Low contamination high density plasma etch chambers and methods for making the same

Abstract
A plasma processing chamber having a chamber liner and a liner support, the liner support including a flexible wall configured to surround an external surface of the chamber liner, the flexible wall being spaced apart from the wall of the chamber liner. The apparatus can include a heater thermally connected to the liner support so as to thermally conduct heat from the liner support to the chamber liner. The liner support can be made from flexible aluminum material and the chamber liner comprises a ceramic material. The flexible wall can include slots which divide the liner support into a plurality of fingers which enable the flexible wall to absorb thermal stresses.
Description




BACKGROUND OF THE INVENTION




1. Field of the Invention




The present invention relates generally to the fabrication of semiconductor wafers, and, more particularly, to high density plasma etching chambers having lining materials that reduce particle and metallic contamination during processing, and associated chamber lining structures.




2. Description of the Related Art




As integrated circuit devices continue to shrink in both their physical size and their operating voltages, their associated manufacturing yields become more susceptible to particle and metallic impurity contamination. Consequently, fabricating integrated circuit devices having smaller physical sizes requires that the level of particulate and metal contamination be less than previously considered to be acceptable.




In general, the manufacturing of the integrated circuit devices (in the form of wafers) includes the use of plasma etching chambers, which are capable of etching selected layers defined by a photoresist mask. The processing chambers are configured to receive processing gases (i.e., etch chemistries) while a radio frequency (RF) power is applied to one or more electrodes of the processing chamber. The pressure inside the processing chamber is also controlled for the particular process. Upon applying the desired RF power to the electrode(s), the process gases in the chamber are activated such that a plasma is created. The plasma is thus configured to perform the desired etching of the selected layers of the semiconductor wafer.




Typically, a processing chamber that is used for etching materials such as silicon oxides requires relatively high energies to achieve the desired etch result, compared to other films etched during fabrication. Such silicon oxides include, for example, thermally grown silicon dioxide (SiO


2


), TEOS, PSG, BPSG, USG (undoped spin-on-glass), LTO, etc. The need for high energies stems from the need to bombard and break the strong bonds of the silicon oxide films and drive chemical reactions to form volatile etch products. These chambers are therefore referred to as “high density oxide etch chambers,” that are capable of producing high plasma densities in order to provide a high ion flux to the wafer and achieve high etch rates at low gas pressures.




While high density oxide etch chambers work well in etching the desired wafer surfaces, the internal surfaces of the etch chamber are also subjected to the high ion power. Therefore, material from the internal surfaces of the etch chamber is removed as a result of the ion bombardment by either physical sputtering or chemical sputtering, depending on the composition of the material and the composition of the etch gas.




Recognizing that the internal surfaces of the etch chamber are exposed to the plasma in high density oxide chambers, chambers are now designed to permit the use of simple lining parts, such as, disks, rings, and cylinders. Because these parts are configured to confine the plasma over the wafer being processed, these parts are continuously exposed and attacked by the processing plasma energies. Due to this exposure, these parts ultimately erode or accumulate polymer buildup, requiring replacement or thorough cleaning. Eventually, all parts wear out to the point that they are no longer usable. These parts are hence referred to as “consumables.” Therefore, if the part's lifetime is short, then the cost of the consumable is high (i.e., part cost/part lifetime).




Because these parts are consumables, it is desirable to have surfaces that are resistant to the plasma energies, which will therefore reduce the cost of the consumable. Prior art attempts to reduce the cost of the consumable have included manufacturing these parts from aluminum oxide (Al


2


O


3


) and quartz materials. Although these materials are somewhat resistant to the plasma energies, in high density oxide etch chambers, the high ion bombardment by the plasma has the down side of producing levels of contamination (e.g., particle contamination and metallic impurity contamination) that are less than acceptable. For example, if the surface of the consumable part is aluminum oxide (i.e., alumina), when the plasma bombards the surfaces, aluminum will be released and then will mix in with the plasma that lies above the wafer. Some of this aluminum becomes embedded in an organic polymer that is deposited on the wafer during etching and on the surfaces of the consumable parts (i.e., chamber liners, covers, and the like). When this happens, the polymer on the surface of the consumable parts may not be able to be completely cleaned during a conventional in-situ plasma clean or “ash” step. Thus, a friable, flaking film or powdery coating that includes C, Al, O, and F is left behind after the in-situ plasma clean, and therefore results in high particle counts. The aluminum deposited in structures being etched and the films on the silicon wafer can cause degradation of devices subsequently formed, for example, by increasing leakage current in DRAM cells.




As mentioned above, quartz is also used as the material of the interior surfaces of the consumable parts. However, quartz surfaces have been found to be an unfortunate source of particles due to the low thermal conductivity of quartz and the high etch rates in high density plasmas used to etch oxides. Additionally, low thermal conductivity quartz makes surface temperature control of these parts very difficult. This results in large temperature cycling and flaking of the etch polymer deposited on the surface of the consumable parts, and therefore causes the unfortunate generation of contaminating particles. A further disadvantage of quartz consumable parts is that the high etch rate in high density oxide etchers tends to cause pitting in the quartz, which then results in spalling of quartz particles.




In view of the foregoing, there is a need for high density plasma processing chambers having consumable parts that are more resistant to erosion and assist in minimizing contamination (e.g., particles and metallic impurities) of the wafer surfaces being processed. There is also a need for consumable parts for use in high density plasma applications, and that are capable of withstanding temperature variations while preventing damage to the consumable parts.




SUMMARY OF THE INVENTION




The present invention fills these needs by providing temperature controlled, low contamination, high etch resistant, plasma confining parts (i.e., consumables) for use in plasma processing chambers. It should be appreciated that the present invention can be implemented in numerous ways, including as a process, an apparatus, a system, a device or a method. Several inventive embodiments of the present invention are described below.




In one embodiment, disclosed is a plasma processing chamber including an electrostatic chuck for holding a wafer, and having consumable parts that are highly etch resistant, less susceptible to generating contamination and can be temperature controlled. The consumable parts include a chamber liner having a lower support section and a wall that is configured to surround the electrostatic chuck. The consumable parts also include a liner support structure having a lower extension, a flexible wall, and an upper extension. The flexible wall is configured to surround an external surface of the wall of the chamber liner, and the liner support flexible wall is spaced apart from the wall of the chamber liner. The lower extension of the liner support is however, configured to be in direct thermal contact with the lower support section of the chamber liner. Additionally, a baffle ring is part of the consumable parts, and is configured to be assembled with and in thermal contact with the chamber liner and the liner support. The baffle ring defines a plasma screen around the electrostatic chuck. A heater is then capable of being thermally connected to the upper extension of the liner support for thermally conducting a temperature from the liner support to the chamber liner and the baffle ring. Also included is an outer support that is thermally connected to a cooling ring that is coupled to a top plate of the chamber. The outer support and the cooling ring are therefore capable of providing precision temperature control to the chamber liner, along with a cast heater. This precision temperature control therefore prevents temperature drifts, which therefore advantageously enables etching a first wafer with about the same temperature conditions as a last wafer.




In a most preferred embodiment, consumable parts including the chamber liner and the baffle ring are made completely from or coated with a material selected from silicon carbide (SiC), silicon nitride (Si


3


N


4


), boron carbide (B


4


C) and/or boron nitride (BN) material. In this manner, these materials, once exposed to the energy of the plasma sputtering, will produce volatile products that are substantially similar to volatile etch products produced during the etching of surface layers of the wafer.




In another embodiment, a plasma etching chamber having consumable parts is disclosed. The consumable parts include a chamber liner having a lower support section and a cylindrical wall that surrounds a center of the plasma etching chamber. A liner support that is configured to surround the chamber liner. The liner support is thermally connected to the lower support section of the chamber liner. The liner support further includes a plurality of slots that divide the liner support into a plurality of fingers. In a preferred embodiment, the chamber liner is made from a material selected from one of a silicon carbide (SiC) material, a silicon nitride (Si


3


N


4


) material, a boron carbide (B


4


C) material, and a boron nitride (BN) material, and the liner support is made from an aluminum material.




In yet another embodiment, a method for using consumable parts for use in a high density plasma etching chamber is disclosed. The method includes use of a chamber liner from a material selected from one of a silicon carbide (SiC) material, a silicon nitride (Si


3


N


4


) material, a boron carbide (B


4


C) material, and a boron nitride (BN) material. The chamber liner can have a wall that surrounds a plasma region of the chamber and a lower support section. The method can include use of an aluminum liner support optionally having a lower extension, a flexible wall and an upper extension wherein a plurality of slots are provided in the flexible wall and the lower extension of the liner support to enable the liner support to expand at elevated temperatures. The method optionally includes use of a baffle ring of silicon carbide (SiC), silicon nitride (Si


3


N


4


), boron carbide (B


4


C) and/or boron nitride (BN). A plurality of slots can be provided in the baffle ring to define a plasma screen. The method can include thermal control of the chamber liner via a thermal path through the liner support and the baffle ring.




According to an embodiment of the invention, a plasma processing chamber includes a chamber liner and a liner support, the liner support including a flexible wall configured to surround an external surface of the chamber liner, the flexible wall being spaced apart from the wall of the chamber liner. For purposes of optional temperature control of the liner, a heater can be thermally connected to the liner support so as to thermally conduct heat from the liner support to the chamber liner. Although any suitable materials can be used for the liner and liner support, the liner support is preferably made from flexible aluminum material and the chamber liner preferably comprises a ceramic material.




The liner support can have various features. For instance, the flexible wall can include slots which divide the liner support into a plurality of fingers which enable the flexible wall to absorb thermal stresses and/or a lower extension of the liner support can be fixed to a lower support section of the chamber liner. If desired, a baffle ring in thermal contact with the chamber liner and the liner support can be used to define a plasma screen around an electrostatic chuck located in a central portion of the chamber. The chamber liner and/or baffle ring are preferably made from one or more of silicon carbide (SiC), silicon nitride (Si


3


N


4


), boron carbide (B


4


C), and boron nitride (BN).




The plasma processing chamber can include various features. For example, the chamber liner can have low electrical resistivity and be configured to provide an RF path to ground. If desired, a gas distribution plate having high electrical resistivity can be provided over an electrostatic chuck and/or a pedestal supporting a focus ring and the electrostatic chuck. The gas distribution plate, the focus ring and/or the pedestal are preferably made from one or more of the silicon carbide (SiC), silicon nitride (Si


3


N


4


), boron carbide (B


4


C), and boron nitride (BN). The plasma can be generated in the chamber by an RF energy source which inductively couples RF energy through the gas distribution plate and generates a high density plasma in the chamber. The RF energy source preferably comprises a planar antenna. The chamber can be used for plasma processing semiconductor wafers. For example, the chamber can be a plasma etching chamber.




The liner can have various configurations. For example, the liner support can include an outer support thermally connected to a lower extension of the liner support and the outer support can be in thermal contact with a water cooled top plate mounted on the chamber. The liner support can also include an upper extension, a flexible wall, and a lower extension, wherein the flexible wall and the lower extension have a plurality of slots that define a plurality of fingers in the liner support. For temperature control, a cast heater ring can be located in thermal contact with the liner support, the heater ring including a resistance heated element which heats the liner support so as to thermally control the temperature of the chamber liner.




According to another embodiment of the invention, a semiconductor substrate is processed in a plasma processing chamber having a chamber liner and a liner support, the liner support including a flexible wall configured to surround an external surface of the chamber liner, the flexible wall being spaced apart from the wall of the chamber liner wherein a semiconductor wafer is transferred into the chamber and an exposed surface of the substrate is processed with a high density plasma. The chamber liner is preferably a ceramic material and the liner support preferably includes an outer support extending between the liner support and a temperature controlled part of the chamber, the outer support being dimensioned to minimize temperature drift of the chamber liner during sequential processing of a batch of semiconductor wafers. During wafer processing, the ceramic liner is preferably removed from the chamber and replaced with another ceramic liner after processing a predetermined number of semiconductor wafers. Further, the chamber liner can include a wafer entry port enabling passage of the wafer into the chamber.




Other aspects and advantages of the invention will become apparent from the following detailed description, taken in conjunction with the accompanying drawings, illustrating by way of example the principles of the invention.











BRIEF DESCRIPTION OF THE DRAWINGS




The present invention will be readily understood by the following detailed description in conjunction with the accompanying drawings. To facilitate this description, like reference numerals designate like structural elements.





FIG. 1

shows a high density plasma etching chamber in accordance with one embodiment of the present invention;





FIGS. 2A through 2C

illustrate in more detail a baffle ring in accordance with one embodiment of the present invention;





FIG. 3A

shows a more detailed cross-sectional diagram of a liner support in accordance with one embodiment of the present invention;





FIG. 3B

shows a side view of the liner support from cross section A—A of

FIG. 3A

, in accordance with one embodiment of the present invention;





FIG. 3C

illustrates the flexibility of the liner support when subjected to temperature stresses in accordance with one embodiment of the present invention;





FIG. 4

illustrates how the chamber liner is assembled with the liner support in accordance with one embodiment of the present invention;





FIG. 5A

shows a partial cross-sectional view of the chamber liner, the liner support, and the baffle ring, assembled in accordance with one embodiment of the present invention;





FIG. 5B

shows a side view of an outer support in accordance with one embodiment of the present invention;





FIG. 6

illustrates a three-dimensional assembled view of the chamber liner, the baffle ring, and the liner support, in accordance with one embodiment of the present invention;





FIG. 7

shows another three-dimensional view of the assembled chamber liner, liner support, and the baffle ring, in accordance with one embodiment of the present invention; and





FIG. 8

shows an exploded view of portions of the high-density plasma etching chamber of

FIG. 1

in accordance with one embodiment of the present invention.











DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS




The invention provides one or more temperature controlled, low contamination, high etch resistant, plasma confining parts (i.e., consumables) for use in plasma processing chambers. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. It will be understood, however, to one skilled in the art, that the present invention may be practiced without some or all of these specific details. In other instances, well known process operations have not been described in detail in order not to unnecessarily obscure the present invention.




The plasma confining parts of the present invention are preferably in the form of, for example, chamber liners, baffle rings, gas distribution plates, focus rings, liner supports, and other non-electrically driven parts. These parts are preferably configured to be substantially non-contaminating and etch resistant, and they are preferably temperature controlled without damaging the parts. The plasma confining parts are preferably made from materials that consist of elements that are innocuous to devices being fabricated on the wafer, such as silicon (Si), carbon (C), nitrogen (N), or oxygen (O). In this manner, when the plasma confining parts are bombarded by ions (i.e., sputtered by the plasma), volatile products that combine with the process gases are produced. These volatile products can then be removed from the chamber using a vacuum pump and will not end up on the wafer causing contamination. In a preferred embodiment wherein the plasma confining parts are in a plasma etch chamber, such parts can be more resistant to the etch gases and the life of the parts can be prolonged.




The plasma confining parts of the present invention are preferably made from one or more materials such as, for example, silicon carbide (SiC), silicon nitride (Si


3


N


4


), boron carbide (B


4


C), and boron nitride (BN). These materials all have the desirable characteristics of having high etch resistance, non-contaminating elements, and volatile etch products. In a most preferred embodiment, the plasma confining parts (also referred to as consumable parts) are made from solid silicon carbide (SiC), which therefore reduces metal and/or particle contamination of the processed wafer. The SiC used for the baffle ring


132


and liner


130


is preferably electrically conductive so that when it is in contact with the plasma it presents a good ground path for the RF current. Higher resistivity SiC can be used for a gas distribution plate (“GDP”) (i.e.,


120


of

FIG. 1

) in order to permit inductive coupling of RF power through it. As mentioned above, the SiC also etches at a slow rate by the plasma making it a cost-effective consumable part.




Moreover, because the SiC is of high purity, wafer contamination resulting from chemical sputtering of the SiC by the plasma can be minimized. Further, the grounded SiC can reduce sputtering of other surfaces in the chamber by causing a reduction in the plasma potential and hence ion bombardment energy to any non-silicon carbide surfaces. The SiC component also provides a very stable plasma potential so that etch results are more repeatable within an individual chamber and from chamber to chamber. For more information on the use of plasma confining parts capable of reducing contamination high density plasma processing, reference may be made to a commonly assigned U.S. patent application having application Ser. No. 09/050,902, filed on Mar. 31, 1998, and entitled “Contamination Controlling Method and Apparatus For A Plasma Processing Chamber.” This application is hereby incorporated by reference. The various embodiments of the present invention will now be described with reference to

FIGS. 1 through 8

.





FIG. 1

shows a high density plasma etching chamber


100


in accordance with one embodiment of the present invention. A chamber housing


102


is shown containing a semiconductor substrate such as a silicon wafer


104


, that may be subjected to a plasma etching operation. In this embodiment, the etching operating is preferably a high density plasma operation that is configured to etch materials such as silicon oxides, that may be formed on the surface of the wafer


104


. The high density (e.g., plasmas having a densities between about 10


11


-10


12


ions/cm


3


) plasma is established in the chamber by ensuring that the chamber is held at a relatively low pressure of below about 80 mTorr, and most preferably between about 1 mTorr and about 40 mTorr. The pressure in the chamber is generally maintained by implementing a suitable vacuum pump at the bottom of the chamber.




The wafer


104


is shown supported over an electrostatic chuck


106


. Beneath the electrostatic chuck


106


is a lower electrode


108


which contains a backside cooling ring


110


for controlling the temperature of the electrostatic chuck


106


. The electrostatic chuck


106


is confined by a pedestal


112


and a focus ring


114


that surrounds the wafer


104


. In one embodiment of the present invention, the pedestal


112


and the focus ring


114


are preferably made from a material selected from a group including: (a) silicon carbide (SiC), (b) silicon nitride (Si


3


N


4


), (c) boron carbide (B


4


C), or (d) boron nitride (BN). In a most preferred embodiment, Si


3


N


4


is selected as the material for the pedestal


112


and the focus ring


114


.




According to one embodiment, an insulating alumina ring


116


sits between an aluminum pedestal


118


and the lower electrode


108


and the silicon carbide pedestal


112


. A chamber liner


130


is preferably a cylindrical liner which can be attached to a baffle ring


132


. The baffle ring


132


generally includes an inner ring


132




a


that makes good electrical contact as well as good thermal contact with the chamber liner


130


. The baffle ring


132


also has an integral array of teeth


132




b


which will be described in greater detail with reference to

FIGS. 2A through 2C

.




Above the wafer


104


is a gas distribution plate (GDP)


120


which functions as a showerhead to release the etch gas chemicals into the processing chamber. Above the gas distribution plate


120


sits a ceramic window


122


. Above the ceramic window


122


is an RF coil system


120


(i.e., an RF antenna), which is used to supply a top RF power into the reactor chamber


100


. The RF coils


120


are preferably cooled via a cooling channel that is integrated at the center of the RF coils


120


. In this simplified illustration, a gas feed port


126


is used to feed processing gases into channels that are defined between the ceramic window


122


and the gas distribution plate


120


. For more information on process chambers, reference may be made to a TCP 9100™ plasma etching reactor, which is available from Lam Research Corporation, of Fremont, Calif.




An RF impedance matching system


127


is configured to mount over the processing chamber and make suitable contact with the RF coils


122


in order to control the delivery of power as well as other reactor controlling parameters. As mentioned above, the ceramic window


122


is designed to be in contact with the gas distribution plate that mounts within a top plate


124


. The top plate


124


defines an interface between atmospheric pressure and a desired vacuum condition within the high density plasma etching chamber


100


. As should be apparent to those skilled in the art, the desired pressure interface is established by placing a suitable number of O-rings between interfaces of the chamber housing


102


, the top plate


124


, the GDP


120


, the ceramic window


122


, and the RF match system


127


.




A liner support


134


is also provided within the high density plasma etching chamber


100


to enable precision control and transfer of a desired temperature to the chamber liner


130


and the baffle ring


132


. In this embodiment, the liner support


134


is made of aluminum to facilitate its flexibility and improve its thermal conductivity. The liner support


134


includes an upper extension


134




a


, a flexible wall


134




b


, a lower extension


134




c


, and a liner support extension


134




d


. The lower extension


134




c


is shown assembled in direct thermal contact with the chamber liner


130


, and the baffle ring


132


. In this embodiment, the flexible wall


134




b


is slightly separated from the chamber liner


130


. A heater


140


is capable of being secured in direct thermal contact with the upper extension


134




a


of the liner support


134


. To power up and control the heater


140


, a power connection


142


is used to couple to a heater power system


129


. The liner support is therefore well suited to control a desired temperature that can be thermally transferred to the chamber liner


130


and the baffle ring


132


without causing damage to the (more brittle) chamber liner


130


or baffle ring


132


.




Also shown is an outer support


131


, which is thermally connected to the lower extension


134




c


of the liner support


134


. The outer support is also thermally coupled to the top plate


124


, which is designed to receive a cooling ring


121


. As will be described in greater detail below with reference to

FIGS. 5A and 5B

, the outer support


131


is used to achieve precision temperature control of the chamber liner


130


during wafer processing operations (e.g., etching). The precision temperature control provided by the outer support


131


and cooling ring


121


will therefore advantageously assist in preventing the chamber liner temperature from gradually drifting upwards (due to the plasma energies) faster than the liner's ability to radiate the heat to its surroundings.




As mentioned above, the chamber liner


130


and the baffle ring


132


are preferably made of a pure silicon carbide material. In addition, the gas distribution plate


120


, the focus ring


114


and the pedestal


112


are also made of a pure silicon nitride or carbide materials, or at least silicon carbide coated. In this manner, substantially all of the surfaces that confine the high density plasma will be pure silicon carbide, or coated silicon carbide. In a broad context, other materials that consist only of elements that are innocuous to devices on the wafer being processed, such as silicon (Si), carbon (C), nitrogen (N), or oxygen, which form volatile etch products with the etch gases, may be used. In this manner, the volatile products produced when the internal surfaces that confine the plasma are bombarded, will mix with the excess etch gases that are commonly removed from the chamber (using a vacuum pump or the like). Because the products produced when the plasma bombards the internal surfaces of the chamber (i.e., the consumable parts) are volatile, these products will not end up on the surface of the wafer causing contamination, nor end up embedded in the polymer deposited on the consumable parts.





FIGS. 2A through 2C

illustrate in more detail the baffle ring


132


in accordance with one embodiment of the present invention. As shown in

FIG. 1

, the baffle ring


132


functions as a plasma screen for the passage of gases and by-products to a vacuum pump connected at the bottom of the chamber


102


. As shown, the baffle ring


132


has an array of teeth


132




b


that assist in maintaining the plasma in the top half of the chamber


102


, where the silicon carbide surfaces (of the consumables) confine the plasma substantially over the wafer


104


. The baffle ring


132


also has an inner ring


132




a


which is used to make good thermal contact with the chamber liner


130


.





FIG. 2B

is a three-dimensional view of a pair of teeth


132




b


. Generally, the open areas provided by the spaces


132




c


are configured such that a percentage ranging between 50 and 70 percent open area is maintained to allow a sufficient passageway for the gases and by-products to be pumped out of the chamber


102


. To make each of the spaces


132




c


, as shown in

FIG. 2C

, the solid silicon carbide material (or coated SiC material) must be machined such that a suitable aspect ratio that is at least 1.5 or greater, is maintained. In this exemplary configuration, the width of the spaces


132




c


are preferably set to about 0.13 inch, and the height is set to about 0.28 inch. These preferred dimensions therefore provide an aspect ratio of about 2.0.




The inner diameter (ID) of the baffle ring


132


, in this 200 mm wafer chamber embodiment, is set to about 10.75 inches, such that about {fraction (1/16)} inch clearance is provided between the pedestal


112


shown in FIG.


1


. However, the inner diameter (ID) may of course be larger, depending upon the size of the wafer being processed. For example, for a 300 mm wafer, the inner diameter may be as large as about 14 inches.




In alternative embodiments, the baffle ring


132


may be manufactured such that the teeth


132




b


are replaced with an array of holes or slots. When an array of holes or slots are manufactured in place of the teeth


132




b


, it is still desired to maintain an open area (i.e., pathway), that amounts to between about 50 percent and 70 percent. The baffle ring


132


is also shown having a plurality of screw holes


150


which are designed around the outer ring


132




a


. As shown in

FIG. 1

, the screw holes


150


will be configured to receive a suitable screw that will help interconnect the baffle ring


132


to the chamber liner


130


and the liner support


134


. Other fasteners such as clamps could be envisioned that would supply the necessary contact force to permit sufficient heat transfer.





FIG. 3A

shows a more detailed cross-sectional diagram of the liner support


134


in accordance with one embodiment of the present invention. As mentioned above, the liner support


134


has a flexible wall


134




b


which is configured to flex in response to heat deformation that may occur when the heater


140


applies the desired heat level. Preferably, the flexible wall


134




b


is cylindrical and is slotted into a plurality of fingers. As mentioned above, the liner support is preferably made of an aluminum material which will have good thermal conductivity and will also provide good flexibility when a desired temperature is applied by the heater


140


. Because the lower extension


134




c


is bolted to the chamber liner


130


and the baffle ring


132


, the lower extension


134




c


will remain in place while the upper extension


134




a


, which is coupled to the heater


140


at a heat-conductive interface


141


, may be able to flex outwardly as illustrated in FIG.


3


C.




The heater


140


is preferably secured to the upper extension


134




a


using a suitable number of screws


144


to ensure that the heat conductive interface


141


is maintained all the way around the upper extension


134




a


. In a preferred embodiment, the screws


144


will be capable of maintaining the heater


140


in contact with the upper extension


134




a


with a pressure of about 1,000 pounds per square inch.




When the high-density plasma etching chamber


100


is configured to process an 8-inch wafer (i.e., 200 mm wafer), the liner support


134


may have an inner diameter of about 14½ inches. The thickness


170


of the flexible wall


134




b


may range between about {fraction (1/16)} inch and about {fraction (3/32)} inch. The {fraction (1/16)} inch dimension is preferably used for processing temperatures ranging up to about 300° C., while the {fraction (3/32)} dimension is reserved for chambers having processing temperatures up to about 1000° C.




The separation


176


between the lower extension


134




c


and the upper extension


134




a


is preferably set to about 2½ inches, depending upon the chamber height. However, the greater the separation


176


is, the greater the thermal resistance in the liner support


134


. Therefore, the separation


176


is kept just short enough such that the aluminum material of the liner support will not become too stressed as temperatures reach 300° C. and above. The exemplary thickness


172


for the upper extension


134




a


is preferably set to about {fraction (9/16)} inch, while the exemplary thickness of the lower extension


134




c


is set to about ⅝ inch.





FIG. 3B

shows a side view of the liner support


134


from cross section A—A of

FIG. 3A

, in accordance with one embodiment of the present invention. To facilitate the flexibility of the liner support


134


, slots


152


are defined into the sides of the liner support


134


defining a plurality of fingers. The slots


152


vertically extend through the flexible wall


134




b


and through the lower extension


134




c


. Because the liner support


134


is preferably a cylindrically shaped unit, the separation between the slots


152


must be configured such that a suitable level of flexibility remains in the flexible wall


134




b


. Therefore, the separation between slots


152


is preferably set to about 15 degrees. However, the actual separation between the slots


152


may vary and also change depending upon the diameter of the liner support


134


and the degree of flexibility that is desired. Also shown, are the screw holes


150


which are defined in the lower extensions


134




c.






To illustrate the flexibility provided by the liner support


134


,

FIG. 3C

shows the liner support extending outwardly from a Y axis (relative to a horizontal X-axis) to achieve a separation


133


. In certain cases, the separation may be as much as {fraction (1/16)} inch, or more. Accordingly, the liner support


134


will advantageously be able to withstand the thermal stress placed on the aluminum material of the liner support


134


, while insulating the less flexible chamber liner


130


and the baffle ring


132


from temperature deforming stresses.





FIG. 4

illustrates how the chamber liner


130


is assembled with the liner support


134


in accordance with one embodiment of the present invention. In this embodiment, when the chamber liner


130


is made of silicon carbide, it will provide a high integrity RF return path to ground for the powered electrode


108


(bottom electrode). As is well known to those skilled in the art, providing a high integrity RF ground path in the processing chamber brings the advantage of having excellent process repeatability. Further, the grounded SiC can reduce sputtering of other surfaces in the chamber by causing a reduction in the plasma potential and hence ion bombardment energy on any non-silicon carbide surfaces.




Additionally, the materials used for the chamber liner


130


, such as SiC, can have their electrical resistivity modified over a wide range. For example, the resistivity of SiC can be tailored for the specific application. When used for the chamber liner


130


and the baffle plate


132


, the SiC is modified to provide a low resistivity that will facilitate the good conductive path to ground for the RF power. On the other hand, high resistivity is needed when the part must have RF power inductively coupled through it, in order to minimize power dissipation in the part. Thus, high resistivity SiC is preferably used for the gas distribution plate (GDP)


120


.




As shown, the screw holes


150


are configured to go through the chamber liner


130


at a lower support section and then go into the liner support


134


. Generally, a suitable number of screws are used to interconnect the chamber liner


130


and the liner support


134


such that a good thermally conductive interface


156


is maintained. In this manner, the heat conducted through the liner support


134


may be thermally communicated to the chamber liner


130


and the baffle ring


132


.




In this preferred embodiment, the liner support


134


is preferably spaced apart from the chamber liner


130


by a space


154


. The space


154


is preferably set to about {fraction (1/16)} inch. This separation is generally desired because the liner support


134


is configured to flex as described with reference to FIG.


3


C. For a 200 mm wafer chamber, a diameter


179


of the chamber liner


130


is about 14 inches. The thickness of the chamber liner


130


is preferably set, in this embodiment, to be between about 0.1 inch and about 0.3 inch, and most preferably, to about 0.2 inch. The height


177


of this exemplary chamber liner may be between about 3 inches and about 12 inches, and most preferably about 5 inches.




Also shown is the outer support


131


, which is thermally connected to the lower extension


134




c


of the liner support


134


. Preferably, the outer support is spaced apart from the flexible wall


134




b


so that it can flex without substantial obstruction. The outer side of the outer support


131


has an upper extending wall having a surface


123


′, which is configured to make good thermal contact with the top plate


124


. In this manner, a cooling ring


121


, shown in more detail in

FIG. 5A

, can be used to control the temperature of the chamber liner


130


and the internal regions of the chamber. Accordingly, through the combined simultaneous control of both the heater


140


and cooling ring


121


, the temperature of the chamber liner


130


can be maintained to within less than ±10 degrees C. from a no plasma condition through a sustained plasma on condition. Thus, the first wafer etched can be etched with the same chamber liner


130


temperature as the last wafer etched, to within the ±10 degrees C. variation.





FIG. 5A

shows a partial cross-sectional view of the chamber liner


130


, the liner support


134


, and the baffle ring


132


assembled in accordance with one embodiment of the present invention. As shown, the chamber liner


130


and the liner support


134


are assembled to achieve a good thermal conductive interface


156


as described above.




As mentioned above, the outer support


131


is thermally connected to the lower extension


134




c


through a plurality of screws


135


. The outer support


131


, in a most preferred embodiment, has a flexible wall


131




a


, which is shown to be thermally connected to the top plate


124


. A side view of the outer support


131


is also provided in

FIG. 5B

, to illustrate how a plurality of fingers


131




d


, separated by a plurality of slots


131




c


, assist in providing the necessary flexibility to the flexible wall


131




a


. The top plate


124


is further configured to receive the cooling ring


121


on a top lip of the top plate


124


. Of course, other configurations for applying the cooling ring


121


, or other type of cooling system, to the top plate


124


may be used.




In this embodiment, the combined use of the heater


140


and the cooling ring


121


will enable precision temperature control in narrow temperature ranges. For example, the chamber liner


130


is typically run at high temperatures, such as 200 degrees C. or more, while heat is lost to the surroundings primarily through radiation. When plasma is initiated, the plasma dumps more heat into the chamber liner


130


by ion bombardment. The chamber liner


130


will slowly increase in temperature over time because it generally cannot transfer this heat to its surroundings by radiation as fast as it gains heat from the plasma. Thus, the outer support


131


, which is thermally coupled to the cooling ring


121


, is well suited to eliminate the chamber liner's temperature drift. In this embodiment, the heat loss to the outer support


131


from the liner support


134


can be set by adjusting the cross-section and length of the outer support


131


. This adjustment, can therefore be made to control the heat loss path from the liner support


134


to the temperature controlled top plate


124


.




As shown, the chamber liner


130


will also provide a good thermal conductive interface


157


with the baffle ring


132


. To achieve this good conductive interface, the baffle ring


132


, the chamber liner


130


, and the liner support


134


are secured together using a plurality of screws


150


′. Preferably, the screws


150


′ are fitted through a spacer ring


131




b


which is in direct contact with the inner ring


132




a


of the baffle ring


132


, a spacer


131




a


′, and the chamber liner


130


.




The spacer ring


131




b


and the spacer


131




a


′ are preferably made of aluminum and provide a good surface for applying pressure to the screws


150


′ and the brittle surfaces of the baffle ring


132


and the chamber liner


130


. That is, because the baffle ring


132


is preferably a ceramic, applying too greater of a force with screws directly to the baffle ring may cause a crack in the baffle ring or the chamber liner


130


. Once the screws


150


′ are secured all the way around the chamber, the chamber liner, the baffle ring and the liner support (i.e., the consumable parts) will be ready for use in the high density plasma etching chamber


100


of FIG.


1


. As used herein, these parts are referred to as consumable parts, however, when silicon carbide (or other alternative materials described herein) is used for the parts that confine the high density plasma, these parts will have a longer lifetime, and therefore, a lower cost of consumables.




When replacement is needed, these parts may be swiftly replaced with replacement parts (i.e., using a quick clean kit). Because the liner support


134


is not designed to be in contact with the high density plasma, it may not wear out as fast as the chamber liner


130


and the baffle ring


132


. Thus, the liner support


134


may be removed from worn out consumable parts (that may be cleaned off-line and re-used or discarded), and then used with the replacement consumable parts. When the chamber is being used in fabrication where chamber down time translates into lower yields, the ability to quickly replace these consumables will have the benefit of reducing the mean time to clean the chamber.





FIG. 6

illustrates a three-dimensional assembled view of the chamber liner


130


, the baffle ring


132


, and the liner support


134


, in accordance with one embodiment of the present invention. As shown, the top surface of the upper extension


134




a


of the liner support


134


, is configured with a plurality of screw holes that will receive the heater


140


. Along the walls of the liner support


134


are the plurality of slots


152


that define fingers configured to flex in response to temperature variations. A wafer entry port


160


is defined in the wall of the chamber liner


130


to enable the passage of a wafer into and out of the chamber


100


. Typically, the wafer is preferably passed into the chamber using a robot arm which must partially fit into the port


160


, and release the wafer once over the electrostatic chuck


106


. Therefore, the port


160


should be large enough to receive the wafer and robot arm, but also maintained small enough to not disrupt the plasma profile over the wafer. As shown in

FIG. 7

, an insert with a slot in the shape of the port


160


is attached to the outside of the liner. Like the other consumable parts, the insert can be of SiC, Si


3


N


4


, B


4


C and/or BN.




The liner support


134


typically also includes through holes


162


which are also defined in the chamber liner


130


. The through holes


162


may include holes for probing the pressure within the chamber during processing, and for optically detecting the endpoint in a particular process. Also shown with greater detail are plurality of holes


161


which are used to receive the screws


144


for holding down the heater


140


to the upper extension


134




a


of the liner support


134


.





FIG. 7

shows another three-dimensional view of the assembled chamber liner


130


, liner support


134


, and the baffle ring


132


. From this view, the port hole


160


used for passing a wafer to the electrostatic chuck


106


, is shown in greater detail. Also shown are the teeth


132




b


of the baffle ring


132


. The teeth


132




b


therefore extend in close proximity to the pedestal


112


to screen the plasma from the lower part of the chamber as shown in FIG.


1


.





FIG. 8

shows an exploded view of portions of the high-density plasma etching chamber


100


of

FIG. 1

in accordance with one embodiment of the present invention. This view shows the spacer ring


131




b


that is used in the assembly of the baffle ring


132


, the chamber liner


130


, and the liner support


134


. This perspective also illustrates how the heater


140


is applied over the top extension


134




a


of the liner support


134


. The heater


140


, as shown, is preferably a cast heater. Of course, other types of heating systems may also work. When the heater


104


is appropriately secured, a good thermal contact will be made with the liner support


134


.




The power connection


142


is also shown, which will be passed through a hole


124




a


in the top plate


124


. The top plate


124


is shown capable of receiving the gas distribution plate


120


. The gas distribution plate


120


has channels


120




a


which enable processing gases fed by gas feed ports


126


to be directed into the chamber


100


. Although not shown in this example, the ceramic window


122


may then be lowered over the gas distribution plate


120


.




In a preferred embodiment of the present invention, the high density plasma etch chamber


100


is particularly well suited to etch silicon oxide materials, such as, for example, thermally grown silicon dioxide (SiO


2


), TEOS, PSG, BPSG, USG (undoped spin-on-glass), LTO, etc., while reducing the introduction of unwanted contaminants. For exemplary purposes only, to achieve the high density plasma conditions in the chamber


100


, the pressure within the chamber is preferably maintained below about 80 mTorr, and the RF coil


128


(i.e., top electrode) is preferably set to between about 2500 watts and about 400 watts, and most preferably to about 1,500 watts. The bottom electrode


108


is preferably maintained between about 2500 watts and about 700 watts, and most preferably at about 1,000 watts. In typical high density oxide etch processes, process gases such as, CHF


3


, C


2


H


5


and/or C


2


F


6


are introduced into the chamber to generate the desired etching characteristics.




As mentioned previously, the materials that can be used for the plasma confining parts (e.g., the consumables, including the chamber liner


130


, the baffle ring


132


, the GDP


120


, the focus ring


114


, and the pedestal


112


) are generally innocuous to layers being fabricated on the wafer


104


. That is, volatile etch products that result from etching the surfaces of the wafer


104


will be similar to the volatile products produced when the consumables are bombarded (i.e., sputtered) with the plasma energies. As an advantageous result, these volatile products produced from ion bombardment of the consumables will join the normal volatile etch products.




This therefore facilitates the removal of these combined volatile products from the internal region of the chamber


100


through the use of a vacuum pump that connects to the chamber. Due to the fact that the volatile products from the consumables are able to be expeditiously removed from the wafer processing region, substantially fewer levels of particulates and metallic contaminants will interfere with the devices being fabricated on the surface of the wafer


104


. While this invention has been described in terms of several preferred embodiments, it will be appreciated that those skilled in the art upon reading the preceding specifications and studying the drawings will realize various alterations, additions, permutations and equivalents thereof. Therefore, although specific details are provided with respect to reducing contamination for semiconductor wafers, such benefits may also apply to flat panel display substrates, and the like. Furthermore, although a preferred material for the consumable parts is pure silicon carbide (SiC), the material may also be a SiC coated material such as SiC coated graphite, or principally SiC with 10 to 20% Si added to fill porosity in reaction bonded SiC. As also mentioned previously, the consumable parts may also be made from materials such as, silicon nitride (Si


3


N


4


), boron carbide (B


4


C), and boron nitride (BN). These materials all have the desirable characteristics of having high etch resistance, non-contaminating elements, and volatile etch products.




It is therefore intended that the present invention include all such alterations, additions, permutations, and equivalents as fall within the true spirit and scope of the invention.



Claims
  • 1. A method of processing a semiconductor substrate in a plasma processing chamber having a chamber liner and a liner support within an interior of the plasma processing chamber, the liner support including a flexible wall configured to surround an external surfaces of the chamber liner, the flexible wall being spaced apart from the external surface of the chamber liner, wherein a semiconductor wafer is transferred into the chamber and an exposed surface of the substrate is processed with a high density plasma.
  • 2. The method of processing a semiconductor substrate as recited in claim 1, wherein the chamber liner is a ceramic material and the liner support includes an outer support extending between the liner support and a temperature controlled part of the chamber, the outer support being dimensioned to minimize temperature drift of the chamber liner during sequential processing of a batch of semiconductor wafers.
  • 3. The method of processing a semiconductor substrate as recited in claim 1, wherein the chamber liner is a ceramic liner which is removed from the chamber and replaced with another ceramic liner after processing a predetermined number of semiconductor wafers.
  • 4. The method of processing a semiconductor substrate as recited in claim 1, wherein a heater is thermally connected to the liner support so as to thermally conduct beat from the liner support to the chamber liner.
  • 5. The method of processing a semiconductor substrate as recited in claim 1, wherein the flexible wall includes slots which divide the liner support into a plurality of fingers which enable the flexible wall to absorb thermal stresses during processing of the semiconductor wafer.
  • 6. The method of processing a semiconductor substrate as recited in claim 1, a baffle ring is in thermal contact with the chamber liner and the liner support, the baffle ring defining a plasma screen around an electrostatic chuck located in a central portion of the chamber during processing of the semiconductor wafer.
  • 7. The method of processing a semiconductor substrate as recited in claim 1, wherein the chamber liner has low electrical resistivity and provides an RF path to ground during processing of the semiconductor wafer.
  • 8. The method of processing a semiconductor substrate as recited in claim 1, wherein process gas is supplied into the chamber through a gas distribution plate and the semiconductor wafer is supported on an electrostatic chuck.
  • 9. The method of processing a semiconductor substrate as recited in claim 1, wherein an RF energy source inductively couples RF energy through a gas distribution plate and generates the high density plasma in the chamber.
  • 10. The method of processing a semiconductor substrate as recited in claim 1, wherein the RF energy source comprises a planar antenna.
  • 11. The method of processing a semiconductor substrate as recited in claim 1, wherein the liner support further includes an outer support thermally connected to a lower extension of the liner support, the outer support being in thermal contact with a water cooled top plate mounted on the chamber.
  • 12. The method of processing a semiconductor substrate as recited in claim 1, wherein the exposed surface is etched with the high density plasma.
  • 13. The method of processing a semiconductor substrate as recited in claim 1, wherein a cast heater ring is in thermal contact with the liner support, the heater ring including a resistance heated element which heats the liner support so as to thermally control the temperature of the chamber liner.
Parent Case Info

This application is a divisional of application Ser. No. 09/487,325, filed Jan. 19, 2000, U.S. Pat. No. 6,394,026 which is a continuation of application Ser. No. 09/161,074, filed Sep. 25, 1998, U.S. Pat. No. 6,129,808 which is a Continuation-In-Part of application Ser. No. 09/050,902, filed Mar. 31, 1998, now abandoned.

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Continuations (1)
Number Date Country
Parent 09/161074 Sep 1998 US
Child 09/487325 US
Continuation in Parts (1)
Number Date Country
Parent 09/050902 Mar 1998 US
Child 09/161074 US