers.
“Instant flour” is pregelatinized (precooked) for easier incorporation in gravies and sauces.
“Pastry flour” or “cookie flour” or “cracker flour” has slightly higher protein content than cake flour but lower than all-purpose flour. Its protein content ranges from 9% to 10%. It is available as a white flour, a whole-wheat flour, or a white flour with the germ retained but not the bran. Pastry flour is suitable for pie pastry and tarts, some cookies, muffins, biscuits and other quick breads. Flour is typically passed through a sieve to reduce the amount of lumps for cooking pastry.
“Whole-wheat flour” contains the wheat germ, endosperm, and bran.
“White flour” or “refined flour” contains only the endosperm.
“Whole-wheat white flour” is white flour that contains the endosperm, bran, and germ.
“Enriched flour” is white flour with nutrients added to compensate for the removal of the bran and germ.
“Bleached flour” is a white flour treated with flour bleaching agents to whiten it (freshly milled flour is yellowish) and give it more gluten-producing potential. Oxidizing agents are usually employed, most commonly organic peroxides such as acetone peroxide or benzoyl peroxide, nitrogen dioxide, or chlorine. A similar effect can be achieved by permitting the flour to oxidize with oxygen in the air (“natural aging”) for approximately 10 days. However, this process is more expensive due to the time required.
“Bromated flour” has a maturing agent added. The agent's role is to help with developing gluten, a role similar to flour bleaching agents. Bromate is often used. Other choices are phosphates, ascorbic acid, and malted barley.
“Self-rising” or “self-raising flour” is white flour that is sold premixed with chemical leavening agents.
“Spelt flour” is produced from a type of wheat called “spelt”. It is less commonly used in modern cooking than other wheat varieties but is used for specialty baking.
In Canada, “whole wheat flour” may have up to 5% of the grain removed, e.g., most of the germ is often removed to prevent the flour from going rancid. “Whole grain flour” contains the whole grain, including bran, germ and endosperm, but not the chaff.
“Sharp flour” is produced in Fiji and primarily used in Indian cuisine.
In India, flours are generally categorized by how much of the grain is stripped away. “Wheat powder/flour” and “whole grain” flour are a mixture of germ, endosperm, and bran. “Atta flour” is a mixture of endosperm and bran. “Maida flour” is bleached endosperm, and a very white flour similar to the American bleached flour. “Sooji/rava” is coarse-ground endosperm.
“Tang flour” or wheat starch is a type of wheat flour used primarily in Chinese cuisine for making the outer layer of dumplings and buns. It is also used in Vietnamese cuisine, where it is called bot loc trong.
Protein—and/or Polysaccharide-Complexed Nutritional Oil
The protein- and/or polysaccharide-complexed MCT and/or other nutritional oil(s) within composite flours disclosed herein comprise nutritional oil droplets or particles encapsulated by and/or complexed with a wall structure. Where MCT oil is included, the MCT oil droplets or particles contained within complexed MCT oil comprise one or more of C6 triglyceride, C8 triglyceride, C10 triglyceride, C12 triglyceride, or mixed triglyceride thereof. In preferred embodiments, MCT droplets or particles comprise one or more of C8 triglyceride, C10 triglyceride, or C8/C10 mixed triglyceride. The nutritional oil may contain MCT oil and/or one or more other nutritional oils (e.g., that contain unsaturated fatty acids, long-chain fatty acids, and/or short-chain fatty acids), which supplement and/or replace a portion of the MCT oil. Unsaturated fatty acids can provide a source of omega-3 and omega-6 polyunsaturated fatty acids, which are essential fatty acids that provide health benefits when not consumed in excess and provided in the correct ratio. Long-chain fatty acids provide a source of fat. Short-chain fatty acids can improve gut health.
Nutritional oils that can be used in addition to and/or in place of MCT oil include a wide variety of plant- and animal-derived oils. A benefit of encapsulating nutritional oils in wall material is that it can hide or mask the taste and feel of such oils, while providing desired nutritional benefits. Example supplemental oils that can be included in addition to and/or that replace at least a portion of the MCT oil, include but are not limited to açai oil, almond oil, amaranth oil, animal fats, apricot oil, apple seed oil, argan oil, avocado oil, babassu oil, beech nut oil, ben oil, black seed oil, blackcurrant seed oil, borage seed oil, Borneo tallow nut oil, Brazil nut oil, butterfat, butternut squash seed oil, Camelina sativa oil, camellia oil, canola oil, carob pod oil, castor oil, cocklebur oil, cocoa butter, coriander seed oil, corn oil, cottonseed oil, date seed oil, egusi seed oil, fish oil, evening primrose oil, flaxseed oil, grape seed oil, hazelnut oil, hemp seed oil, kapok seed oil, kenaf seed oil, krill oil, lard, long-chain fatty acids and glycerides thereof, macadamia oil, mafura oil, marula oil, mustard oil, Niger seed oil, nutmeg butter, okra seed oil, olive oil, palm oil, papaya seed oil, peanut oil, peach kernel oil, pecan oil, perilla seed oil, persimmon seed oil, Pequi oil, pili nut oil, pine nut oil, pistachio oil, pomegranate seed oil, poppyseed oil, pracaxi oil, prune kernel oil, pumpkin seed oil, quinoa oil, ramtil oil, rice bran oil, royle oil, sacha inchi oil, safflower oil (e.g., high oleic), salicornia oil, sapote oil, seje oil, sesame oil, shea butter, short-chain fatty acids and glycerides thereof, soybean oil, sunflower oil, taramira oil, thistle oil, tigernut oil, tomato seed oil, walnut oil, watermelon seed oil, and wheat germ oil. Some are considered to be more nutritional than others, and more nutritionally sound oils are preferred. Nevertheless, when used in relatively small amounts, even oils considered to be less nutritional can provide a source of essential omega-3 and omega-6 polyunsaturated fatty acids when consumed in minor quantities and that provide a healthy ratio of polyunsaturated fats. Butterfat can provide a source of healthy butyric acid.
Protein- and/or polysaccharide-complexed nutritional oil in the composite flours disclosed herein can have a particle size less than about 10 m, or less than about 5 m, or less than about 1 m, or less than about 500 nm, or less than about 250 nm, or less than about 100 nm.
The protein and/or polysaccharide used to make the wall material and wall structure of complexed nutritional oil may be considered to be “added protein” and “added polysaccharide”, with the plant flour providing the “primary protein” for the composite flours disclosed herein and the “primary polysaccharide” forming the wall structure.
Example proteins used to make wall material to encapsulate and/or complex MCT oil and/or other nutritional oil(s) can be plant protein or animal protein. Example plant proteins include, but are not limited to, one or more of pea protein, hemp protein, pumpkin seed protein, rice protein, soy protein, sunflower seed protein, sacha inchi (Plukenetia volubilis) protein, chia protein, and quinoa protein. Example animal proteins include, but are not limited to, one or more of whey protein, casein, egg protein, beef protein, chicken protein, fish protein, and collagen. In currently preferred embodiments, the protein comprises one or more plant proteins, more preferably pea protein.
Example added polysaccharides include, but are not limited to, acacia fiber, starch, pectin, cellulose derivatives, inulin, xylan, arabinoxylan, and chitin. Example starches include, but are not limited to, corn starch, potato starch, wheat starch, rice starch, and cassava starch. A preferred added polysaccharide used in addition to or in place of the added protein, e.g., pea protein, is acacia fiber.
Pea protein is a common source of plant food protein and can be derived and extracted from yellow and green split peas, Pisum sativum. It can be used as a dietary supplement to increase an individual's protein or other nutrient intake, or as a substitute for other food products. As a powder, it can used as an ingredient in food manufacturing, such as a thickener, foaming agent, or emulsifier.
Pea protein can be extracted in powder form and processed and produced in different ways. It can be an isolate through wet fractionation, which produces a high protein concentration. It can be a concentrate through the process of dry fractionation, which produces a low protein concentration. It can be in textured form, which is when it is used in food products as a substitute for other products, such as meat alternatives Pea protein is a food source due to its availability, low allergenicity, and high nutritional value.
Pea protein is rich in nutrients such as protein and carbohydrates, contains vitamins and minerals, and is low in fat. Peas typically contain 23.1-30.9% protein, 1.5-2.0% fat, and minor constituents such as vitamins, phytic acid, saponins, polyphenols, minerals, and oxalates. They also contain several classes of protein: globulin, albumin, prolamin, and glutelin. The proteins are mainly albumins and globulins, which account for 10-20% and 70-80% of the protein in the pea seed, respectively. The albumins are water soluble and considered to be metabolic and enzymatic proteins, while the globulins are salt soluble and act as the storage proteins for the seed. Globulins can be further classified into legumin and vicilin. Legumin is a hexameric protein, and vicilin proteins are trimers.
Pea seeds contain 60-65% carbohydrates, mainly composed of oligosaccharides, monosaccharides, polysaccharides, and disaccharides. The major carbohydrate fraction in peas is starch, which is the major storage carbohydrate in the cotyledons. Peas also contain high levels of dietary fiber, which consists of cellulose, gums, hemicellulose, pectin, mucilage, lignin, and resistant starches. Dry peas have 17-27% dietary fiber depending on cultivar, environment, and global growing region. Pea seeds also contain 5-6% sucrose and raffinose. Sucrose ranges from 2.2% to 2.6%, stachyose ranges from 1.3-3.2%, verbascose ranges from 1.2-4.0%, and raffinose ranges from 0.2-1.0% depending on cultivar and environment.
The fat content of pea seeds ranges from 1.2% to 1.8% depending on cultivar. About 25% of fatty acids are composed of oleic acid and 50% of linoleic acid. Pea seeds are also a rich source of minerals and vitamins, such as folic acid, riboflavin, pyridoxine, and niacin.
The emulsifier used to make the wall material for forming the wall structure used to make complexed MCT and/or other nutritional oil can be one or more of gum Arabic, acacia fiber, xanthan gum, guar gum, gellan gum, carrageenan, locust bean gum, pectin, starch, soy lecithin, egg lecithin, agar-agar, dextrin, monoglycerides, or diglycerides. In currently preferred embodiments, the emulsifier comprises gum Arabic.
The optional co-emulsifier used to make the wall material for forming the wall structure used to make complexed MCT and/or other nutritional oil can be one or more of calcium stearoyl lactylate, sodium stearoyl lactylate, cetearyl alcohol, cetyl alcohol, calcium stearate, magnesium stearate, phosphates, polyglycerol esters, polysorbate, sorbitan monostearate, or sucrose fatty acid ester. In currently preferred embodiments, the co-emulsifier comprises calcium stearoyl lactylate and/or sodium stearoyl lactylate.
An example embodiment of a method of manufacturing composite flour comprises:
Another example embodiment of a method of manufacturing composite flour comprises:
In some embodiments, the first and second portions of native plant flour can be the same flour or different flours. For example, the first portion of native plant flour can have a relatively high quantity of polysaccharide that can form part of the wall structure, and the second first portion of native plant flour can be a low carbohydrate plant flour having a relatively low quantity of polysaccharide.
The use of high-speed shearing to form the initial emulsion causes at least some of the native flour particles to release polysaccharide (e.g., starch), which results in a physical and/or chemical transformation of the native flour to form modified plant flour particles. The polysaccharide released from the native flour combine with the added protein (or acacia fiber) and emulsifier(s) to form a new type of composite wall material. This composite wall material encapsulates and/or forms a complex with MCT and/or other nutritional oil droplets or particles to form a new type of composite flour particles having advantageous properties not found in traditional flours or blended MCT flours. The composite flours disclosed herein include composite flour-nutritional oil particles that have been physically and/or chemically transformed relative to native plant flour and MCT and/or other nutritional oil starting materials.
Forming dried complexed MCT and/or other nutritional oil maintains the stability, freshness, and powdered nature of the complexed MCT and/or other nutritional oil and composite flour that incorporates the complexed MCT and/or other nutritional oil. Depending on the ratio of wall material to MCT and/or other nutritional oil, there may be an excess of wall material such that a portion of the wall material may form empty micelles, vesicles, or assembled complexes that do not contain and/or are not complexed with MCT and/or other nutritional oil. In some cases, “empty” micelles include a water droplet instead of MCT and/or other nutritional oil. In other cases, assembled complexes may include only wall material. Including an excess of wall material ensures that all or substantially all of the MCT and/or other nutritional oil is encapsulated by and/or complexed with wall material.
The composite flours typically comprise clusters comprised of micro- and/or nanosized complexed MCT and/or other nutritional oil, modified and/or unmodified plant flour particles, and excess wall material, such as nanomicelles, nanovesicles, uncombined protein, and/or uncombined emulsifier, which may form clusters with themselves, complexed MCT and/or other nutritional oil, or modified and/or unmodified plant flour particles. In a preferred embodiment, a portion of the wall material used to form the complexed MCT and/or other nutritional oil is provided by plant flour particles, which release starch or other polysaccharide during formation. The release of polysaccharide from plant flour yields modified plant flour particles that include protein but are depleted in polysaccharide.
The various components that make up the composite flour may be considered to involve a physical and/or chemical transformation compared to native plant flour and traditional forms of MCT and/or other nutritional oil. Such transformations yield composite flours that store well, mix well, have increased nutrition, and higher product quality (e.g., improved quality of baked goods). The composite flours have lower bulk density than flours made from the same type of flour, such as native flour and a blend of native flour and MCT powder. They also yield food products with higher volume (i.e., for a given weight or volume of composite flour used to replace traditional flour counterparts in recipes).
The composite flours of the disclosure are markedly different than and perform substantially better than blended MCT flour, which is a simple dry blend of native plant (e.g., coconut) flour and traditional MCT powder (e.g., MCT oil spray-dried with a polysaccharide). MCT powder typically contains up to 50% polysaccharide. Thus, dry blending MCT powder with native plant flour significantly increases polysaccharide content and reduces protein content of the blended flour. The composite flours of the disclosure are also different in composition and structure compared to a hypothetical flour made by directly applying MCT oil to native flour particles. Blended MCT flours tend to create GI distress due to the MCT contained in the MCT powder within the blended flour.
A high-speed shearing mixer 112 is used to form an emulsion 114. The emulsion 114, preferably a nano-emulsion, comprises various components, including MCT and/or other nutritional oil droplets or particles 116 encapsulated by wall material forming composite micelles, nanovesicles 118 having a double layer structure with a hydrophilic shell surface and aqueous phase inside containing water, nanomicelles 120 having a hydrophilic outer surface and hydrophobic core, excess protein particles 122, excess emulsifier and/or co-emulsifier particles 124, and flour fragments 126.
A high pressure nanolizer device or system 130 processes the emulsion droplets 128 to form composite flour-nutritional oil nanocapsules 132, which are sent to a spray-drying apparatus or system 134. In the first embodiment illustrated in
In first feeding step 206, protein and/or acacia fiber, emulsifiers, co-emulsifiers, and native plant flour (e.g., a first portion of native plant flour) are dispersed into water to form a wall material aqueous slurry. In a second feeding step 204, liquid MCT and/or other nutritional oil, and optionally a supplemental oil, is added to the wall material aqueous solution to form a heterogeneous mixture.
In high-speed shearing step 208, the heterogeneous mixture is mixed evenly by high-speed shearing to form an initial nano-emulsion, which is mainly comprised of complexed plant flour-MCT and/or other nutritional oil microcapsules, nano-micelles and nanovesicles formed by emulsifiers and co-emulsifiers, free plant protein and emulsifier nanoparticles, modified flour particles in which at least a portion of starch or other polysaccharide is released, and optionally unmodified flour particles. The complexed MCT and/or other nutritional oil microcapsules comprise MCT and/or other nutritional oil droplets or particles at least partially encapsulated by and/or complexed with wall material, forming complexed micelles. The wall material includes polysaccharide released from at least some of the native plant flour particles, which become modified plant flour particles depleted in polysaccharide.
In some embodiments, protein nanoparticles and emulsifiers/co-emulsifiers are assembled at the oil/water interface, with starch or other polysaccharide released from the modified plant flour particles acting as a polymer to fill crevices in the wall material or structure, thus forming complete outer shells to at least partially encapsulate MCT and/or other nutritional oil droplets or particles, thereby forming complexed plant flour-MCT and/or other nutritional oil microcapsules.
In sterilization step 210, the initial nano-emulsion is sterilized, such as at a temperature of about 90° C. to about 100° C., such as for about 25 to about 35 seconds, to remove or kill essentially all microorganisms.
In high pressure nanolization step 212, the initial nano-emulsion is homogenized under a pressure of about 40 MPa to about 100 MPa. The high mechanical pressure generated by high pressure disperses the mixture of complexed plant flour-MCT and/or other nutritional oil microcapsules, nanomicelles, and nanovesicles into homogeneous complexed plant flour-nutritional oil nanocapsules.
In spray-drying step 214, the nanoemulsion of complexed plant flour-nutritional oil nanocapsules is converted into complexed plant flour-nutritional oil nanocapsule clusters. The inlet air temperature is maintained at about 160° C. to about 220° C., and the outlet air temperature is maintained at about 75° C. to about 100° C. The complexed plant flour-nutritional oil nanocapsule clusters can be intermediate composite flour particles that are somewhat moist.
In mixing and sieving step 216, the intermediate composite flour particles are mixed in a blender (e.g., with a second portion of native plant flour) and then sieved to obtain a complexed flour with relatively uniform particle size. The complexed flour can be the final product or it can be blended with other foodstuffs to form a different product. In some embodiments, the complexed flour can be blended with another native plant flour and/or another complexed flour to form a blended flour.
In packing step 218, the complexed flour (or blended flour) is packed into aluminum foil bag using a packaging machine known to those skilled in the art.
In storage step 220, complexed flour (or blended flour) is stored in a cool, ventilated, and dry environment. To maintain cleanliness, the storage warehouse should be equipped with an electronic rodent proof device, fly extinguisher, and other pest control facilities.
In some embodiments, dried composite flour particles made by processes disclosed herein, but before sieving, can be the final composite flour product. In other embodiments, the dried composite flour particles can be mixed (e.g., with a second portion of native plant flour) and sieved to produce a refined composite flour product with more uniform particle size. The larger particles removed by sieving can be reground and added back to the refined composite flour product, used as a coarser composite flour product for making food products, and/or recycled back to the wall material slurry and/or heterogeneous mixture used to form the initial emulsion in the process above.
In some embodiments, the composite flour can be blended with one or more other materials to form a composite blended flour product. For example, a first composite flour made using a first native flour can be blended with a second composite flour made using a different native flour. Alternatively, a composite flour or composite flour mixture can be blended with one or more native flours to form a blended flour product having desired nutrition and/or performance properties.
The composite flours disclosed herein can replace and/or supplement traditional flours to make food products, such as baked goods, fried goods, boiled goods, and non-cooked goods, including but not limited to, breads, biscuits, rolls, buns, cakes, cupcakes, pies, bagels, muffins, flatbread, cakes, brownies, pastries, cookies, crackers, tarts, puff pastries, donuts, tarts, turnovers, crepes, pancakes, waffles, crumpets, cornbread, muffuletta, breaded meats, dumplings, pasta, noodles, tortellini, ravioli, ice cream, yogurt, and the like.
In some cases, the composite flours disclosed herein can increase the volume of products made compared to traditional flours (e.g., all-purpose white flour). The composite flours were typically found to yield products having 25% greater volume, when using the amount of flour specified in recipes, compared to all-purpose white flour or other traditional flour. The volume increase can be at least 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45% or 50% compared to an equivalent quantity of traditional flour (on a volume and/or weight basis). The result is a greater quantity (volume) of food product made using the same quantity of composite flour and/or a reduced quantity of composite flour to make a given quantity of food product.
The reason for this surprising and unexpected increase in volume is believed to be the way in which the composite flours are manufactured. In one aspect, MCT and/or other nutritional oil droplets or particles are encapsulated and/or complexed with a protein-based wall structure that includes protein and/or acacia fiber, polysaccharide released from the plant flour particles, emulsifier (typically a polysaccharide), and co-emulsifier. The complexed MCT and/or other nutritional oil provides homogeneously dispersed packets of fat, protein, polysaccharide, and co-emulsifier that contribute to formation of an extended and easily expandable network of protein and polysaccharide chains that coordinate with water during the mixing and cooking process.
In addition, the manufacturing process, including the high-shear mixing of heterogenous mixture to form the emulsion, partially breaks down at least some of the flour particles, releasing starch or other polysaccharide into the mixture, which contributes to the extended and expandable network of protein and polysaccharide chains that coordinate with water during the mixing and cooking process. In contrast, fluor particles that have not been processed by such high shear mixing remain intact and do not release and distribute starch or other polysaccharide into the mixture. As evidence of this, bread must be vigorously kneaded to release and develop the elastic gluten protein. Absent input of energy required to break down the flour particles, their volume producing capability remains smaller.
Another explanation is that the network structure (texture) formed by pea or other added protein, dextrin or other polysaccharide, and flour is different from that of native flour. Compared with native flour, the network structure in composite flour is highly elastic but with lower rebound tension compared to the elasticity from gluten protein in ordinary gluten flour, which has higher rebound tension and cannot expand as much during rising and/or baking. During the baking process, the volume of bread made using ordinary flour rises to a certain extent and is pulled/prevented by the elastic network structure with strong rebound tension, while composite flour can rise to a larger volume due to the lower rebound tension of the dough structure.
Another explanation is that the fat content of composite flour is significantly higher than that of ordinary flour. In the process of raising or kneading dough, the oil and emulsifier in the composite flour form a membrane in the dough, which provides the dough with better gas barrier properties to a certain extent. Gas (air and steam) generated inside the dough during baking cannot easily escape from the dough, thus forming many small air or steam compartments, which causes the dough to increase in volume like a balloon.
Food products made using the composite flours are reportedly more moist, fluffier, lighter in taste, and sometimes sweeter, even when less sweetener is used, than food products made using traditional flour. The composite flours may allow for a reduction in the amount of oil and/or sugar that would otherwise be required to yield a product of desired taste and quality. Such reduction can yield lower calorie food products. Food products made using composite flours disclosed herein have been found to stay fresher longer, e.g., before becoming stale, developing mold, becoming rancid, and the like. The complexed MCT oil in the flour reduces or eliminates GI tract issues caused by conventional uses of MCT oil or MCT powder. When other nutritional oils are used in addition to or in place of MCT oil, the complexed oil(s) have improved taste and feel as a result of being encapsulated. The composite flours reduces glycemic spikes because they have lower carbohydrate load, higher protein content, and higher fat content and increase the digestive slowness of the carbohydrates.
The examples describe exemplary composite flours that can be used in place of traditional flours for making baked goods and other food products.
Composite wheat-MCT flour with reduced gluten and carbohydrate includes MCT droplets or particles encapsulated by and/or complexed with a wall structure. The wall structure comprises wall material formed from pea protein (added protein source and emulsifier), starch released from the wheat flour during the manufacturing process, calcium stearoyl lactylate (co-emulsifier), and sodium stearoyl lactylate (co-emulsifier). The materials are added in the following amounts:
The composite wheat-MCT flour is made by (i) initially forming a wall material slurry comprising 50 wt % water and 50 wt % wall material comprised of a first portion (e.g., about 10%) of the all-purpose wheat flour, pea protein, calcium stearoyl lactylate, and sodium stearoyl lactylate, (ii) high shear mixing of the MCT oil with the wall material slurry to form an emulsion comprised of microencapsulated MCT oil droplets surrounded by wall material micelles and modified wheat flour particles from which a portion of the starch has been released to form a portion of the wall material, (iii) and nanolizing and spray drying to form intermediate composite wheat-MCT flour particles, which can form complexes. The intermediate composite wheat-MCT flour particles are mixed with a second portion (e.g., about 90%) of the all-purpose wheat flour to form final composite wheat-MCT flour particles, wherein at least some of the second portion of the all-purpose wheat flour particles form agglomerates with the intermediate composite plant-MCT flour particles. The final final composite wheat-MCT flour particles are sieved to remove larger particles, which can be recycled back to the wall material slurry and/or material used to form the emulsion.
The composite wheat-MCT flour can be used as a substitute for all-purpose wheat flour or blended all-purpose wheat and MCT flour but with a better nutritional profile (e.g., by including added protein) and reduced or no GI tract problems compared to MCT powder. The composite wheat-MCT flour can be used in place of traditional all-purpose wheat flour or blended MCT flour to make baked goods, fried goods, boiled goods, and non-cooked goods, including but not limited to, breads, biscuits, rolls, buns, cakes, cupcakes, pies, bagels, muffins, flatbread, cakes, brownies, pastries, cookies, crackers, tarts, puff pastries, donuts, tarts, turnovers, crepes, pancakes, waffles, crumpets, cornbread, muffuletta, breaded meats, dumplings, pasta, noodles, tortellini, ravioli, ice cream, yogurt, and the like
In some cases, the composite wheat-MCT flour can be included in the amount specified in the recipe, and the total volume of food product is increased by up to 25%. In other cases, the composite wheat-MCT flour can be included in reduced amounts in order for the yield to be as specified in the recipes.
Composite wheat-MCT flour with reduced gluten and carbohydrate includes MCT droplets or particles encapsulated by and/or complexed with a wall structure. The wall structure comprises wall material formed from pea protein (added protein source), starch released from the wheat flour during the manufacturing process, gum Arabic (emulsifier), calcium stearoyl lactylate (co-emulsifier), and/or sodium stearoyl lactylate (co-emulsifier). The materials are added in the following amounts:
The composite wheat-MCT flour is made by (i) initially forming a wall material slurry comprising 50 wt % water and 50 wt % wall material composed of a first portion (e.g., about 10%) of the all-purpose wheat flour, pea protein, gum Arabic, and calcium stearoyl lactylate and/or sodium stearoyl lactylate, (ii) high shear mixing of the MCT oil with the wall material slurry to form an emulsion comprised of microencapsulated MCT oil droplets surrounded by wall material micelles and modified wheat flour particles from which a portion of the starch has been released to form a portion of the wall material, (iii) and nanolizing and spray drying to form intermediate composite wheat-MCT flour particles, which can form complexes. The intermediate composite wheat-MCT flour particles are mixed with a second portion (e.g., about 90%) of the all-purpose wheat flour to form final composite wheat-MCT flour particles, wherein at least some of the second portion of the all-purpose wheat flour particles form agglomerates with the intermediate composite plant-MCT flour particles. The final composite wheat-MCT flour particles are sieved to remove larger particles, which can be recycled back to the wall material slurry and/or material used to form the emulsion. The composite wheat-MCT flour is used as in Example 1.
Composite wheat-MCT flour was made by the following process:
The composite wheat-MCT flour particles were sieved to remove larger particles, which can be recycled back to the wall material slurry and/or material used to form the emulsion. The composite wheat-MCT flour can be used as in Example 1.
Examples 1-3 are modified by replacing at least a portion of the pea protein and/or gum Arabic with acacia fiber. The composite wheat-MCT flour produces similar food products but with slightly altered nutritional profile.
Examples 1-4 are modified by replacing at least a portion of the pea protein with at least one plant protein selected from hemp protein, pumpkin seed protein, rice protein, soy protein, sunflower seed protein, sacha inchi (Plukenetia volubilis) protein, chia protein, or quinoa protein.
Examples 1-5 are modified by replacing at least a portion of plant protein with at least one animal protein selected from whey protein, casein, egg protein, beef protein, chicken protein, fish protein, or collagen.
Composite flour is made by replacing at least a portion of the all-purpose wheat flour in Examples 1-6 with one or more gluten flours selected from barley flour, rye flour, spelt flour, graham flour, or triticale flour.
Reduced gluten composite flour is made by replacing 5-50% of the gluten flour in Examples 1-7 with one or more gluten-free flours selected from oat flour, corn flour, white rice flour, buckwheat flour, sorghum flour, amaranth flour, teff flour, arrowroot flour, brown rice flour, chickpea flour, tapioca flour, cassava flour, tigernut flour, soy flour, potato flour, millet flour, or quinoa flour.
Gluten-free composite flour is made by replacing the gluten flour in Examples 1-7 with one or more gluten-free flours selected from oat flour, corn flour, white rice flour, buckwheat flour, sorghum flour, amaranth flour, teff flour, arrowroot flour, brown rice flour, chickpea flour, tapioca flour, cassava flour, tigernut flour, soy flour, potato flour, millet flour, or quinoa flour.
Reduced gluten and reduced carbohydrate composite flour is made by replacing 5-50% of the gluten flour in Examples 1-7 with one or more gluten-free and low carbohydrate flours selected from coconut flour, almond flour, peanut flour, sesame flour, sunflower seed flower, hazelnut flour, walnut flour, soy flour, chickpea flour, flaxseed (linseed) flour, fava bean flour, pumpkin seed flour, lupine flour, red lentil flour, or white bran flour.
Gluten-free and low carbohydrate composite flour is made by replacing the flour in Examples 1-10 with one or more gluten-free and low carbohydrate flours selected from coconut flour, almond flour, peanut flour, sesame flour, sunflower seed flower, hazelnut flour, walnut flour, soy flour, chickpea flour, flaxseed (linseed) flour, fava bean flour, pumpkin seed flour, lupine flour, red lentil flour, or white bran flour.
The composite flour of any of Examples 1-11 is modified by including one or more nutritional oils in addition to and/or that replace at least a portion of the MCT oil, including one or more of açai oil, almond oil, amaranth oil, animal fats, apricot oil, apple seed oil, argan oil, avocado oil, babassu oil, beech nut oil, ben oil, black seed oil, blackcurrant seed oil, borage seed oil, Borneo tallow nut oil, Brazil nut oil, butterfat, butternut squash seed oil, Camelina sativa oil, camellia oil, canola oil, carob pod oil, castor oil, cocklebur oil, cocoa butter, coriander seed oil, corn oil, cottonseed oil, date seed oil, egusi seed oil, fish oil, evening primrose oil, flaxseed oil, grape seed oil, hazelnut oil, hemp seed oil, kapok seed oil, kenaf seed oil, krill oil, lard, long-chain fatty acids and glycerides thereof, macadamia oil, mafura oil, marula oil, mustard oil, Niger seed oil, nutmeg butter, okra seed oil, olive oil, palm oil, papaya seed oil, peanut oil, peach kernel oil, pecan oil, perilla seed oil, persimmon seed oil, Pequi oil, pili nut oil, pine nut oil, pistachio oil, pomegranate seed oil, poppyseed oil, pracaxi oil, prune kernel oil, pumpkin seed oil, quinoa oil, ramtil oil, rice bran oil, royle oil, sacha inchi oil, safflower oil (e.g., high oleic), salicornia oil, sapote oil, seje oil, sesame oil, shea butter, short-chain fatty acids and glycerides thereof, soybean oil, sunflower oil, taramira oil, thistle oil, tigernut oil, tomato seed oil, walnut oil, watermelon seed oil, or wheat germ oil. When only a portion of the MCT oil is replaced with one or more other nutritional oils, the other nutritional oil(s) may be considered to be “supplemental oil(s)”.
A mixed composite flour is made by blending a composite flour of any of Examples 1-12 with any other composite flour(s) of Examples 1-12.
A blended composite flour is made by blending a composite flour of any of Examples 1-13 with one or more native plant flours.
Cupcakes were made from cupcake batter comprising the following ingredients:
The cupcakes were made in a cupcake baking pan containing wells into which the cupcake batter was placed and baked at ordinary temperature and time in an oven according to the recipe. The cupcakes were comparable or superior in quality and taste compared to cupcakes made using traditional all-purpose or cake flour and had superior nutrition profile.
Bread was made from bread dough comprising the following ingredients:
Bread loaves were made by kneading the bread dough as usual, letting it rise, beating the raised dough down, placing the dough into baking pans, allowing the dough to rise a second time, and baked at ordinary temperature and time in an oven according to the recipe. The bread was comparable or superior in quality and taste compared to bread made using traditional all-purpose or bread flour and had superior nutrition profile.
Biscuits were made from biscuit dough comprising the following ingredients:
The biscuits were made on a flat baking sheet onto which pieces of biscuit dough were placed and baked at ordinary temperature and time in an oven according to the recipe. The biscuits were comparable or superior in quality and taste compared to biscuits made using traditional all-purpose or cake flour and had superior nutrition profile.
Thin pancakes were made from thin pancake batter comprising the following ingredients:
The thin pancakes were made in a frying pan into which batter was placed and cooked at ordinary temperature and time according to the recipe. The thin pancakes were comparable or superior in quality and taste compared to thin pancakes made using traditional all-purpose or cake flour and had superior nutrition profile.
Muffins were made from muffin batter comprising the following ingredients:
The muffins were made in a muffin baking pan containing wells into which muffin batter in muffin cups were placed and baked at ordinary temperature and time in an oven according to the recipe. The muffins were comparable or superior in quality and taste compared to muffins made using traditional all-purpose or cake flour and have superior nutrition profile. The muffins were lighter, fluffier and more moist compared to conventional muffins made using all-purpose flour instead of the composite wheat-MCT flour.
Coffee cake was made from cake batter comprising the following ingredients:
The coffee cake was made in a glass cake pan into which the cake batter was placed and baked at ordinary temperature and time in an oven according to the recipe. The coffee cake was comparable or superior in quality and taste compared to coffee cake made using traditional all-purpose or cake flour and had superior nutritional profile. The coffee cake was lighter, fluffier, and more moist compared to conventional coffee cake made using all-purpose flour instead of the composite wheat-MCT flour.
Banana nut bread was made from cake batter comprising the following ingredients:
The banana nut bread was made in a greased metal bread pan into which the cake batter was placed and baked at ordinary temperature and time in an oven according to the recipe. The banana nut bread was comparable or superior in quality and taste compared to banana nut bread made using traditional all-purpose or cake flour and had superior nutritional profile. The banana nut bread was lighter, fluffier and more moist compared to conventional banana nut bread made using all-purpose flour instead of the composite wheat-MCT flour.
Pasta was made from pasta dough comprising the following ingredients:
The pasta dough was mixed, kneaded and pressed through a pasta maker according to the recipe and formed into individual pasta noodles. The pasta noodles were placed into boiling water and cooked according to the recipe until soft and tender but not sticky. The pasta was comparable or superior in quality and taste compared to pasta made using traditional all-purpose or cake flour and had superior nutritional profile. The pasta had superior texture compared to conventional pasta made using all-purpose flour instead of the composite wheat-MCT flour.
Conventional blended MCT flour is used instead of the composite flours in any of Examples 1-22. The food products have inferior quality and nutrition profile, with higher carbohydrates and less protein, and they cause GI tract issues, particularly with increasing amounts of MCT powder.
A gastrointestinal tolerance study was conducted by having test subjects eat cakes made from four different flours and then comparing the outcomes. Consumption of MCT oil can cause gastrointestinal (GI) distress. Acceptable intakes of MCT need to be determined. The purpose of this study was to determine the GI tolerance of baking products made using composite wheat-MCT flours with different MCT contents compared to all-purpose wheat flour or blended wheat-MCT flour. It was a randomized, double-blind, placebo-controlled design with parallel groups.
Small soy-based cakes of four different varieties were made using equivalent amounts of the following four flours mixed with soya-bean milk and baked using conventional means:
The subjects were divided into four groups in a random order and changed their diets every two days. The total study period was six days. The subjects consumed the test diet and completed a GI tolerance questionnaire. At day 7, the subjects were required to record their satisfaction with GI comfort over the past one week.
A GI tolerance questionnaire was used to record the occurrence and severity of eight GI domains including bloating, nausea, flatulence, GI cramping, diarrhea, constipation, abdominal pain, and GI rumbling. GI domains were scored with a 4-point scale (0=none, 1=mild, 2=moderate, 3=severe). These domains were chosen based on published articles of GI tolerance. For simplicity, a composite GI tolerance score was produced by averaging the different scores from the eight GI domains.
The results of the GI tolerance study are set forth in Table 1 and depicted graphically in
The mean score is the average of all symptom scores in each group all-purpose cake flour (Control), blended all-purpose cake and MCT flour, composite all-purpose cake-MCT (7%) flour, and composite all-purpose cake-MCT (10%) flour. The mean score reflects the occurrence and severity of GI distress, with the subjects evaluating their GI symptoms on the 4-point scale (0=none, 1=mild, 2=moderate, 3=severe). The number of subjects were counted for each score in each group (Table 1), and calculated mean score for each participant in the groups.
Subjects who consumed cakes made using all-purpose cake flour had a mean score of 0.205, which was the control mean score.
Subjects who consumed cakes made using blended all-purpose cake flour and MCT powder showed the greatest mean score (0.286), which is significantly higher than the other groups (p<0.05). This indicates that consuming cakes made using MCT powder caused obvious GI distress.
Subjects who consumed cakes made using composite all-purpose cake-MCT (7%) flour and composite all-purpose cake-MCT (10%) flour had mean scores of 0.208 and 0.216, respectively, which are close to the control group mean scope of 0.205. This indicates that the composite all-purpose cake-MCT flours were generally well tolerated.
A comparative volume study was conducted by making cakes of various sizes using all-purpose flour as the control and a composite wheat-MCT flour of the disclosure. The composite wheat-MCT flour contained 10% encapsulated MCT oil made according to Example 3, using C8 triglyceride as the MCT oil, all-purpose wheat flour as the flour component, pea protein as the encapsulation protein, gum Arabic as the emulsifier, and calcium and sodium stearoyl lactate as the co-emulsifiers.
The cake batters for the comparative volume study were made according to the bread recipe set forth in Table 2:
There were two types of batter: one that used all-purpose wheat flour and another that used the composite wheat-MCT flour. Each type of cake batter was loaded into metal cake pans in the following weights: 50 g, 100 g, 200 g, and 300 g. For each of the 50 g, 100 g, and 200 g cakes, two batches were made for each type of cake batter; for the 300 g cakes, sixty batches were made for each type of cake batter.
The cakes were baked in an oven for 30 minutes at a top heat temperature of 170° C. (338° F.) and a bottom heat temperature of 180° C. (356° F.). The comparative volume data for the smaller cakes (50 g, 100 g, and 200 g) are set forth in Table 3:
The data clearly show that the volumes of the cakes made using composite wheat-MCT flour were much higher than the cakes made using all-purpose wheat flour. Averaging the two batches together, the increases in volume for cakes made using composite wheat-MCT flour in amounts of 50 g, 100 g and 200 g were 24%, 33% and 39% greater, respectively, than the corresponding cakes made using all-purpose wheat flour. Unexpectedly, the volume increase was incrementally greater as the cake size was increased. This may have been due to a decrease in the exposed surface area-to-volume ratio as the amount of cake batter was increased.
The comparative volume data for the sixty 300 g cakes for each type of cake batter is set forth in Table 4:
The data again clearly show that the volumes of the cakes made using composite wheat-MCT flour were substantially higher than the cakes made using all-purpose wheat flour. Averaging the sixty batches together, the increase in volume for the 300 g cakes made using composite wheat-MCT flour was 41% greater than the 300 g cakes made using all-purpose wheat flour. Unexpectedly, the volume increase was even higher (41%) than the increase for the 200 g cakes (39%), again due perhaps to the decrease in exposed surface area-to-volume ratio.
Not only did the cakes made using composite wheat-MCT flour have significantly higher volume than the correspondingly weighted cakes made using all-purpose wheat flour, an analysis of the data set forth in Tables 3 and 4 also shows that cakes made using composite wheat-MCT flour had more consistent volume than the correspondingly weighted cakes made using all-purpose wheat flour. This is shown in Table 5:
For the 50 g cakes, cakes made using composite wheat-MCT flour had volumes that only deviated ±1.4 cm3 from the average volume of 125.0 cm3. In contrast, 50 g cakes made using all-purpose wheat flour had volumes that deviated ±2.1 cm3 from the average volume of 100.5 cm3. For the largest size cakes (300 g), the decrease in volume deviation for cakes made using composite wheat-MCT flour compared to cakes made using all-purpose wheat flour is even more impressive considering the 41% greater average volume, which yields a percent deviation that is even smaller (0.6% deviation for cakes made using composite wheat-MCT flour versus 1.3% deviation for cakes made using all-purpose wheat flour).
A comparative bulk density study was conducted to determine the relative bulk densities of different flour types made from three different native plant flours: (1) all-purpose wheat flour; (2) buckwheat flour; and (3) corn flour. For each of the three native plant flours, three flour types were compared: (i) composite flour; (ii) simple blend of plant flour and MCT powder; and (iii) native plant flour alone. The amount of MCT oil in the composite flours made according to the invention was the same as the amount of MCT oil in the corresponding blend of native plant flour and MCT powder (i.e., 10 wt %).
Table 6 shows a comparison of the measured bulk densities for the three flour types that contain all-purpose wheat flour.
As shown by the bulk density data in Table 6, the composite wheat-MCT flour of the invention had significantly lower bulk density than both the all-purpose wheat flour alone and the simple blend of all-purpose wheat flour and MCT Powder. The lower bulk density of the composite wheat-MCT flour of the disclosure compared to the simple blend of all-purpose wheat flour and MCT Powder shows they are chemically and structurally different from each other. In other words, the composite wheat-MCT flour of the disclosure is a different composition than the simple blend of all-purpose wheat flour and MCT Powder based on the comparative bulk density data.
Table 7 shows a comparison of the measured bulk densities for the three flour types that contain buckwheat flour.
As shown by the bulk density data in Table 7, the composite buckwheat-MCT flour of the invention had significantly lower bulk density than both the buckwheat flour alone and the simple blend of buckwheat flour and MCT Powder. The lower bulk density of the composite buckwheat-MCT flour of the disclosure compared to the simple blend of buckwheat flour and MCT Powder shows they are chemically and structurally different from each other. In other words, the composite buckwheat-MCT flour of the disclosure is a different composition than the simple blend of buckwheat flour and MCT Powder based on the comparative bulk density data.
Table 8 shows a comparison of the measured bulk densities for the three flour types that contain corn flour.
As shown by the bulk density data in Table 8, the composite corn-MCT flour of the invention had significantly lower bulk density than both the corn flour alone and the simple blend of corn flour and MCT Powder. The lower bulk density of the composite corn-MCT flour of the disclosure compared to the simple blend of corn flour and MCT Powder shows they are chemically and structurally different from each other. In other words, the composite corn-MCT flour of the disclosure is a different composition than the simple blend of corn flour and MCT Powder based on the comparative bulk density data.
A second comparative volume study was conducted to determine the relative volumes of muffins and cookies made using either composite wheat-MCT flour or all-purpose wheat flour. Muffins were made from muffin batter comprising the following ingredients:
The muffins were made in a muffin baking pan containing wells into which muffin batter in muffin cups were placed and baked at ordinary temperature and time in an oven according to the recipe. The weight of muffin batter for each muffin and the relative volumes and growth rate for muffins made using the different flours are set forth in Table 9.
Consistent with previous examples in the first comparative volume study, muffins made using composite wheat-MCT flour of the disclosure had substantially greater volume (41.9% greater) than muffins made using all-purpose wheat flour.
Cookies were made from cookie dough comprising the following ingredients:
The cookies were made by placing pre-measured units of cookie dough onto a greased cookie sheet and baked at ordinary temperature and time in an oven according to the recipe. The weight of cookie dough for each cookie and the relative volumes and growth rate for cookies made using the different flours are set forth in Table 10.
Consistent with previous examples, cookies made using composite wheat-MCT flour of the disclosure had somewhat greater volume (7% greater) than cookies made using all-purpose wheat flour. The smaller increase in volume compared to the muffins is believed to be the result of the greater surface area-to-volume ratio of the cookies compared to the muffins in the previous example.
The present invention may be embodied in other specific forms without departing from its spirit or essential characteristics. The described embodiments are to be considered in all respects only as illustrative and not restrictive. The scope of the invention is, therefore, indicated by the appended claims rather than by the foregoing description. All changes which come within the meaning and range of equivalency of the claims are to be embraced within their scope.
This application is a continuation of U.S. patent application Ser. No. 18/373,043, filed Sep. 26, 2023, which is a continuation-in-part of U.S. patent application Ser. No. 18/096,784, filed Jan. 13, 2023, now U.S. Pat. No. 11,871,773, which is a continuation of U.S. patent application Ser. No. 17/972,037, filed Oct. 24, 2022, which claims the benefit of U.S. Provisional Application No. 63/412,721, filed Oct. 3, 2022, which are incorporated by reference in their entirety.
| Number | Date | Country | |
|---|---|---|---|
| 63412721 | Oct 2022 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 18373043 | Sep 2023 | US |
| Child | 18434136 | US | |
| Parent | 17972037 | Oct 2022 | US |
| Child | 18096784 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 18096784 | Jan 2023 | US |
| Child | 18373043 | US |
