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The present invention relates generally to techniques for the manufacture of photovoltaic devices. More particularly, the present invention provides a system for forming thin-film photovoltaic device and a method for enhancing molybdenum adhesion on bottom shield. Merely by way of examples, the present invention is implemented in a sputtering compartment for forming a bottom electrode of thin-film photovoltaic device without causing a buildup of deposited material on the bottom shield, but it would be recognized that the invention may have other applications.
From the beginning of time, mankind has been challenged to find way of harnessing energy. Energy comes in the forms such as petrochemical, hydroelectric, nuclear, wind, biomass, solar, and more primitive forms such as wood and coal. Over the past century, modern civilization has relied upon petrochemical energy as an important energy source. Petrochemical energy includes gas and oil. Gas includes lighter forms such as butane and propane, commonly used to heat homes and serve as fuel for cooking. Gas also includes gasoline, diesel, and jet fuel, commonly used for transportation purposes. Heavier forms of petrochemicals can also be used to heat homes in some places. Unfortunately, the supply of petrochemical fuel is limited and essentially fixed based upon the amount available on the planet Earth. Additionally, as more people use petroleum products in growing amounts, it is rapidly becoming a scarce resource, which will eventually become depleted over time.
More recently, environmentally clean and renewable sources of energy have been desired. An example of a clean source of energy is hydroelectric power. Hydroelectric power is derived from electric generators driven by the flow of water produced by dams such as the Hoover Dam in Nevada. The electric power generated is used to power a large portion of the city of Los Angeles in California. Clean and renewable sources of energy also include wind, waves, biomass, and the like. That is, windmills convert wind energy into more useful forms of energy such as electricity. Still other types of clean energy include solar energy. Specific details of solar energy can be found throughout the present background and more particularly below.
Solar energy technology generally converts electromagnetic radiation from the sun to other useful forms of energy. These other forms of energy include thermal energy and electrical power. For electrical power applications, solar cells are often used. Although solar energy is environmentally clean and has been successful to a point, many limitations remain to be resolved before it becomes widely used throughout the world. As an example, one type of solar cell uses crystalline materials, which are derived from semiconductor material ingots. These crystalline materials can be used to fabricate optoelectronic devices that include photovoltaic and photodiode devices that convert electromagnetic radiation into electrical power. However, crystalline materials are often costly and difficult to make on a large scale. Additionally, devices made from such crystalline materials often have low energy conversion efficiencies. Other types of solar cells use “thin film” technology to form a thin film of photosensitive material to be used to convert electromagnetic radiation into electrical power. Similar limitations exist with the use of thin film technology in making solar cells. In particularly, although many techniques have been applied to form thin film photovoltaic devices based on copper indium gallium diselenide CIGS material, some were still found to be less effective. For example, sputtering deposition is widely used for forming bottom electrode layer of the CIGS based thin film solar device. In-line deposition method is good for large scale manufacture but shows limitation in the sample flow due to certain bottle-neck processes which results in one or more process issues. Therefore, it is desired to provide an improved system and method for performing thin film deposition in an in-line sputtering system, which can be found throughout the present specification.
The present invention relates generally to techniques for the manufacture of photovoltaic devices. More particularly, the present invention provides a system for forming thin-film photovoltaic device and a method for enhancing molybdenum adhesion on bottom shield. Merely by way of examples, the present invention is implemented in a sputtering compartment for forming a bottom electrode of thin-film photovoltaic device without causing a buildup of deposited material on the bottom shield, but it would be recognized that the invention may have other applications.
In a specific embodiment, the present invention provides an in-line sputtering system for the manufacture of thin film solar devices. The system includes a first vacuum compartment configured to grow a barrier layer overlying both top and bottom surfaces of a first planar substrate. Additionally, the system includes a conveyer comprising a plurality of rollers configured to move a plurality of planar substrates loaded horizontally in a row through the first vacuum compartment. The plurality of planar substrates includes the first planar substrate with at least a gap distance away from a second planar substrate next in the row on the conveyer. Furthermore, the system includes a second vacuum compartment configured to receive the plurality of planar substrates including the first and the second planar substrates from the first vacuum compartment. Each of the plurality of planar substrates has its bottom surface being supported by the rollers to move horizontally under a molybdenum target to have its top surface being coated by a molybdenum layer. Moreover, the system includes a bottom shield disposed on entire bottom region of the second vacuum compartment except a few places for the rollers.
The bottom shield comprises a corrugated surface region subjecting to deposition from the molybdenum target whenever the gap distance between any neighboring planar substrates moves over the bottom shield. Further, the corrugated surface region is configured to adhere substantially the deposited molybdenum layer free of any peel-off effect.
In another specific embodiment, the invention provides an in-line sputtering system. The system includes a chamber and a sputtering target near a top region of the chamber. The system further includes a moving device located on a bottom region of the chamber. The moving device is configured to move a plurality of planar substrates loaded horizontally in a row with at least a gap distance between any neighboring substrates. The gap distance allows the bottom region to be subjected to a deposition from the sputtering target as the gap distance moves across the entire bottom region along with the plurality of planar substrates by the moving device. Furthermore, the system includes a bottom shield disposed to cover entire bottom region except the moving device and configured to adhere substantially the deposition through the gap distance from the sputtering target for preventing a deposition buildup.
Many benefits can be achieved by applying the embodiments of the present invention. The present invention provides an in-line thin film deposition system for large scale manufacture of thin film photovoltaic modules. In particular, the thin-film photovoltaic module is copper-indium-gallium-silenide (CGIS) material based device grown directly on a glass substrate. Embodiments of the present invention are applied to the process of forming base electrodes of the thin film solar modules by sputtering a molybdenum film over a barrier layer that is specifically wrapped around entire surfaces of the glass substrate. A specific embodiment is to dispose a bottom shield made by either a single plate with a roughened top surface region or a double-layer shield having a first grating layer over a second solid plate to cover the bottom member. Such bottom shields enhance adhesion of the sputtering molybdenum deposited through a gap between loaded glass substrates and prevent abnormal buildup the molybdenum material to cause damages to the barrier layer on the bottom surface of the glass substrate that faces the top surface region of the bottom shield. One major benefit of the present invention is to substantially prolong system working time without need of frequent shutting down to replace the bottom shield. The invention provide effective solution to eliminate possible damage to the barrier layer wrapped on the glass which has been proved to be very important for forming a high-performance CIGS material based thin-film photovoltaic module. These and other benefits may be described throughout the present specification and more particularly below.
The present invention relates generally to techniques for the manufacture of photovoltaic devices. More particularly, the present invention provides a system for forming thin-film photovoltaic device and a method for eliminating target material deposition buildup. Merely by way of examples, the present method implements a sputtering compartment for forming bottom electrode of thin-film photovoltaic device without causing seed layer to build up in the bottom shield, but it would be recognized that the invention may have other applications.
Additionally, the system 1000 includes a conveyer 100, in current example, linearly disposed through the whole system from entry to exit. The conveyer 100 is configured to support and transfer planar substrates (though it may be configured to transfer exotic shaped substrates) linearly from entry to exit, indicated by an arrow mark 101 in
In a specific embodiment, the system 1000 is configured to fabricate thin-film photovoltaic device and particularly to form its base electrode layer on a glass substrate. The first vacuum compartment 120 is designated for coating a barrier layer to wrap around the glass substrate for many technical advantages. For example, the glass substrate used in the system 1000 is soda lime glass and the corresponding barrier layer is a silicon oxide film made by sputtering a Silicon target in a reduced atmosphere environment with a controlled oxygen pressure. Specifically, the silicon oxide barrier layer is formed overlying the soda lime glass for preventing diffusion of certain unwanted impurities from the glass substrate into thin-film formed afterwards. One or more process conditions are designated to form a high-density silicon oxide film to be an effective barrier. For example, a silicon oxide barrier layer with a density of 1.1 g/cm3 or greater is desired. Preferably, the whole surfaces of the glass substrate should be fully wrapped by the barrier layer substantially without any scratches or broken regions. In an embodiment, the first vacuum compartment 120 is configured to sputter deposit the barrier layer on both top and bottom surfaces of a loaded planar substrate at a same time. The planar substrate is in motion by the conveyer 100 passing through the first vacuum compartment 120. In another embodiment, the first vacuum compartment 120 is configured to sputter deposit the barrier layer on just the top surface of the loaded planar substrate and is also configured to couple with one or more intermediate compartments 140 to reconfigure the planar substrate and reload the planar substrate on the conveyer 100 with the original bottom surface flipped to the top, then depositing the barrier layer overlying the bottom (now on top) surface. While, the terms of “top” or “bottom” are merely for description convenience, they should not limit the system or substrate loading within the system to one particular configuration. The horizontal loading scheme is merely an example and should be able to change into other orientations without leaving the scope covered by the claims herein.
Referring to
In an implementation of the present invention, the sputtering target 320 is a molybdenum target designated for forming a base electrode on the top surface of any loaded planar glass substrate 301 or 302 for fabricating a thin-film photovoltaic device. The sputtering target 320 is shown as an example to be in a square or rectangular shaped plate. It may also be made into a spherical shape or hemispherical shape, or others, disposed near a top region of the chamber 3000. A substrate moving device, which can be part of a conveyer 110 constructed for the whole in-line deposition system 1000, is operated through a plurality of rollers 330 disposed near a bottom region of the chamber 3000. Each roller 330 may be set partially above a bottom surface level of the chamber 3000 with a small spatial distance below the bottom surface of the moving substrate, allowing a free insertion of a bottom shield 310 in between. Each planar substrate, e.g., a soda lime glass substrate 301 or 302, has its bottom surface supported on the rollers 330 and its top surface subjected to the sputtering target 320 to receive a film deposition 321 therefrom while being moved (towards right in the figure) by the rolling rollers during a normal operation. Referring to description of the in-line deposition system, the bottom surface of each planar substrate has been coated with a barrier layer, now facing the bottom shied 310 below.
In a specific embodiment, any two neighboring loaded substrates has a gap distance 391, which also moves along with the moving substrates. In an example, the gap distance 391 between two large size (e.g., 65×165 cm) glass panels could be several inches to several tens of inches. As the gap 391 moves under the target 320 during the operation, a corresponding area of the bottom shield 310 is exposed to the target 320 and subjected to a partial film deposition 321 therefrom. The bottom shield 310 is thin plate disposed with intention to cover and protect the bottom member of the chamber 3000 as it can be removed easily during down time of the system for convenient system maintenance. Because of the exposure to the sputtering target due to the moving gap 391, the sputtered material, molybdenum in an example, is deposited and accumulated on the bottom shield 310.
Molybdenum is found to be relatively poor in adhesion on flat metal plate especially for irregularly interrupted deposition with constantly changed surface condition. Worst scenario of the accumulated sputtering molybdenum buildup is a formation of “molybdenum bubbles” so that one or more molybdenum pieces can grow abnormally due to peel off effect. Some of these abnormal molybdenum pieces may have their height near or even greater than the spatial distance between the bottom surface of the loaded planar substrate 301 and the top surface of the bottom shield 310. As the planar substrate is moved along, the barrier layer on the bottom surface of the planar substrate may be scratched or damaged by these abnormally-grown molybdenum pieces.
According to one or more embodiments of the present invention, the bottom shield 310 is configured to provide a corrugated upper surface to enhance adhesion of the sputtered material to suppress or substantially eliminate unwanted localized material buildup. As shown in
In an embodiment, the corrugated top region includes a plurality of roughened surface features having a character lateral dimension of about 2 mm and a depth of about 2 mm or greater, which is found to be very effective to cause the sputtering molybdenum material to be adhere on the top region. For example, as shown in
In a specific embodiment, the bottom shield 310 disposed to cover the bottom member of the sputtering chamber 3000 is a two-piece plate. A first piece is a thin flat plate including a plurality of through-holes and is placed directly over a second piece that simply is a flat solid plate. The plurality of through-holes is distributed across the whole area of the first piece and each through-hole, can be in any shape, has a feature lateral dimension of about 2 mm and the plate thickness is about 2 mm or greater. Effectively, the first piece of plate having the plurality of through-holes is performed like a grating structure. The first piece of the two-piece plate is directly exposed to the incoming sputtering molybdenum material and through-holes allow some molybdenum coating to penetrate therein to effectively improve adhesion both locally and anchoring of the film across the first piece of the two-piece plate. The second piece of two-piece plate is a solid piece for preventing any spray-thru of molybdenum deposition. The improved adhesion of the molybdenum material through the two-piece shield structure can help to substantially prolong the process life time by reducing the potential of accumulation abnormal material buildup on the bottom shield and removing dangers of barrier layer damages caused by molybdenum peel off effect.
In an alternative example,
It is also understood that the examples, figures, and embodiments described herein are for illustrative purposes only and that various modifications or changes in light thereof will be suggested to persons skilled in the art and are to be included within the spirit and purview of this application and scope of the appended claims.
Number | Date | Country | |
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61728221 | Nov 2012 | US |