The integrated circuit (IC) industry has experienced exponential growth. Technological advances in IC materials and design have produced generations of ICs, where each generation has smaller and more complex circuits than the previous generation. In the course of IC evolution, functional density (i.e., the number of interconnected devices per chip area) has generally increased while geometry size (i.e., the smallest component (or line) that can be created using a fabrication process) has decreased. This scaling down process generally provides benefits by increasing production efficiency and lowering associated costs.
Such scaling down has also increased the complexity of processing and manufacturing ICs and, for these advances to be realized, similar developments in IC processing and manufacturing are needed. For example, planar transistors have been replaced by three-dimensional fin-like field effect transistors (FinFET), and polysilicon gates have been replaced by metal gates in an effort for improving device performance with decreased feature size. However, there are challenges in implementing metal gates for FinFET. In one example, after the metal gate replaces the polysilicon gate, the metal gate is cut (or etched) for individual transistors. How to efficiently cut the metal gates needs further improvements.
The present disclosure is best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale and are used for illustration purposes only. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
The following disclosure provides many different embodiments, or examples, for implementing different features of the invention. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact.
In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed. Moreover, the formation of a feature on, connected to, and/or coupled to another feature in the present disclosure that follows may include embodiments in which the features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the features, such that the features may not be in direct contact. In addition, spatially relative terms, for example, “lower,” “upper,” “horizontal,” “vertical,” “above,” “over,” “below,” “beneath,” “up,” “down,” “top,” “bottom,” etc. as well as derivatives thereof (e.g., “horizontally,” “downwardly,” “upwardly,” etc.) are used for ease of the present disclosure of one features relationship to another feature. The spatially relative terms are intended to cover different orientations of the device including the features.
The present disclosure is generally related to methods for semiconductor device fabrication, and more particularly to methods of cutting metal gate structures, or alternatively referred to as a cut metal gate (CMG) process, in fin-like field effect transistors (FinFETs) that form memory devices and logic devices. The FinFET devices may be, for example, complementary metal-oxide-semiconductor (CMOS) devices comprising a p-type metal-oxide-semiconductor (PMOS) FinFET device and an n-type metal-oxide-semiconductor (NMOS) FinFET device. The following disclosure will continue with a FinFET example to illustrate various embodiments of the present application. Metal gate structures in FinFET devices may include a variety of configurations and compositions depending upon the devices' desired functions (e.g., memory versus logic devices). Fabricating metal gate structures in FinFET devices often entails cutting or shortening the metal gate structures to accommodate further device processing. For metal gates having different gate lengths and multiple different metal layers, implementing a CMG process that can effectively remove all metal layers poses challenges. For example, etch selectivity of a given etchant may vary based on the composition of the metal layers. Further, loading efficiency of the etchant may vary due different gate lengths. Accordingly, the present disclosure contemplates methods of implementing CMG processes by tuning one or more etching parameters employed therein.
Processing steps of method 100 as illustrated in
Method 100 includes an operation 102, which includes providing a substrate 206 that is configured to have a first region 202 and a second region 204 as shown in
Referring to
Referring to
The fins 210 and the isolation features 208 can be formed by any suitable process. In an exemplary embodiment, the process can include the following steps: one or more processes for patterning a hard mask layer (not shown) over the substrate 206, an etching process (e.g., a dry etching and/or wet etching process) to etch trenches in the substrate 206 not covered by the patterned hard mask layer, and a deposition process (e.g., a chemical vapor deposition process and/or a spin-on glass process) to fill in the trenches with one or more insulating materials to form the isolation features 208. The trenches may be partially filled, where the substrate remaining between trenches forms the fins 210. The hard mark layer (not shown) may be patterned using one or more photolithography processes, including double-patterning or multi-patterning processes. Generally, double-patterning or multi-patterning processes combine photolithography and self-aligned processes, allowing patterns to be created that have, for example, pitches smaller than what is otherwise obtainable using a single, direct photolithography process. For example, in one embodiment, a sacrificial layer is formed over the substrate 206 and patterned using a photolithography process. Spacers are formed alongside the patterned sacrificial layer using a self-aligned process. The sacrificial layer is then removed, and the remaining spacers, or mandrels, become the patterned hard mask layer.
Alternative to partially filling the trenches with the insulating material, operation 104 may completely fill the trenches with the insulating material, planarize a top surface of the filled trenches to remove any excessive insulating material using, for example, a polishing process such as chemical mechanical polishing/planarization (CMP), and selectively grow one or more layers of epitaxial semiconductor materials over the exposed substrate 206 thereby forming the fins 210 with isolation features 208 disposed in between the fins 210. The epitaxial semiconductor material can be, for example, silicon, germanium, silicon germanium, other suitable materials, or combinations thereof. In some embodiments, the filled trenches may have a multi-layer structure such as a thermal oxide liner layer filled with silicon nitride or silicon oxide. Accordingly, the fins 210 formed by embodiments provided herein may comprise the same material as the substrate 206 or, alternatively, they may comprise one or more layers of epitaxially grown semiconductor materials over the substrate 206. In the depicted embodiments, the fins 210 comprise the same material as the substrate 206.
The hard mask layer (not shown) includes any suitable material, for example, silicon oxide, silicon nitride, silicon carbide, silicon oxycarbide, silicon oxynitride, spin-on glass (SOG), a low-k dielectric material, tetraethylorthosilicate (TEOS), plasma-enhanced oxide (PE-oxide), high-aspect-ratio-process (HARP) formed oxide, or other suitable materials, and may be formed by a suitable method, such as thermal oxidation, chemical vapor deposition (CVD), high-density plasma CVD (HDP-CVD), physical vapor deposition (PVD), atomic-layer deposition (ALD), plating, other suitable methods, or a combination thereof. An exemplary etching process can include a dry etching process, a wet etching process, other suitable etching process, or combinations thereof. In some embodiments, a wet etching process implements an etching solution that includes ammonium hydroxide (NH4OH), hydrogen peroxide (H2O2), sulfuric acid (H2SO4), tetramethylammonium hydroxide (TMAH), other suitable wet etching solution, or combinations thereof. For example, the wet etching solution can utilize an NH4OH:H2O2 solution, an NH4OH:H2O2:H2O solution (known as an ammonia-peroxide mixture (APM)), or an H2SO4:H2O2 solution (known as a sulfuric peroxide mixture (SPM)). In some embodiments, a dry etching process employs an etchant gas that includes a fluorine-containing etchant gas (e.g., CF4, SF6, CH2F2, CHF3, and/or C2F6), an oxygen-containing gas, a chlorine-containing gas (e.g., Cl2, CHCl3, CCl4, and/or BCl3), a bromine-containing gas (e.g., HBr and/or CHBR3), an iodine-containing gas, other suitable gases and/or plasmas, or combinations thereof. In some embodiments, a reactive ion etching (RIE) process is performed. After the etching process, the patterned hard mask layer is removed from the substrate 206.
Referring back to
As shown in
In some embodiments, a hard mask layer (not shown) may also be formed over the gate electrode 224 by a suitable process to accommodate various fabrication processes during the implementation of method 100. The hard mask layer may include any suitable material such as, for example, silicon nitride, titanium nitride, silicon oxynitride, silicon carbide, silicon oxycarbide, spin-on glass (SOG), a low-k dielectric material, tetraethylorthosilicate (TEOS), plasma enhanced CVD oxide (PE-oxide), high-aspect-ratio-process (HARP) formed oxide, and/or other suitable material.
In some embodiments, gate spacers 216 may be formed on sidewalls of the dummy gate structures 212 and 214. The gate spacers may comprise a dielectric material, such as silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, other dielectric material, or combinations thereof, and my comprise one or multiple layers of material. The gate spacers 216 may be formed by depositing a spacer material as a blanket over the isolation features 208, the fins 210, and the dummy gate structures 212 and 214. Subsequently, the spacer material is etched back anisotropically during an etching process. Portions of the spacer material on the sidewalls of the dummy gate structures 212 and 214 remain and form the gate spacers 216. For clarity purposes, ends of the gate structure 212 (both dummy and the subsequent metal gate structure) including the gate spacer 216 are omitted in
In the depicted embodiments, portions of the dummy gate structures 212 and 214 are subjected to a high-k metal gate (HK MG) replacement process after high thermal budget processes are performed. In some embodiments, the dummy gate electrode 224 is replaced with a plurality of metal layers to form a conductive electrode, while the dummy gate dielectric layer 218 is replaced with a high-k gate dielectric layer 220.
Referring back to
Forming the source/drain features 228 further includes forming epitaxial structures over the fins 210 in the source/drain regions of the FinFET device 200. In some embodiments, the epitaxial structure includes one or more epitaxial (EPI) layers. A suitable epitaxial semiconductor material includes, for example, a single element semiconductor material such as germanium (Ge) or silicon (Si); or a compound semiconductor material, such as gallium arsenide (GaAs), aluminum gallium arsenide (AlGaAs); or a semiconductor alloy, such as silicon germanium (SiGe), gallium arsenide phosphide (GaAsP). In some embodiments, the epitaxial structures provided herein may include various dopants according to the type of device desired. For example, where an NMOS FinFET device is desired, the epitaxial structure may include one or more EPI layers of silicon (EPI Si) or silicon carbon, where the silicon or silicon carbon is doped with an n-type dopant such as arsenic, phosphorus, other n-type dopant, or combinations thereof. Alternatively, where a PMOS FinFET device is desired, the epitaxial structure may include one or more EPI layers of silicon germanium (EPI SiGe), where the silicon germanium is doped with a p-type dopant such as boron, indium, other p-type dopant, or combinations thereof. In some embodiments, operation 108 may form the source/drain features 228 for NMOS FinFET and PMOS FinFET devices separately.
In some embodiments, the epitaxial structures provided herein are formed by a suitable deposition process such as, for example, CVD, MO-CVD, other deposition method, or combinations thereof. Any suitable process (e.g., an ion implantation process, a diffusion process, an in-situ doping process, or combinations thereof) can be implemented for doping the epitaxial semiconductor material deposited over the recessed fins 210. In some embodiments, a selective epitaxial growth (SEG) process is performed to grow an EPI layer of semiconductor material on the recessed fins 210, where dopants are introduced into the semiconductor material during the SEG process (e.g., by adding dopants to a source material of the SEG process) forming a doped epi layer. The SEG process can be implemented with CVD deposition techniques (e.g., vapor-phase epitaxy (VPE), ultra-high vacuum CVD (UHV-CVD), LP-CVD, and/or PE-CVD), molecular beam epitaxy, other suitable SEG processes, or combinations thereof. The SEG process can use gaseous precursors (e.g., silicon-containing gases, such as SiH4 and/or germanium-containing gases, such as GeH4) and/or liquid precursors, which interact with a composition of the fins 210 to form EPI Si or EPI SiGe layers. One or more annealing processes may be performed to activate the epitaxial structure. The annealing processes include rapid thermal annealing (RTA) and/or laser annealing processes.
Referring back to
The CESL (not shown) may comprise silicon nitride, silicon oxynitride, silicon nitride with oxygen or carbon elements, and/or other materials, and may be formed by CVD, PVD, ALD, or other suitable methods. The ILD layer 222 is deposited over the isolation features 208 and the CESL, filling space between the dummy gate structures in the first region 202 and the second region 204.
In some embodiment, the ILD layer 222 includes a dielectric material including, for example, TEOS, un-doped silicate glass, or doped silicon oxide such as borophosphosilicate glass (BPSG), fused silica glass (FSG), phosphosilicate glass (PSG), boron doped silicon glass (BSG), and/or other suitable dielectric materials. The ILD layer 222 can include a multilayer structure having multiple dielectric materials. The ILD layer 222 may be formed by a deposition process such as, for example, CVD, PVD, ALD, HDP-CVD, MO-CVD, RP-CVD, PE-CVD, LP-CVD, AL-CVD, AP-CVD, plating, other suitable methods, or combinations thereof.
Subsequent to the deposition of the ILD layer 222, a planarization process may be performed such that a top portion of the dummy gate electrode 224 is exposed. In some embodiments, the planarization process may be a chemical-mechanical planarization/polishing (CMP) process. Then, a portion of the at least one of the dummy gate structures 212 and 214 is removed, thereby forming the trench (i.e., opening) 226 and exposing any material layers (e.g., an interfacial layer) disposed underneath the dummy gate electrode 224. In some embodiments, forming the trenches 226 includes performing an etching process that selectively removes the dummy gate electrode 224. The etching process may be a dry etching process, a wet etching process, or combinations thereof. A selective etching process can be tuned, such that the dummy gate electrode 224 is subjected to an adequate etch rate relative to the CESL (not shown) and the ILD layer 222.
The HK MG replacement process 110 proceeds to forming the high-k metal gate structures 212 and 214 in the first region 202 and the second region 204.
In some embodiments, forming the high-k metal gate structures 212 and 214 begins with forming a high-k gate dielectric layer 220 in the trenches 226. Though not depicted herein, some embodiments provide that an interfacial layer may be formed in the trenches 226 prior to depositing the high-k dielectric layer 220. The interfacial layer may be formed using chemical oxidation, thermal oxidation, ALD, CVD, and/or other suitable methods. The high-k gate dielectric layer 220 may include one or more high-k dielectric materials (or one or more layers of high-k dielectric materials), such as hafnium silicon oxide (HfSiO), hafnium oxide (HfO2), alumina (Al2O3), zirconium oxide (ZrO2), lanthanum oxide (La2O3), titanium oxide (TiO2), yttrium oxide (Y2O3), strontium titanate (SrTiO3), or a combination thereof. The high-k dielectric layer 108 may be deposited using CVD, ALD and/or other suitable methods.
Subsequently, the HK MG replacement process 110 proceeds to forming the gate electrode of metal gate structures 212 and 214, respectively. In the depicted embodiments, forming each gate electrode comprises depositing multiple metal layers (i.e., conductive layers), a process exemplified in
In some embodiments, the gate electrode layer of the gate structures 212 and 214 may include only one WFM layer or, alternatively, three or more WFM layers similar to the first metal layer 302 and the second metal layer 304. Advantageously, threshold voltage of devices provided herein can be tuned by a combination of different WFM layers. In some embodiments, the gate structures 212 and 214 comprise the same type, i.e., n-type or p-type, of WFM layers. In alternative embodiments, the gate structures 212 and 214 comprise different types of WFM layers.
Accordingly, as depicted in
The WFM layers (i.e., the first metal layer 302 and the second metal layer 304), and the bulk conductive layer (i.e., the third metal layer 306) can be formed by various deposition processes such as, for example, CVD, PVD, ALD, plating, other suitable methods, or combinations thereof. A CMP process can be performed to remove excess material (such as any excess work function layers and/or any excess bulk conductive layer), planarizing top surfaces of the gate structures 212 and 214.
Referring back to
A resist layer (not depicted) is then applied over the hard mask layer 404 and patterned using a series of photolithography processes. The pattern is then transferred to the hard mask layers 402 and 404 as shown in
In some embodiments, method 100 proceeds to a CMG process that includes a first etching process represented by operation 112 of method 100 as seen in
Following the first etching process 112, residual amounts 408 of the WFM layer 302 and the high-k gate dielectric layer 220 remain along sidewalls of the metal gate structure 214 in the trench 406 following the first etching process 112, while no metal layers remain along sidewalls of the metal gate structure 212 (
In some embodiments, the etchant employed for the second etching process comprises a mixture of gases including oxygen and one or more fluorine-based gas. An exemplary embodiment provides that the gas mixture comprises one or more of the following: CF4, SF6, NF3, O2, and other suitable gases. In some embodiments, the duration of the second etching process ranges between about 30 seconds and about 100 seconds. In some embodiments, the power of the applied bias of the second etching process 114 is substantially lower than that of the first etching process 112 and can be, for example, less than about 20 W. In one example, no bias is applied for the second etching process 114 (i.e., the power is 0 W). The substantially lower applied bias for the second etching process 114 is intended for a more isotropic (i.e., in both horizontal and vertical directions), rather than anisotropic, etching effect to remove any remaining portions of the metal layers (e.g., 302, 304, and 306) and the gate dielectric layer 220. Thereafter, the patterned hard mask layers 402 and 404 are removed from the surface of the device 300.
As noted above, the second etching process 114 is implemented using a fluorine-based etchant(s) while the first etching process 112 is implemented using a chlorine-based etchant(s). The reason for this difference is related to the chemical reactivity and etching efficiency of the etchants used with respect to the metal layers to be removed. For example, chlorine-based etchants are much more effective at removing WFM layers 302 and 304 (comprising, for example, titanium and/or tantalum) but reacts with the bulk conductive layer 306 (comprising, for example, tungsten) at a much slower rate. On the other hand, fluorine-based etchants tend to form etching byproducts that may be difficult to remove when reacting with WFM layer metals (e.g., titanium and tantalum), but is much more effective at etching a bulk conductive metal, such as tungsten.
In some embodiments, following the second etching process 114, a bottom surface of each of the trenches 406 and 410 is below a top surface of the isolation features 208. In further embodiments, the bottom surface of the trench 410 is not coplanar with but is lower than the bottom surface of the trench 406, as depicted in
Referring back to
Accordingly, as a result of the metal gate cutting process exemplified herein, sidewalls of the gate isolation structures 414 in the first region 202 are in direct contact with the bulk conductive layer 306, whereas sidewalls of the gate isolation structure 412 in the second region 204 are in direct contact with one WFM layer (e.g., WFM layer 304) but not the bulk conductive layer 306.
The FinFET device 400 formed in accordance with various embodiments provided herein may be included in a microprocessor, a memory, and/or other integrated circuit device. In some embodiments, the FinFET device 400 may be a portion of an IC chip, a system on chip (SoC), or portion thereof, that includes various passive and active microelectronic devices such as resistors, capacitors, inductors, diodes, metal-oxide semiconductor field effect transistors (MOSFET), complementary metal-oxide semiconductor (CMOS) transistors, bipolar junction transistors (BJTs), laterally diffused MOS (LDMOS) transistors, high voltage transistors, high frequency transistors, other suitable components, or combinations thereof. Additional features can be added to the FinFET device 400 by subsequent processing steps. For example, various vertical interconnect features such as contacts and/or vias, and/or horizontal interconnect features such as lines, and multilayer interconnect features such as metal layers and interlayer dielectrics can be formed over the substrate 206, configured to connect the various features or structures of the FinFET 400. The various interconnect features may implement various conductive materials including aluminum, aluminum alloy (e.g., aluminum/silicon/copper alloy), copper, copper alloy, titanium, titanium nitride, tantalum, tantalum nitride, tungsten, polysilicon, metal silicides, other suitable metals, or combinations thereof. The metal silicides may include nickel silicide, cobalt silicide, tungsten silicide, tantalum silicide, titanium silicide, platinum silicide, erbium silicide, palladium silicide, or combinations thereof.
Although not intended to be limiting, one or more embodiments of the present disclosure offer improvements for semiconductor devices and methods of fabricating the same. For example, embodiments of the present disclosure provide capabilities to simultaneously cut metal gate structures having different gate lengths and compositions in different device regions, thereby consolidating patterning and etching procedures and improving efficiency of the overall fabrication process. Further, various embodiments of the methods provided herein can be readily integrated into existing semiconductor manufacturing processes in which formation of metal gates for memory devices (e.g., SRAM devices) and logic devices is desired.
Accordingly, the present disclosure provides many different embodiments of metal gates in semiconductor devices and methods of fabricating the same. In one aspect, the present disclosure provides a method of fabricating a semiconductor device that includes providing a semiconductor structure that comprises a first region and a second region, the first region including a first metal gate structure formed over multiple first fins and the second region including a second metal gate structure formed over multiple second fins; simultaneously cutting the first metal gate structure to form a first trench and the second metal gate structure to form a second trench, the cutting comprising a first etching process and a second etching process; and depositing an insulating material in the first trench and the second trench to form a first gate isolation structure in the first metal gate structure and a second gate isolation structure in the second metal gate structure, respectively.
In one aspect, the present embodiments provide a semiconductor structure that includes a first metal gate disposed over a first device region of a semiconductor substrate, where the first metal gate includes a first work function metal layer, a second metal gate disposed over a second device region of the semiconductor substrate, where the second metal gate includes a second work function metal layer, a first gate cut feature separating the first metal gate, where sidewalls of the first gate cut feature are defined by the first work function metal layer and a bulk conductive layer, and a second gate cut feature separating the second metal gate, where sidewalls of the second gate cut feature are defined by the second work function metal layer but not by a bulk conductive layer.
In another aspect, the present embodiments provide a semiconductor structure that includes a first metal gate disposed in a first device region of a semiconductor substrate, where the first metal gate is defined by a first gate length, a first isolation feature disposed on a sidewall of the first metal gate, where the first isolation feature contacts a work function metal layer and a bulk conductive layer of the first metal gate, a second metal gate disposed in a second device region of the semiconductor substrate, where the second metal gate is defined by a second gate length that is less than the first gate length and where the second metal gate is free of any bulk conductive layer, and a second isolation feature disposed on a sidewall of the second metal gate, where the second isolation feature contacts the work function metal layer of the second metal gate.
In yet another aspect, the present embodiments provide a semiconductor structure that includes a semiconductor substrate including a first region and a second region adjacent to the first region, semiconductor fins protruding from the semiconductor substrate in the first region and the second region, where the semiconductor fins are oriented lengthwise along a first direction, a first metal gate stack disposed over the semiconductor fins in the first region and oriented lengthwise along a second direction generally perpendicular to the first direction, and a second metal gate stack disposed over the semiconductor fins in the second region and oriented lengthwise along the second direction. In the present embodiments, the semiconductor structure further includes a first gate cut feature separating the first metal gate stack, where sidewalls of the first gate cut feature are defined by a first work function metal layer, a second work function metal layer, and a bulk conductive layer, and where the first gate cut feature has a first length along the second direction, and a second gate cut feature separating the second metal gate stack, where sidewalls of the second gate cut feature are defined by the first work function metal layer and the second work function metal layer but are free of contact with the bulk conductive layer, and where the second gate cut feature has a second length along the second direction, the second length being less than the first length.
The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
This is a continuation application of U.S. application Ser. No. 16/578,792 filed Sep. 23, 2019, which is a divisional application of U.S. application Ser. No. 15/808,618, now U.S. Pat. No. 10,424,588, filed on Nov. 9, 2017, the entire disclosure of which is hereby incorporated.
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20200279854 A1 | Sep 2020 | US |
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Parent | 15808618 | Nov 2017 | US |
Child | 16578792 | US |
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Parent | 16578792 | Sep 2019 | US |
Child | 16876525 | US |