Embodiments of the present disclosure relate to electronic packaging, and more particularly, to electronic packages with nano-roughened copper surfaces and methods of forming such electronic packages.
Substrates for next generation chip-to-chip interconnect technologies require significantly high speed and higher density input/output (I/O) routing. Accordingly, next generation packaging solutions are trending to higher I/O densities to meet the rapidly increasing demand for greater connectivity and faster speeds. This drives the electronic packaging roadmap to deliver ever more complex packages with embedded silicon dies and/or multi-chip enabled packages. One particular issue that arises with such architectures is that the surface roughness of the traces starts playing a significant role in the signal losses at high frequencies. As the surface roughness of the traces increases, the signal losses also increase.
However, surface roughness in the traces is currently needed in order to provide high reliability. In currently available electronic packages, the copper traces are roughened to create micro-roughened copper for improving adhesion between the copper and the dielectric material. The micro-roughened copper typically has an average depth of valleys (Rv) that is between 2 μm-10 μm. This delivers a reliable package, but provides poor electrical performance as evidenced by high insertion loss characteristics.
Accordingly, improving the adhesion of the dielectric material to smooth copper surfaces is an area of interest for improving electronic packages. For example, spray or dip equipment based deposition of organic adhesion promoters in conjunction with low amplitude micro-roughened copper has been proposed. Such solutions rely on intermolecular polymerization to form polymerized layers on the copper surface. While such solutions deliver some benefit to the insertion loss characteristics, this solution still provides reduced package reliability. Additionally, the adhesion promoters need to be customized for different dielectric materials.
Described herein are electronic packages with nano-roughened copper surfaces and methods of forming such electronic packages, in accordance with various embodiments. In the following description, various aspects of the illustrative implementations will be described using terms commonly employed by those skilled in the art to convey the substance of their work to others skilled in the art. However, it will be apparent to those skilled in the art that the present invention may be practiced with only some of the described aspects. For purposes of explanation, specific numbers, materials and configurations are set forth in order to provide a thorough understanding of the illustrative implementations. However, it will be apparent to one skilled in the art that the present invention may be practiced without the specific details. In other instances, well-known features are omitted or simplified in order not to obscure the illustrative implementations.
Various operations will be described as multiple discrete operations, in turn, in a manner that is most helpful in understanding the present invention, however, the order of description should not be construed to imply that these operations are necessarily order dependent. In particular, these operations need not be performed in the order of presentation.
As noted above, high signaling speeds in advanced electronic packaging architectures is leading towards the need to reduce the surface roughness of conductive traces. However, reduced surface roughness leads to poor package reliability due to poor adhesion between the dielectric layers and the smooth conductive traces. Accordingly, embodiments disclosed herein include a high-frequency low-amplitude nanoroughened surface. Such surfaces enable the high speed interconnects needed for advanced packaging architectures without sacrificing the reliability of the electronic package.
Particularly, embodiments disclosed herein provide a bimetallic layer disposed over the main body of the conductive trace. The bimetallic layer comprises a first metallic material and a second metallic material that is different than the first metallic material. The second metallic material is selectively etched relative to the first metallic material in order to provide a porous film of the first metallic material. The low-amplitude of the surface (e.g., an average depth of valleys (Rv) that is less than 2 μm) provides improved insertion loss characteristics, and the adhesion to the dielectric material is still adequate due to the high-frequency of the peaks and valleys (e.g., an average width of the peaks and valleys may be 50 nm or less). Furthermore, the amplitude and frequency can be tuned by controlling the gradient deposition profile of the bimetallic film layer. Additionally, embodiments disclosed herein are enabled with existing materials and toolsets (e.g., etching chemistries, plating processes, lithography tools, and the like). Accordingly, further capital investment may be limited or eliminated in order to implement embodiments disclosed herein.
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In an embodiment, the first metallic material 155 may have a plurality of ligaments 163 and pores 162. The ligaments 163 may be characterized with an average width L, and the pores 162 may have an average width S. For example, the pores 162 may have an average width S that is less than 50 nm and the ligaments 163 may have an average width that is less than 50 nm. In other embodiments, the average width S of the pores 162 may be 10 nm or less, and the average width L of the ligaments 163 may be 10 nm or less. In an embodiment, the average width S of the pores 162 may be substantially equal to an average width L of the ligaments 163. In other embodiments, the average width S of the pores 162 may be different than the average width L of the ligaments 163.
The morphology of the film 152 (i.e., the microstructure of the first metallic material 155 and the second metallic material 154) may be controlled by modulating processing conditions during a plating process (e.g., an electrolytic plating process) used to form the film 152. For example, the volume percentage of the first metallic material 155 may decrease with respect to greater Z-heights in the film 152. That is, a bottom portion of the film 152 proximate to the main body 151 of the conductive trace 150 may have a higher volume percentage of the first metallic material 155 compared to a top portion of the film 152 opposite from the main body 151 of the conductive trace 150.
In an embodiment, the film 152 may have a thickness T. The thickness T may be chosen in order to provide a desired surface morphology after the second metallic material is removed. For example, increasing the thickness T may increase an average depth of valleys Rv of the first metallic material 155. In an embodiment, the thickness T may be 5 μm or less, 2 μm or less, or 1 μm or less.
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Due to the selectivity of the etching process to the second metallic material 154, only the top surface 157 is provided with a nanoroughened surface. Particularly, the top surface 157 may have a surface roughness that is greater than a surface roughness of sidewall surfaces 156 of the main body 151. Such embodiments are particularly beneficial with improving the electrical performance of the conductive trace 150, because less of the overall surface is roughened (compared to typical copper roughening processes currently used which roughen the top surface and the sidewall surfaces). Accordingly, embodiments disclosed herein exhibit reduced insertion losses and enables the high speed data transfers needed for advanced packaging architectures, such as embedded multi-die interconnect bridge (EMIB), etc.
In an embodiment, the surface roughness of the top surface 157 may be characterized as having a high-frequency and low amplitude. Particularly, the amplitude (i.e., the average depth of valleys (Rv)) may be correlated to the thickness T of the film 152. As such, the average depth of valleys Rv may be as high as 5 μm or 1 μm or less. This is a significantly smaller amplitude than is possible with existing copper roughening processes (e.g., wet chemistry based copper roughening with metal etch) which can only provide Rv values greater than 2 μm. Reduced amplitude roughening typical of embodiments disclosed herein further reduces insertion losses and, therefore, improves electrical performance.
While amplitude is decreased, it is to be appreciated that adhesion is not sacrificed. Particularly, the increased frequency of the ligaments 163 and pores 162 (e.g., due to the reduction in the average widths L and S) provides increased adhesion relative to existing copper roughening processes (e.g., wet chemistry based copper roughening with metal etch). Existing processes can only provide frequencies that are approximately 1 μm or greater, and embodiments disclosed herein provide frequencies that are orders of magnitude smaller. As noted above, the high-frequency features are provided since the average widths L and S are orders of magnitude may be 50 nm or less, or 10 nm or less. Accordingly, embodiments disclosed herein provide a nanoroughened surface that has reduced amplitude (in order to improve electrical performance) while at the same time have a high-frequency (in order to increase adhesion).
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In an embodiment, a seed layer 307 may be disposed over the surface of the dielectric layer 305. For example, the seed layer 307 may be deposited with a plating process (e.g., electrolytic or electroless plating), sputtering, or the like. In an embodiment, the seed layer 307 is blanket deposited over the entire exposed surface of the dielectric layer 305.
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In an embodiment, the conductive trace 350 may be deposited with an electrolytic plating process. In some embodiments, the main body 351 and the film 352 are plated in a single plating bath. For example, the plating parameters may be have a first setting to provide the main body 351, and a second setting (or second settings) that provide the film 352 comprising the first conductive material co-deposited with the second conductive material. In an embodiment, the second settings may be modulated to provide a gradient with a larger volume percentage of the first conductive material proximate to the main body 351 and a lower volume percentage of the first conductive material away from the main body 351.
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In an embodiment, the film 352 comprises a first metallic material 355 and a second metallic material 354. The first metallic material 355 may comprise a plurality of ligaments 363 and pores 362. The pores 362 may be filled with the second metallic material 354. That is, the second metallic material 354 may conform to the surfaces of the first metallic material 355. In an embodiment, the pores 362 may have an average width S that is 50 nm or less, or 10 nm or less, and the ligaments 363 may have an average width L that is 50 nm or less, or 10 nm or less.
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In an embodiment, the top surface 357 may have a first surface roughness and sidewall surfaces 356 may have a second surface roughness that is smaller than the first surface roughness. The use of a bimetallic film 352 allows for the surface roughening to be localized to the top surface since the sidewall surfaces 356 remain protected by the resist layer 312 during the plating of the film layer 352. Accordingly, embodiments disclosed herein allow for improved electrical performance since not all surfaces of the conductive trace 350 are roughened (as is the case in existing copper roughening processes).
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In an embodiment, the package substrate 400 may be electrically coupled to a board 498, such as a printed circuit board (PCB) with interconnects 499. For example, the interconnects 499 may comprise solder bumps, pins, or any other interconnect architecture. In an embodiment, the board 498 may comprise a plurality of conductive features 493 (e.g., pads, traces, vias, and the like). In an embodiment, one or more of the conductive features may include a nanoroughened surface, such as the nanoroughened surfaces described above. Accordingly, embodiments include a board 498 that is suitable for high speed signaling applications while maintaining high reliability.
These other components include, but are not limited to, volatile memory (e.g., DRAM), non-volatile memory (e.g., ROM), flash memory, a graphics processor, a digital signal processor, a crypto processor, a chipset, an antenna, a display, a touchscreen display, a touchscreen controller, a battery, an audio codec, a video codec, a power amplifier, a global positioning system (GPS) device, a compass, an accelerometer, a gyroscope, a speaker, a camera, and a mass storage device (such as hard disk drive, compact disk (CD), digital versatile disk (DVD), and so forth).
The communication chip 506 enables wireless communications for the transfer of data to and from the computing device 500. The term “wireless” and its derivatives may be used to describe circuits, devices, systems, methods, techniques, communications channels, etc., that may communicate data through the use of modulated electromagnetic radiation through a non-solid medium. The term does not imply that the associated devices do not contain any wires, although in some embodiments they might not. The communication chip 506 may implement any of a number of wireless standards or protocols, including but not limited to Wi-Fi (IEEE 802.11 family), WiMAX (IEEE 802.16 family), IEEE 802.20, long term evolution (LTE), Ev-DO, HSPA+, HSDPA+, HSUPA+, EDGE, GSM, GPRS, CDMA, TDMA, DECT, Bluetooth, derivatives thereof, as well as any other wireless protocols that are designated as 3G, 4G, 5G, and beyond. The computing device 500 may include a plurality of communication chips 506. For instance, a first communication chip 506 may be dedicated to shorter range wireless communications such as Wi-Fi and Bluetooth and a second communication chip 506 may be dedicated to longer range wireless communications such as GPS, EDGE, GPRS, CDMA, WiMAX, LTE, Ev-DO, and others.
The processor 504 of the computing device 500 includes an integrated circuit die packaged within the processor 504. In some implementations of the invention, the integrated circuit die of the processor may be packaged in an electronic system that comprises a package substrate with conductive features that comprise a nanoroughened surface, in accordance with embodiments described herein. The term “processor” may refer to any device or portion of a device that processes electronic data from registers and/or memory to transform that electronic data into other electronic data that may be stored in registers and/or memory.
The communication chip 506 also includes an integrated circuit die packaged within the communication chip 506. In accordance with another implementation of the invention, the integrated circuit die of the communication chip may be packaged in an electronic system that comprises a package substrate with conductive features that comprise a nanoroughened surface, in accordance with embodiments described herein.
The above description of illustrated implementations of the invention, including what is described in the Abstract, is not intended to be exhaustive or to limit the invention to the precise forms disclosed. While specific implementations of, and examples for, the invention are described herein for illustrative purposes, various equivalent modifications are possible within the scope of the invention, as those skilled in the relevant art will recognize.
These modifications may be made to the invention in light of the above detailed description. The terms used in the following claims should not be construed to limit the invention to the specific implementations disclosed in the specification and the claims. Rather, the scope of the invention is to be determined entirely by the following claims, which are to be construed in accordance with established doctrines of claim interpretation.
Example 1: an electronic package, comprising: a first layer of a package substrate; and a conductive trace over the first layer of the package substrate, wherein the conductive trace comprises: a conductive body with a first surface over the first layer of the package substrate, a second surface opposite the first surface, and sidewall surfaces coupling the first surface to the second surface, wherein the second surface has a first roughness and the sidewall surfaces have a second roughness that is less than the first roughness.
Example 2: the electronic package of Example 1, wherein the first roughness comprises an average depth of valleys (Rv) that is less than 2 μm.
Example 3: the electronic package of Example 1 or Example 2, wherein the first roughness comprises an Rv that is less than 1 μm.
Example 4: the electronic package of Examples 1-3, wherein a frequency of the first roughness is 50 nm or less.
Example 5: the electronic package of Examples 1-4, wherein the second surface comprises a plurality of pores.
Example 6: the electronic package of Examples 1-5, wherein the second surface comprises a bicontinuous nanoporous structure.
Example 7: the electronic package of Examples 1-6, further comprising: a second layer of the package substrate over the conductive trace and the first layer of the package substrate.
Example 8: the electronic package of Examples 1-7, wherein the second layer of the package substrate conforms to the second surface of the conductive trace.
Example 9: the electronic package of Examples 1-8, further comprising: a first die over the second layer of the package substrate; and a second die over the second layer of the package substrate, wherein a conductive path between the first die and the second die comprises the conductive trace.
Example 10: the electronic package of Examples 1-9, wherein the first die is a processor.
Example 11: a method of forming an electronic package, comprising: disposing a seed layer over a first dielectric layer; disposing a resist layer over the seed layer; patterning the resist layer to provide an opening in the resist layer; disposing a conductive trace into the opening, wherein the conductive trace comprises a main body having a first metallic material, and a film over the main body, wherein the film comprises the first metallic material and a second metallic material; removing the resist layer; removing exposed portions of the seed layer; and removing the second metallic material from the film.
Example 12: the method of Example 11, wherein the first metallic material is copper, and wherein the second metallic material is zinc, tin, or nickel.
Example 13: the method of Example 11 or Example 12, wherein the film over the main body has a thickness that is less than 2 μm.
Example 14: the method of Examples 11-13, wherein removing the second metallic material from the film provides a nanoroughened surface having a plurality of pores.
Example 15: the method of Examples 11-14, wherein the film has a bicontinuous nanoporous structure.
Example 16: the method of Examples 11-15, wherein an average depth of valleys (Rv) of the film after the second metallic material is removed is less than 200 nm.
Example 17: the method of Examples 11-16, wherein the valleys have a frequency that is 50 nm or less.
Example 18: the method of Examples 11-17, wherein the main body and the film are deposited with an electrolytic plating process.
Example 19: the method of Examples 11-18, wherein the main body is plated in a first processing bath, and wherein the film is plated in a second processing bath.
Example 20: the method of Examples 11-19, wherein the main body and the film are plated in the same processing bath.
Example 21: the method of Examples 11-20, further comprising: disposing a second dielectric layer over the first dielectric layer and the conductive trace, wherein the second dielectric layer conforms to a surface of the film.
Example 22: the method of Examples 11-21, wherein the main body comprises sidewall surfaces, and wherein the film has a first surface roughness and the sidewall surfaces have a second surface roughness that is less than the first surface roughness.
Example 23: an electronic system, comprising: a board; an electronic package coupled to the board; and a die coupled to the electronic package, wherein the electronic package comprises a plurality of conductive traces electrically coupled to the die, wherein the plurality of traces each comprise: sidewall surfaces; and a top surface with a nanoroughened structure.
Example 24: the electronic system of Example 23, wherein the nanoroughened structure has a first surface roughness that is greater than a second surface roughness of the sidewall surfaces.
Example 25: the electronic system of Example 23 or Example 24, wherein the first roughness comprises an average depth of valleys (Rv) that is less than 2 μm.